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Eamcet 2014 Engineering Key Solutions
Andhracolleges
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2 2 Ma y 2 0 1 4
E A MC E T 2 0 1 4 -
E N G I N E E R I N G
P A P E R ( C O D E -
A ) 38

136.Which one of the
following correctly
represents the
variation of
electronegativity
(EN) withatomic
number (Z) of group
13 elements ?
(1) (2) (3) (4)
Key: 3Sol:
Conceptual
137.Which one of the
following elements
reacts with steam ?
(1)
Ge
(2)
Si
(3)
Sn
(4)
C
Key: 3Sol:
Conceptual
138.What are X and
Y in the following
reaction ?
uv22
C F C l X + Y

(1)
242
C F , C l ( 2
)
2
C F C l , F ( 3
)
22
CCl, F
:
(4)
2
CFCl,Ci
Key: 4Sol:
Conceptual
139.What are the
shapes of ethyne and
methane ?
( 1) t et rahedral
and t ri gonal
pl anar( 2) l i near
and
t et rahedral ( 3 )
t r i g o n a l
p l a n a r a n d
l i n e a r ( 4 )
s q u a r e p l a n a r
a n d l i n e a r
Key: 2Sol:
Conceptual
140.What is Z in the
following reaction ?
NaOHCaO+322

C H - C H -
C O N a Z


( 1 ) n -
b u t a n e ( 2 )
e t h a n e ( 3 )
e t h y n e ( 4 )
p r o p a n e
Key: 2Sol:
NaOHCaO+3
2 2
3 3

C H - C H -
C O N a C H -
C H


De carboxilation in
presence of sodalime
141.Which one of the
following gives sooty
flame on combustion
?
(1)
4
C H ( 2
)
26
C H ( 3
)
66
C H (
4 )
24
CH
Key: 3Sol:
Conceptual
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2 2 Ma y 2 0 1 4
E A MC E T 2 0 1 4 -
E N G I N E E R I N G
P A P E R ( C O D E -
A ) 39

142.Which one of the
following elements on
doping with
germanium, make it a
p-type semiconductor
(1)
Sb
(2)
As
(3)
Ga
(4)
Bi
Key: 1Sol:
Conceptual
143.The molar mass
of a solute X in g
1
mo l ,

if its 1% solution is
isotonic with a 5%
solution of
canesugar (molar
mass
1
=342gmol

), is
(1)
34.2
(2)
136.2
(3)
171.2
(4)
68.4
Key: 4Sol:
Osmatic pressure of
x

Osmatic pressure of
cane
sugar 1 1 0 0 0
5 1 0 0 0
R T = R
T M 1 0 0 3 4
2 1 0 0
M=68.4
144.Vapour pressure
in mm Hg of 0.1 mole
of urea in 180 g of
water at
0
25C
is(The vapour
pressure of water at
0
25C
is 24 mm Hg)
(1)
20.76
(2)
23.76
(3)
24.76
(4)
2.376
Key: 2Sol:
s0
P=P mole fraction
of urea
s
0.1P 2 4 2 . 3 7
6 2 4 0 . 2 4 2
3 . 7 6 0 . 1 1 0

145.At 298 K the
molar conductivities
at infinite dilution

0m

of
4
NHCl,KOH
and
KCl
are
152.8,272.6
and
2-1
149. 8Scmmol
respectively. The
0m

of
4
NHOH
in S
2-1
cmmol
and %dissociation
of 0.01
4
MNHOH
with
2-1m
2 5 . 1 c mmo l
S

at the same
temperature are
(1)
275.6,9.1
(2)
269.6,9.6
(3)
30,84
(4)
275.6,0.91
Key: 1Sol:

00044
NHOH=NHCl+KOHK
Cl
m m m

152. 8272. 6149. 8

275.6


0
25.19.1275.6
mm


146.In a first order
reaction the
concentration of the
reactant decreases
from 0.6 M to 0.3 M
in 15minutes. The
time taken for the
concentration to
change from
0.1M
to
0.025M
in minutes is
( 1 )
1 2 ( 2 )
3 0 ( 3 )
3 ( 4 )
1 . 2
Key: 2Sol:
12
t 1 5 m i n


0.12.303t 1 5
l o g 3 0
0 . 6 9 3 0 . 2 5

147.Assertion (A) :
Van der Waals are
responsible for
chemisorptionReaso
n (R) : High
temperature is
favourable for
chemisorptionThe
correct answer is
(1) (A) and (R) are
correct and (R) is the
correct explanation of
(A)(2) (A) and (R) are
correct but (R) is not
the correct
explanation of (A)(3)
(A) is correct but (R)
is not correct(4) (A) is
not correct but (R) is
correct
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2 2 Ma y 2 0 1 4
E A MC E T 2 0 1 4 -
E N G I N E E R I N G
P A P E R ( C O D E -
A ) 40

