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The MSDS of 1-Bromopropane
The MSDS of 1-Bromopropane
1-bromopropane
B78106 602-019-00-5
1.2 2. 2.1
106-94-5 Relevant identified uses of the substance or mixture and uses advised against
Identified uses Laboratory chemicals, Manufacture of substances
HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Flammable liquids (Category 2) Reproductive toxicity (Category 1B) Specific target organ toxicity - repeated exposure (Category 2) Eye irritation (Category 2) Specific target organ toxicity - single exposure (Category 3) Skin irritation (Category 2) Specific target organ toxicity - single exposure (Category 3)
2.2
Hazard statement(s) H225 H315 H319 H335 - B78106 H336 H360FD H373 Precautionary statement(s) P201 P210 P261 P305 + P351 + P338 P308 + P313 Supplemental Hazard Statements Restricted to professional users.
May impair fertility. Also harmful: danger of serious damage to health by prolonged exposure through inhalation. Highly flammable. Irritating to eyes, respiratory system and skin.
Possible risk of harm to the unborn child. Vapours may cause drowsiness and dizziness. Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
2.3 3. 3.1
1-Bromopropane
CAS-No. EC-No. Index-No.
4. 4.1
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
- B78106
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2
4.3 5. 5.1
Further information
Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
6.2
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
6.3
6.4 7. 7.1
7.2
7.3
- B78106
8. 8.1 8.2
EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
9. 9.1
PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties
a) Appearance b) Odour c) Odour Threshold d) pH e) Melting point/freezing point f) Initial boiling point and boiling range g) Flash point h) Evaporation rate i) j) Form: clear, liquid Colour: light brown no data available no data available no data available Melting point/range: -110 C - lit. 71 C - lit. 22 C - closed cup no data available
Flammability (solid, gas) no data available Upper/lower Lower explosion limit: 4,6 %(V) flammability or
no data available 4,25 - (Air = 1.0) 1,354 g/cm3 at 25 C soluble log Pow: 2,1 no data available no data available no data available no data available no data available
m) Relative density n) Water solubility o) Partition coefficient: noctanol/water p) Autoignition temperature q) Decomposition temperature r) Viscosity s) Explosive properties t) Oxidizing properties
9.2
Skin corrosion/irritation
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
May cause congenital malformation in the fetus. May damage the unborn child. Presumed human reproductive toxicant - B78106 Reproductive toxicity - rat - Inhalation Paternal Effects: Spermatogenesis (including genetic material, sperm morphology,motility, and count). Reproductive toxicity - rat - Inhalation Paternal Effects: Prostate, seminal vessicle, Cowper's gland, accessory glands. May cause reproductive disorders. May damage fertility.
Aspiration hazard
no data available
Harmful if inhaled. Causes respiratory tract irritation. Vapours may cause drowsiness and dizziness. Harmful if swallowed. Harmful if absorbed through skin. Causes skin irritation. Causes serious eye irritation.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Additional Information
RTECS: TX4110000
12. ECOLOGICAL INFORMATION 12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 67,3 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates Biodegradability EC50 - Daphnia magna (Water flea) - 208,9 mg/l - 48 h
15.
REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
16.