"manishkumarphysics.

in"
1
CHEMISTRY
uai fariii aii s4ifn+ +ifa+ ui4a-I
uai fariii
1. uaai +t +ifa +t niai (Calculation of Degree of Unsaturation (DU))
l+=i = --- ti:i +i- n <i ti:i- nii~i +i +ni -=+i ~= ---i +i +il i ti:i - ---i +tni-i t
) O DU (
CH C H C H
3 2 3
=

H 2

H 2
CH
3
C CH or CH
2
= C = CH
2
or
~ii- <i ti:i - +i +ni = 1 DU
(i) 1DU = 1 n i 1 l,i +i -l-i-i
(ii) 2DU= 2 l, i i 1 lzi i i <i n i 1 l,i ~i 1 n +i -l-i-i
G.F. D.U.
(i) C
x
H
y
(x + 1) |
.
|

\
|
2
y
(ii) C
x
H
y
O
z
(x + 1) |
.
|

\
| +
2
o y
(iii) C
x
H
y
X
s
(x + 1) |
.
|

\
| +
2
s y
(iv) C
x
H
y
N
w
(x + 1) |
.
|

\
|
2
w y
(v) C
x
H
y
O
z
X
s
N
w
(x + 1) |
.
|

\
| +
2
w s y
2. iainitat+i
(+ (-+ - i (+ =i:+ni (-+ - +i l+i t ni - (Cl
2
, Br
2
, F
2
, I
2
) = +i: i-i t . (+ +i i =il-+ ~lil+i
ti -i t ~i (+ C H-i -i t -ii C Cl -i --i t ~- (+ H-nii . t ni - nii ,ii l--iil-
ti-i t. -i := ni -i t ni-i+i ~lil+i +t- t
Ex.1 CH
4

v h / Cl
2
CH
3
Cl + HCl Ex.2 CH
3
CH
3

Sunlight / Cl
2
CH
3
CH
2
Cl + HCl
Ex.3

v h / Cl
2
Cl

+ HCl Ex.4

v h / Cl
2
+ HCl
Ex.5

v h / Cl
2
Cl

+ HCl
as4in : l< +i : ~i n (+ = ~li+ +i + H-nii i-i t . - ni -i +ni i-i+i t ni -i +ni i =nili +i lni
--i t t =ii =nii l-il- =nii ti - t
fa+i : :== t l-+i l-+n-i t l+ ni -i +ni i i ln+ + l-il- =nili +i + n = i H-nii + +i + i ti -i
t i l+ ~li+n + n -l-il- t lli-- +i + H-nii ~i +i ~=n ti: i - i ~- - ti: i - i i=il-+
= li-- ti: i - ii +t- t
"manishkumarphysics.in"
2
CHEMISTRY
Ex.6 CH
3
CH
2
CH
3

jhuhdj.k eksuksDyks
2 =--in+ ni-i+nii -i<
Ex.7 CH
3
CH
2
CH
2
CH
3

jhuhdj.k eksuksDyks
2 =--in+ ni-i+nii -i<
Ex.8 CH
3
CH
2
CH
2
CH
2
CH
3

jhuhdj.k eksuksDyks
3 =--in+ ni-i+nii -i<
Ex.9
jhuhdj.k eksuksDyks
4 =--in+ ni-i+nii -i<
Ex.10
CH
3

jhuhdj.k eksuksDyks
5 =--in+ ni-i+nii -i<
fasit : (i n l+ ti: i +i -i n iz ini + H-nii ~i +i +ni i-i+i ti -i t . l+-- -i- n + Hnii -iii ti -
t ziz -i- +i ni-i +ni i-i+i -ti ti -i
Ex.11

CH
3

v h / Cl
2

CH Cl
2
3. C = C; C C +i a-s+t4 ririat+i
(i) (-+i-. (-+i:-. i ni:- ~i i ni~i:-= ~il< +i ti: i -i+i - + Ni/Pt/Pd ,ii +n + -i l+i i
=+-i t
(ii) =ii C Ct -i (C= C, C C) +i ti: i -i+i ti -i t ~lil+i +i l+=i ii niln+ l-il- -ti
i+i i =+-i
(iii) (inl+ t -i +n + -i -iii ti- t. l+-- --- -i ti:i -i+i ti =+-i t
(iv) :== l-+i l-+ini i =+-i t l+ (-+i-. (-+i:- i +i : ii ~= - -- i ln+ +i ti: i -i+i -i< =<
=--- iln+ ti-i t
(v) (+ nin iln+ n +- ti:i- + nini +i =i -l-i- t -ii +i = i + =ni- ti -i t
(vi) l-il- =nii (-+i- i (-+i:- (tn-i) +i ti:i-i+i +- =ni- -i< <- t
(vii) -+i ti:i-i+i n +i- ++in n +i: <ni -ti ~i-i t
uii-4 fif+4i :-
R CH = CH R + H
2

