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Kimia P3 SBP Mid Year SPM 2008
Kimia P3 SBP Mid Year SPM 2008
……
4541/3
Kimia
Kertas 3
Mei
2008
1½ Jam
SEKTOR SEKOLAH BERASRAMA PENUH
KEMENTERIAN PELAJARAN MALAYSIA
_______________________________________________
KIMIA
KERTAS 3
1 18
2 15
3 17
JUMLAH 50
Marks awarded:
Mark Description
4541/3 2 SULIT
SULIT
1. An experiment was conducted to find out the effect of temperature on the rate of reaction.
50 cm3 of sodium thiosulphate solution 0.2 mol dm-3 at 30 oC was put into a 150 cm3
conical flask. Then the conical flask was placed on an “X” sign on a piece of white paper.
5 cm3 of sulphuric acid 1.0 mol dm-3 was added to the sodium thiosulphate solution and
shaken. At the same time, the stop watch was started. The stop watch was stopped as
soon as the “X” sign was no longer visible. The same steps of the experiment were
repeated for sodium thiosulphate solution which was heated to 35oC, 40oC, 45oC and
50oC.
Diagram 1 shows the reading of the stop watch for each of the reaction at different
temperatures.
(a) Record the time for each reaction in the spaces provided in Diagram 1.
[3 marks]
4541/3 3 SULIT
SULIT
……………………………………………………………………………………
……………………………………………………………………………………
[3 marks]
(c) Construct a table and record temperature, time, and 1/ time for this experiment.
[3 marks]
(d) (i) Plot a graph of temperature of sodium thiosulphate solutions against 1/ time.
[3 marks]
4541/3 4 SULIT
SULIT
4541/3 5 SULIT
SULIT
(ii) Based on the graph in (d) (i), state the relationship between the rate of reaction
and temperature.
……………………………………………………………………………….
………………………………………………………………………………
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[3 marks]
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4541/3 6 SULIT
SULIT
2. The pupil carried out an experiment to construct the electrochemical series of metals
using 0.5 mol dm-3 copper(II) sulphate solution as the electrolyte.
Cu Y
Diagram 2
Table 2 shows the voltmeter readings of each cell that obtained from the pairs of metals.
Table 2
…………………………………………………………………………………
…………………………………………………………………………………
[ 3 marks ]
4541/3 7 SULIT
SULIT
(ii) Based on the change in size that you observed at the magnesium electrode after
30 minutes, state the inference.
…………………………………………………………………………………
…………………………………………………………………………………
…………………………………………………………………………………
[ 3 marks ]
(b) Predict the voltmeter readings of the cell when zinc and lead metals are used.
…………………………………………………………………………………………
[ 3 marks ]
(c) Based on Table 2, arrange the metals zinc, iron, magnesium, lead and copper
in an ascending order based of their tendency to release electron.
…………………………………………………………………………………………
…………………………………………………………………………………………
…………………………………………………………………………………………
[ 3 marks ]
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[ 3 marks ]
4541/3 8 SULIT
SULIT
Beaker A Beaker B
Diagram 3
You are told that the two colourless solutions are calcium nitrate and magnesium nitrate. You are
required to label correctly the name of each solution in the containers.
Design an experiment to identify which is calcium nitrate and which is magnesium nitrate
solution by using aqueous of ammonia solution as a reagent.
[17 marks]
4541/3 9 SULIT
SULIT 4541/1/2/3
4541
Chemistry
Marking Scheme
Mei
2008
BAHAGIAN SEKOLAH
KEMENTERIAN PELAJARAN MALAYSIA
______________________________________________
PEPERIKSAAN PERTENGAHAN TAHUN 2008
FORM 5 CHEMISTRY
1
PAPER 1
1 B 21 D 41 D
2 C 22 D 42 B
3 B 23 B 43 D
4 C 24 A 44 C
5 D 25 C 45 B
6 A 26 A 46 A
7 B 27 D 47 B
8 A 28 A 48 D
9 D 29 C 49 C
10 D 30 A 50 B
11 D 31 A
12 C 32 B
13 A 33 D
14 A 34 A
15 C 35 C
16 B 36 A
17 C 37 D
18 C 38 B
19 C 39 B
20 C 40 D
2
PAPER 2-SECTION A
1 a G 1
Has stable /octet electron arrangement//8 valence electron 1
c G,E,D, A,J,L 1
3
3 a (i) 3H2 + N2 2NH3 1
(ii) ( Extract from ) air 1
b (i) Neutralization 1
(ii) H2SO4+ 2NH3 (NH4)2SO4 1
//H2SO4+ 2NH4OH (NH4)2SO4 + H2O
(iii) Fertilizer 1
c (i) Tin 1
(ii)
Copper atom
Copper atom Tin atom
(1+1)
d In pure copper the layer of atom are easily slide over each
other when external force is applied on them. 1
The different size of foreign atoms in allloy are prevent the
layers of atom from slide each other when external force is 1
applied.
