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Halogen derivatives of alkanes and haloarenes

Q.1. What are monohalogen derivatives of alkanes ? How are they classified ? Q.2. Give IUPAC names of i) (CH3)2 CHCH2Br ii) CH2 = CH CH2Br iii) (CH)3 C CH2Cl iv) CH3 CH2 C(CH3)2 CH2Cl Q.3. Draw i) 1 ii) 1 iii) 2 the structures of Chloro 2,2 dimethylpropane Chloro 4 ethylcyclohexane Bromo 3 ethyl 2 methylhexane.

Q.4. How will you prepare bromoethane using i) Ethyl alcohol ii) Ethane iii) Ethene Q.5. Write a note on i) Finkelstein reaction ii) Wurtz reaction iii) Friedel crafts reaction Q.6. What is the action of following on chloroethane. i) aq. KOH ii) alc.KCN iii) Na iv) alc. NaOC2H5 v) alc. AgCN vi) alc silver acetate vii) Magnesium Q.7. Define i) Optical activity iii) Levorotatory compound v) Asymmetric carbon atom

ii) iv)

Dextrorotatory compound Racemic mixture

Halogen derivatives of alkanes and haloarenes

Mahesh Tutorials Science

Q.8. Explain SN1 Reaction mechanism Q.9. Explain SN2 Reaction mechanism Q.10. Aryl halides are less reactive towards nucleophilic substitution reaction than alkyl halides. Explain. Q.11. What is the action of following on chlorobenzene i) NaCN + CuCN ii) Cl 2 iii) Conc. HNO3 iv) Conc. H2So4 O v) CH3Cl vi) CH3 C Cl

Q.12. Explain optical activity of : i) 2chlorobenzene Q.13. Give any 2 uses i) Iodoform

ii)

Lactic acid

ii)

Freons

Q.14. How will you prepare Bromobenzene from aniline ? Q.15. Identify A and B in the following i)

Cl + Mg
NH2

dry ether

A
Cu2X2

H2O

ii) iii) C2H5OH iv) CH3COOH v)

NaNO2/HX 273 K

B + N2

Na

A
Ag

C 2H 5Br

B B A
Cl2

A
HB r

C 2H 5Br

CH3 CH2 CH2 Cl

Na

B B

vi) CH3 CH = CH2

alc. KOH

Halogen derivatives of alkanes and haloarenes

Mahesh Tutorials Science

Q.16. Write the products i) C6H5 CH2 CH = CH2 + HBr ii) C6H5 CH = CH2 + HBr

CH3 CH3
iii) CH3 C = C CH3 + HI

CH3
iv) v)

CH3 C = CH CH3 + HBr

OH + SOCl2

Halogen derivatives of alkanes and haloarenes