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Simulation of Paraffin Deposition and Removal in Wellbores
Simulation of Paraffin Deposition and Removal in Wellbores
Simulation of Paraffin Deposition and Removal in Wellbores
“9 ‘With these two equations, the cell pressures in the annulus and the bottom hole flowing pressure p,, are obtained. Once the temperatures, pressures, and phases saturations in the production tubing and in the annulus are determined as described above, the quantity of solid paraffin that deposits onto the i ‘may be calculated. le ofthe production tubing Paraffin Precipitation and Deposition in Tubing. Before solid paraffin can deposit onto ‘the inside of the production tubing, it must precipitate from solution. To calculate the amount of mass that precipitates from solution the solubility curve that is used in the reservoir simulator was used again, This solubility curve is documented by Peddibhotla” and Ring To calculate the amount of deposited solid paraffin, diffusion and shear deposition models proposed by Weingarten and Euchner are used." These models define the ‘amount of solid paraffin that deposits onto the inside of the production tubing. ‘The following paragraphs describe ‘was programmed into the simulator. Diffusion deposition is driven by a concentration gradient and the deposition rate is calculated with the following equation originally iffusion deposition and how this mechanism proposed by Weingarten and Euchner: a9) a where C, is their lab determined diffusion constant. With a diffusion deposition cell, the diffusion deposition rates for dead oil were measured for a range of conditions. The deposition cell is a cylindrical pressure vessel that has five circular steel plates in it.47 ‘These steel plates made six separate oil chambers that were not sealed from each other. ‘Therefore these steel plates were incorporated into this cell to act as sights where paraffin deposition could occur. The temperatures on the top and bottom ends of this eylindrical cell could be adjusted. Fora typical experiment one end of the cell was heated and the coher end was cooled. This temperature difference was held constant for a period of 48 to 170 hours. Then, the oil was drained while the temperature gradient was maintained. Next, cell was disassembled and the remaining mixture of wax and oil was removed. Finally, an acetone precipitation procedure was used to determine the amount of wax deposited.” ‘The results of these experiments were plotted ini the following manner. The product of the diffusion constant C, and the derivative of the mole fraction of paraffin in solution x,, with respect to the temperature T were plotted as a function of the temperature of the cold surface on a semilog plot (log(C, dx,/47} vs. 7). This plot resulted in two straight lines that intersected at about 70 ‘F. The low temperature line ranged from 30 °F to 70 “F. ‘The high temperature line ranged from 70 “F to 95 °F. Since it is uncommon for the production tubing to be colder than 70 °F, the high temperature line was programmed into the wellbore simulator with the following equation. G os = 199s HED a7 where 7, is the temperature of the production tubing. By coupling this equation to finite difference approximation of the diffusion deposition equation Eq, 16, the following procedure was developed. This procedure is used to calculate the amount of paraffin that deposited from diffusion, First the derivative of the mole fraction of paraffin in solution x,, with respect to ‘the temperature Tis calculated. To do this, the mole fraction of paraffin in the liquid phase at the fluid temperature 7, and at the tubing temperature 7, is calculated with the solubility curve, ‘Then, the following two point finite difference approximation is used to calculate this derivative.4B Sy, Hat et io a7 -% Next, the diffusion constant C, is calculated from the previous two equations. This constant may be multiplied by a user defined deposition constant C, . This deposition constant was used to increase the amount of paraffin that is depositing onto the inside of the production tubing, If the user defines a deposition constant equal to ‘one, then the diffusion deposition of paraffin onto the inner wall of the production tubing ‘will be proportional to the diffusion deposition obtained from the lab experiments performed by Weingarten and Euchner, Next, the following two point finite difference approximation is used to calculate the derivative of the mole fraction of paraffin in solution x, with respect to the radius 7, Sy, Fut — Fos 9) a 7; for use in Eq, 2-26, In this approximation r, is the radius of the tubing, x,,, and py are the mole fraction of paraffin in solution at the tubing and fluid temperatures respectively. Finally, the wellbore simulator calculates the density of the paraffin p, , the viscosity of the liquid jz, and the surface