TOTAL 10
4 a 1 Diagram of set up of apparatus complete and functional 1
2 Label
(Anode) – impure copper and (cathode )– pure copper 1
3 ( Electrolyte) – copper (II) sulphate / copper (II) chloride // copper
(II) nitrate solution 1
a: chemical formula
4
ions at the anode is the same as the rate of discharge of Cu2+ at
cathode. 1
c (i) 1
Rate of reaction in experiment II is higher than experiment I
(ii) The concentration/number of molecule per unit volumeof 1
hydrogen peroxide in II is higher
1
The frequency of collision between H2O2 molecule is higher
1
The frequency of effective collision is higher
d Volume of gas/cm3
II
Time(s)
1
Label Y axes and X axes 1
Correct curve and label I and II
TOTAL 10
5
6 a A compound that contain element of carbon and derive from living 1
organisms.
b (i) C2H4 1
(ii) ethene 1
(iii) double bond between carbon atoms 1
(a: C=C )
c (i) Acidified potassium manganat (VII) // Acidified potassium 1
dicromate (VI)
(ii) Oxidation 1
(iii) Purple to colourless // orange to green 1
6
SECTION B
(ii)
Compound that form between non metal atom by sharing their
valence electron to achieve stable/octet /duplet electron
1
arrangement
b Between P and Q
Atom X has 1 valence electron
1
+
Atom X loses/donates/transfers 1 electrons to form X ion //
X X+ + e- and attain stable octet electron arrangement 1
Atom Y has 7 valence electrons
1
Atom gains/receives/accept 1 electron to formY- ion// 1
Y + e-Y-
attain the stable /octet electron arrangement 1
The two oppositely-charged ions// the X+ and Y- ion are
bonded together by a strong electrostatic force 1
To form a ionic compound with the formula XY// diagramn 1
Max 7
7
(ii)
Between Y and Z
Atom Z has 4 valence electrons and atom Y has 1 valence 1
electrons
One atom Z contributes 4 electrons and (each) atom Y
1
contributes one electron for sharing .
Atom Z shared 4 pairs of electron with 4 atoms Y 1
1
to attain a octet /stable electron arrangement respectively 1
diagram
Z Y
Y
(iii)
Magnesium oxide is an ionic compounds 1
8
TOTAL 20
8 a Empirical formula- Formula shows simplest ratio of atoms of each
1
element in the compound
Molecular formula- Formula shows actual number of atoms of
1
each element in the compound
b
Molecular Formula = ( Empirical formula )n
= ( CH2 )n
9
Element Z O 1
Empirical Formula ZO 1
TOTAL 20
10
PAPER2 –SECTION C
No Rubric Mark
9 a Sample answer :
Zn + HNO3 Zn(NO3)2 + H2O
ZnCO3 + HNO3 Zn(NO3)2 + H2O + CO2
ZnO + HNO3 Zn(NO3)2 + H2O
Any two 2
c(i) Procedure :
11
(ii) ZnCO3 + H2SO4 ZnSO4 + H2O + CO2 1
TOTAL
20
10a (i) catalyst 1
esterification
(ii) 1
(iii) CH3COOH + C3H7OH CH3COOC3H7 + H2O
Correct reactant 1
Correct product
1
(iv)
Ethyl propanoate
Sweet smell/fruity smell/fragrant smell
//insoluble in water/soluble in organic solvent
//colourless
//less dense than water
2
any two properties (1+1)
(v)
12
Bacteria will produce lactic acid/H+ ions which neutralize
b (i)
negatives charge of the protein membrane/ rubber molecules
1
The rubber molecules will be collide with each other and
1
cause protein membrane broken
Rubber polymer are released and lump together
1
or
Resistant to oxidation :
The presence of cross-linkage of sulphur atoms between
the rubber molecule
1
Diagram
1
C=C in vulcanized rubber is less than C=C in the
