Hunan Zhongchuang Chemical Co., Ltd. MATERIAL SAFETY DATA SHEET 1.

Product and Company Identification Product Sec-butyl acetate Synonyms 2-butanol acetate Molecular formula C6H12O2 Molecular mass 116.16 CAS Number 105-46-4 O CH3 Structrural formula CH3 C O CHCH2CH3 Hazard class the 3.2 species intermediate flash point flammable liquid Chemic species Acetate 2. Composition / Information on Ingredients Main basis 97.5% Appearance& Odor Clear, colorless mobile liquid; fruity odor Product Use Solvent for inks & printing, paints & coatings; process solvent;

other uses. 3. Hazards Identification Routes of exposure Skin, eyes, inhalation, ingestion. Potential health effects May cause eye and respiratory tract irritation, have the anaesthesia function. Dry skin. 4. First Aid Measures Skin: Remove contaminated clothes. Rinse and then wash skin with water and soap. Eyes: Immediately flush eyes with plenty of water. Get medical attention. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Ingestion: Rinse mouth. Refer for medical attention. 5. Fire Fighting Measures Combustibility flammable Flash point() 31

Generated by Foxit PDF Creator . Foxit Software http://www.foxitsoftware.com For evaluation only. Explosure lower limit(%) 1.5 Explosure upper limit(%) 15.0 Hazard identity Flammable. The vapour mixes well with air, explosive mixtures are easily formed. React with strong oxidants, strong bases, strong acids and nitrates, causing fire and explosion hazard. Vapor is heavier than air and can travel considerable distance to a source of ignition and flashback. Fire Fighting Instructions Water spray, dry chemical, chemical foam, dry powder, carbon dioxide. Water may be ineffective, but chould be used to cool fire-exposed structures and vessels.

6. Accidental Release Measures Keep unnecessary people away; isolate hazard area and deny entry. Ventilation. Eliminate ignition sources. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do not wash away into sewer (extra personal protection: a filter for organic vapours). Avoid run-off into storm sewers and ditches leading to waterways. If required, notify state and local authorities. Place leaking containers in well-ventilated area. Clean up small spills by using a nonflammable absorbent or flushing sparingly with water. Contain larger spills with nonflammable diking or absorbent. Clean up by vacuuming or sweeping. 7. Handling and Storage Keep container in a cool, well-ventilated area away from heat. Keep away from heat, sparks and flame. Keep the area temperature lower than 30. Prevent the sunlight perpendicular incidence. Keep container tightly closed and sealed until ready for use. Separated from strong oxidants, strong bases, strong acids. Avoid all possible sources lighting and material handling) equipment with the switch outside the of ignition (spark or flame). Use explosion-proof

electrical (ventilating, house. Provide the corresponding variety and the quantity fire equipment. Avoid using any tool or mechanical device which may produce spark. A periodic inspection is necessary to make sure that divulge phenomenon is excluded. Pay attention to the speed of flow when fill it to container (not to surpass 3 m/s). Containers should be bonded and grounded for transfers to avoid static sparks. Load and unload lightly when transport, prevent damaging the packing and the vessel. 8. Exposure Controls / Personal Protection China MACmg . m3No data Soviet Russia MACmg . m3200 America TVL-TWA OSHA 200ppm950mg . m3 ACGIH 200ppm950mg . m3

Generated by Foxit PDF Creator . Foxit Software http://www.foxitsoftware.com For evaluation only. America TLV-STEL No data Monitoring Methods Engineering Controls Closed system, ventilation. A safety shower and eyebath should be readily available. Respiratory Protection wear a self-filters gas mask (half face guard), Use self-contained breathing apparatus with full face piece or any respirator specifically approved for escape. Eye/face protection Use chemical safety goggles. Hand protection Protective gloves. Body Wear clothes that guard against the static electricity. Else No smoking in working place, take a shower after work, pay attention to the individual cleaning. 9. Physical and Chemical Properties Melting/Freezing Point -98.9 Boiling Point 112.2 Relative Vapor Density (water=1) 0.86 Relative Vapor Density (air=1) 4.0 Vapor PressureMPa 2.0025 Octanol/water partition coefficient as log pow 1.51 Flash point() 31 Solubility

Do not dissolve in the water, may mix dissolves in most organic solvent such as the ethyl alcohol, the ether and so on. 10. Stability and Reactivity Stability Stable Conditions to Avoid Avoid heat , flames, sparks, and other sources of ignition. Incompatibility Keep away from peroxides and other polymerization initiators, oxidizing agents such as nitric acid, perchloric acid, chromium trioxide, chlorosulfonic acid, silica gel, alumina, strong acids or amines. Hazardous combustion or decomposition products Thermal decomposition products may include oxides of carbon. Hazardous Polymerization Hazardous polymerization will not occur.

Generated by Foxit PDF Creator . Foxit Software http://www.foxitsoftware.com For evaluation only. 11. Toxicological Information Acute Exposure LD50 LC50 12. Ecological Information May do harm to the environment ,do pay attention to the water. 13. Disposal Considerations Dispose of spilled material in accordance with state and local regulations for hazardous waste. Recommended methods are incineration or biological treatment at a federally or state-permitted disposal facility. Note that this information applies to the material as manufactured; processing, use, or contamination may make this information inappropriate, inaccurate, or incomplete. Note that this handling and disposal information may also apply to empty containers, liners and rinsate. State or local regulations or restrictions are complex and may differ from federal regulations. This information is intended as an aid to proper handling and disposal; the final responsibility for handling and disposal is with the owner of the waste. 14. Transport Information Hazard Regulation Number 32130 UN Number 1123 Packing Group Packing Mark 7 Packing Measure Small aperture steel barrel, thread mouth glassplastic jar. 15. Regulatory Information Commonly used dangerous chemical classification and symbol (GB13690-92) divides this material into 3.2 kind of flash point flammable liquid. 16. Other Information For industrial use only. The information contained herein is accurate to the best of our

knowledge. We do not suggest or guarantee that any hazards listed herein are the only ones which exist. Hunan Zhongchuang Chemical Co., Ltd. makes no warranty of any kind, express or implied, concerning the safe use of this material in your process or in combination with other substances. Effects can be aggravated by other materials and/or this material may aggravate or add to the effects of other materials. This material may be released from gas, liquid, or

Generated by Foxit PDF Creator . Foxit Software http://www.foxitsoftware.com For evaluation only. solid materials made directly or indirectly from it. User has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated. User must meet all applicable safety and health standards. Possession of an Internet MSDS does not indicate that the possessor of the MSDS was a purchaser or user of the subject product.