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Membrane Process For Desalination and Water Reuse
Membrane Process For Desalination and Water Reuse
Membrane Process For Desalination and Water Reuse
Membrane Processes for Desalination
and Water Reuse
and Water Reuse
Raphael Semiat
1
2004 Water deficiency
1 5B
1.5B
2004
3B2025
2004 2025
Source: Seckler et al, 2002
2
Driving Forces for Water R&D
Related
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Need for Water
Global need, Industry, Agriculture, Remote
L ti
Locations, Desertification,
D tifi ti Et
Etc.
Cost Difference - (Industry/Urban - Agriculture)
C t Diff
Cost Difference - (Thermal
(Th lPProcesses - Membrane
M b Processes)
P )
Technologies for Export
3
RDL GWRI Technion 3
RO DESALINATION
Large
g plants:
p NAHAL TANINIM (1997) MIZPE SHALEM ((1983))
BRACKISH (SURFACE) WATER 50 m3/day
GROFIT (1974)
RO DESALINATION 50 m3/day
4
SDE UVDA 2 (1980)
500 m3/day (RESERV.) 4
Eilat Plants
Eilat Plants
Sabha A: 25,500m3/day BW
Sabha B: 10,000 BW
Sabha C: 10,000 SW
RDL
5 GWRI Technion
5
cent/m3 - feed water Initial Design Actual Design Changes
%
Investment 4.0 2.6 -35.0%
Ch i l
Chemicals 58
5.8 24
2.4 -58.6%
58 6%
- HCl 2.96 1.85 -37.5%
- NaHSO 3 1.16 -100.0%
Operational - FeCl3 0.70 0.34 -51.7%
- NaOCl 0.99 0.22 -78.1%
Experience:
9.8
-78.1%
Saving on - NaOCl
-51.7%
10.0 - FeCl3
chemicals
chemicals. C
H N HSO3 -100%
- NaHSO3 100%
9.0 E - HCl -37.5%
M
Eilat plants 8.0 I
C
5.8 A
7.0 L
cent//m - feed water
S 5.0
6.0
-58.6%
5.0
3
I
40
4.0 N 24
2.4
V
E
3.0 S
T
4.0 M
2.0 E
-35.0%
N
2.6
1.0 T
0.0
Initial Design Actual Design
7
Ashkelon Plant
100,000.000 M3/year
8
Reverse Osmosis ‐ Membrane Desalination
10
RDL GWRI Technion Picometer 10-12 m Femtometer 10-15m …
Significant membrane properties
Main Characteristic properties:
p p
Selectivity Membrane thickness,
Permeability P
Permeability,
bilit rejection,
j ti
Mechanical stability (creep and compaction) Size, size distribution
Anti fouling treatment
Anti-fouling
Chemical
h i l Stability
bili (Hydrolytic
( d l i stability,
bili
Catalitic reactivity.
Organic material stability, pH,
Microbial resistance, Cl2 attack, etc.
•Surface anti-fouling properties
(Phtalates, cellulose acetate, Chlorine in water, NaOH in
cleaning,
IInitial
iti l fluxes
fl reduction,
d ti suspended
d d materials
t i l andd
precipitants (CaCO3, CaSO4, SiO2, CaF2, SrSO4, BaSO4,
RDL GWRI Technion
etc.)
Expensive product, 50/50 mm. A tool for production of the cheapest
product on Earth, 5-6 m2
12
Spiral Wound
Membranes
membranes thickness-
200 nm and down
down.
Holes size and size
distribution,, membrane
properties
RDL
13 GWRI Technion
Bio-Fouling
14
RDL GWRI Technion
Man made polluted waters: Industrial, agriculture and urban effluents
Secondary
treatment
Sludge/ solids
treatment
Adsorption
Reverse-Osmosis Polishing
Concentrate disposal
15 or Nano-Filtration
RDL GWRI Technion
16 RDL GWRI Technion
Prof. Moris eizen
17
Performance of new membranes
40
ejection (%)
30
20
Re
10
0
1 2 3 4 5 6 7
membrane type
18
Module view and sampling
3 2 1
7 6 5 4
11 10 9 8
15 14 13 12
18 17 16
19
Energy usage in Desalination ‐ comparison
Subject \ Fuel
Subject \ Fuel Gas Gasoil Heavy fuel
Heavy fuel Coal
Caloric value Kcal/Kg fuel 9000 10750 10000 7700
Caloric Value Kwht/Kg fuel 10.5 12.5 11.6 9
Electricity production (45% eff.)
Electricity production (45% eff.)
Kwhe/Kg fuel large Power station 4.7 5.6 5.2 4
Electricity production (80% eff.)
High efficiency gas turbine
High efficiency gas turbine
Kwh/Kg fuel 8.4
Capacity ‐ Seawater Desal (50%
Recovery) m3/ kg fuel
Recovery) m3/ kg fuel 1.3
1 3 16
1.6 15
1.5 12
1.2
80% efficiency 2.4
Fuel consumption/ ton
Desalinated water Kg fuel /m3
Desalinated water Kg fuel /m3 0.7
0 7 06
0.6 07
0.7 09
0.9
80% efficiency 0.4
How many km can I drive with 1
m3 Desal water fuel consumption?
m3 Desal water fuel consumption? 27
2‐7 2‐6
26
How many hours of AC ‐ single
room (2.5 Kw‐h) can I operate? 1.4
Household Energy Consumption
Electricity, transportation and desalinated water…
A small family, consumes water at a rate of 18 m3/month,
1200 KWh f l
1200 KWh of electricity /month, Drives 1500 km/month, consumes
i i / h Di 1500 k / h
160 liter gasoil/month
Energy consumption assuming only desalinated seawater used ‐
140 KWh/
140 KWh/month (fuel value)
th (f l l )
Energy consumption ‐ driving a car ‐ 1500 KWh/month (fuel value)
Energy consumption ‐ electricity ‐ 1200/0.45=2667 KWh/month
(f l l )
(fuel value)
Energy for desalination/ energy for transportation ‐
gy gy p 9.3%
Energy for desalination/ energy for electricity ‐ 2.6%
Energy for desalination/ total energy consumption ‐ 3.4%
Can we save 3 4% in our household energy consumption?
Can we save 3.4% in our household energy consumption?
Where we should put our energy for use? In water? In high energy
consuming cars? In overused AC?
Desalination and proper water usage
p p g
Other costs should be included
besides Energy
besides Energy
• Cost of water in negligible for regular household
• Cost of water is tolerable for most industries
• Cost of water is significant in agriculture
Cost of water is significant in agriculture
Make better usage of water:
– Use of greenhouses
Use of greenhouses
– Use Drip‐Irrigation – save 30‐90% of water
consumption by other irrigation techniques – reduce
consumption by other irrigation techniques reduce
the cost problem
Pushing the Limits of Desalination
R d ti off RO d
Reduction desalination
li ti process costs
t
Main directions for reducing desalination costs
M b
Membrane improvement
i
Permeability, rejection, resistance to fouling
Concentration polarization - Flow
Improvement of membrane modules
Foulingg and scalinggpprevention
Optimization of the water recovery level
The boron problem
Pretreatment – MF, UF etc.
Energy aspects
Concentrates - Environmental
23
Process optimization RDL GWRI Technion