Vidyamandir Classes

VMC/Gaseous State 12 HWT-Solutions/Chemistry

Solutions to Home Work Test/Chemistry
3.(A) 1 atm =
5 2
1.01 10 N/ m 760 mm = of
5
Hg 1.01 10 Pa =
Note : Pound is a unit of mass and not force. Pressure is force per unit area and not mass per unit area.)
4.(B) Nitrogen is third most electronegative and hydrogen is highly electropositive and thus strong dipoles develop in
3
NH molecule causing strong dipole-dipole interactions. Note that carbon is less electronegative as compared
to nitrogen and hence the dipoles (positive negative charge centers developed in
4
CH molecule are not as
strong as they are in
3
NH and in
2
CO the dipoles developed will be even weaker as both oxygen and carbon
are electronegative atoms and hence the electronegativity differences will be less compared to
3 4
NH and CH .
5.(C) 3.36 lt O
2
(at S.T.P.)
2 2
3.36
mol O 0.15 O
22.4

0.15 mol
2
H required 0.15 2 0.3g = H
2
required.
6.(B)
0 gas
(M ) 2 V.D 2 11.2 22.4 = = =
11.2
11.2g gas 0.5 mol gas 11.2lt
22.4
= (at STP.)
7.(D)
1 1 2
2 1
2 2 1
V T T 313
V V 128 136.7 ml
V T T 293
| |
= = = =
|
\ .
(At P, n const.) ~ 137 ml
8.(C) Use
1 1
2 2
P T
P T
= (at n, v const.)
2
2 1
1
T 40
P P 2 4 atm
T 20
| |
= = =
|
\ .
9.(D)
gas
gas
P
r
M

Note :
gas
P is the pressure of the gas in that container from which gas is effusing out. In this question since nothing is mentioned about
the pressure we will assume pressure of both gases to be the same.

2
2
O
gas
O gas
M
r
32 1 1
r 4 2 M 128
= = = =
10.(B)
2
2 2
H O2
O H
r M
r M
=
2
H
n / t
2
O
n / t
32
2
=

2 2
2 2
H 0 H
O 0 O
g /(M )
32
4
g /(M ) 2
= =
2
H
g / 2
4
4/ 32
=
2
H
g 1g =
1.(C) Use
1 1 2 2
1 2
P V P V
T T
=
1
1 1 2
2
1 2
5 V
P V T
P
T V

= =
273
819
1

1
3
( V
45 atm
/ 3)
=
4.(C)
2
gases total H He NO
1 2 3
(n ) n n n 0.5 0.5 0.1 1.1
2 4 30
= + + = + + = + + =

nRT 1.1 0.08 300

P ~ 24atm
V 1.1

= =
Gaseous State HWT - 1
Gaseous State HWT - 2
Vidyamandir Classes
VMC/Gaseous State 13 HWT-Solutions/Chemistry
6.(A) Total K.E =
3
nRT
2

He
0.3 T 0.4 400 =
He
1600
T 533.33 K
3
= =
7.(D)
T
C
M

1
1
T
u
m
and
2
2
T
u
m

1 1 2 2
u m u m =
2 2
1 1 2 2
m u m u =
8.(B)
2
2
2
H
H
H
P
50ml
r
20min M
=
2 2
H O
(P P similar conditions) =
2
2
2
O
O
O
P
40ml
r
t min M
=
50/ 20 32
40/ t 2
=

50t
4
40 20
=

t = 64 min
9.(D)
avg avg
RT T T
C C Check
M M M
8
=
t
10.(B) K.E
avg
per molecule
23 21
3 3
KT 1.38 10 298 ~ 6.17 10 J
2 2

= =
3.(C) , )
2
rms
O 3
3 8.314 300
C
32 10

(Note : M
0
has to be in kg/mol and not g/mol)
4.(D)
2 2 2
rms
1 2 2 9
C 3 1.73 m/ s
3 3
+ +
= = = =
2.(A) Open container P and V are const. (Think why ?)
1 1 2 2
n T n T =
1 1 1
2 1
2
n T n 300 3
n n
T 400 4

