WAREHOUSE FIRE

Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

10643-02 QRA (RunRow Warehouse) Study Doors Closed- 20 m2/1800 s Warehouse Inputs Warehouse Material Name Stored Mass kg Active Mass Fraction fraction

HN03 Morpholine Diethanolamine HCL H3P04 Belite (50 % Isopropanol) Sulfolane Hydrazine Hydrate MDEA Activated MDEA INEOS Activated MDEA SERDET (25% Sulphuric acid) NALCO-8514 Enriched premix solution Dowtherm A Heat transfer fluid Defoamer 530
Event Frequency Data

15,200.00 15,000.00 50,000.00 16,920.00 18,800.00 4,000.00 15,000.00 10,000.00 75,000.00 25,000.00 25,000.00 60,000.00 40,000.00 65,000.00 1,000.00 500.00

1.00 0.99 1.00 1.00 1.00 0.50 0.80 0.55 0.99 0.80 0.60 0.25 0.25 0.80 0.90 1.00

Is Event Frequency in Use? Event Frequency

Building Dimensions and Ventilation

Yes
8.80000E-004

/AvgeYear

Surface area for storage Height of building Width of building Length of building Building Wake Effects
Base Case Data

4,875.00 10.00 65.00 75.00 Yes

m2 m m m

\10643-02 QRA\Study\Manual Door closing\Warehouse\Doors Closed- 20 m2/1800 s Relative or Absolute Coordinates? Absolute East 492.23 North 1,001.92
Scenario Inputs

m m

Probability or Frequency? Probability Fire surface area Fire duration Is Ventilation Factor Infinite? Ventilation Factor

Probability 0.41 20.00 1,800.00 No 4.00

fraction m2 s /hr

Date:

11/7/2012

1 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\F 2m/s 2.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

0.28 4.57 0.06 0.39 0.26 0.35

kmol/s kmol/s fraction fraction fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

2.00 kg/s 0.21 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

2 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

3 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\D 5m/s 5.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

0.28 4.57 0.06 0.39 0.26 0.35

kmol/s kmol/s fraction fraction fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

2.00 kg/s 0.21 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

4 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

5 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Doors Closed- 50 m2/1800 s Warehouse Inputs Warehouse Material Name Stored Mass kg Active Mass Fraction fraction

HN03 Morpholine Diethanolamine HCL H3P04 Belite (50 % Isopropanol) Sulfolane Hydrazine Hydrate MDEA Activated MDEA INEOS Activated MDEA SERDET (25% Sulphuric acid) NALCO-8514 Enriched premix solution Dowtherm A Heat transfer fluid Defoamer 530
Event Frequency Data

15,200.00 15,000.00 50,000.00 16,920.00 18,800.00 4,000.00 15,000.00 10,000.00 75,000.00 25,000.00 25,000.00 60,000.00 40,000.00 65,000.00 1,000.00 500.00

1.00 0.99 1.00 1.00 1.00 0.50 0.80 0.55 0.99 0.80 0.60 0.25 0.25 0.80 0.90 1.00

Is Event Frequency in Use? Event Frequency

Building Dimensions and Ventilation

Yes
8.80000E-004

/AvgeYear

Surface area for storage Height of building Width of building Length of building Building Wake Effects
Base Case Data

4,875.00 10.00 65.00 75.00 Yes

m2 m m m

\10643-02 QRA\Study\Manual Door closing\Warehouse\Doors Closed- 50 m2/1800 s Relative or Absolute Coordinates? Absolute East 492.23 North 1,001.92
Scenario Inputs

m m

Probability or Frequency? Probability Fire surface area Fire duration Is Ventilation Factor Infinite? Ventilation Factor

Probability 0.40 50.00 1,800.00 No 4.00

fraction m2 s /hr

Date:

11/7/2012

6 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\F 2m/s 2.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

0.28 4.57 0.06 0.39 0.26 0.35

kmol/s kmol/s fraction fraction fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

5.00 kg/s 0.53 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

7 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

8 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\D 5m/s 5.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

0.28 4.57 0.06 0.39 0.26 0.35

kmol/s kmol/s fraction fraction fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

