1.

TiO2

(
)(DuPont Taiwan LTD.,)

() 78 10 18
(-3(78) 053879 )
81 10 15 (-6)
83 9 8 (-7
)

72 10 13 1854

() 77 7
()77 11 18 ((77) 044417 )

()78 6 3 ((78) 15594 )(

-2)
()78 10 18 ((78) 053879 )(-3)

1-1

1.2

76 3 (75-3128
)

76 4 10 (76) 1839 (
-1)

()
( 2-3 )
566
4141-152556063646772757680 12 (
) 80
27.85 ( 26.97 )

1.3

1996 ISO 9002 2008 ISO 14001

2009 OHSAS() 18001
TSHMS()

()

(
NGO
)

1-2

()

27.8503 0.8789
26.9714
1.4 1.4-4
()
186,000

--
1.
3TiO2+3C+6Cl23TiCl4+3CO2
2.
TiCl4+O2TiO2+2Cl2
3.
()

120,000

1.3-1

1. 84.5% 93%(93/84.5)

1-3

120,000=132,070 /
2. 300 345 (345/300)
132,070=151,880 /
3.
(
) 20%
179,573 /()

1.3-1
()
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100

() 1

116,50010%
116,50010%
116,50010%
116,50010%
116,50010%
116,50010%
116,50010%
116,50010%
116,50010%
129,99610%
154,00810%
154,00810%
154,00810%
154,00810%
154,00810%

() 2

135,839
135,839
135,839
135,839
135,839
135,839
135,839
135,839
135,839
151,575
179,573
179,573
179,573
179,573
179,573

()
27,152
59,389
76,887
93,995
84,187
95,222
103,998
103,414
108,606
122,901
126,500
133,030
142,634
154,043
149,173
157,218
173,654
160,879

1
2(coating)
3%() 6%

()
()

()

( 1.3-2~1.3-3)
( 1.3-1 )

1-4

( 1.3-2~1.3-3 )

1.3-2 90~100

90
91
92
93
94
95
96
97
98
99
100

TSP

SOx

103,414
108,606
122,901
126,500
133,030
142,634
154,043
149,173
157,218
173,654
160,879

33.7
65.8
84.5
80.7
66.6
51.2
49.2
49.7
53.7
58.3
51.7

333.3
371.8
425.6
343.4
440.6
425.4
382.5
359.1
378.4
418.7
386.2

NOx
/
376.0
503.6
535.5
440.7
373.3
271.5
292.4
195.4
230.6
267.6
261.9

CO

HCl

Cl2

45.9
28.5
46.2
80.8
67.0
24.2
29.5
35.1
100.3
49.3
55.0

7.19
7.57
8.63
8.43
0.98
0.32
1.48
1.10
2.20
2.36
1.83

0.24
0.31
0.64
0.33
0.12
0.22
0.59
0.41
0.05
0.03
0.04

1.3-3 90~100

/
103,414
108,606
122,901
126,500
133,030
142,634
154,043
149,173
157,218
173,654
160,879