Key: 4Sol:
Conceptual
148.What is the role
of limestone during
the extraction of
iron from haematite
ore ?
( 1 ) o x i d i z i n g
a g e n t ( 2 )
r e d u c i n g
a g e n t ( 3 )
f l u x ( 4 )
l e a c h i n g
a g e n t
Key: 3Sol:
Conceptual
149.The charring of
sugar takes place
when treated with
concentrated
24
H S O .
What is the type
of reaction involved
in it ?
( 1 )
H y d r o l y s i s
r e a c t i o n ( 2 )
A d d i t i o n
r e a c t i o n ( 3)
Di s pr opor t i onat
i on r e ac t i on( 4)
De hy dr at i on
r e ac t i on
Key: 4Sol:
Conceptual
150.The structure of
4
XeOF
is
( 1) Squar e
pl anar ( 2)
Squar e
pyr ami dal ( 3)
Pyr ami dal ( 4)
Tr i gonal
bi pyr ami dal
Key: 2Sol:
Structure

of
4
XeOF
151.Which one of the
following ions has
same number of
unpaired electrons
as those present in
3+
V
ion ?
(1)
2
Ni

(2)
2
Mn

(3)
3
Cr

(4)
3
Fe

Key: 1Sol:
+ 3 2 0
V = 3 d 4 s

+80
Ni=3d4s
152Match the
followingL i
s t -
I L i s
t -
I I (A) sp
3
(I)

336
C o N H


(B) dsp
3
(II)

4
NiCo

(C) sp
3
d
2
(III)

322
P t N H C l

(D) d
2
sp
3
(IV)

36
CoF

(V)

5
F e C o

( A ) (
B ) ( C
) ( D ) 1
) ( V ) ( I
I ) ( I V )
( I I I ) 2
) ( I I ) (
I I I ) ( I
V ) ( I ) 3
) ( I I ) (
I I I ) ( I
) ( V ) 4
) ( I I I )
( I I ) ( I
V ) ( I )
Key: 2Sol:
Conceptual
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2 2 Ma y 2 0 1 4
E A MC E T 2 0 1 4 -
E N G I N E E R I N G
P A P E R ( C O D E -
A ) 41

153.Identify the
corpolymer from the
following:
1) [
22

C F C F ]

n
2)
[
22
Cl

C H C C H C H
]


n
3) [
2
Cl

C H C H ]


n
4) [
222
H56
C

C H C H C H C
H C H C H ]


n
Key: 4Sol:
Conceptual
154.Lactose is a
disaccharide of
________
1)
D G l u c o s e a n d D
G a l a c t o s e

2)
D G l u c o s e a n d D
R i b o s e

3)
D G l u c o s e a n d D
G a l a c t o s e

4)
D G l u c o s e a n d D
F r u c t o s e

Key: 1Sol:
Conceptual
155.What are the
substances which
mimic the natural
chemical
messengers?
1 )
A n t a g o n i s t s
2 )
A g o n i s t s 3 )
R e c e p t o r s
4 )
A n t i b i o t i c s
Key: 2Sol:
Conceptual
156.Which one of the
following is more
readily hydrolysed
by S
N
1 mechanism?
1)
652
C H C H B r 2
)

653
C H C H C H B r
3)

652
C H C H B r
4)

6532
C H C C H B r
Key: 4Sol:
Conceptual
157.
HI6 5 2
3
C H O C H
C H Y Z


Identify Y and Z in the
above reaction:YZ
1)
25
CHI
65
C HC HO 2)
65
CHI
32
HCCHOH3)
65
C H O H
32
H C C H I 4)
65
C H O H
33
HCCH
Key: 3Sol:
HI6 5
2 3 6
5 3 2

C H O C H C H
C H O H + H C
C H I

158.
Y
X B e n z o q u i n o n
e

Indetify X and Y in
the above reaction:
XY1)
2 2 7 2 4
NaCrO/HSO2)
2 2 7 2 4
NaCrO/HSO3) Zn4)
Zn
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2 2 Ma y 2 0 1 4
E A MC E T 2 0 1 4 -
E N G I N E E R I N G
P A P E R ( C O D E -
A ) 42

Key: 1Sol:
OH O
2 5 7 2 4
NaCrOHSO
O
159.
3
HODryether 32
H C M g
B r C O Y
Z


Identify Z from the
following:
1 ) A c e t i c
a c i d 2 )
P r o p a n i c
a c i d 3 ) Me t h y l
a c e t a t e 4 )
E t h y l a c e t a t e
Key: 1Sol:
3
dryether
3
2
3
3
C H M g B r + C O
O O H O
C H C O C H
C O H




160.What is Z in the
following reaction
sequence?
652
23223
i ) NaNOHCl / 273K i i )
H P O H O iii)CO, HCl;anhy
drousAlCl/CuCl
C H
N H
Z


1)
65
C H O H 2
)
65
C H C H O 3
)
66
C H 4
)
652
C H C O H
Key: 2Sol:
322232
H P O + H O NaNO,HCl,275KCO,HC
l+-
6 5
2 6
5 2
6 6
6 5 Anh
ydrousAlClCuCl
C H N H
C H -
N C l C
H C H -
C H O


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