Component

NH3
Urea
Carbamate
Biuret
H2O
TOTAL

COMPOSITION FROM HIGH PRESSURE DECOMPOSER TO LOW PRESSURE DECOMPOSER

Mass Flowrate, kg/day Molar Mass, Kg/kmol
Molar Flowrate, Kmol/day Heat of formation Hf, KJ/kmol Cp, KJ/kmol
534.24
17
31.42588235
-46190
332345.11
60
5539.085167
-333190
257068.95
78
3295.755769
-647279
33237.41
103
322.693301
-565800
79762.82
18
4431.267778
-241820
702948.53
13620.2279

H, KJ/Kmol H,KJ/day
%
3645.73
-42544.27
-1336991.224 0.0262
10005
-323185
-1790149240 35.093
16282.5
-630996.5
-2079610355 40.767
16412.5
-549387.5
-177283665.9 3.4754
4240.98 -237579.02
-1052776256 20.638
5101156508
100

Component
NH3
CO2
TOTAL

Mass Flowrate, kg/day Molar Mass, Kg/kmol

52889.29
62148.54
115037.83

Molar Flowrate, Kmol/day Heat of formation Hf, KJ/kmol Cp, KJ/kmol

17
3111.134706
-46190
44
1412.466818
-393500
4523.601524

H, KJ/Kmol H,KJ/day
%
3645.73
-42544.27
-132360954.9 19.426
4826.19 -388673.81
-548988859.7 80.574
681349814.7
100

H47= -5101156508 KJ/day

H48= -1582501010 KJ/ day
H49= -3065094858 KJ/ day
Q= (H48 + H49) - H47 = 453560640 KJ/ day

Assumptions:
1. There is no heat losses to the environment
2. There is absorption during the CO2 removal from the casing head gas

Component
NH3
CO2
Biuret
Urea
H2O

Cp @ 80
b*10^5

a*10^3

c*10^8

Cp, KJ/kmol

d*10^12

29
36.11

0.2199
4.234

0.5723
-2.887

-2.871
7.464

33.46

0.688

0.7604

-3.593

1598.636808
2048.505243
7221.5
4402.2
1851.119486

Component
NH3
CO2
TOTAL

COMPOSITION FROM LOW PRESSURE DECOMPOSER TO LOW PRESSURE ABSORBER

Mass Flowrate, kg/day Molar Mass, Kg/kmol
Molar Flowrate, Kmol/day Heat of formation Hf, KJ/kmol Cp, KJ/kmol
111464.04
17
6556.708235
-46190
145013.25
44
3295.755682
-393500
256477.29
9852.463917

H, KJ/Kmol H,KJ/day
%
1598.64 -44591.36
-292372537.3 18.475
2048.51 -391451.49
-1290128472 81.525
1582501010 100

H48 = -2274144289 KJ/ day

H50 = -2993982061 KJ/ day
Q = H50 - H48 = -719837772 KJ/ day

Assumptions:
1. There is no heat losses to the environment
2. There is absorption during the CO2 removal from the casing head gas

Component
NH3
CO2
TOTAL

COMPOSITION FROM HIGH AND LOW DECOMPOSERS TO LOW PRESSURE ABSORBERS

Mass Flowrate, kg/day Molar Mass, Kg/kmol
Molar Flowrate, Kmol/day Heat of formation Hf, KJ/kmol Cp, KJ/kmol
164353.83
17
9667.872353
-46190
207161.79
44
4708.2225
-393500
371515.62
14376.09485

Component
NH3
Urea
Biuret
H2O
TOTAL

COMPOSITION FROM LOW PRESSURE DECOMPOSER TO VACUUM CONCENTRATOR

Mass Flowrate, kg/day Molar Mass, Kg/kmol
Molar Flowrate, Kmol/day Heat of formation Hf, KJ/kmol Cp, KJ/kmol
112.59
17
6.622941176
-46190
332345.11
60
5539.085167
-333190
33237.41
103
322.693301
-565800
79762.82
18
4431.267778
-241820
445457.93
10299.66919

H, KJ/Kmol H,KJ/day
%
1598.64
-44591.36
-431103576.5 18.957
2048.51 -391451.49
-1843040713 81.043
2274144289
100

1598.64
4402.2
7221.5
1851.12

H, KJ/Kmol H,KJ/day
-44591.36
-295325.9543
-328787.8
-1821183626
-558578.5
-180249540
-239968.88
-1063366366
3065094858

%
0.0096
59.417
5.8807
34.693
100

Component
NH3
Biuret
Urea
H2O

Cp @ 85
b*10^5

a*10^3

c*10^8

Cp, KJ/kmol

d*10^12

29

0.2199

0.5723

-2.871

33.46

0.688

0.7604

-3.593

1744.360954
7878
4802.4
2020.519847

H58= -1100641900 KJ/ day

H59= -193617889 KJ/ day
H49= -3065094858 KJ/ day
Q= (H58 + H59) - H49 = 835069 KJ/ day

Assumptions:
1. There is no heat losses to the environment
2. There is absorption during the CO2 removal from the casing head gas

