Question No. Explanation Mark I Mark I (a) b(D (iD c(i) (iD d(D (iD (iii) No ofelectrons: 18, No of neutrons = 22 The total number ofprotons and neutrons in the nucleus of an atom 40 2. 7 w.Y Isotoires have the same number ofvalence electl'ons./proton number Carbin dating to estimate the age of fossils /artefacts/wood Total Marks 1+l 1 1 1 2 1 I 1 10 www.banksoalanspm.com Question No. Explaration Mark X Mark 2(a) (b) (D (iD (c) (d) (D (iiD (e) (0 Ts a represenktion of a chemical substance using lerters for atoms and subscripts for each type of atoms present in the substance. I Able to name suitable acid and metal and its equation ] For example Hydrochloric acid and zinc metal Zn+2HCl ) ZnCl 2 + LI 2 Hydrogen gas must be flowed/through/into the combustion tube for a few minutes before heating/ The flow o1'hydrogen gas must be continuous throughout the experimenV I Accept any one answer] Number of mole of copper = i.62 64 ' 0. 025mo1e Number of mole of oxygen = 0.40 t b : 0. 025mo1e Numper of mole of copper : Number of mole of oxygen 0.025 : 0.025 The simplest ratio 1 : 1 'I'he empirical formula of copper(Il) oxide is CuO Iron(II) oxide / Tin(II) oxide / Lead(II) oxide Burning of metal in exccss o.xygen Total marks I I 1 1 I I I I I r 0 www.banksoalanspm.com Question No. Explanation MK I Mark 3 (aX0 (ii) (bXD (iD c(i ) (i D d(D (iD Group 1 G and Period 4 DzL Soluble in water// high melting / boiling poinV/ conducts electricity in molten or aqueous solution E The nuclei attraction towards the valence electrons is weaker in E. 'I'hus it is easier for E to lose / release an electron to form a positively charged ion. L//M Covalent bond Total Marks 1+ 1 1 I 1 1 I 1 i 10 www.banksoalanspm.com Question No. Explanation Ivlark X Mark 4 (a) (b) (c) (d) (e) (r) (e) (i) (iD A weak acid is an acid that dissociates partially in water to produce hydrogen ions I Sour I t I Colourless to pink I t Neutralisation is an exothermic reaction./ releases heat I 1 Some ofthe energy produced during the reaction I between a weak acid and strong base is used to I ionise/dissociate completely the weak acid molecules. I t H - + OH - t I - I 2 O I I I Number of moles of malic acid= )=Q0 I = l'oo,r, -", I t I Number ofmoles ofsodium hydroxide used I : 2. 00 x 17. 30 | l ooo ] : 0.0746 mol i I I 1 mble of H* reacts with 1 mole of OH- l ThuS. number of mole of H+ ions I I in the sample = 0.0746 I t l l ] . O.O:Z+ mote of malic acid produces 0.0746 mole of I L nydrogen lon. I I Hence, I mole of malic acid produces 0.0J46 i I o.orz: l l ^ : 2mol eof r f I ' l o ' | ilo rf -of" of malic,acid : No^of mole of NaoH ] l 1 : 2 I I Therefore, malic acid is diprotic (proven) i ] total ma4r ] 10 www.banksoalanspm.com Question No. t r w nl onot i nn Mark X Mark sa(i) (iD (i i D (b) (c)(i) (iD Haber Prooess 3H2+N2) 2NH: Catalyst : Iron Temperature : 450oC Sulphur trioxide is dissolved in concentrated HzSQ+ to lorm oloum Oleum is diluted with water to produce sulphuric acid (NH+)zSO+ % of N: 4! D x 100% 132 : 21.21vo Total marks I 1 l I I l l r l 1 l I 1 1 1 l 0 www.banksoalanspm.com Question No. Explanation Mark I Mark 6(aXD (iD Ethanol One mole of ethanol when completely bumt in oxygen (undcr standard conditions) will release i260 kJ ofheat energy No of moles of alcohol : 0.23 I 46 : 0.005 mol I nrol ot alcohol burnt released lf60 kJ Thus, 0.005 mol ofalcohol burnt released 6.3 kJ mca: 6,3 kJ Mcs: 6. 3 x 1000 6: 6300/ 20Ox 4. 2 = 7. s" C (bXD (i l ) (cJ Heat is lost to the sunounding // Heat is absorbed by the apparatus or containers // Incomplete combustion (d) C z H s OH + 3 0 2 A F i : - 1260 KJMOI I Reaction path I Lub"l "n".gy -d diagram has 2 different energy levels I Balanced chemical equation (e) I - 2656 kJmorr // 2500-2700 kJmofl Total marks I I I I I I 1 I 1 I 10 www.banksoalanspm.com Question No. Explanation Mark X Mark 7(a) (bXD (iD (c) but-1-ene but-2-ene / 2-methylpropene 1. Correct skuctural formula 2. Correct name [Any two structural formulae and related names] X: propanol / propan-l -ol / propan-2-ol Y: propan-1,2-diol Z : propane React i on I : C: Ho+ Hzo)C: HzOH Reaction II : C:He + H20 + [O] ) C3Hr6(Oll)2 Reaotion III : C: Ik + FIz I C:Hr 1. Hexene is a unsaturated hydrocarbon while hexane is a saturated hydrocarbon 2. Hexene has a double bond between carbon and carbon atoms 3. Undergoes addition reaction when it reacts with bromine water 4. Hexane has single bond between carbon and carbon atoms 5. Cannot react with bromine water 6. ' /o of C in CaHr+ = 6(12) x 100% 86 7. : 83. 