area of the production tubing A, With all these values, the diffusion deposition equation (Eq. 16) is used to calculate the diffusion deposition rate. This rate is multiplied by the timestep size to obtain the mass of the paraffin that deposits onto the production tubing from diffusion deposition. ‘Shear deposition is the other mechanism used in the wellbore simulator to define paraffin deposition that occurs in the production tubing. Shear deposition is driven by a velocity gradient (shear rate 7”) and is calculated with the following equation that was also proposed by Weingarten and Euchner:* a eres? 20) where A, is the surface area of the production tubing and k* is a shear deposition constant defined by lab experiments. A loop of 1/4 inch stainless steel tubing was used49 to obtain k*. Oil was circulated through this tube which was emersed in a glycol cooling bath. The amount of paraffin that was depositing onto the inside of this tubing was measured indirectly with the pressure drop. A uniform distribution of paraffin was assumed to calculate this volume. Diffusion deposition also adds to this deposited volume. ‘Therefore, the shear deposition rate was obtained by subtracting a calculated diffusion deposition rate from the total deposited rate. Then, the shear deposition rate ‘was normalized and plotted as a function of the shear rate. The normalized deposition rate was defined with the following equation. sy 1} a en The slope of this plot was approximately constant for shear rates less 2,650 second”. This slope for these shear rates was reported to be 1.022 hr-secift Es 102 2) 1 For shear rates greater than 2,450 second", the solid paraffin sloughed off the tubing. In this study itis assumed that this sloughing would not occur and that shear deposition only occurs at shear rates less than 2450 sec". ‘Therefore, the shear deposition constant e* could be calculated from Eq, 22. In the wellbore simulator, the concentration of precipitated paraffin C, is calculated with the following equation. eae where ris the moles of solid paraffin suspended in the liquid, ny, is moles of gas in solution, ,, is the moles of oil and ny, is moles of paraffin in solution. “The shear rate’? is obtained from the velocity of the liquid phase. This velocity ‘was calculated with the two phase flow correlation, With this velocity and the relative radius ofthe tubing 7, the shear rate was calculated with the following finite difference approximation50 ”, "Tg (24) ‘The liquid velocity v, was assumed to be an average velocity. For laminar flow, the average velocity occurs at a radius of yO F,, which justifies the use of the adjusted relative radius (Y0.5 7,) in this finite difference approximation. With the shear rate, the concentration of the suspended solid paraffin, the deposition constant and the area of the surface area of the production tubing, the shear deposition rate is calculated with Eq, 2- 30. Together shear deposit paraffin that will deposit onto the inside of the production tubing in the wellbore n and diffusion deposition quantify the total amount of simulator. Paraffin Removal in Tubing. There are various techniques used to remove paraffin once thas deposited. This study is limited to the following thermal methods:"* (1) electric, downhole heaters (2) electrical heating of the tubing, and (3) injection of hot (see Fig. 1-2). The only removal mechanism used in this simulator is the dissolving of the solid paraffin. Once the paraffin had been deposited onto the tubing, it is not removed until undersaturated oil comes in contact with the deposit. For the oil to be undersaturated, the temperature of the liquid must be raised above its cloud point temperature, When this occurs, the oil is resaturated with the deposited paraffin, If the oil in a wellbore cell could hold all the deposited paraffin, then all the solid paraffin is removed from the inner wall of the production tubing, This allows the solid paraffin to be dissolved and transported away in the liquid phase. This is apparently somewhat elementary compared to the elaborate depositional mechanisms. However, since studies concerning the removal of the solid paraffin by sloughing are not available, this removal mechanism is neglected, and therefore most likely a conservative amount of paraffin is removed with this simulator. Hot Oil Injection. The energy rate that is supplied by injecting hot31 the user. This energy is split between the tubing and the casing according to the user. These two increments of energy are distributed with the following linear frst order differential equation to the designated depth aE a where Z, is the heated depth. This technique of modelling hot cil injection was verified with field data form Sandia National Laboratories. Sandia performed a field test of heat AE @5) transfer that occurs during hot oil injection. This was done by setting a bridge plug