Organic Chemistry

You might also like

Download as pdf or txt
Download as pdf or txt
You are on page 1of 1

Model Test Paper 2011 M.Sc.

Chemistry (Previous) Organic Chemistry-I

Time : 3 hrs.
Note Attempt one question from each section.Each question carries 20 marks.

M.M.:100

Unit I Q.1 Explain the following(a) Cross conjugation (b) Catenanes and rotaxanes (c) Inclusion compounds Explain Huckel rule in detail Unit II Q.3 Explain with example (a) Hammett equation (b) Carbanions (c) Linear free energy relationship Write down the application of NMR spectroscopy in determining the structure of organic compounds. Unit III Give mechanism of he following reaction (a) Vilsmier reaction (b) Gattermann Koch Reaction (c) Diazonium coupling. Explain SN1 and benzyne mechanism for aromatic nucleophilic subtitution. Unit IV Explain Michal reaction and sharpless asymmetric epoxidation. Give mechanism for the following condensation reactions. (a) Benzoin condensation. (b) Claisen condensation. (c) Aldol condensation.

Q.2

Q.4

Q.5

Q.6

Q.7 Q.8

Unit V Q.9 What are sigma tropic re arrangements? Explain in detail. Q.10 Draw Woodward Hoffmann correlation diagram for 4n+2 cycloaddition reaction.

You might also like