MATERIAL SAFETY DATA SHEET

1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION PRODUCT :

Nital (2%, 5%, or 10%)

SAN 4394

MANUFACTURER: Syncrude Canada Ltd. P.O. Bag 4009 Fort McMurray, AB Canada T9H 3L1 Emergency Telephone No. (780) 790-5094 SYNONYMS: PRODUCT USE: PREPARED BY: None Metal etchant Nathalie Brub (780) 790-4544 August 23, 2006

DATE OF PREPARATION/REVISION: 2. COMPOSITION, INFORMATION ON INGREDIENTS Hazardous Ingredients Methanol Nitric Acid 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Composition 90 - 98 Vol. % 2 - 10 Vol. %

CAS # 67-56-1 7697-37-2

8-Hour OEL 200 ppm (skin) 2 ppm

A flammable, corrosive, toxic liquid. Nital is unstable at concentrations greater than 10% of Nitric Acid, and may decompose violently. Nital can also become unstable if contaminated with heavy metals; do not dip an applicator brush into the material. Fumes are also flammable, toxic, and corrosive. Methanol is toxic through skin absorption. ROUTE OF ENTRY: Eye contact, Skin contact, Inhalation, Ingestion EFFECTS OF ACUTE EXPOSURE: EYES: May cause severe irritation and burns. SKIN: Corrosive to skin. INHALATION: Nitric acid causes upper respiratory irritation that may seem to clear up, only to return in a few hours and more severely. INGESTION: Nitric acid is corrosive to skin, mucous membranes, and teeth. Methanol is moderately toxic, and large doses may result in coma or death. EFFECTS OF CHRONIC EXPOSURE:

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SAN 4394

Nital

Material Safety Data Sheet

EYES: Methanol exerts a toxic effect on the optic nerves, and possible the retinae, and may cause permanent blindness. SKIN: Nitric acid is corrosive to skin. Methanol can be absorbed through the skin. INHALATION: Chronic exposure to methanol can cause changes in circulation, cough, dyspnea, headache, lacrimation, nausea or vomiting, optic nerve neuropathy, respiratory effects and visual field changes. INGESTION: Because of its slow elimination from the body, methanol should be regarded as a cumulative poison. 4. FIRST AID MEASURES EYES: Immediately flush with water for at least 15 minutes. In all cases, seek medical attention. SKIN: Wash affected area with soap and water. If irritation persists, seek medical attention. INHALATION: Remove the source of contamination, or move victim to fresh air. If breathing has stopped, trained personnel should begin artificial respiration, or, if the heart has stopped, cardiopulmonary resuscitation (CPR) immediately. Oxygen may be beneficial if administered by a person trained in its use, preferably on a physician's advice. GENERAL: In all cases, seek medical attention immediately. 5. FIRE FIGHTING MEASURES FLASH POINT (PMCC): FLAMMABLE LIMITS IN AIR: AUTO-IGNITION TEMPERATURE: 12 C (methanol) 6.0% - 36.5% (methanol) 470 C (methanol)

FIRE AND EXPLOSION HAZARDS: Dangerous when exposed to heat or flame. Vapours form flammable or explosive mixtures with air at room temperature. Vapour or gas may spread to distant ignition sources and flash back. Containers may explode in heat of fire. Irritating or toxic substances may be emitted upon thermal decomposition. Vapours or gas may accumulate in low areas. Vapours may concentrate in confined areas. EXTINGUISHING MEDIA: Class B fire extinguishers: Carbon dioxide, dry powder, polymer foam. Water fog can be used by trained fire fighting personnel. FIRE FIGHTING PROCEDURES: Evacuate all personnel from danger area. Shut off source of flow if possible. Use a water spray to cool fire-exposed containers and structures, and to protect personnel. If leak has not ignited, ventilate area and use water spray to disperse gas or vapour, and to protect personnel attempting to stop a leak. Exposed firefighters must wear full bunker gear, including a NIOSH approved positive pressure selfcontained breathing apparatus with full-face mask. 6. ACCIDENTAL RELEASE MEASURES LEAK AND SPILL PROCEDURE: Forms explosive mixtures with air (see Section 5). Immediately evacuate all personnel from danger area. Use self-contained breathing apparatus. Remove all sources of ignition if without risk. Absorb the liquid on inert material. Ventilate area of leak, or move leaking container to a well-ventilated area.

Syncrude Canada Ltd.