between the perforations and the bottom of the tubing and then circulating out cool oi ‘with hot water, The temperatures that were recorded as a function of depth immediately after circulating the hot water were used to validate the temperatures obtained from the linear first order differential equation. A very good agreement was obtained ‘When hot oil is injected, the liquid level in the annulus increases accordingly. ‘The paraffin concentration of the liquid added to the annulus is specified by the user. ‘Therefore, the effects of removing the light ends (all the solution gas and some of the oil) is also being simulated. This high paraffin concentration hot oil was also capable of flowing back into the reservoir. When this occurs paraffin can deposit within the reservoir and reduce the effective permeability of the reservoir. The possibility of this ‘occurring has been well documented: This paraffin simulator has been designed to address this situation with a simplistic approach. This simulator lets the user specify the concentration of the oil at the perforations at any time. If no concentrations are specified, then the concentration of the oil in the first cell of the simulator is used. Downhole Heater, To model a downhole heater, an energy rate is specified, This energy rate is added to the cell that connects the wellbore model to the reservoir model (pert-cell). Then with a single cell thermal energy balance, the temperature of the perf-cell is calculated. All three pseudocomponents as well as all three phases are present in the perf-cell. The following three pseudocomponent, three phase thermal energy balance is used in the perfcell to calculate the temperature,52 26) Fates + eaSute * Pats] = dow * dew * ex * ere * ee ‘The accumulation of thermal energy is modeled with the first term in this equation and the following terms are qoy the thermal energy rate specified by the user, dr, + dere the sum of all heat flows due to convection (reservoir, production tubing, and annular fluids) and qcpy"+ dcop the sum of all the heat flow due to conduction (reservoir, cement, casing, annular fluid, tubing, produced liquid). This one dimensional nonlinear equation ‘was solved for the temperature of the perforation cell with Newton's method, ‘An operating maximum and minimum downhole temperatures are also specified. This thermal control is analogous to a thermostat. When the temperature of the perforation cell exceeds the specified maximum temperature, the thermal energy rate is temporarily set to zero, Once the temperature reaches specified operating minimum temperature, the thermal energy rate is returned to its original value, The user may also tum this downhole heater on and off any time during the run, Hectic Heating of the Tubing. To model electric heating of the tubing requires an energy rate. This user specified energy rate is added to the tubing and the casing. According to published results,” approximately 70 to 75 percent of the electrical energy added to the tubing is dissipated in the tubing for typical tubing/casing sizes. The rest of the electrical energy goes through the contactor (see Fig. 2) and is dissipated in the casing. Dissipation of electrical energy in the cement and the formation were neglected. However, the transfer thermal energy throughout the wellbore and the overburden is considered, In this model, the fraction of the total electrical energy that is dissipated by the tubing, may be specified by the user. These two increments of electrical energy are distributed evenly along the tubing and casing to the designated depth (the depth of the contactor). This distribution is a realistic interpretation of electric heating of the tubing according to a major manufacturer tubing heating hardware.**53 RESULTS ‘To validate the results obtained from this simulator, paraffin deposition and removal data ‘would have to be obtained from the field. This data was not available, therefore this study only documents the results obtained from this paraffin simulator by running, the following four cases: (1) paraffin deposition, (2) hot oil injection, (3) downhole heater, ‘and (4) electric heating of the tubing. With these four cases, conclusions are made from ‘observing the behavior of the simulator. Paraffin Deposition (Case 1) ‘This case was designed to illustrate paraffin deposition in the production tubing. The data used to simulate this case were chosen to represent a typical well with paraffin problems (see Table 1). This 5000 foot well has a constant production rate of one hundred stock tank barrels per day. The liquid entering the production tubing has a paraffin content of 6,83 percent by weight. The original cloud point temperature of liquid is 111.69 °F. The reservoirs temperature is 120.0 °F. Therefore, the liquid which is entering the production tubing is undersaturated with paraffin and all the paraffin exists