MATERIAL SAFETY DATA SHEET l.

PRODUCT NAME: PRODUCT ID: SYNONYMS: ISSUE DATE: EDITION NO.:

CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Trichloroethylene Trichloroethane Trichlorethylene: Trichlor C!HCI! 11/26/2002 17

0085

PP" In#$%trie%! Inc. One PP" Place! Pitt%&$r'h! PA ()*+*! USA *,-ho$r E.er'ency Tele/hone N$.&er: (-01,-2,0-(011
For Pro#$ct In3or.ation 42a.-)/. Ea%tern ti.e5: (-211-*,0-6++, 4CIA5 PREPARER: Pro#$ct Sa3ety. Che.ical%

2.
Materiai7CAS N$.&er

COMPOSITION/INFORMATION ON INGREDIENTS
Percent

Trichloroethylene 4Sta&ili8e#5 9::

79-01-6

Note: Te%te# Mi;t$re

3.
EMER"ENCY O<ER<IE=: Pa'e ( o3 +

HAZARDS IDENTIFICATION

=ARNIN"7 May ca$%e irritation to eye% an# %>in. <a/or har.3$l. Har.3$l i3 %?allo?e#. Po%%i&le cancer ha8ar# &a%e# on te%t% ?ith la&oratory ani.al% @@ oAere;/o%$re .ay create cancer ri%>. Do not %hi/ li'htly %ta&ili8e# 'ra#e% in al$.in$. trailer%. Preca$tion%: AAoi# contact ?ith eye%. AAoi# /rolon'e# or re/eate# contact ?ith the %>in. U%e only ?ith a#eB$ate Aentilation Do not &reathe Aa/or%. Hi'h Aa/or concentration% can ca$%e #i88ine%%! $ncon%cio$%ne%%! central nerAo$% %y%te. #e/re%%ion or #eath. Lon'Cter. oAere;/o%$re .ay ca$%e liAerD>i#ney inE$ry. Do not $%e in /oorly Aentilate# or con3ine# %/ace% ?itho$t /ro/er re%/iratory /rotection. <entilation .$%t &e %$33icient to li.it e./loyee e;/o%$re to thi% /ro#$ct &elo? /er.i%%i&le e;/o%$re li.it%. Eye irritation! #i88ine%% an#Dor #r$n>enne%% are %i'n% o3 oAere;/o%$re. Do not %?allo?. =a%h thoro$'hly eAery #ay a3ter ?or>. Do not eat! #rin> or %.o>e in ?or> area.

Pa'e ( o3 +

I7

PP"

112) Trichloroethylene

11/26/2002

4.

FIRST AID MEASURES

INHALATION: MoAe /er%on to 3re%h air. I3 not &reathin'! 'iAe arti3icial re%/iration! /re3era&ly .o$th to.o$th. I3 inhale#! re.oAe 3ro. area to 3re%h air. "et .e#ical attention i3 re%/iratory irritation #eAelo/% or i3 &reathin' &eco.e% #i33ic$lt I3 &reathin' i% #i33ic$lt! 'iAe o;y'en. Call a /hy%ician. EYEDSFIN CONTACT: In ca%e o3 contact! i..e#iately 3l$%h eye% an# %>in ?ith /lenty o3 ?ater 4%oa/ an# ?ater 3or %>in5 3or at lea%t 15 .in$te%! ?hile re.oAin' conta.inate# clothin' an# %hoe%. "et .e#ical attention i3 irritation /er%i%t%. Thoro$'hly clean conta.inate# clothin' an# %hoe% &e3ore re$%e or #i%car#. IN"ESTION: I3 %?allo?e#! 'iAe at lea%t 0-, 'la%%e% o3 ?ater! &$t #o not in#$ce Ao.itin'. Do not 'iAe anythin' &y .o$th to an $ncon%cio$% or conA$l%in' /er%on. "et .e#ical attention.

