Kelompok 2

11521054 Ari Ahmad Izzah

11521080 Retno Elakadesci
11521101 Muzaini
12521002 Adiliawan Imam A.
12521004 Noni Ayu Rizka
12521005 Herlina Yudha S. P .
12521007 Syelda Pratiwi
12521011 Annisa Sholicha

3-2. An ideal gas (Cp = 5, Cv = 3) is changed from P
1
= 1 (atm) V
1
= 359 (ft)
3
to P
2
= 10 (atm) and V
2
=
35.9 (ft)
3
by the following reversible processes:
a. Isothermal compression
b. Adiabatic compression followed by cooling at constant pressure
c. Adiabatic compression followed by cooling at constant volume
d. Heating at constant volume followed by cooling at constant pressure
e. Cooling at constant pressure followed by heating at constant volume
Calculate the work required, the heat transferred, and the changes in internal energy and enthalpy
for each of these overall processes. Sketch the paths followed in each process on a single PV
diagram.

Jawab

a. Isotermal

P
1
= 1 atm P
2
= 10 atm T
1
=

= 491,646 R
V
1
= 359 ft
3
V
2
= 35,9 ft
3


W = RT ln

= 0,7302 ( 491,646) ln

= -1377,02

1 2



b. Isobar Isometris


P
1
= 1 atm P
a
= 10 atm P
2
= 10 atm
V
1
= 359 ft
3
V
a
= ? V
2
= 35,9 ft
3

T
1
= ? T
a
= ? T
2
= ?

T
1
=

= 491,646 R
T
2
=

= 491,646 R

T
a
=

. (491,646 R)
= 1238 ,95 R
0
50
100
150
200
250
300
350
400
1 atm 10 atm
Diagram PV
Diagram PV
1 2
1



P
1
V
1

= P
a
V
a

V
a
=

1
=

= 7,675 ft
3
(1-a ) adiabatic (a-2) isobar
W = - CV (T
a
- T
1
) Q = H = C
p
dT
= -3 (1238,95 491,646) = 5 ( 491,646 1238,95 )
= -2241,912 = -3736,52
Q = 0
V = -W = 2241,912
H = 0

W = p d v
= p (V
2
V
a
) = 10 (35,9 7,675)
= 282 , 25
V = V - W
= -3736,52 - 282,25 = - 4018,77

W
1 2
= -2241,912 + 282,25 = - 1959,662
Q
1 2
= 0 3736,52 = - 3736,52
V = 2241,912 4018,77 = -1776,858
H = 0 3736,52 = - 3736,52

c. Adiabatic isotermis



P
1
= 1 atm P
a
= ? P
2
= 10 atm
V
1
= 359 ft
3
V
a
= 35,9 ft
3
V
2
= 35,9 ft
3

T
1
= 491,646 R T
a
= ? T
2
= 491,646 R
P
a
=

atm
T
a
=

. 491,646 = 2288,97 R

( 1- a) adiabatic (a-2) isotermis
W= - CP ( T
a
T
1
) W= 0
= -3 ( 2288, 97 491 , 646 ) V = Q = Cp dT
= -5391,972 = 3 ( 491,646 2288,97)
V = -W = 5391,972 H = 0
H = 0
Q = 0

W
1 2
= -5391,972 + 0 = -5391,972
Q
1 2
= 0 5391,972 = - 5391,972
H = 0
V = 5391,972 5391, 972 = 0

d. isometris isobar


P
1
= 1 atm P
a
= 10 P
2
= 10 atm
V
1
= 359 ft
3
V
a
= 359 ft
3
V
2
= 35,9 ft
3

T
1
= 491,646 R T
a
= ? T
2
= 491,646 R
T
a
=

(1-a ) isometric ( 1-2) isobar
W = 0 H = Q = Cp ( T
2
- T
a)

Q = V = CV (T
a
T
1
) = 5 (491,646-4916,46)
= 3 ( 4916,46-491,646) =5 (491,646- 4916,46)
= 13274,442 = - 22124,07
H = 0 W = 10 ( 35,9 -359) = -3231
V = H W
= -22124,07 + 3231
= - 18893,07
W
1 2
= 0 3231 = - 3231
Q
1 2
= 13274,442 22124,07 = -8849,628
V
1 2
= 13274,442 18893,07 = -5610,628
H
1 2
= 0 22124,07 = -22124,07

e. Isobar isometris


P
1
= 1 atm P
a
= 1 atm P
2
= 10 atm
V
1
= 359 ft
3
V
a
= 35,9 ft
3
V
2
= 35,9 ft
3

T
1
= 491,646 R T
a
= ? T
2
= 491,646 R
isobar (1-a) isometris
H = Q = Cp (T
a
T
1
) W = 0
= 5 (49,1646 491,646 ) Q = V = Cv (T
2
- T
a
)
= -2212 , 407 = 3 (491,646 49,1646)
V = -2212 , 407 1 (359 359) = 1327,4442
= -2212,407 H = 0

W = 1 ( 359-359) = 0
W
1 2
= 0 + 0 = 0
Q
1 2
= - 2212,407 + 1327,4442 = - 884,9628
V
1 2
= - 2212,407 + 1327,4442 = - 884,9628
H
1 2
= - 2212,407 + 0 = -2212,407

4-16. One method for determination of the second virial coefficient B of pure material involves the use
of the Claperyron equation with independently measured values of the heat of vaporization

, the molar volume

of the saturated liquid, and the vapor liquid saturation pressure

Using the Clapeyron equation, estimate B [in(cm)

3
/(g mol)] for methyl ethyl ketone (MEK)
at 75
0
C. The following data are available for MEK:
a.

= 7.553 cal/g.mol at 75
0
C
b.

= 96,491 cm
3
/g.mol for the liquid at 75
0
C
c.

= 43,53916 5.622,7/T 4,70504 ln T, where

is in atm and T is in K
d.

e.

Penyelesaian :
Persamaan Clapeyron

(4-6),
Mencari B

Untuk mendapatkan nilai B, data MEK harus dalam kondisi uap (gas)
Mencari V
uap
(satuan dalam SI)

Menghitung B
Asumsi: pada suhu 75
0
C terjadi pada tekanan 1 atm = 101,325 kPa, R = 8314 cm
3
/kPa.mol.K