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Material Safety Data Sheet

Nital

SAN 4394

CAUTION: Flammable gas may spread from spill. Before entering area, especially confined areas, check atmosphere with appropriate device. 7. HANDLING AND STORAGE HANDLING PROCEDURES AND EQUIPMENT: Avoid exposure to vapours. Avoid skin contact. Wash thoroughly after handling. Avoid contamination of Nital with any metals - do not dip an applicator brush into the material. Nital can become unstable if contaminated with heavy metals. STORAGE REQUIREMENTS: Store in a cool, dry location away from ignition sources. Do not store near oxidizing materials. Provide adequate ventilation. Keep containers tightly closed. Avoid exposing the containers to heat, as this will cause a pressure build-up. Keep storage quantities to a minimum. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION EXPOSURE LIMITS: Methanol: Nitric Acid:

8-hour OEL: 15 minute OEL: 8-hour OEL: 15 minute OEL:

200 ppm 250 ppm 2 ppm 4 ppm

ENGINEERING CONTROLS: Ventilate confined space before entry. Provide local exhaust where appropriate to minimize fugitive vapours or mists. PERSONAL PROTECTIVE EQUIPMENT: Gloves: Acrylonitrile or neoprene Respirator: A NIOSH approved air purifying organic vapour/acid gas cartridge can be used at low concentrations (below OEL). If exposure limits are exceeded or if irritation is experienced, a NIOSH approved positive pressure self-contained breathing apparatus should be worn. Prevent eye contact with this material. Wear chemical tight goggles. Provide an eyewash station immediately accessible to the work area. Do not wear contact lenses when working with this substance.

Eyes:

9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Clear, colourless liquid ODOUR: Light alcohol odour. PHYSICAL STATE: Liquid. pH: < 2 (strong acid) VAPOUR PRESSURE: Not available VAPOUR DENSITY (Air = 1): 1.1 (methanol) FREEZING POINT: Not available BOILING POINT: Approx. 65 C

Syncrude Canada Ltd.

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SAN 4394

Nital

Material Safety Data Sheet

EVAPORATION RATE (n-Butyl Acetate = 1): Approx. 5 COEFFICIENT OF WATER/OIL DISTRIBUTION: Miscible with water ODOUR THRESHOLD: Not available 10. STABILITY AND REACTIVITY STABILITY: Normally stable; may be unstable when contaminated with heavy metals. CONDITIONS TO AVOID: Avoid exposure to sources of ignition. MATERIALS TO AVOID: Strong oxidizing materials. HAZARDOUS COMBUSTION PRODUCTS: Oxides of nitrogen, Carbon monoxide 11. TOXICOLOGICAL INFORMATION LD50: Methanol: 5628 mg/kg (oral rat) Nitric Acid: Not available LDLO: (Lowest Lethal Dose) Methanol: 143 mg/kg (oral human) Nitric Acid: 430 mg/kg (oral human) CARCINOGENICITY: This product is not considered to be carcinogenic. REPRODUCTIVE TOXICITY: Both Methanol and Nitric Acid are reported to have experimental reproductive effects. TERATOGENICITY: Nitric Acid has been reported as an experimental teratogen. MUTAGENICITY: No effects reported. SYNERGISTIC EFFECTS: No effects reported. 12. ECOLOGICAL INFORMATION Not available 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL: This product is known to be a hazardous waste according to Canada and U.S. RCRA regulations. Provincial jurisdictions use various hazardous waste control regulations and the Transportation of Dangerous Goods Act to define hazardous waste and appropriate packaging, reporting, storage, and transport. Contact federal, provincial/state, and local authorities in order to generate or ship a waste material associated with this product to ensure materials are handled properly and meet all criteria for disposal of hazardous waste. DO NOT ATTEMPT TO DISPOSE OF BY UNCONTROLLED IGNITION.

Syncrude Canada Ltd.

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Material Safety Data Sheet

14. TRANSPORT INFORMATION: CANADIAN TDG:

Nital

SAN 4394

Hazard Class: 3 (8) P.G. II Product Identification Number (PIN): UN2924 Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.* (Methanol, Nitric Acid) 15. REGULATORY INFORMATION WHMIS CLASS: B-2; E This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. All compounds in this product are listed in the Canada Domestic Substances List (DSL) and the United States Toxic Substances Control Act (TSCA) Chemical Substance Inventory (1985). 16. OTHER INFORMATION References: Sax's Dangerous Properties of Industrial Materials, Ninth Edition; R. J. Lewis; Van Nostrand Reinhold, 1996. DISCLAIMER The information and recommendations contained in this MSDS are believed to be accurate as at the date of its preparation. Syncrude Canada Ltd. makes no representations or warranties, express or implied, with respect to the accuracy or completeness of the information contained herein. Syncrude Canada Ltd. assumes no responsibility for incorrect handling or use of the product or the inherent hazards involved in the nature of the product itself.

Syncrude Canada Ltd.

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