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56 2 1 Chemistry
56 2 1 Chemistry
Series OSR/2
Code No.
amob Z.
56/2/1
Roll No.
A{YH$V_ AH$ : 70
Maximum Marks : 70
1
P.T.O.
gm_m` {ZX}e :
(i)
(ii)
Z-g`m 1 go 8 VH$ A{V bKw-Cmar` Z h & `oH$ Z Ho$ {bE 1 AH$ h &
(iii)
(iv)
(v)
(vi)
Amd`H$VmZwgma bmJ Q>o~bm| H$m `moJ H$a| & H$Hw$boQ>am| Ho$ Cn`moJ H$s AZw_{V Zht h &
General Instructions :
(i)
(ii)
(iii)
(iv)
(v)
(vi)
1.
(collectors) H$m
`m H$m` hmoVm
1
What is the function of collectors in the froth floatation process for the
concentration of ores ?
2.
3.
EH$b
NN
Am~Y EH$b
PP
(isomerism) X{eV
H$aVm h
[Co(NH3)6][Cr(CN)6]
What type of isomerism is shown by the following complex :
[Co(NH3)6][Cr(CN)6]
5.
b.c.c.
(r)
(a)
Ho$ Amngr
1
Express the relationship between atomic radius (r) and the edge
length (a) in the b.c.c. unit cell.
6.
(IUPAC) Zm_
{b{IE
7.
8.
-byH$moO
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P.T.O.
9.
Ho$ EH$ {db`Z H$m b{Q>Z_ Ho$ BboQ>moS>m| Ho$ ~rM 5.0 Eonr`a {dwV Ymam go
20 {_ZQ> VH$ dwV AnKQ>Z {H$`m J`m & H$WmoS> na {ZH$b H$m {H$VZm `_mZ {Zjo{nV
hmoJm ?
Ni(NO3)2
({X`m J`m h : {ZH$b H$m na_mUw `_mZ = 58.7 g mol1, 1 F = 96500 C mol1)
A solution of Ni(NO3)2 is electrolysed between platinum electrodes using
a current of 5.0 ampere for 20 minutes. What mass of nickel will be
deposited at the cathode ?
(Given : At. Mass of Ni = 58.7 g mol1, 1 F = 96500 C mol1)
10.
A{^{H$`m H$s AY Am`w H$s n[a^mfm {b{IE & {ZZ Ho$ AY Am`w Ho$ {b`o `OH$
{b{IE :
(i)
(ii)
11.
(i)
(ii)
12.
g\$a Ho$ Xmo A{V _hdnyU Ana$nm| Ho$ Zm_ {b{IE & BZ XmoZm| _| go H$mZ-gm H$j Vmn
na Wm`r hmoVm h ? `m hmoVm h O~ Wm`r $n H$mo 370 K go D$na Ja_ {H$`m OmVm h ?
AWdm
56/2/1
(i)
gnH$ {d{Y go H2SO4 H$s m{ H$mo A{YH$V_ ~ZmZo Ho$ {V~Y {b{IE &
(ii)
Ob _o
H2SO4 Ho$
Name the two most important allotropes of sulphur. Which one of the two
is stable at room temperature ? What happens when the stable form is
heated above 370 K ?
OR
13.
(i)
(ii)
MnO 4
(i)
(ii)
Cr2O7
+ 5 S2 + 16 H+
+ 2 OH
14.
(i)
2 MnO 4 + 5 S2 + 16 H+
(ii)
Cr2O7
+ 2 OH
IUPAC Zm_
{b{IE &
Write the state of hybridization, shape and IUPAC name of the complex
[CoF6]3 . (Atomic no. of Co = 27)
15.
(ii)
O~ {ZOb
OmVr h &
AlCl3
KOH go
CH3COCl
go A{^{H$`m H$s
56/2/1
(i)
(ii)
P.T.O.
16.
(a)
{ZZ `w_m| go {H$g EopH$b hobmBS> H$s Amn SN2 {H$`m{d{Y mam A{YH$ VrdVm
go A{^{H$`m H$aZo H$s Amem H$a|Jo Ama `m| ?
CH3 CH2 CH CH3
Br
(b)
SN1 A{^{H$`mAm|
(a)
Which alkyl halide from the following pairs would you expect to
react more rapidly by an SN2 mechanism and why ?
(b)
17.
Br
Racemisation occurs in SN1 reactions. Why ?
HBr
CH3CH2OH
CH3CH2Br H2O
Write the mechanism of the following reaction :
HBr
CH3CH2OH
CH3CH2Br H2O
18.
56/2/1
(i)
(ii)
Butan-2-one to Butan-2-ol
(iii)
(iv)
19.
(i)
KCl {H$g
(ii)
{g{bH$mZ H$mo
(iii)
(iv)
(i)
(ii)
(iii)
CO2 or SiO2
20.
(iv)
(i)
(ii)
H2 O2
make
better
magnets,
gob
3
(i)
(ii)
Calculate Ecell .
56/2/1
P.T.O.
21.
SO2Cl2
`moJ
1
0 .4
100
0 .7
log 2 = 0.3010)
The following data were obtained during the first order thermal
decomposition of SO2Cl2 at a constant volume :
Time/s1
Total pressure/atm
0 .4
100
0 .7
(a)
(b)
(c)
56/2/1
(a)
(b)
(c)
23.