Component
NH3
Urea
Biuret
H2O
TOTAL

Component
NH3
Urea
Biuret
H2O
TOTAL

Mass Flowrate, kg/day

56.295
332345.11
16868.71
3988.14
353258.255

COMPOSITION FROM VACUUM CONCENTRATOR TO EVAPORATOR BOTTOM

Molar Mass, Kg/kmol
Molar Flowrate, Kmol/day Heat of formation Hf, KJ/kmol Cp, KJ/kmol
17
3.311470588
-46190
60
5539.085167
-333190
103
163.7738835
-565800
18
221.5633333
-241820
5927.733854

Mass Flowrate, kg/day

56.295
6.65
16868.71
75744.68
92676.335

COMPOSITION FROM VACUUM CONCENTRATOR TO EVAPORATOR TOP

Molar Mass, Kg/kmol
Molar Flowrate, Kmol/day Heat of formation Hf, KJ/kmol Cp, KJ/kmol
17
3.311470588
-46190
60
0.110833333
-333190
103
163.7738835
-565800
18
4208.037778
-241820
4375.233965

1744.36
4802.4
7878
2020.52

H, KJ/Kmol H,KJ/day
-44445.64
-147180.4296
-328387.6
-1818966884
-557922
-91373052.63
-239799.48
-53130772.12
1963617889

%
0.0075
92.633
4.6533
2.7058
100

1744.36
4802.4
7878
2020.52

H, KJ/Kmol H,KJ/day
-44445.64
-147180.4296
-328387.6
-36396.29233
-557922
-91373052.63
-239799.48
-1009085271
1100641900

%
0.0134
0.0033
8.3018
91.682
100

Component
NH3
Biuret
Urea
H2O

Cp @ 27
b*10^5

a*10^3

c*10^8

Cp, KJ/kmol

d*10^12

29

0.2199

0.5723

-2.871

33.46

0.688

0.7604

-3.593

58.00441325
262.6
160.08
66.93378026

H59= -1963617889 KJ/ day

H60= -130007357.1 KJ/day
H61= -1935301363 KJ/ day
Q= (H60 + H61) - H59 = -101690831.1 KJ/ day

Assumptions:
1. There is no heat losses to the environment
2. There is absorption during the CO2 removal from the casing head gas

Component
NH3
Urea
Biuret
H2O
TOTAL

Mass Flowrate, kg/day

28115
332334.11
174.22
1000
361623.33

COMPOSITION FROM EVAPORATOR TO PRILLING TOWER

Molar Mass, Kg/kmol
Molar Flowrate, Kmol/day Heat of formation Hf, KJ/kmol Cp, KJ/kmol
17
1653.823529
-46190
60
5538.901833
-333190
103
1.691456311
-565800
18
55.55555556
-241820
7249.972375

H61 = -1935301363 KJ/day

H62 = -2421365.587 KJ/ day
H63 = -1857553292 KJ/day
Q = (H62+ H63) - H61 = 75326705.41 KJ/ day

58
160.08
262.2
69.93

H, KJ/Kmol H,KJ/day
-46132
-76294187.06
-333029.92
-1844620034
-565537.8
-956582.4807
-241750.07
-13430559.44
1935301363

%
3.9422
95.314
0.0494
0.694
100

Component
NH3
Carbamate
TOTAL

COMPOSITION FROM LOW PRESSURE ABSORBER TO HIGH PRESSURE ABSORBER

Mass Flowrate, kg/day Molar Mass, Kg/kmol
Molar Flowrate, Kmol/day Heat of formation Hf, KJ/kmol Cp, KJ/kmol
4274.26
17
251.4270588
-46190
367241.36
78
4708.222564
-647279
371515.62
4959.649623

H, KJ/Kmol H,KJ/day
3059.24
-43130.76
-10844240.13 0.3622
13677.3
-633601.7
-2983137821 99.638
2993982061
100

H50 = -2993982061 KJ/day

H51 = -754830889.5 KJ/ day
Q = H51 - H50 = 2239151172 KJ/ day

Assumptions:
1. There is no heat losses to the environment
2. There is absorption during the CO2 removal from the casing head gas

GAS COMPOSITION FROM PSA UNIT 1 TO

COMPRESSOR

Component
N2

Mass
Flowrate,
kg/day

Molar Mass,
Kg/kmol

Molar Flowrate,
Kmol/day

Cp,
KJ/kmol

Heat of formation
Hf, KJ/kmol

2128.39

28

76.01392857

435.25

CH4

179151.58

16

11196.97375

-74580

520.81

C2H6

44402.58

30

1480.086

-84680

756.14

C3H8

93.21

44

2.118409091

-103580

1045.75

C4H10

19.38

58

0.334137931

-126150

1395.64

H,
KJ/Km
ol
435.25
74059.1
9
83923.8
6
102534.
25
124754.
36

H,KJ/da
y
%
33085.06 0.0
241 03
8292388 86.
06.4 95
1242145 13.
30.3 02
217209.4 0.0
873 23
41685.16 0.0
374 04

TOTAL

225795.14

12755.52623

9537453
16.3 100