unvulcanized rubber, 1
so vulcanize rubber is more resistant to oxidation
1
TOTAL
20
13
PAPER 3
[Able to record all the times accurately but without units / no decimal place] 2
t1 55.0 , t2 48.0 , t3 42.0 , t4 37.0 , t5 33.0 //
// t1 55 s , t2 48.0 s , t3 42 s, t4 37s, t5 33s
Suggested answer:
Temperature, 30 35 40 45 50 3
o
C
Time , s 55.0 48.0 42.0 37.0 33.0
1 / time , s-1 0.018 0.021 0.024 0.027 0.030
[Able to construct a table correctly containing three labeled columns with 2
correct units and record all the time and 1/time but not accurately]
14
EXPLANATION SCORE
[Able to draw a graph accurately that consists of the following aspects] 3
Suggested answer:
15
Temperature /oC
50 X
45 X
40 X
35 X
30
X
0.015 0.020 0.025 0.030 1/time , s-1
16
1(e) KK0510 - State variables
EXPLANATION SCORE
[Able to state three variables and three action to be taken]
Suggested answer:
[Able to state any one variables and any one action to be taken] 1
Mg + Cu2+ Mg2+ + Cu
Mg + CuSO4 MgSO4 + Cu 2
Mg Mg2+ + 2e // Cu2+ + 2e Cu 1
No response given / wrong response 0
17
2(b) KK 0505 - Predicting
EXPLANATION SCORE
[Able to state the voltage value] 3
0.65 V
0.63 – 0.64 V // 0.66 – 0.67 V 2
< 0.64 V // > 0.67 V 1
No response given / wrong response 0
[Able to arrange the position of at least four metals in ascending order based 1
on tendency to release electrons correctly]
The further the metal is from copper in the electrochemical series, the greater
is their voltage reading. //
The further apart the metal is in the electrochemical series, the greater the
potential difference / voltage reading.
18
3.(a) KK051021 – Statement of problem
EXPLANATION SCORE
[Able to make a suitable statement of problem] 3
Suggested answer:
EXPLANATION SCORE
[Able to state all the three variables correctly]
Suggested answer:
Manipulated variable : magnesium nitrate and calcium nitrate // Mg2+ and Ca2+
Responding variable: formation of white precipitate
Controlled variable : aqueous ammonia solution
[Able to state any two of the variables correctly]
[Able to state one of the variables correctly or state idea regarding variable]
19
3(d) KK051205 – List of substances and apparatus
EXPLANATION SCORE
[Able to state the list of substances and apparatus correctly and completely] 3
Suggested answer:
Test tube
0.5 mol dm-3 magnesium nitrate solution, 0.5 mol dm-3 calcium nitrate
solution, aqueous ammonia solution.
[Able to state an idea about the list of substances and apparatus] 1
Suggested answer:
Test tube
magnesium nitrate, calcium nitrate
No response given / wrong response 0
EXPLANATION SCORE
[Able to state a complete experimental procedure] 3
Suggested answer:
1. 2 cm3 of solution A is poured into a test tube.
2. A few drops of aqueous ammonia solution are added into the test tube
using a dropper and the test tube is shaken well.
3. If the precipitate is formed, aqueous ammonia solution is added
continuously until no further change occurred / until excess
4. The mixture is shaken well.
5. The changes occur is recorded in a table.
6. Steps 1 to 4 are repeated using solution B.
20
3(f) Tabulation of data
EXPLANATION SCORE
[Able to exhibit the tabulation of data correctly ]
Reagent Observation
Test tube/Solution A Test tube/Solution B
Aqueous
ammonia solution 3
21