5.00 kg/s 0.53 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

9 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

10 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Doors Closed- 100 m2/1800 s Warehouse Inputs Warehouse Material Name Stored Mass kg Active Mass Fraction fraction

HN03 Morpholine Diethanolamine HCL H3P04 Belite (50 % Isopropanol) Sulfolane Hydrazine Hydrate MDEA Activated MDEA INEOS Activated MDEA SERDET (25% Sulphuric acid) NALCO-8514 Enriched premix solution Dowtherm A Heat transfer fluid Defoamer 530
Event Frequency Data

15,200.00 15,000.00 50,000.00 16,920.00 18,800.00 4,000.00 15,000.00 10,000.00 75,000.00 25,000.00 25,000.00 60,000.00 40,000.00 65,000.00 1,000.00 500.00

1.00 0.99 1.00 1.00 1.00 0.50 0.80 0.55 0.99 0.80 0.60 0.25 0.25 0.80 0.90 1.00

Is Event Frequency in Use? Event Frequency

Building Dimensions and Ventilation

Yes
8.80000E-004

/AvgeYear

Surface area for storage Height of building Width of building Length of building Building Wake Effects
Base Case Data

4,875.00 10.00 65.00 75.00 Yes

m2 m m m

\10643-02 QRA\Study\Manual Door closing\Warehouse\Doors Closed- 100 m2/1800 s Relative or Absolute Coordinates? Absolute East 492.23 North 1,001.92
Scenario Inputs

m m

Probability or Frequency? Probability Fire surface area Fire duration Is Ventilation Factor Infinite? Ventilation Factor

Probability 0.09 100.00 1,800.00 No 4.00

fraction m2 s /hr

Date:

11/7/2012

11 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\F 2m/s 2.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

0.28 4.57 0.06 0.39 0.26 0.35

kmol/s kmol/s fraction fraction fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

5.93 kg/s 0.62 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Ventilation 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

12 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

13 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\D 5m/s 5.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

0.28 4.57 0.06 0.39 0.26 0.35

kmol/s kmol/s fraction fraction fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

5.93 kg/s 0.62 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Ventilation 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

14 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

15 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Doors Closed- 300 m2/1800 s Warehouse Inputs Warehouse Material Name Stored Mass kg Active Mass Fraction fraction

HN03 Morpholine Diethanolamine HCL H3P04 Belite (50 % Isopropanol) Sulfolane Hydrazine Hydrate MDEA Activated MDEA INEOS Activated MDEA SERDET (25% Sulphuric acid) NALCO-8514 Enriched premix solution Dowtherm A Heat transfer fluid Defoamer 530
Event Frequency Data

15,200.00 15,000.00 50,000.00 16,920.00 18,800.00 4,000.00 15,000.00 10,000.00 75,000.00 25,000.00 25,000.00 60,000.00 40,000.00 65,000.00 1,000.00 500.00

1.00 0.99 1.00 1.00 1.00 0.50 0.80 0.55 0.99 0.80 0.60 0.25 0.25 0.80 0.90 1.00

Is Event Frequency in Use? Event Frequency

Building Dimensions and Ventilation

Yes
8.80000E-004

/AvgeYear

Surface area for storage Height of building Width of building Length of building Building Wake Effects
Base Case Data

4,875.00 10.00 65.00 75.00 Yes

m2 m m m

\10643-02 QRA\Study\Manual Door closing\Warehouse\Doors Closed- 300 m2/1800 s Relative or Absolute Coordinates? Absolute East 492.23 North 1,001.92
Scenario Inputs

m m

Probability or Frequency? Probability Fire surface area Fire duration Is Ventilation Factor Infinite? Ventilation Factor

Probability 0.01 300.00 1,800.00 No 4.00

fraction m2 s /hr

Date:

11/7/2012

16 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\F 2m/s 2.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

0.28 4.57 0.06 0.39 0.26 0.35

kmol/s kmol/s fraction fraction fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

5.93 kg/s 0.62 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Ventilation 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

17 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

18 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\D 5m/s 5.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

0.28 4.57 0.06 0.39 0.26 0.35

kmol/s kmol/s fraction fraction fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

5.93 kg/s 0.62 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Ventilation 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

