Sample Paper 2009 Class XII Subject Chemistry

Time: Three Hours Max. Marks: 70 General Instructions 1. All questions are compulsory. 2. %. '. (. uestion nos. 1 to ! are "ery short ans#er questions an$ carry 1 mark each. uestion nos. & to 1! are short ans#er questions an$ carry 2 marks each. uestion nos. 1& to 27 are also short ans#er questions an$ carry % marks each. uestion nos. 2! to %0 are lon) ans#er questions an$ carry ( marks each.

*. +se lo) ta,les i- necessary. use o- calculators is not allo#e$. 1. /ame the non0 stoichiometric $e-ect responsi,le -or colour in alkali hali$es. 2. A reaction is -irst or$er in A an$ secon$ or$er in 1. Ho# is the rate a--ecte$ #hen concentration o- 1 is triple$2 %. Gi"e the I+3A4 name o- 4H%4H56H74H24H24H24H24H6. '. A )roup 1' element is to ,e con"erte$ into n 89:type semi con$uctor ,y $opin) it #ith suita,le impurity .To #hich )roup shoul$ this impurity ,elon)2 (. A reaction is -irst or$er in A an$ secon$ or$er in 1. Ho# is the rate a--ecte$ #hen the concentration o- ,oth A an$ 1 is $ou,le$. *. Gi"e the structure o- : (06xohexanoic aci$. 7. In the rin) test -or i$enti-ication o- nitrate ion. #hat is the -ormula o- the compoun$ responsi,le -or the ,ro#n rin) -orme$ at the inter-ace o- t#o liqui$s2 !. ;hat type o- ,on$in) helps in sta,ili<in) the a0helix structure o- proteins. &. Aluminium crystalli<es in a cu,ic close packe$ structure. Its89= metallic ra$ius is 12( pm. 5a7 #hat is the len)th o- the si$e o- the unit cell. 5,7 Ho# many unit cells are there in 1cm% o- aluminium 10. Ho# $o you account -or molar con$ucti"ity o- stron) an$ #eak electrolyte #ith concentration2 3lot the )raphs also. 11. >xplain the >lectrophoresis #ith $ia)rams. 12. 5a7 /ame the catalyst an$ the promoter use$ in Ha,er89=s process -or Manu-acture o- ammonia. 5,7 ;hy is -erric chlori$e pre-erre$ o"er potassium chlori$e in case o- a cut ?ea$in) to ,lee$in)2 1%.5a7 Ho# is nitric aci$ o,taine$ on lar)e scale ,y 6st#al$ process2 5,7 All the ,on$s in the molecules o- 34l( are not equal. ;hy 6@ 5a7 H2A is less aci$ic than H26. 5,7 H26 is a liqui$ an$ H2A is a )as.

1'. Accomplish the -ollo#in) con"ersions: 5a7 /itro,en<ene to phenol 5,7Methanamine to >thanamine 1(. 5a7 Bluorine exhi,it oxi$ation state o- 89:1 only #hereas other halo)ens exhi,it C1. C%. C(. C7 oxi$ation states also. .#hy 5,7 Bluorine -orms only one oxoaci$. H6B 1*. Gi"e one chemical test to $istin)uish: i. Acetal$ehy$e an$ 1en<al$ehy$e ii. 1en<ophenone an$ Acetophenone 17. ;rite the mechanism o- nucleophilic a$$ition reaction in al$ehy$es. 1!. Gi"e example -or -ollo#in) name reaction: i. @eimer0Tiemann reaction ii. Dol,e89=s reaction 1&.5a7 4on$ucti"ity o- 0.002'1M acetic aci$ is 7.!&* E 100* A cm01. 4alculate its molar con$ucti"ity. I- FG0 -or acetic aci$ is %&0.( A cm2 mol01. ;hat is its $issociation constant2 5,7 ;hen a current o- 0.7(A is passe$ throu)h a 4uA6' solution -or 2( min. 0.%*&) o- copper is $eposite$ at the 4atho$e. 4alculate the atomic mass o- copper. 20. 5a7 ;rite short notes on the -ollo#in): 6r$er o- reactionH Molecularity 5,7 The rate o- a reaction qua$ruples #hen the temperature chan)es -rom 2&% D to %1% D. 4alculate the ener)y o- acti"ation o- the reaction assumin) that it $oes not chan)e #ith temperature. 21. 5a7 ;hat is the role o- $epressant in -roth -lotation metho$2 5,7 Gi"in) chemical equations explain ho# leachin) is use$ in metallur)y o- sil"er. 22.5a7 Ioes the hy$rolysis o- EeB* lea$ to a re$ox reaction2 5c7;rite the ,alance$ equations in"ol"e$ in the preparation o- 3H%. 2%. 5a7 +sin) I+3A4 norms #rite the -ormulae -or Iichlori$o ,is 5ethane01. 20$iamine7 co,alt 5III7 5,7 Ira# all the structures o- optical isomers o- J4r4l5en725/H%7K2C 5c7 Ira# $ia)ram to sho# splittin) o- $ 89: or,ital in octahe$ral crystal -iel$ 2'. 5a7 Al$ehy$es are more reacti"e than Detones to#ar$s /ucleophilic a$$ition reaction 5,7 There are t#o 89: /H2 )roup in semi car,a<i$e ho#e"er only one is in"ol"e$ in the -ormation o- semi car,a<ones. 5c7 Iurin) the preparation o- esters -rom a car,oxylic aci$ an$ an alcohol in the presence o- an

