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Molecular Geometry Summary Sheet

Shaded squares represent geometries which give non-polar molecules when all substituents X are identical. Total # Electron Pair # of # of Geometry Approximate Bonding Shape Examples of Geometry Lone Name Bond Angle Groups Directions Pairs (Hybridization) (# of X) (# of E) (VSEPR class) of e linear 2 0 BeH2, 2 linear 180o (sp) (AX2) CO2 3 3 trigonal planar (sp2) 120o 2 4 4 tetrahedral (sp3) 109.5o 3 1 1 0 tetrahedral (AX4) trigonal pyramidal (AX3E) bent (AX2E2) CH4 NH3 0 trigonal planar (AX3) bent (AX2E) BF3, NO3 SO2

H2O

5 trigonal bipyramidal (sp3d) 120o (in plane) & 90o (above & below) 4

0 trigonal bipyramidal (AX5) 1 seesaw (AX4E) PCl5

SF4

2 T-shaped (AX3E2)

ClF3

3 linear (AX2E3)

XeF2

6 octahedral (sp3d2) 90o 5

0 octahedral (AX6) square pyramidal (AX5E) SF6 BrF5

Molecular Geometry Summary Sheet


Shaded squares represent geometries which give non-polar molecules when all substituents X are identical. 4 2 XeF4 square planar (AX4E2) 3 3 T-shaped (AX3E3) 2 4 linear (AX2E4)

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