(a)
(b)
(c)
3d-bmH$
`m| ?
AWdm
{ZZ Ho$ {bE Cn`w$ H$maU {b{IE
+3
Fe2+
(a)
AnZr
(b)
Sc (Z = 21)
(c)
(a)
(b)
(c)
hmoVm h O~{H$
3d
Ti3+ aJrZ
Zn
H$s
hmoVm h &
OR
Assign suitable reasons for the following :
(a)
The Mn2+ compounds are more stable than Fe2+ towards oxidation
to their + 3 state.
(b)
(c)
56/2/1
P.T.O.
24.
{ZZ A{^{H$`mAm| _|
A, B Ama C H$s
gaMZmE ~VmBE :
(i)
HNO2
LiAlH4
KCN
CH3Br A
B
C
273 K
(ii)
NH3
CHCl NaOH
Br2 KOH
CH3COOH
A
B 3
C
25.
(i)
HNO2
LiAlH4
KCN
CH3Br A
B
C
273 K
(ii)
NH3
CHCl NaOH
Br2 KOH
CH3COOH
A
B 3
C
26.
(a)
Anomers
(b)
Denaturation of proteins
(c)
(i)
(iii)
(i)
(ii)
(iii)
(ii)
56/2/1
10
27.
bmpQ>>H$ Ho$ Wbm| na {V~Y bJ OmZo Ho$ CnamV, EH$ Hy$b Ho$ N>mm| Zo {ZU` {b`m {H$
dh bmoJm| H$mo dmVmdaU Ama `_wZm ZXr na bmpQ>>H$ Ho$ Wbm| Ho$ hm{ZH$maH$ ^mdm| go
gy{MV H$a|Jo & ~mV H$mo A{YH$ ^mdr ~ZmZo Ho$ {bE, Chm|Zo Xgao Hy$bm| Ho$ gmW {_bH$a
EH$ abr aMr Ama gpO`m ~oMZo dmbm|, XH$mZXmam| Ama {S>nmQ>_oQ>b Q>moam| _| H$mJO Ho$
Wbo ~mQ>o & g^r N>mm| Zo U {H$`m {H$ do `_wZm ZXr H$mo ~MmZo Ho$ {bE ^{d` _| nmbrWrZ
Ho$ Wbm| H$m `moJ Zht H$a|Jo &
Cn`w$ boIme H$mo nT>H$a {ZZ Zm| Ho$ Cma Xr{OE
(i)
(ii)
(iii)
After the ban on plastic bags, students of one school decided to create
awareness among the people about the harmful effects of plastic bags on
the environment and the Yamuna river. To make it more impactful, they
organized a rally by joining hands with other schools and distributed
paper bags to vegetable vendors, shopkeepers and departmental stores.
All students pledged not to use polythene bags in future to save the
Yamuna river.
After reading the above passage, answer the following questions :
56/2/1
(i)
(ii)
(iii)
11
P.T.O.
28.
(a)
(b)
(a)
(b)
(a)
dmnerb Ad`dm| dmbo {db`Z Ho$ {bE amCQ> {Z`_ {b{IE & g^r gmUm|o Ama
VmnH$_m| na amCQ> {Z`_ AZwgma ahZo dmbo {db`Z H$m Zm_ {b{IE &
Ob _| 10 g CaCl2 KmobZo go m hE {db`Z Ho$ {bE dWZmH$ C`Z
H$mo n[aH${bV H$s{OE & (Ob Ho$ {bE Kb = 0.512 K kg mol1,
CaCl2 H$m _moba `_mZ = 111 g mol1)
AWdm
200 g
pWadmWr (Eo{O`moQ>mon)
(ii)
(iii)
9.8% (w/w) H2SO4 Ho$ {db`Z H$s _mobaVm n[aH${bV H$s{OE `{X Bg {db`Z
H$m KZd 1.02 g ml1 hmo & (H2SO4 H$m _moba `_mZ = 98 g mol1)
(a)
(b)
56/2/1
Azeotrope
(ii)
Osmotic pressure
(iii)
Colligative properties
(b)
29.
(a)
(b)
(i)
XeOF4
(ii)
HClO4
AWdm
(a)
(b)
(a)
(b)
H2S2O8
(ii)
bmb
P4
(i)
(ii)
(iii)
(ii)
(iii)
XeOF4
(ii)
HClO4
OR
(a)
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H2S2O8
(ii)
Red P4
13
P.T.O.
30.
(b)
(a)
EoWoZb Ho$ {ZZ A{^H$maH$m| Ho$ gmW A{^{H$`m H$aZo na ~Zo CnmXm| H$mo {b{IE
(i)
CH3MgBr go Ama {\$a H3O+ go
(ii) Zn-Hg/gm HCl go
(iii)
(b)
56/2/1
(a)
(b)
(a)
Write the products formed when ethanal reacts with the following
reagents :
(i)
(ii)
Zn-Hg/conc. HCl
(iii)
(b)
(ii)
(a)
(b)
56/2/1
(ii)
There
are
two
NH2 groups
in
semicarbazide
(H2NNHCONH2). However, only one is involved in the
formation of semicarbazone.
Rosenmund reduction
(ii)
Hell-Volhard-Zelinsky reaction
(iii)
Cannizzaro reaction
15
2,800
P.T.O.