19 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

20 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Doors Open- 20 m2/1800 s Warehouse Inputs Warehouse Material Name Stored Mass kg Active Mass Fraction fraction

HN03 Morpholine Diethanolamine HCL H3P04 Belite (50 % Isopropanol) Sulfolane Hydrazine Hydrate MDEA Activated MDEA INEOS Activated MDEA SERDET (25% Sulphuric acid) NALCO-8514 Enriched premix solution Dowtherm A Heat transfer fluid Defoamer 530
Event Frequency Data

15,200.00 15,000.00 50,000.00 16,920.00 18,800.00 4,000.00 15,000.00 10,000.00 75,000.00 25,000.00 25,000.00 60,000.00 40,000.00 65,000.00 1,000.00 500.00

1.00 0.99 1.00 1.00 1.00 0.50 0.80 0.55 0.99 0.80 0.60 0.25 0.25 0.80 0.90 1.00

Is Event Frequency in Use? Event Frequency

Building Dimensions and Ventilation

Yes
8.80000E-004

/AvgeYear

Surface area for storage Height of building Width of building Length of building Building Wake Effects
Base Case Data

4,875.00 10.00 65.00 75.00 Yes

m2 m m m

\10643-02 QRA\Study\Manual Door closing\Warehouse\Doors Open- 20 m2/1800 s Relative or Absolute Coordinates? Absolute East 492.23 North 1,001.92
Scenario Inputs

m m

Probability or Frequency? Probability Fire surface area Fire duration Is Ventilation Factor Infinite? Ventilation Factor

Probability 0.05 20.00 1,800.00 Yes

fraction m2 s /hr

Date:

11/7/2012

21 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\F 2m/s 2.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

kmol/s 4.57 kmol/s 0.39 fraction 0.26 fraction 0.35 fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

2.00 kg/s 0.21 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

22 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

23 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\D 5m/s 5.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

kmol/s 4.57 kmol/s 0.39 fraction 0.26 fraction 0.35 fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

2.00 kg/s 0.21 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

24 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

25 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Doors Open- 50 m2/1800 s Warehouse Inputs Warehouse Material Name Stored Mass kg Active Mass Fraction fraction

HN03 Morpholine Diethanolamine HCL H3P04 Belite (50 % Isopropanol) Sulfolane Hydrazine Hydrate MDEA Activated MDEA INEOS Activated MDEA SERDET (25% Sulphuric acid) NALCO-8514 Enriched premix solution Dowtherm A Heat transfer fluid Defoamer 530
Event Frequency Data

15,200.00 15,000.00 50,000.00 16,920.00 18,800.00 4,000.00 15,000.00 10,000.00 75,000.00 25,000.00 25,000.00 60,000.00 40,000.00 65,000.00 1,000.00 500.00

1.00 0.99 1.00 1.00 1.00 0.50 0.80 0.55 0.99 0.80 0.60 0.25 0.25 0.80 0.90 1.00

Is Event Frequency in Use? Event Frequency

Building Dimensions and Ventilation

Yes
8.80000E-004

/AvgeYear

Surface area for storage Height of building Width of building Length of building Building Wake Effects
Base Case Data

4,875.00 10.00 65.00 75.00 Yes

m2 m m m

\10643-02 QRA\Study\Manual Door closing\Warehouse\Doors Open- 50 m2/1800 s Relative or Absolute Coordinates? Absolute East 492.23 North 1,001.92
Scenario Inputs

m m

Probability or Frequency? Probability Fire surface area Fire duration Is Ventilation Factor Infinite? Ventilation Factor

Probability 0.04 50.00 1,800.00 Yes

fraction m2 s /hr

Date:

11/7/2012

26 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\F 2m/s 2.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

kmol/s 4.57 kmol/s 0.39 fraction 0.26 fraction 0.35 fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

5.00 kg/s 0.53 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

27 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

28 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\D 5m/s 5.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

kmol/s 4.57 kmol/s 0.39 fraction 0.26 fraction 0.35 fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

5.00 kg/s 0.53 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

29 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

30 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Doors Open- 100 m2/1800 s Warehouse Inputs Warehouse Material Name Stored Mass kg Active Mass Fraction fraction