in the liquid phase. As the liquid is produced up the tubing, paraffin solidifies at and below the original cloud point temperature. At the surface, the fluid temperature is 93.84 °F, The paraffin content in the liquid phase is reduced to 1.43 percent by weight at this lower temperature. However, only a small fraction of the precipitated paraffin deposits onto the production tubing. Most of the solid paraffin is produced as solid particles with the liquid. Since only a small amount of the precipitated paraffin deposits onto the tubing, this is nearly a steady state process. Therefore, the total paraffin content does not change much as the fluid travels up the tubing. In other words at the surface, 1.43 percent of the paraffin is in the liquid phase and almost all the rest, 5.40 percent of paraffin, is suspended as solid particles in the liquid phase as solid particles. However, sinceTABLE 1 - DATA USED TO SIMULATE (CASES 1-5). Oil Density Paraffin Density at Standard Conditions Cloud Point Temperature Latent Heat of Fusion of Paraffin ‘Melting Point Temperature of Paraffin User Defined Deposition Coefficient Thermal Conductivity of Oil ‘Thermal Conductivity of Gas ‘Solid Material Properties Density of Steel Density of Cement Density of Overburden and Underburden Isobaric Heat Capacity of Stee! Isobarie Heat Capacity of Cement Isobaric Heat Capacity of Rock ‘Thermal Conductivity of Steel ‘Thermal Conductivity of Cement ‘Thermal Conductivity of Rock Wellbore Data Tubing Head Pressure Casing Head Pressure Surface Mean Temperature Pump Rate Grid Data ‘Number of Vertical Grids in Well ‘Number of Vertical Grids in Overburden Number of Radial Grids in Overburden Number of Grids in Fluid ‘Number of Grids in Tubing ‘Number of Grids in Annulus ‘Number of Grids in Casing ‘Number of Grids in Cement Outer Radius of Rods Inner Radius of Tubing Outer Radius of Tt Inner Radius of Casing Outer Radius of Casing Outer Radius of Cement 50.66 56.61 111.69 30.0 185.0 33000.0 1.70 0.70 487.0 1200 1350 0.3 0.210 0.200 600.0 150 35.0 250.0 $0.0 70.0 i00. 25 15 9 1 1 2 1 4 0,000 1.2205 1.4375 2.506 2.75 3.0 Ibmift? Iomift? °F Keal/g-mole F dimensionless BrwD-f--F BrwD-f-F Ibmift? Tomift? Tbm/ft? Btulbm-"F Brulbm-"F Brulbm-"F BrwD-ft-F BrwD-f-F BtwD-f-F psig. psig ¥ sTBD in in in 5455 paraffin deposition is occurring the total paraffin content increases at a very slow rate, ‘The simulated paraffin deposition profiles are shown in Fig, 17. This figure illustrates that most of the paraffin deposition occurs at the top of the tubing. At this position in the tubing, diffusion deposition and shear deposition are the largest. Diffusion deposition is the largest because the temperature gradient isthe largest atthe top. Shear deposition is the largest, because the concentration of precipitated paraffin particles is also the largest atthe top. ‘The following paragraphs discuss in more detail ‘why the diffusion and shear deposition are the largest at the top of the tubing. 0 — — 1000 ae € 20 = 2000 e t eq 3000 4000 $000! 0 0.05 Ol 0.15 02 Deposited Parafin Thickness (in) ‘Fig. 17 - Simulated paraffin thickness profiles from the depositional period. Diffusion deposition is one of the two mechanism that defines the amount of paraffin deposition, and is driven by a concentration gradient that is produced from a temperature gradient. A temperature gradient only creates a concentration gradient in saturated liquids. The hotter saturated liquid in the center of the tubing will have a higher concentration of paraffin because of the increasing solubility of paraffin with increasing temperatures. Hence, the paraffin will diffuse from the hotter center of the tubing toward the relatively cool inner wall of the tubing. At the surface, the difference56 in the fluid and the tubing temperatures is the largest. Therefore, diffusion deposition is the largest at the top of the tubing. Shear deposition is driven by a velocity gradient and is proportional to the ‘concentration of precipitated paraffin particles. At the top of the tubing, both the velocity gradient in the radial direction (due to a reduction in the effective tubing diameter), and the concentration of precipitated paraffin particles (due to the relatively low fluid temperature) are the largest. Therefore, shear deposition is also the largest at the top of the tubing. With the contributions from both these depositional mechanisms, 0.175 inches of solid paraffin was deposited at the top of the tubing (see Fig. 17). ‘This quantity of deposited paraffin cannot be obtained unless a very large deposition coefficient is used. The deposition coefficient C, is a user defined constant that is used to increase the amount of paraffin depositing onto the inside of the production tubing, If the user defines deposition coefficient equal to one, then theYou might also like
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