Ni
R CH
2
CH
2
R
R C C R + 2H
2

Pd / Pt / Ni
R CH
2
CH
2
R
) (
R CH CH R
vizFkDd`r
=

2
H
R CH
2
CH
2
R
CH
2
= CH CH
2
CH
3

Ni / H 2
2
CH
3
CH
2
CH
2
CH
3

Ni / H 3
2
"manishkumarphysics.in"
3
CHEMISTRY

CH = CH
2
ij rki ds dejs

Ni / H
2

CH CH
3 2
H /Ni
(100 150C)
2

CH CH
3 2
A

] Ni [ H
2
[l+=i ii n-i l-il- ~lil+i +i i +i -ti i =+-i ]
Ex.12
Ni / H 2
2
(X)

v h / Cl
2
C Cl
+
Cl
Ex.13
CH
3

Ni / H
2
CH
3

v h / Cl
2
5 ni-i+nii =--in+ -i<
Ex.14
CH
3

Ni / H
2
CH
3

v h / Cl
2
5 ni-i+nii =--in+ -i<
4. iiat+i :
(i) t ~= - ---i +i l-il- <zii -i t
(ii) (-+i- ( ini(-+i- + ~i i -i+i ~i+=i+i l<n- ti -i t
(iii) (a) ~-i+ ~ii -i+i + ~li+n + l--- t
(i) O
3
(~ii-) (ii) Zn -ii H
2
Oi Zn -ii CH
3
COOHi (CH
3
)
2
S
(b) ~i+=i+i+ ~i i -i+i + ~li+n + O
3
~i H
2
O
2
t
(iv) -i< l< +ii l-n iln+ ((l-ti: i +ii-) t -i := +i +i ~i i-i+i ~-i+ ~ii-i+i +tni-i t
(v) ~i i -i+i ~- l+in+ =n t + =ii l+=i +i +i ii- -ti +-i
uii-4 fif+4i :- R CH = CH R
(1) O
(2) Zn/H O
3
2
R CH = O + O = CH R + ZnO + H
2
O
Ex.15 CH
2
= CH
2
(1) O
(2) Zn/H O
3
2
CH
2
= O + CH
2
= O
Ex.16 CH
3
CH
2
CH = CH
2
(1) O
(2) Zn/H O
3
2
CH
3
CH
2
CH = O + O = CH
2
Ex.17 CH
2
= CH CH
2
CH = CH CH
3
O
3
/ Zn
CH
2
= O + O = CH CH
2
CH = O + O = CH CH
3
Ex.18

Zn O /
3
+ OHC CH
2
CHO (i-i:(n)
"manishkumarphysics.in"
4
CHEMISTRY
as4in :
l+i +i -in ~i n C= C+i l-il- ai- +- n l+i i-i t
l< -i< - = i l- ti - t -i C=C+i l-il- ai- +i i =+-i t =ii C=C-i ((i n l+ +i zi +) =ini-
ll-il-i n ~i+=i+i+ li- ti -i t
--- -i (i n l+ l,-i +i ii ~ii-i+i ti =+-i t
Ex.19
Zn
3
O
O = CH CH
2
C
O
CH
2
HC = O + O = CH
2
Ex.20
Zn
) ( O
3