90
91
92
93
94
95
96
97
98
99
100

CMD
5,262
5,268
5,938
5,262
5,268
5,938
5,796
6,455
6,606
7,288
7,042

CMD
2,780
3,121
3,529
3,288
4,052
4,342
4,492
4,317
4,453
4,731
4,753

COD

BOD

26.9
54.2
73.5
59.7
58.3
58.9
59.9
47.1
49.0
64.8
52.1

5.4
5.7
6.6
11.6
11.8
8.5
16.2
10.0
12.6
7.9
13.5

SS
/
12.7
0.23
16.1
0.17
13.8
0.50
17.4
0.37
12.3
0.18
10.7
0.10
11.9
0.13
12.2
0.10
11.7
0.14
13.7
0.30
17.0
0.34

600

0.02
0.02
0.05
0.05
0.04
0.02
0.01
ND
0.01
ND
0.04

0.01
0.01
0.01
0.02
0.01
0.01
ND
ND
ND
ND
ND

180,000
170,000

500

400

150,000

300

140,000
130,000

200

160,000
TSP
SOx
NOx
CO
HCl
120,000

100

110,000

100,000
2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011

1.3-1

1-5

Cl2

NOx
6.0

4.5

5.0

4.0

4.0 3.64

3.42

3.46

KG/MT-TiO2

KG/MT-TiO2

SOx
5.0

3.31

3.5 3.22

2.98
3.0

2.71

2.48
2.5

2.41

2.41

2.41

2.40

2008

2009

2010

2011

4.64

4.36
3.48
2.81

3.0

1.90

1.90

2.0

1.31

1.47

1.54

1.63

2008

2009

2010

2011

1.0

2.0

0.0
2001

2002

2003

2004

2005

2006

2007

2001

SOx

2002

2003

2004

2005

2006

2007

NOx
Cl2

HCl
0.04

0.5

KG/MT-TiO2

KG/MT-TiO2

0.4
0.3

0.2
0.10.070 0.070 0.070 0.067

0.0023 0.0029

0.007 0.002 0.010 0.007 0.014 0.014 0.011

0.0
2001

2002

2003

2004

2005

2006

2007

2008

2009

2010

0.02

0.0052
0.0026

2011

2001

HCl

0.0038 0.0028
0.0003 0.0002 0.0003

2002

2003

2004

2005

2006

2007

2008

2009

2010

2011

Cl2
CO

TSP
1.5

1.5

KG/MT-TiO2

KG/MT-TiO2

0.0009 0.0015

0.00

1.0
0.61

0.69

0.64
0.50

0.5 0.33

0.36

0.32

0.33

0.34

0.34

0.32

1.0
0.64

0.5

0.64
0.50

0.44

0.38
0.26
0.17

0.19

0.24

2006

2007

2008

0.28

0.34

0.0

0.0

2001

2002

2003

2004

2005

2006

2007

2008

2009

2010

2001

2011

TSP

2002

2003

2004

2005

2009

2010

2011

CO

1.3-2
Fe
12.0

0.8

10.0
G/MT-TiO2

KG/MT-TiO2

SS
1.0

0.6
0.4

8.0
6.0
4.03
4.0

0.2 0.12

0.15

0.11

0.12

2003

2004

0.09

0.07

0.08

0.07

0.08

0.08

0.11

2005

2006

2007

2008

2009

2010

2011

2.27

2.0

0.0

2.76
1.55

1.33

2002

2001

SS

0.66

0.90

2006

2007

2008

2009

1.70

2.11

2002

2003

2004

2005

2010

2011

Fe
Cr+6

Cr
0.50

2.0

0.40
G/MT-TiO2

1.5

G/MT-TiO2

0.87

0.0

2001

1.0

0.5

0.70

0.20

0.16

0.20

0.12

0.38
0.20

0.30

0.32
0.13

0.25
0.06

ND

0.05

0.00

2007

2008

2009

2010

0.10

0.06

0.05

0.07

2003

2004

ND

ND

2005

2006

ND

ND

ND

0.00

0.00

2007

2008

2009

2010

2011

0.00

0.0

2001

2002

2003

2004

2005

2006

2001

2011

2002

Cr+6

Cr

1.3-3

1-6

( 1.3-4 )
20

25

18
20

103CMD
104/

14
12

15

10
8

10

M3/MT

16

2
0

0
1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011

1.3-4

(Co-product)(

TCLP
()
(SHE)

1.

2.(Corporate 2nd Party Audit)

(Corporate Standards)
NFPA
3.(

1-7

)()
4.
(Six-Sigma)

93

5.
90~99 3%
97 (APO)

98 99
100

( 2020
2010 10%)

1.4

1.4.1
(83 12 30 )

()(
)

186,000 ( 345 355

)

1.4-1

1-8

1.4.2

6 /
18.6 / 100
(78 )
( 2.2 )

( 2.1 )
100
() 1.4-1 1.4-1

186,000/

78()
60,000/

83()
120,000/

92
122,901/

100()
160,879/
(179,573/)

1.6/18.6/
2.16.1/18.6/

1.4-1 ()
1.4.3

//

1-9

1.4-1

()

1.

(Du Pont Taiwan LTD.,) 186,000

60,000 ( P.2-1)

2. 60,000

( P.2-9)
(
P.2-19)

186,000

330,150 /

24 /

1-10

23,031 /

7,924 /

()
7,900 /

7,623 /
7 /

()
15,100 /

107,000 /

106,993 /

330,150 /

330,150 /

()

( 1.
P.2-20)

186,000

()

()

76,000
210,000

17,000
45,000

2.
23,000
31,000

1
6

20,000

14,000

8,500

1 50()
6 51,000()

18,000,000()

7,300
3,800
3,400
13,000()
32,000()

1-11

( P.2-26 1. 78

27)
1. 8,150 1. 8,150
10,000 10,000

6,000 /
104942
I

R 104942

1810
2826

(M3/day) (M3/day)
(M3 / day)

W 1016
(1)
580
380
200

I 150
R 150

2800 (2)
2380
420
3470
295
1959
I 8150

8,150
2540
220
2320
6026
R 1664

350
0
350
130
/

1080
220
860
I 1758
I 1664

R 1758
1381

200
150
50
3562
1595

6,000

160
0
10 (3)
W 1078

/ 8,150
0
100
(-100)

259
229

440
0
440

/
W 30

8150
3450
4550

2.