NOTES TO PHYSICIAN: Only a#.ini%ter a#renaline a3ter care3$l con%i#eration 3ollo?in' oAere;/o%$re. Increa%e# %en%itiAity o3 the heart to a#renaline .ay &e ca$%e# &y oAere;/o%$re to thi% /ro#$ct

5. FIRE FIGHTING MEASURES

FLASH POINT: None 4&y DOT te%t .etho#5. FLAMMAGLE LIMITS IN AIRC LO=ER4H5: FLAMMAGLE LIMITS IN AIR- UPPER4H5 7.8% 52%

EITIN"UISHIN" MEDIA: Car&on #io;i#e. Dry che.ical. =ater. SPECIAL FIREFI"HTIN" PROCEDURES: E.it% to;ic 3$.e% $n#er 3ire con#ition%. =hen thi% /ro#$ct i% inAolAe# in 3ire%! it can #eco./o%e to to;ic! corro%iAe hy#ro'en chlori#e an# /o%%i&le trace% o3 /ho%'ene. Fire-3i'hter% .$%t ?ear NIOSH a//roAe# /re%%$re #e.an#! %el3-containe# &reathin' a//arat$% an# 3$ll /rotectiAe clothin' ?hen 3i'htin' che.ical 3ire%. <a/or concentration in a con3ine# or /oorly Aentilate# area can &e i'nite# $/on contact ?ith a hi'h ener'y %/ar>! 3ia.e! or hi'h inten%ity %o$rce o3 heat Thi% can occ$r at concentration% ran'in' &et?een the lo?er an# $//er li.it% 4&y Aol$.e5 li%te# a&oAe.

6.

ACCIDENTAL RELEASE MEASURES

ACTION TO GE TAFEN IF MATERIAL IS RELEASED OR SPILLED: I..e#iately eAac$ate the area. ProAi#e .a;i.$. Aentilation. Un/rotecte# /er%onnel %ho$l# .oAe $/?in# o3 %/ill. Only /er%onnel eB$i//e# ?ith /ro/er re%/iratory an# eyeD%>in /rotection %ho$l# &e /er.itte# in the area. Di>e area to contain %/ill. Ta>e /reca$tion% a% nece%%ary to /reAent conta.ination o3 'ro$n# an# %$r3ace ?ater%. RecoAer %/ille# .aterial on a#%or&ent%! %$ch a% %a?#$%t or Aer.ic$lite! an# %?ee/ into clo%e# container% 3or #i%/o%aL A3ter all Ai%i&le trace%! incl$#in' i'nita&le Pa'e 2 o3 +

Aa/or%! haAe &een re.oAe#! thoro$'hly ?et Aac$$. the area. Do not 3i$%h to %e?er. I3 area o3 %/ill i% /oro$%! re.oAe a% .$ch earth an# 'raAel! etc. a% nece%%ary an# /lace in clo%e# container% 3or #i%/o%al.

Pa'e 2 o3 +

PP":

112) Trichloroethylene

((D*6(*11*

7.