72% 8. % of C i n CeHru: 6(12) x 100% 84 9. = 85.71% 10. The percentage of carbon atoms in CeHr: is higher than CoHr+ Total marks H _ Fr I F I , C : } I H I I H r t t t f l - c = c - c - c - l t l { H F I H F I H l l l l FI - C - C - C - C - H l l H H FI I c . - l { l H t l C _ C : _ H I I{ l + 4 l + 1 l + l + l 1 I I I 1 I I 1 1 I 3 ^ 3 l 0 20 www.banksoalanspm.com Question No. Explanation Mark I Mark 8 (aXD (b) (D (ii) Correct apparatus set up Correct labelling Volume of gas I cmr Time/min Curve labelf ing a.xes with units CaCOr + 2IlCl * CaClz No. of mol es aci d - (0. 1)(50) = 1000 1 I I + CO: + HzO 5 x 10-3 2 mol of I'ICI reaated evolve I mol of COz 0.005 mol of HCI reacted evolve 0.005 mol of COz 2 = 0.0025 mol COz Volume of CC, :(0.0025X24) = 0.05 dm' = 60 cm" Overall average rate ofreaction =Total volume of COz Total time = 60 cm3 300 s = 0 . 2 c m3 s l www.banksoalanspm.com Rate of reaction in Expt II is higher than Expt I Experiment Il is at a higher temperature, the kinetic energy ofthe reaoting oarticles increases and the particles move I'aster Frequency ofcollision between marble and hydrogen ions increases Frequency o f efFectivc collision increases Rate of reaction in Expt III is higher than Expt I Powdered marble in Expt III has greater total surface areal bigger surfbce area per unit volume Powdered marble is more exposed to collision Frequency of collision between marble and hydrogen ions increascs Frequencv of elfcctive collision increase [ -l if students use HCI or particles in the explaination] I I 1 1 1 1 i I 1 1 www.banksoalanspm.com Question No. Explanation Mark I Mark e (a)(i) (b) (c) Precipitation // Exothermic Ag ' + Cl - t Ag c l Salt Y is added into a test tube and distilled water is added to dissolve it. The aqueous solution is separated into 3 portions. Sodium hydtoxide solution is added into one portion until in excess White precipitate formed dissolves in excess sodium hydroxide solution showing zinc ion , lead ion & aluminium ion may be present in salt Y. Ammonia solution is added to another portion until in excess . White precipitate dissolves confirming the presence of ion zinc in salt Y. Dilute sulphuric acid is added to t}te last portion , followed by acidified iron (II) sulphate solution and concentrated sulphuric acid. Brown ring formed sho*s the presence of NOr- ion in salt Y. Preparation of zinc sulphate salt About 50 cm3 of 1 mol dm-3 sulphuric acid is poured into a beaker. The beaker containing the sulphuric acid is heated gently . Zinc oxide powder is added little by liule into the warm sulphuric acid, and stirred continuously till the zinc oxide powder no longer dissolves in the acid. The excess zinc oxide is removed by filtering. The solution ofzinc sulphate /tle filtrate is poured into an evaporating dish and heated until it becomes saturated / concentrated. The hot saturated zinc sulphate solution is allowed to 1 I I I 1 I 1 i 1 1 I 1 I 1 i 1 I I I 2 Max 8 www.banksoalanspm.com cool and crystals of zinc sulphate are formed. The zinc sulphate crystals are filtered and then dried between sheets of filter papers. The equarion lor lhc rcaction is: ZnO + H2SOa---+ ZnSOa+ ll2O (accept procedures in active voice) I I t 0 Total marks 20 Question No. Explanation Mark I Mark 10 (a) I Chemical Equations : tt and III I I Reasons : Involving oxidation and reduction occurring ] simultaneously/at the same time I Reaction II Oxidation: Cu loses electron to form Cu:* I Reduction: Ag- gain electron to form Ag // Electron transfbr from Cu to Ag* or I O,.idution, Zn ioses electron to form Zn2' I ^ , ] Reduct i on: 2H' gai n el ecnon ro f orm H; l o r I Oxidation: Oxidation number of Zn increase from 0 to 2+ ] Reduction: Oxidation number of Ff decrsase from +l to 0 I i/ Eleotron transfer lrom Znto H+ I (bxi) j Bromine water Oxidation number of Ag' decrease from +1 to 0 Terminal Half- Observation negative Fet * ) Fej * +e Green to brown/yellow positive Br 2 I 2s) 2Br - bro$.n to colourless /decolourises (iD t +l I l + 1 Max 6 i l l +l 1 l +l I +1 www.banksoalanspm.com Draw out I cm' of the solution from terminal nesative into a test tube. Add NaOH / NH3 solution / Potassium l{exanocyanofenzte(Il) solution to the test tube Observation: Brown ppt / brown ppt / dark blue ppt respectively. Shows that iron(il) ion is changed / oxidised to iron(Il) ion [ -l if students does not construct a table ] Electrolytic Cells Chemicals Cells Energy change Electrical energy ) Chemical energy Chemical Energy ) Electrical Energy Half-equation at anooe Cu I Cu'- + 2e Zn l Zn"' + 2e Electron flow Electrons flow Iiom anode to cathode. Electrons flow from zinc to copper./ l +l 1+1 1+l www.banksoalanspm.com