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Titrasi Bebas Air
Titrasi Bebas Air
1. Aprotic solvents 2. Protophilic solvents 3. Protogenic solvents 4. Amphiprotic solvents Non Aqueous Titration Of Weak Acids Non Aqueous Titration Of Weak Bases
INTRODUCTION
Definition
Non aqueous titration are those in which titration of weakly acidic or basic substances are carried out using non aqueous solvents so as to get sharp end point. Non aqueous solvents the disadvantages of poor solubility and weak reactivity. Moisture and corbondioxide should be avoided using non aqueous procedures. Moisture should be held to less than 0.05%. Standardisation &titration should be carried out as far as possible at the same temperature.
following order
HCIO4> HBr>H2SO4>HCI>HNO3
The pH is 5.3. when the titration is 110% complete, the concentration of OH- is :
Or a pOH of 5.3. the pH, therefore is pH = pKW-pOH = 14.0-5.3 = 8.7 The change in pH when the titration passes from 90% to 110% completion is
with a Ks of 1 x 10 -20, the pH when the titration is 90% complete is still 5,3. however, when the titration is 110% complete is now :
Types of solvents
The solvents are divided into 4 groups
1. Aprotic solvents 2. Protophilic solvents 3. Protogenic solvents 4. Amphiprotic solvents
as benzene and chloroform. They have a low dielectric constant, do not react with either acids or bases and therefore do not favor ionization. The picric acid gives a colorless solution in benzene or toluene which becomes yellow on adding aniline shows that picric acid is not dissociated in benzene or toluene solution. This type of solvents neither accept or donate protons Ex:-Benzene , dioxan , chlorobenene,chloroform,ethyl acetate, carbon tetra chloride.
Protophilic solvent
Basic in character and react with acids to form solvated proton
HB + Sol. Sol.H+ + BAcid + Basic solvent Solvated proton + Conjugate base of acid
A weakly basic solvent has less tendency than a strongly basic one
to accept a proton. Similarly a weak acid has less tendency to donate protons than a strong acid. As a result a strong acid such as perchloric acid exhibits more strongly acidic properties than a weak acid such as acetic acid when dissolved in a weakly basic solvent.
Ex:-acetone , ether, pyridine ,liquid ammonia
Protogenic solvents
Acidic in nature and donate protons
Ex:- sulphuric acid , formic acid, propionoic acid ,acetic
anhydride etc. They have high dielectric constant and ionised Because of their strength and ability to donate protons.
Amphiprotic solvents
Have both protophilic and protogenic properties. This can accept or donate protons.
can function as a base and combine with protons donated by the perchloric acid to form protonated acetic acid., an onium ion
HClO4 H+ + ClO4CH3COOH + H+ CH3COOH2+ (onium ion)
Since the CH3COOH2+ ion readily donates its proton to a base, a solution of
equivalent amount of acetate ions are produced which have more tendency to accept protons.
Therefore, to titrate a solution of a weak base in acetic acid with
A. Potentiometric titration :
potentiometric method for the detection of the equivalence point
Indicator method:
Color changes Indicator
Crystal violet (0.5 per cent in glacial acetic acid)
Basic
violet
Neutral
blue-green
Acidic
yellowishgreen
-Naphtholbenzein (0.2 per cent in glacial acetic acid) Oracet Blue B (0.5 per cent in glacial acetic acid)
orange
purple
dark-green
pink
magenta yellow
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Ex: - alcohol,chloroform,benzene,chlorobenzene
Acidic solvents:
Ex:-Perchloric acid
Indicatores used in the titration of weak bases
bases)
A solvent such as acetic acid reacts with base, B, to yield the conjugate acid of the base, BH+, and the conjugate base anion, CH3COOB + CH3COOH BH+ + CH3COO-
The conjugate base anion can then react with perchloric acid in the following manner : The titrant reacts with the solvent, and the solvent is protonated : HClO4 + CH3COOH CH3COOH2+ + ClO4The titration reaction, with the conjugate base anion, is as follows : CH3COO- + CH3COOH2+ 2CH3COOH So that the overall reaction can be represented as : B + HClO4 BH+ClO4-
be titrated in an appropiate non aqueous solvents with a sharp end point . Ex:- acidic halides, acids,amino acids, enols(barbiturates,xanthines), phenols, pyrroles sulphonamides etc,.
1)
2) Titrant used in the titration of weak acids: Ex:-sodium methoxide, lithium methoxide, potasium methoxide ,tetrabutyl ammonium hydroxide etc. 3) Indicators used in the titration of weak acids Ex:-azo violet.thymol blue,thymolphthalein.,ONitro aniline