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5bd2有機化學的反應機構論 PDF
5bd2有機化學的反應機構論 PDF
tw
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www.wunan.com.tw
(02)2705-5066
www.wunan.com.tw
(02)2705-5066
www.wunan.com.tw
(02)2705-5066
www.wunan.com.tw
(02)2705-5066
www.wunan.com.tw
(02)2705-5066
LewisLewis Structures
1.1
1.2
1.3
Unsaturated Molecules
1.4
1.5
25
1.6
Formal charges
33
1.7
Ions
38
1.8
Free Radicals
48
Resonance Structures
2.1
2.2
(I)
15
53
53
103
119
3.1
119
3.2
119
3.3
127
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3.4
133
3.5
Rearrangements
152
3.6
Ring closures
171
4.1
4.2
(II)
181
181
191
(III)
207
5.1
207
5.2
Complex Mechanisms
212
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Lewis
Lewis Structures
1.1
G. N. Lewis
Berkeley
LewisLewis
StructureLewisStructure
point
HHOHHHOH
Lewis
Lewis
Lewis
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1.2
Molecules with Functional Groups
1-1Methane
H
H C
H
HHCHH
1-Formicacid
O
C O H
HCOOH
covalentbond
.%
ionic bond
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CH1 Lewis
STRUCTURE
electricpair
nonpolar bondpolar
bond
Cl
Cl H
counttheavailablevalenceelectrons
Cl
Br
Mg
H
1-chloromethaneCHClH
Cl
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H1ee
1C1ee
1Cl1ee
1e
H
1-methanol H C O H
H
H1ee
1C1ee
1O1ee
1e
H
octetrule
H
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CH1 Lewis
STRUCTURE
1.
1-chloromethaneCHCl
H
H
Cl
H
H
Cl
He
Cee
Cle1e
Cl
H
H
Cl
H
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u n s h a r e d
electronsCl
1-methanolCHOH
H
H
H
H
C
H
H
H
H
L e w i s
Lewis
1- 1-chloromethaneLewis
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CH1 Lewis
STRUCTURE
H
H
Cl
C
H
ee
e
1e
CH Cl1e
1-
1eLewis
1-1-chloromethaneLewis
H
H
e10e
e
1e
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CHOH1e
1-
1eLewis
Lewis
1-9
DimethyletherCHO
Dimethylether
H
H
C
O
H
dimethyletherLewis
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CH1 Lewis
STRUCTURE
H
H
Lewis
Lewis
H
H
C
H
H 1ee
C ee
O 1ee
0e
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10
C
H
e1e
ee
0e
Lewis
H
1-10
MethylamineCHNH
Methylamine
H
H
C
H
N
H
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CH1 Lewis
STRUCTURE
11
C
N
H
methylamineLewis
H
H
Lewis
Lewis
H
H
C
H
H
N
H
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12
H 1ee
C 1ee
N 1ee
1e
H
H
H
N
H
e1e
1ee
1e
Lewis
H
H
C
H
H
N
H
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CH1 Lewis
STRUCTURE
13
1-11
MethanethiolCHS
Methylamine
H
H
C
S
H
methylamineLewis
H
H
H
Lewis
Lewis
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14
H
H
H 1ee
C 1ee
S 1ee
1e
methylamineLewis
H
H
H
Lewis
e10e
ee
1e
Lewis
H
H
C
H
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CH1 Lewis
STRUCTURE
15
Lewis
Lewis
1-1EthyleneCH
Ethylene
H
C
H1ee
1Cee
1e
EthyleneLewis
H
C
H
C
H
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16
H
H
C
Lewis
e10e
ee
1e
1e1e
Lewis
C
H
C
H
C
H
H
Lewis
1e
1
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CH1 Lewis
STRUCTURE
17
1e
LewisEthylene
1-1FormaldehydeCHO
Formaldehyde
H
C
H1ee
1C1ee
1O1ee
1e
FormaldehydeLewis
H
C
H
Lewis
ee
ee
1e
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18
1e1e
Lewis
H
C
H
H
Lewis
ee
1
ee
1e
1e
LewisFormaldehyde
1-1AcetonitrileCHCN
Acetonitrile
H
H
C
H
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CH1 Lewis
STRUCTURE
19
H1ee
Cee
1N1ee
1e
acetonitrileLewis
H
H
H
Lewis
e10e
e10e
0e
1e0e
Lewis
[I]
[II]
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20
[I]1e[II]
1e[II]AcetonitrileLewis
1-1FormicacidHCOOH
Formicacid
O
H
H1ee
1C1ee
Oe1e
1e
Formic acidLewis
O
H
Lewis
ee
e1e
0e
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.
., 2014.04
ISBN 978-957-11-7593-5 ()
1.2.
460.31
103005979
5BD2
106 3 3 9 4
(02)2705-5066(02)2706-6100
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