1-12

()

2. 2,340 2. 23.4MW

1,100
3./ 130 3./
225
4. 570 4.

80 ( 27.85 1.
P2-4~P2-6 2.2-2 )

2.
83

1.
(P.2-112-18)

//
//

()

2.
83

1-13

(P.2-20)

()

1-14

(
P.2-29)

&

G1
G2
G3

G5

G4

()

( P.2-34)

HCl

NaOH

pH

pH

PH

(2)

PH

NaOH

pH

(2)

(2)

Do2~Do8

1-15

(
P.2-38)

()

(1)(2)
(3)

()

(Ilmenite)

1920 1950

1-16

59% 75%

1.(TiCl4)
()
2.(TiCl4 + O2 TiO2 + 2Cl2)
3.

1000

(CO)
(CO2)(HCl)(Cl2)(SO2)
(N2)

1-17

1.4-2 1.4-3
1.4-4

1.4-2 ()
330,150 /

7,623 /

330,150 /

330,150 /

1.4-3

1-18

1-19

1.4-4

1.4-2

1.4-2 ()

(TiO2)

84.50 min

(Al2O33H2O)

64 % min

(FeO)

9.12

(Na2O)

0.2% max

(SiO2)

1.59

(SiO2)

0.02% max

(MnO)

1.41

(Fe)

80 ppm

(Al2O3)

1.15

(MgO)

1.1

(NaOH)

45.0 ~ 45.5 %

(ZrO2)

0.34

(H2O)

55 54.5 %

(V2O5)

0.3

(NaCl)

22,000 ppm max.

(Cr2O3)

0.16

(Na2CO3)

0.5% max.

(CaO)

0.15

(Na2SO4)

400 ppm max.

(Nb2O3)

0.12

(Fe2O3)

20 ppm max.

(SrO)

0.03

(P2O5)

0.02

28 30 %

(CeO2)

0.02

9 10 %

(Fe2O3)

0.015% max.

94.0 min

4.5 max

0.2 max

99.6 min

0.5 max

0.5 max

()

1.

1-20

1.4-5
1.4-6

1.4-5 ()

N
W

E
61

S
0

2000m

61

64
61

15
15
15

66

66
15
15

66

1.4-6
2.

1-21

1.4-7

1.4-7

1.4-3

1.4-3

()
(1 6 )
()

(1)

(2)
10 mg/m3TWA(3)
1 ppmTWA

2 mg/m3

10 mg/m3TWA
0.5 mg/m3TWA(4)

(1)(U.S. DOT)=U.S. Dept. of Transportation

(2)(MSDS)
(3)TWA( 8 )
(4)()
(5)-

()

1. 8,150
10,000 1.4-8

1-22

I2 104942
2826

R1 104942
1810

W1 1016

I1 8150

3470

1959

I3 150

R2 150
295

R3 1664

6026

130

I4 1664

I5 1758

1381

1595

R4 1758
3562

W2 1078

259

229

W3 30

1.4-8

2. 2,3400kW
3./
4. 3,100 Kpa 45,000 kg/hr
6 1,890

5.

6. 180
7.

1.4-9

1-23

G1
G2
G3

G5

G4

&

1.4-9
()
(G-1)
(G-2)(G-3)(G-4)
(G-5)

1.(G-1)
1.4-10

(HCl)

()

46 33 /

1-24

1.4-10

2.(G-2)
(HCl)
(TiCl4)

3.(G-3)

4.(G-4)

( 98%)

5.(G-5)

1-25

(
98%)
6.

45,000 6 ( 0.5%)
54.9l/min

7.

8.

Cl2 2 NaOH NaCl NaOCl H 2O

3NaOCl 2 NaOH CONH 2 2 3NaCl Na2CO3 N2 3H 2O

9.

1-26

1.4-11
pH

pH

(2)

(2)

PH

pH

(2)

Do2~Do8

1.4-11

10.

11.(L-1)

()
pH

1-27

pH

12.

()(Aggregate)
(Antioch, California) 1986
-

1.4-12

(California State department

of Transportation)

1-28

1.4-12

1.5

(94.06.17.) 51

36 38
(94.06.17.) 37

1-29