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MSDS of 1,4-Dioxane (Cas 123-91-1)
MSDS of 1,4-Dioxane (Cas 123-91-1)
MSDS of 1,4-Dioxane (Cas 123-91-1)
1,4-dioxane
07-5390 Katayama OEM Partner 603-024-00-5 123-91-1 Laboratory chemicals, Manufacture of substances
1.2 2. 2.1
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Flammable liquids (Category 2) Carcinogenicity (Category 2) Eye irritation (Category 2) Specific target organ toxicity - single exposure (Category 3)
2.2
Signal word Hazard statement(s) H225 H319 H335 H351 Precautionary statement(s) P210 P261 Katayama OEM Partner - 07-5390 P281 P305 + P351 + P338
Danger Highly flammable liquid and vapour. Causes serious eye irritation. May cause respiratory irritation. Suspected of causing cancer. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Use personal protective equipment as required. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard information (EU) EUH019 May form explosive peroxides. EUH066 Repeated exposure may cause skin dryness or cracking.
Highly flammable. May form explosive peroxides. Irritating to eyes and respiratory system. Limited evidence of a carcinogenic effect. Repeated exposure may cause skin dryness or cracking. Keep container in a well-ventilated place. Keep away from sources of ignition - No smoking. Wear suitable protective clothing and gloves. If swallowed, seek medical advice immediately and show this container or label.
2.3
3. 3.1
1,4-Dioxane
CAS-No. EC-No. Index-No.
4. 4.1
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Katayama OEM Partner - 07-5390
4.2
4.3 5. 5.1
Further information
Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
6.2
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
6.3
6.4 7. 7.1
charge.
7.2
EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
9. 9.1
PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties
a) Appearance b) Odour c) Odour Threshold d) pH e) Melting point/freezing point f) Initial boiling point and boiling range g) Flash point h) Evaporation rate i) j) Form: liquid Colour: colourless no data available no data available 6,0 - 8 at 500 g/l at 20 C Melting point/range: 10 - 12 C - lit. 100 - 102 C - lit. 12 C - closed cup no data available
Flammability (solid, gas) no data available Upper/lower Upper explosion limit: 22 %(V) flammability or Lower explosion limit: 2 %(V) explosive limits 36 hPa at 20 C 53 hPa at 25,20 C 3,04 - (Air = 1.0) 1,034 g/cm3 at 25 C completely miscible log Pow: -0,27
k) Vapour pressure l) Vapour density m) Relative density n) Water solubility o) Partition coefficient: noctanol/water
no data available no data available no data available no data available no data available 36,9 mN/m at 25 C
9.2
Skin corrosion/irritation
Skin - Human Remarks: Chronic exposure causes drying effect on the skin and eczema. Skin - rabbit - No skin irritation
Carcinogenicity
This product is or contains a component that has been reported to be possibly carcinogenic based on its IARC, ACGIH, NTP, or EPA classification. Limited evidence of carcinogenicity in animal studies IARC: 2B - Group 2B: Possibly carcinogenic to humans (1,4-Dioxane)
Reproductive toxicity
no data available
Aspiration hazard
no data available
May be harmful if inhaled. Causes respiratory tract irritation. May be harmful if swallowed. May be harmful if absorbed through skin. May cause skin irritation.
Additional Information
RTECS: JG8225000
EC50 - Desmodesmus subspicatus (green algae) - > 500 mg/l - 72 h Result: < 5 % - Not readily biodegradable.
Contaminated packaging
Dispose of as unused product.
ADR/RID: 3
15.
REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
16.
of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. guidechem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.