HANDLING AND STORAGE

PRECAUTIONS TO GE TAFEN DURIN" HANDLIN" AND STORA"E: <a/or% are heaAier than air an# ?ill collect in lo? area%. Fee/ container clo%e# ?hen not in $%e. Store only in clo%e#! /ro/erly la&ele# container%. Thi% .aterial or it% Aa/or% ?hen in contact ?ith 3la.e%! hot 'lo?in' %$r3ace% or electric arc% can #eco./o%e to 3or. hy#ro'en chlori#e 'a% an# /o%%i&le trace% o3 /ho%'ene. AAoi# conta.ination o3 ?ater %$//lie%. Han#lin'! %tora'e an# $%e /roce#$re% .$%t &e care3$lly .onitore# to aAoi# %/ill% or lea>%. Any %/ill or lea> ha% the /otential to ca$%e $n#er'ro$n# ?ater conta.ination ?hich .ay! i3 %$33iciently %eAere! ren#er a #rin>in' ?ater %o$rce $n3it 3or h$.an con%$./tion. Conta.ination that #oe% occ$r cannot &e ea%ily correcte#. A chlorinate# %olAent $%e# a% a 3la%h/oint %$//re%%ant .$%t &e a##e# in %$33icient B$antity or the re%$ltant .i;t$re .ay haAe a 3la%h/oint lo?er than the 3la..a&le co./onent Do not $%e c$ttin' or ?el#in' torche% on #r$.% that containe# thi% /ro#$ct $nle%% /ro/erly /$r'e# an# cleane#. Do not %hi/ li'htly %ta&ili8e# 'ra#e% in al$.in$. trailer%. The only e;ce/tion i% Ty/e 145 Aa/or #e'rea%in' 'ra#e. LiB$i# o;y'en or other %tron' o;i#ant% .ay 3or. e;/lo%iAe .i;t$re% ?ith thi% /ro#$ct

8.

EXPOSURE CONTROLS/PERSONAL

PROTECTION

E;/o%$re Li.it%: 2-ho$r Ti.e =ei'hte# AAera'e 4T=A5 ()-.in$te Short-Ter. E;/o%$re Li.it 4STEL5 OSHA: )1 //. T=A *11 //. STEL. AC"IH: )1 //. T=A (11 //. STEL. RESPIRATORY PROTECTION: Air&orne concentration% %ho$l# &e .aintaine# &elo? the e;/o%$re li.it%. =hen re%/iratory /rotection i% reB$ine# 3or certain o/eration% 4J(O; e;/o%$re li.it5! $%e an air /$ri3yin' re%/irator. The e33ectiAene%% o3 an air /$ri3yin' re%/irator i% li.ite#. U%e only 3or a %in'le %hortter. e;/o%$re. U%e %el3-containe# &reathin' a//arat$% 4SCGA5 or 3$ll 3ace /iece airline re%/irator ?ith a$;iliary SCGA o/erate# in the /re%%$re #e.an# .o#e 3or e.er'encie% an# 3or all ?or> /er3or.e# in %tora'e Ae%%el%! /oorly Aentilate# roo.%! an# other con3ine# area%. OAere;/o%$re to Aa/or% .ay &e /reAente# &y en%$rin' /ro/er Aentilation control%! Aa/or e;ha$%t or 3re%h air entry. A NIOSH-a//roAe# air /$ri3yin' re%/irator ?ith the a//ro/riate che.ical cartri#'e% or a /o%itiAe /re%%$re air-%$//lie# re%/irator .ay al%o re#$ce e;/o%$re. Rea# the re%/irator .an$3act$rerK% in%tr$ction% an# literat$re care3$lly to #eter.ine the ty/e o3 air&orne conta.inant% a'ain%t ?hich the re%/irator i% e33ectiAe! it% li.itation%! an# ho? it i% to &e /ro/erly 3itte# an# $%e#. <ENTILATION: U%e local e;ha$%t or 'eneral roo.D#il$tion Aentilation %$33icient to .aintain e./loyee e;/o%$re &elo? /er.i%%i&le e;/o%$re li.it%. EYE AND FACE PROTECTION: S/la%h/roo3 'o''le%. PROTECTI<E "LO<ES: <itonL. SilAer Shiel#L. PolyAinyl alcohol 4#e'ra#e% in ?ater5. OTHER PROTECTI<E EMUIPMENT: Goot%. a/ron%. or che.ical %$it% %ho$l# &e $%e# ?hen nece%%ary to /reAent %>in contact. Pa'e 5 o3 +

PP":

112) Trichloroethylene

((D*6D*11*

9.