HN03 Morpholine Diethanolamine HCL H3P04 Belite (50 % Isopropanol) Sulfolane Hydrazine Hydrate MDEA Activated MDEA INEOS Activated MDEA SERDET (25% Sulphuric acid) NALCO-8514 Enriched premix solution Dowtherm A Heat transfer fluid Defoamer 530
Event Frequency Data

15,200.00 15,000.00 50,000.00 16,920.00 18,800.00 4,000.00 15,000.00 10,000.00 75,000.00 25,000.00 25,000.00 60,000.00 40,000.00 65,000.00 1,000.00 500.00

1.00 0.99 1.00 1.00 1.00 0.50 0.80 0.55 0.99 0.80 0.60 0.25 0.25 0.80 0.90 1.00

Is Event Frequency in Use? Event Frequency

Building Dimensions and Ventilation

Yes
8.80000E-004

/AvgeYear

Surface area for storage Height of building Width of building Length of building Building Wake Effects
Base Case Data

4,875.00 10.00 65.00 75.00 Yes

m2 m m m

\10643-02 QRA\Study\Manual Door closing\Warehouse\Doors Open- 100 m2/1800 s Relative or Absolute Coordinates? Absolute East 492.23 North 1,001.92
Scenario Inputs

m m

Probability or Frequency? Probability Fire surface area Fire duration Is Ventilation Factor Infinite? Ventilation Factor

Probability 0.01 100.00 1,800.00 Yes

fraction m2 s /hr

Date:

11/7/2012

31 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\F 2m/s 2.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

kmol/s 4.57 kmol/s 0.39 fraction 0.26 fraction 0.35 fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

10.00 kg/s 1.05 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

32 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

33 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\D 5m/s 5.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

kmol/s 4.57 kmol/s 0.39 fraction 0.26 fraction 0.35 fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

10.00 kg/s 1.05 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

34 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

35 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Doors Open- 300 m2/1800 s Warehouse Inputs Warehouse Material Name Stored Mass kg Active Mass Fraction fraction

HN03 Morpholine Diethanolamine HCL H3P04 Belite (50 % Isopropanol) Sulfolane Hydrazine Hydrate MDEA Activated MDEA INEOS Activated MDEA SERDET (25% Sulphuric acid) NALCO-8514 Enriched premix solution Dowtherm A Heat transfer fluid Defoamer 530
Event Frequency Data

15,200.00 15,000.00 50,000.00 16,920.00 18,800.00 4,000.00 15,000.00 10,000.00 75,000.00 25,000.00 25,000.00 60,000.00 40,000.00 65,000.00 1,000.00 500.00

1.00 0.99 1.00 1.00 1.00 0.50 0.80 0.55 0.99 0.80 0.60 0.25 0.25 0.80 0.90 1.00

Is Event Frequency in Use? Event Frequency

Building Dimensions and Ventilation

Yes
8.80000E-004

/AvgeYear

Surface area for storage Height of building Width of building Length of building Building Wake Effects
Base Case Data

4,875.00 10.00 65.00 75.00 Yes

m2 m m m

\10643-02 QRA\Study\Manual Door closing\Warehouse\Doors Open- 300 m2/1800 s Relative or Absolute Coordinates? Absolute East 492.23 North 1,001.92
Scenario Inputs

m m

Probability or Frequency? Probability Fire surface area Fire duration Is Ventilation Factor Infinite? Ventilation Factor

Probability 0.00 300.00 1,800.00 Yes

fraction m2 s /hr

Date:

11/7/2012

36 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\F 2m/s 2.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

kmol/s 4.57 kmol/s 0.39 fraction 0.26 fraction 0.35 fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

30.00 kg/s 3.15 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

37 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

38 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\D 5m/s 5.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

kmol/s 4.57 kmol/s 0.39 fraction 0.26 fraction 0.35 fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

30.00 kg/s 3.15 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

39 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

40 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Doors Open- 900 m2/1800 s Warehouse Inputs Warehouse Material Name Stored Mass kg Active Mass Fraction fraction

HN03 Morpholine Diethanolamine HCL H3P04 Belite (50 % Isopropanol) Sulfolane Hydrazine Hydrate MDEA Activated MDEA INEOS Activated MDEA SERDET (25% Sulphuric acid) NALCO-8514 Enriched premix solution Dowtherm A Heat transfer fluid Defoamer 530
Event Frequency Data

