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Molecular Geometry
Molecular Geometry
Shaded squares represent geometries which give non-polar molecules when all substituents X are identical. Total # Electron Pair # of # of Geometry Approximate Bonding Shape Examples of Geometry Lone Name Bond Angle Groups Directions Pairs (Hybridization) (# of X) (# of E) (VSEPR class) of e linear 2 0 BeH2, 2 linear 180o (sp) (AX2) CO2 3 3 trigonal planar (sp2) 120o 2 4 4 tetrahedral (sp3) 109.5o 3 1 1 0 tetrahedral (AX4) trigonal pyramidal (AX3E) bent (AX2E2) CH4 NH3 0 trigonal planar (AX3) bent (AX2E) BF3, NO3 SO2
H2O
5 trigonal bipyramidal (sp3d) 120o (in plane) & 90o (above & below) 4
SF4
2 T-shaped (AX3E2)
ClF3
3 linear (AX2E3)
XeF2