PHYSICAL AND CHEMICAL PROPERTIES

,.), (,6)P *1D*1 c 6.+ to +.) 1.(( (**(&%D'alP *1 C (11 )+.2 .. H'P *1 C 1.*2 4ethyl etherN(5 NA LiB$i# Ether-li>e ClearDColorle%%

GOILIN" POINT: <APOR DENSITY 4AirN(5: SPECIFIC "RA<ITY 4=aterN(5: /H: FREEOIN"DMELTIN" POINT: SOLUGILITY 4?t.H in ?ater5: GULF DENSITY: <OLUMEH <OLATILE: <APOR PRESSURE: E<APORATION RATE: HEAT OF SOLUTION: PHYSICAL STATE: ODOR: COLOR:
1

86-88 c

-864 c

10.
STAGILITY: Sta&le.

STABILITY AND

REACTI ITY

HAOARDOUS POLYMERIOATION: =ill not occ$r. INCOMPATIGILITY 4CONDITIONSDMATERIALS TO A<OID5: O/en 3ta.e%! hot 'lo?in' %$r3ace% or electric arc%. AAoi# conta.ination ?ith ca$%tic %o#a! ca$%tic /ota%h or o;i#i8in' .aterial%. Shoc> %en%itiAe co./o$n#% .ay &e 3or.e# HAOARDOUS THERMAL DECOMPOSITIONDCOMGUSTION PRODUCTS: Hy#ro'en chlori#e 'a%. Po%%i&le trace% o3 /ho%'ene.

11.

TOXICOLOGICAL INFORMATION
4.o$%e5 2,)1 //. 4, ho$r%5. Sli'ht to Aery lo? to;icity. 4ra&&it5 9*111 .'D>' Sli'ht to Aery lo? to;icity. Mil#ly irritatin'. Mo#erately irritatin'. 4rat5 )6)1 .'D>'. Sli'ht to Aery lo? to;icity.

ACUTE INHALATION LC)1: ACUTE DERMAL LD)1: SFIN IRRITATION: EYE IRRITATION: ACUTE ORAL LD)1:

CHRONIC EFFECTSDCARCINO"ENICITY: Trichloroethylene i% li%te# &y NTP a% a %$%/ect carcino'en! an# &y IARC a% a "ro$/ *A carcino'en. MEDICAL CONDITIONS A""RA<ATED: Prolon'e# e;/o%$re a&oAe the OSHA /er.i%%i&le e;/o%$re li.it .ay co./licate e;i%tin' liAer an# >i#ney #i%ea%e%. EFFECTS OF O<EREIPOSURE:

Pa'e 6 o3 +

ACUTE:

Pa'e 7 o3 +

II

PP":