aci$ catalyst. the #ater or the ester shoul$ ,e remo"e$ as -ast as it is -orme$. 2(. 5a7 /ame the $e-iciency $iseases cause$ $ue to lack o- "itamin 1*. 5,7 ;rite the reactions #hen I0Glucose reacts #ith -ollo#in): 5i7HI5ii74oncH/6% 2*. ;rite the structure o- monomerH uses each o- 1una/. Te-lon. 1akelite. 27. >xplain the -ollo#in) terms #ith suita,le examples: 5a7 4ationic $eter)ents 5,7 Anionic $eter)ents 5c7 non0ionic $eter)ents 6@ 27. 5a7. ;hat pro,lem arises in usin) alitame as arti-icial s#eetener2 5,7Aleepin) pills are recommen$e$ ,y $octors to the patients su--erin) -rom sleeplessness ,ut it is not a$"isa,le to take its $oses #ithout consultation #ith $octor. ;hy2 5c7 ;hich tranquili<er is use$ in controllin) $epression an$ hypertension2 2!. 5a7 4alculate Molality. Molarity H Mole -raction o- DI i- the $ensity o- 20 L5 massMmass7 aqueous DI is 1.202)Mml. 5,7 >xplain alon) #ith $ia)rams the con$itions -or the /on i$eal solutions exhi,itin) 3ositi"e $e"iations. ;rite some examples o- /on i$eal solutions exhi,itin) 3ositi"e $e"iations. 6@ 6@ 2!. 5a7 6ut o- 1M solution o- Au)ar an$ 1 M solution o- +rea. #hich #ill ha"e )reater ,oilin) point2 ;hy. 5,7 A solution containin) 2.(* )m o- sulphur in 100 ) o- car,on $isulphi$e )a"e a -ree<in) point lo#erin) o- 0.%!% D .4alculate the molecular -ormulae o- Aulphur J k- o- car,on $isulphi$e N %.!% D k)Mmol Atomic mass o- A N%2 amuK 5c7 ;hat is re"erse osmosis2 Gi"e its application. 2&. Account -or the -ollo#in): 1. On. 4$ an$ H) are not consi$ere$ as transition elements. 2. Acan$ium is a transition element ,ut Oinc is not. %. Ail"er atom has completely -ille$ $ or,ital 5'$107 in its )roun$ state. yet it is transition element '. Transition metals ha"e hi)h meltin) an$ ,oilin) points. (. Transition elements exhi,it hi)her enthalpies o- atomi<ation. 6@ 2&. a7 Iescri,e Ho# 3otassium $ichromate is ma$e -rom 4hromite ore. Gi"e the equations -or the 4hemical reactions in"ol"e. 5,7 ;rite ,alance$ ionic equations -or reactin) ions to represent the action o- aci$i-ie$ 3otassium $ichromate solution on:

5i7 3otassium io$i$e solution JiiK iron 5II7 solution JiiiK H2A 5c7 The chromates an$ $ichromates are intercon"erti,le in aqueous solution $epen$in) upon pH o- the solution. %0. 5a7 3rimary alkyl hali$e 4'H&1r 5a7 reacte$ #ith alcoholic D6H to )i"e compoun$ 5,7.4ompoun$ 5,7 is reacte$ #ith H1r to )i"e 5c7 #hich is an isomer o- 5a7.;hen 5a7 is reacte$ #ith so$ium metal it )i"es 4ompoun$ 5$7.4!H1! #hich is $i--erent -rom the compoun$ -orme$ #hen n0,utyl ,romi$e is reacte$ #ith so$ium .Gi"e the structural -ormula o- 5a7 an$ #rite the equations -or all the reactions. 2. 5,7 An or)anic compoun$ 89PA89= #ith molecular -ormula 4(H(6 . It $oes not re$uce Tollen89=s or Behlin)89=s rea)ent ,ut -orms a ,isulphite compoun$. It also )i"es io$o-orm tests. I$enti-y A 6@ 5a7An or)anic compoun$ 89PA89= #ith molecular -ormula 4(H!62 is re$uce$ to n0pentane on treatment #ith On0H)MH4I. 89PA89= -orms a $ioxime #ith hy$roxylamine an$ )i"es a positi"e io$o-orm test an$ Tollen89=s test. I$enti-y the compoun$ A an$ $e$uce its structure. 5,7 An aromatic compoun$ A on treatment #ith aqueous ammonia an$ heatin) -orms compoun$ 1 #hich on heatin) #ith 1r2 an$ D6H -orms a compoun$ 4 o- molecular -ormula 4*H7/ .;rite the structures an$ I+3A4 names o- compoun$s A.1.4.