= = =

3
th
4
of the gas is present inside the container at 127 C
3.(C)
dry air dry air total
P P 0.98 1.2 1.176 atm = _ = =
4.(A) Molecular attractions decrease and mean free path increases on increasing temp
T
P
| |

|
\ .
. Though Rate of collisions among particles
increases on increasing temp but Pressure in a container is not due to collisions of particles amongst themselves but it is due to collision
of particles with the walls of the container (so option B is also incorrect).
9.(D) K.E is only function of temp.
Translational K.E. (per molecule)
3
KT
2
=
Gaseous State HWT - 3
Gaseous State HWT - 4
Vidyamandir Classes
VMC/Gaseous State 14 HWT-Solutions/Chemistry
1.(C)
2 2
rms N rms N
(C ) 7(C ) =

3R
2
H
3
T 3R
7
2 10

2
N
3
T
28 10

2 2
H N
H2
2
T T
T
7 TH
1 284 2
= =

2 2
H N
T T <
2.(B)
2 0.08 540
P 1.97 ~ 2atm
44.8

= =
8.(C)
0
1 M d R 300 = , Now
0
1 M 0.75d R T =
d 300 0.75d T =
300
T 400K
0.75
= =
1.(C)
0
0
PM 2 16
PM dRT d ~ 1.3 g/ lt
RT 0.08 300

= =

2.(A)
gas
He
gas He
He gas
r
M
(assuming P P )
r M
= =
Now
gas He gas
gas
1 1 4
r r M 25 4 100
5 5 M
= = = =
3.(D)
1 1 2 2 1 1 2 1 1 1
2
1 2 1 2 1 1
P V P V P V T P V 2T
V
T T T P T P / 2
| |
= = =
|
\ .
= 4V
1
4.(B)
4
CH
PV 16 9
n 6
RT 0.08 300

= = =

4 4 4
CH CH 0 CH
g n (M ) = = 6 16 96g =
2.(B)
4 4 4 4
2 2 2 2
CH CH CH 0 CH
H H H 0 H
P n g /(M )
2 1
P n g /(M ) 16 8
= = = =

2
2 4
H
H CH
P
8
P P 9
=
+
Gaseous State HWT - 5
Gaseous State HWT - 6
Gaseous State HWT - 7
Vidyamandir Classes
VMC/Gaseous State 15 HWT-Solutions/Chemistry
2.(A)
avg
T
C
M
for
avg
C to be same
4 2
4
4
CH O
CH
CH 2
T T
300
T 16 150K
M MO 32
= = =
5.(B)
2 2
23
O O
3 2 1 1
n n 6 10
0.08 300 4 4

= = =

=
23
1.5 10
7.(D)
324
324g A 12mol
27
=
2 2
12 3
A mol Cl 18 mol Cl
2

= 18 22.4 lt of
2
Cl at S.T.P = 403.2 lt
8.(A)
2
2
2
N O gas
N O gas
N O gas
M r
(assuming P P )
r M
= =

Ax / t 44 1 x 1
A( x) / t 176 2 x 2
= = =

2x x = 3x 13 = =
13
x 4.33
3
= = x 13 4.33 = 8.66 = 9
th
row from front.
9.(B)
2 2 2
eff N N O 0
M 2 V.D 2 14.4 28 .8 M M = = = =_ + _
2 2
N N
28 (1 ) 32 = _ + _

2
N
28.8 32 4 = _
2 2
N 2 N
3.2
0.8 %N 100 80%
4
_ = = =_ =
3.(B)
0 0
1.15 0.08 373
PM dRT M 44
0.8

= = =
7.(C) , )
2
rms
O 3
3RT 3 8.3 300
C 483.5 ~ 484 m/ s
M
32 10

= = =

8.(C)
V
1 V P P 4 atm
4
= =
3.(C)
, )
, )
3 2
3
2
rms
O O
rms O
O
C
M
32 2
C M 48 3
= = =
7.(B) As pressure increases, the tendency of liquification of a gas increases (or in other words the tendency of vapourisation of the gas
decreases)
Boiling point of the liquid (corresponding to the gas) increases. This is what happens in pressure cooker.
10.(D) d 0.001293 g/ ml = =1.293g/ lt .
Now
0 air
d R T
(M )
P

=
1.293 224 28.96 = =
0 air
(M ) 28.96
V.D. 14.48
2 2
= = =
Gaseous State HWT - 8
Gaseous State HWT - 9
Gaseous State HWT - 10