0085 Trichloroethylene

((D*6D*11*

Inhalation: Thi% /ro#$ct i% /ri.arily a central nerAo$% %y%te. #e/re%%ant. Inhalation can ca$%e irritation o3 the re%/iratory tract! #i88ine%%! na$%ea! hea#ache! lo%% o3 coor#ination an# eB$ili&ri$.! $ncon%cio$%ne%% an# eAen #eath in con3ine# or /oorly Aentilate# area%. Fatalitie% 3ollo?in' %eAere acute exposure to various chlorinated solvents have been attributed to ventricular fibrillation. EyeDS>in: LiB$i# %/la%he# in the eye can re%$lt in #i%co.3ort! /ain an# irritation. Prolon'e# or re/eate# contact ?ith liB$i# on the %>in can ca$%e irritation an# #er.atiti%. The /ro&le. .ay &e accent$ate# &y liB$i# &eco.in' tra//e# a'ain%t the %>in &y conta.inate# clothin' an# %hoe%. S>in a&%or/tion i% not e;/ecte# to &e o3 to;icolo'ical %i'ni3icance $n#er nor.al in#$%trial $%e. In'e%tion: S?allo?in' o3 thi% .aterial .ay re%$lt in irritation o3 the .o$th an# "l tract alon' ?ith other e33ect% a% li%te# a&oAe 3or inhalation. <o.itin' an# %$&%eB$ent a%/iration into the l$n'% .ay lea# to che.ical /ne$.onia an# /$l.onary e#e.a ?hich i% a /otentially 3atal con#ition. CHRONIC: Prolon'e# e;/o%$re a&oAe the OSHA /er.i%%i&le e;/o%$re li.it% .ay re%$lt in liAer an# >i#ney #a.a'e. Pr$#ent han#lin' /ractice% %ho$l# &e 3ollo?e# to .ini.i8e h$.an e;/o%$re. CARCINO"ENICITY: In a National Cancer In%tit$te &ioa%%ay! little i3 any e33ect ?a% o&%erAe# in rat% &$t he/atocell$lar carcino.a% ?ere B$ite co..on in &oth %e;e% o3 .ice 3e# hi'h #o%e%. A %$&%eB$ent %t$#y inAe%ti'atin' the /o%%i&le #i33erence% in .eta&oli%. 3o$n# that .ice .eta&oli8e# trichloroethylene to a .$ch 'reater e;tent than other %/ecie%. A##itionally! #ata 3ro. thi% %t$#y %ho?e# that t$.or 3or.ation occ$rre# Aia a non'enetic .echani%.. The Science A#Ai%ory Goar# o3 the EPA ha% %$''e%te# ca$tion in concl$#in' 3ro. ani.al %t$#ie% that trichloroethylene /re%ent% a ri%> o3 h$.an cancer &eca$%e o3 the ne'atiAe e/i#e.iolo'y %t$#ie% an# al%o &eca$%e o3 .eta&oli%. studies showing differences between the human and mouse response. MUTA"ENESIS: =hen actiAate# ?ith .icro%o.al en8y.e%! trichloroethylene ha% &een %ho?n to &e ?ea>ly /o%itiAe in certain .icro&ial .$ta'en te%t %y%te.% EPIDEMIOLO"Y: In a retro%/ectiAe cohort %t$#y o3 (,!,)+ /eo/le 3ollo?e# 3or at lea%t *6 year%! the inAe%ti'ator% concl$#e# that e./loyee% occ$/ationally e;/o%e# to trichloroethylene #i# not %ho? any %i'ni3icant a%%ociation &et?een %eAeral .ea%$re% o3 e;/o%$re to trichloroethylene an# any e;ce%% o3 cancer. REPRODUCTI<EDDE<ELOPMENTAL: Trichloroethylene ?a% not e.&ryoto;ic or terato'enic in rat% or .ice inhalin' the co./o$n#. In a teratolo'y-re/ro#$ction %t$#y con#$cte# &y NTP! rat% an# .ice 3e# .icroenca/%$late# trichloroethylene at #o%e% a% hi'h a% 011 .'D>'D#ay 4rat%5 an# +)1 .'D>'D#ay 4.ice5 %ho?e# little e33ect.

12.

ECOLOGICAL INFORMATION

ECOTOIICOLO"ICAL INFORMATION: Sli'htly to;ic to aB$atic li3e. Shee/%hea# Minno?% - :6-ho$r LC)1 - )* .'D( My%i# Shri./- :6Cho$r LC)1- (, .'D( Pa'e ) o3 +

Marine Al'a - :6-ho$r EC)1 - :) .'D(

1!. 1".

DISPOSAL

CONSIDERATIONS

DISPOSAL METHOD:

TRANSPORT INFORMATION
Trichloroethylene 6.( 4To;ic5 Ill UN(+(1

Pro/er Shi//in' Na.e: Ha8ar# Cla%%: UN N$.&er: Pac>in' "ro$/:

Conta.inate# %an#! %a?#$%t! Aer.ic$lite! %oil or /oro$% %$r3ace .$%t &e #i%/o%e# o3 in a /er.itte# ha8ar#o$% ?a%te .ana'e.ent 3acility. RecoAere# liB$i#% .ay &e re/roce%%e# or incinerate# or .$%t &e treate# in a /er.itte# ha8ar#o$% ?a%te .ana'e.ent 3acility. =a%te .aterial .$%t &e #i%/o%e# o3 in accor#ance ?ith 3e#eral! %tate! /roAincial! an# local enAiron.ental control re'$lation%. E./ty container% %ho$l# &e recycle# or #i%/o%e# o3 thro$'h an a//roAe# ?a%te .ana'e.ent 3acility.