15,200.00 15,000.00 50,000.00 16,920.00 18,800.00 4,000.00 15,000.00 10,000.00 75,000.00 25,000.00 25,000.00 60,000.00 40,000.00 65,000.00 1,000.00 500.00

1.00 0.99 1.00 1.00 1.00 0.50 0.80 0.55 0.99 0.80 0.60 0.25 0.25 0.80 0.90 1.00

Is Event Frequency in Use? Event Frequency

Building Dimensions and Ventilation

Yes
8.80000E-004

/AvgeYear

Surface area for storage Height of building Width of building Length of building Building Wake Effects
Base Case Data

4,875.00 10.00 65.00 75.00 Yes

m2 m m m

\10643-02 QRA\Study\Manual Door closing\Warehouse\Doors Open- 900 m2/1800 s Relative or Absolute Coordinates? Absolute East 492.23 North 1,001.92
Scenario Inputs

m m

Probability or Frequency? Probability Fire surface area Fire duration Is Ventilation Factor Infinite? Ventilation Factor

Probability 0.00 900.00 1,800.00 Yes

fraction m2 s /hr

Date:

11/7/2012

41 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\F 2m/s 2.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

kmol/s 4.57 kmol/s 0.39 fraction 0.26 fraction 0.35 fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

90.00 kg/s 9.46 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

42 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

43 of

45

Time:

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)

Unique Audit Number:

1,174,294

Phast Risk 6.7

Weather: Speed:

Default Weathers\D 5m/s 5.00 m/s

Stability:

Calculated Quantities Warehouse Results

Mass of material in warehouse Average Molecular Weight Moles of material Moles of oxygen for complete combustion Fraction of material that is active Mass of active material Average composition of Warehouse material (number of atoms): C: H: 3.09 8.83 N: S: 0.77 0.07 Br: F: 0.00 0.00 Mn: Sn: 0.00 0.00 I: 0.00 O: Cl: P: Zn:

436,420.00 95.40 3,384.99 15,476.86 0.74 322,920.00 1.83 0.14 0.06 0.00

kg kg/kmol kmol kmol fraction kg

Composition of combustion product (moles per mole of Warehouse material): CO2: SO2: HF: ZnO: N2: 3.09 0.07 0.00 0.00 0.35 H2O: HCl: P2O5: SnO2: 4.34 0.14 0.03 0.00 NO2: HBr: MnO2: I2: 0.08 0.00 0.00 0.00

Oxygen flowrate available to fire Moles O2 required / mole completely combusted Molar burn rate assuming oxygen-limited fire Proportion of HCl, HF, HBr in representative plume Proportion of NO2 in representative plume Proportion of SO2 in repesentative plume
Scenario Results

kmol/s 4.57 kmol/s 0.39 fraction 0.26 fraction 0.35 fraction

Mass burning rate Release rate for representative plume Release rate for unburned highly-toxic material Release rate for dioxin-generating material Calculated Fire duration
Other Results

90.00 kg/s 9.46 kg/s n/a kg/s kg/s 1,800.00 s

Velocity Surface or Ventilation limit flag Release Temperature Ratio oxygen required for Categories 10:0 & 11:0 Ratio oxygen required for Category 2:0 Toxic products per unit mass Category 0 Unburned highly toxic per unit mass Category 0 Other burned material per unit mass Category 0
Date:

0.00 m/s Surface 50.00 degC fraction fraction 0.11 fraction fraction 1.77 fraction 45
Time:

11/7/2012

44 of

8:50:02PM

WAREHOUSE FIRE
Study Folder: 10643-02 QRA (RunRow Warehouse)
PCDD & PCDF generated per unit mass Category 0

Unique Audit Number:

1,174,294

Phast Risk 6.7

fraction

Note: Category 0 are materials that form toxic combustion products Category 10 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of less than 100 degC Category 11 are highly toxic materials with LD50 for rates of less than 25mg/kg and flash points of more than 100 degC Category 2 are potential PCDD and PCDF generating compounds

Date:

11/7/2012

45 of

45

Time:

8:50:02PM