Chemistry 4B: Worksheet 1 (1/23-1/30)

This is the first in a series of worksheets intended to guide your learning of pertinent information in the 4B course. The questions and exercises are organized according to chapter. It would be wise of you to read the chapter prior to attempting the relevant questions. This will allow you to determine the amount of information you understood and retained from the chapter and it will allow you to assess what information you should focus on in depth. I will post solutions to the worksheets the following weekend from posting. !ll chapters are from "arris unless otherwise noted. If you have any questions from the worksheet or in general feel free to e#mail me at bmcnicholas$4%berkeley.edu "appy studying& Chapter 0:
'xercise () *rovide definitions for the following key terms from the chapter a. +ualitative !nalysis) b. +uantitative !nalysis) c. ,alibration ,urve) d. -tandard -olution) e. "omogeneous -olution) f. "eterogeneous -olution)

Chapter 1:
'xercise () *rovide definitions and relevant equations for the following terms) a. .olarity) b. .olality) c. 'lectrolyte)

d. -olute) e. -olvent) f. /eight *ercent) g. *arts *er .illion) h. *arts *er Billion) i. 0ilution) 1. *rimary -tandard) k. Back Titration) l. 0irect Titration) 'xercise 2) 3egina 4eorge is analyzing her new nail polish for dibutyl phthalate 5.olecular /eight) 26$.74g8mol9 a chemical that can potentially cause reproductive issues. !fter analyzing (:m; 5assume an aqueous solution9 of the polish she finds that it contains <.<:<mg of 0B*. a. /hat is the molarity of 0B* in this sample of nail polish=

b. If the density of this solution is <.>6g8m; what is the concentration of the 0B* in parts per million= c. If she wants to make a dilution that reduces the molarity of the 0B* to <.7< of its initial value what volume of water must she add=

d. !ssuming the same density as above for the (:m; of the solution what is the percent composition of 0B* in this solution=

In an unrelated experiment 3egina wants to produce her own 0B* by reacting n#butanol 564.(2g8mol9 with phthalic anhydride 5(4$.(g8mol9. e. !ssuming these react in a two#to#one ratio what amount of each reactant is necessary to produce <.<:<mg of 0B* if the reaction goes to completion=

f. !fter performing the reaction 3egina discovers that the reaction results in only <.<76mg of 0B*. /hat is the percent yield in this reaction=

Chapter 2:
'xercise () *rovide definitions for the following terms) a. !dsorption)

b. !bsorption)

c. .eniscus)

d. *arallax)

Chapter 3:
'xercise () *rovide definitions for the following terms) a. -ystematic80eterminate 'rror)

b. 3andom8Indeterminate 'rror)

c. *recision)

d. !ccuracy)

'xercise 2) *rovide the number of significant figures for the following numbers and for the calculations provide the answer with the appropriate number of significant figures. a. 7.<<< b. <.<<<<<<: c. 2.4:? (<: d. :.::?x(<.227: e. :.(74:@2.7 f. log5::<9 g. p"A6.< 'xercise 7) Bor the following numbers calculate the uncertainty using the operation indicated) (.7:?5 <.<74 (.2$(5 <.<($ (.4?:5 <.<?2 (.4225 <.<27 9 5The numbers below refer to these 4 numbers9 a. !ddition)

b. .ultiplication)

c. !ddition of ( and 2 multiplied by 4

d. !ddition of 2 and 4 multiplied by 7

e. !ddition of 2 and 7 divided by 4 then added to (

'xercise 4) 4iven the following number perform the indicated operations on it and calculate the uncertainty of the result. 2.:6$5 .27$ a. Take the logarithm of the number)

b. Take the natural logarithm of the number)

c. Take e to the power of the number)

Chapter 11:
'xercise () *rovide definitions for the following terms a. ;ewis !cid)

b. ;ewis Base)

c. ,helating ;igand)

d. ,helate 'ffect)

e. .onodentate ;igand)

f. Bormation ,onstant)

g. .asking !gent)

h. Indirect Titration)

i. 0isplacement Titration)

1. .asking !gent)

k. ,omplexometric Titration)

l. .etal#Ion Indicator)

'xercise 2) "ow many protons are present on '0T! at the following p" values 5"int) Cou can use a table&9 a. p"A: b. p"A6 c. p"A> 'xercise 7) '0T! Titrations& Cou have a :<m; solution containing both <.<4. "f4@ and <.<:. Tl@ at a p" of :.<<. !nswer the following questions concerning the solution) a. /hich metal will react with '0T! more favorably and why= 5"int) Cou can use a table&9 b. /rite the conditional formation constant for the reaction that will occur when the solution is titrated with '0T!

c. The solution is then titrated with <.<2. '0T!. ,alculate the concentration of the more favorable metal at (< 2: :< and 6:m; of '0T! added and determine the volume of '0T! solution that corresponds to the equivalence point.

'xercise 4) Back titrations are sometimes necessary to analyze the amount of metal in a solution. a. 4ive a reason why a back titration should be performed on a solution of a particularly difficult metal.

b. 'xplain the method for performing a back titration.

Chapter 22:
+uick definition& /hat is the partition coefficient=

'xercise () Back to 3egina 4eorge& -ay the partition coefficient for 0B* is 2: for ethyl acetate to water. !nswer the following questions for :<m; of a <.<:. solution of 0B*. a. If 3egina performs ( separation of the 0B* solution with 2:m; of ethyl acetate what is the mass of 0B* now in the ethyl acetate layer=

b. 0oes the ethyl acetate layer lie above or below the aqueous layer= /hy=

c. If 3egina performs the separation of the layer with another 2:m; of ethyl acetate how much 0B* 5in mg9 remains in the aqueous layer=

d. Dow 3egina wants to test the efficiency of extraction based on number of extractions and volume of extraction liquid. If she performs one extraction with :<m; of ethyl acetate and the original solution what can you say about the ideal way to separate given the results from the above parts=

10.1-10.3 (Oxtoby)
'xercise () Bor each compound indicate all forms of intermolecular forces present and the dominant force. !lso provide a definition for all of the forces that you use in the exercise. a. 3bB b. "exane c. /ater d. ,opper e. ",l f. Br2 g. ,E 0efinitions)

'xercise 2) ! ,lassic +uestion& /hy do ,l2 Br2 and I2 all differ in their states of matter=