USA-RM! Ha8ar#o$% S$&%tance an# M$antity: >'. Marine Poll$tant: None

(11 l&%.D,).,

15.

REGULATORY

INFORMATION

USA TSCA: All co./onent% o3 thi% /ro#$ct are li%te# on the TSCA InAentory. EUROPE EINECS: All co./onent% in thi% /ro#$ct are li%te# on EINECS. CANADA DOMESTIC SUGSTANCES LIST 4DSL5: Thi% /ro#$ct an#Dor all o3 it% co./onent% are li%te# on the Cana#ian DSL. AUSTRALIA AICS: All co./onent% o3 thi% /ro#$ct are li%te# on AICS. FOREA ECL: All co./onent% in thi% /ro#$ct are li%te# on the Forean E;i%tin' Che.ical% InAentory 4FECI5. QAPAN MITI 4ENCS5: All co./onent% in thi% /ro#$ct are li%te# on the Qa/ane%e E;i%tin' an# Ne? Che.ical S$&%tance% 4ENCS5 che.ical inAentory. PHILIPPINES PICCS: All o3 the co./onent% in thi% /ro#$ct are li%te# on the Phili//ine% InAentory o3 Che.ical% an# Che.ical S$&%tance% 4PICCS5. SARA TITLE Ill: SARA 40((! 0(*5 Ha8ar# Cla%%: Ac$te Health Ha8ar#. Chronic Health Ha8ar#. SARA 40(05 Che.ical%: Li%te#. SARA E;tre.ely Ha8ar#o$% S$&%tance: Not li%te#. Pa'e 9 o3 7

CERCLA Ha8ar#o$% S$&%tance: Li%te# in Ta&le 01*, o3 ,1 CFR Part 01* a% a ha8ar#o$% %$&%tance ?ith a re/orta&le B$antity o3 (11 /o$n#%. Relea%e% to air! lan# or ?ater ?hich e;cee# the RM .$%t &e re/orte# to the National Re%/on%e Center! 211-,*,-221*. RCRA: =a%te trichloroethylene an# conta.inate# %oil%D.aterial% 3ro. %/ill clean$/ are U**2 ha8ar#o$%

Pa'e 10 o3 7

PP":

112) Trichloroethylene

((D*6D*11*

?a%te a% /er 40 CFR 26t33 an# .$%t &e #i%/o%e# o3 accor#in'ly $n#er RCRA CALIFORNIA PROPOSITION 65:

cause cancer.

Thi% /ro#$ct i% a che.ical >no?n to the State o3 Cali3ornia to Al%o contain% &$tylene o;i#e 4CAS No. (16-22-+5.

NQ RI"HT-TO-FNO= LIST:

CANADA RE"ULATIONS 4=HMIS5: Cla%% 1(G- To;ic Material%. Sen%iti8ation to /ro#$ct: None >no?n. O#or thre%hol#: A//ro;. 21 //.. Pro#$ct $%e: #e'rea%in' %olAent.

16.

OTHER

INFORMATION

The 3ollo?in' ha% &een reAi%e# %ince the la%t i%%$e o3 thi% MSDS: Date. E#ition. Section 3 ha% &een $/#ate#. Section 8 ha% &een $/#ate#. Section 13 ha% &een $/#ate#. Section 14 ha% &een $/#ate#. Section 15 ha% &een $/#ate#.

Previous revision date: PreAio$% e#ition n$.&er:

NA N Not AAaila&le

1:D*+D*11(

16

Pa'e 11 o3 7