A
Ex.21
CH = CH CH
3

Zn / O3

rki fuEu

CH = O
+ O = CH CH
3
Ex.22
CH = CH
O /H Zn
2
3
O

C
6
H
5
CH = O
POC-I :
ifjp;
(+ +i i=i-a +i n - z - +i l-+ i ln+i +i = --i +i l-ii i +-i t i l+ ~-i zi z ~-ii n i
-i i+ l-+ -zii- i i nziini n -i i- t
-
+i l-+ i ln+ +i =ti = --i l-ii i n l+=i ii +i l-+ i ln+ n -l-i- - l+in+ =n t +i l-ii i ~iz+ t
a- +i st+ii (nii-+ fznii) :-
-
~li+- +i l-+ iln+ 2 = 5 ~nn~nn - i- t
-
n (principal) - +i -. ti:i- ~i ~i+=i- t
-
+n i i- in - -i:i-. =-+ ~i tni- ti- t
-
+ z +i l-+ i ln+i n . +i-+i = ~i ii- ii -l-i- t- t
-
+il-+ i ln+i n i i- in -i +i il+-i -i- <i n: t :-
+i- tnzii -l-i-
ti: i - nnin tnzii -l-i-
~i+=i-

=ini- -l-i-
-i:i-. tni-, =-+ +ii+ii -l-i-
+i-+i = ~i ii-

t- +n -l-i-
-
+il-+ iln+i n -i:i-. =-+ ~i tni- +i l-iii n =i- i-ii ,ii l+i i-i t
-
+i l-+ i ln+ (N,S~i t ni -) =i ln ii- + =ii ~lil+i +- t . -il+ - ~i-i+ - ~+i l-+ <ii n <n
i = -i:i- =iln =i-i: n. =-+ =iln =-+i: n. tni- =iln tni: n
-
=i-i:. =-+i: ~i tni: ~i- ni ln- n lli-- i-ii ,ii l-lz-- ti i- t t ni ln-
n=i- l-+i +tni-i t
"manishkumarphysics.in"
5
CHEMISTRY
4.1 +ifa+ 4ifn+i asfia a-i +t sria
2. =-+
3. tni-
4. +i-+i=
5. -i: i -
~i =-+
fa+i
-in t n i lzi- n n +i
l<ii: <-i -i:i- +i -l-il-
vnili- +-i t
=+ < ~-i +i vi-- ti-i =-+
+i -l-il- <zii-i t
n-i n +i --i =-+ +i
-l-il- +i vnili- +-i t
=+< ~-i i NH
4
OHn ln
t . +ni i- +i -l-il- <zii -i t
t-+i in n +i ~-i l=+i
+ z iin NH
4
OHn ln t i ni-
+i -l-il- +i <zii-i t
in n +i ~-i i i-i
NH
4
OHn ~ln t . ~ii i- +i
-l-il- <zii-i t
~lil+i n vi-- n -ilzin
i:i+i-+ +i =+< ~-i
+i-+i= +i -l-il- +i <zii-i
t
+- + =ni- nin n +i --i
-i:i- ( =-+ <i-i +i
-l-i- +i vnili- +-i t
a-
1. -i: i-
st+ii / fif+4i
n=i- i-ii
Na + C + N NaCN
FeSO
4
+ 6NaCN Na
4
[Fe(CN)
6
] + Na
2
SO
4
3Na
4
[Fe(CN)
6
] + 4FeCl
3
Fe
4
[Fe(CN)
6
]
3
+ 12NaCl
(a) ~i+=i+i i-ii
3KNO
3
3KNO
2
+ 3[O]
Na
2
CO
3
+ S + 3[O] Na
2
SO
4
+ CO
2
BaCl
2
(aq) + Na
2
SO
4
(aq) BaSO
4
+ + 2NaCl(aq)
(b) n=i- i-ii
2Na + S Na
2
S
Na
2
S + Na
2
[Fe(CN)
5
NO] Na
4
[Fe(CN)
5
NO.S]
n=i- i-ii
X + Na NaX
NaX +AgNO
3
NaNO
3
+Ag X +
H
2
PO
4
+ n-lzii lni MgP
2
O
7
+ H
2
O
2MgNH
4
PO
4
Mg
2
P
2
O
7
+ + 2NH
3
+ H
2
O
n=i- i-ii
Na + C + N + S NaSCN
3
FeCl
Fe(SCN)
3
"manishkumarphysics.in"
6
CHEMISTRY
f
+
4
i
-

+
u

r
C

C
C
=
C
/
C

C
C
=
C
C

C
R

C
H
(
R

O
H
)
R
O
H
3

i
+

+
=
i
-
<

H
2
S
O
4
=
i
-
<

N
a
O
H
K
M
n
O
4
L
i
A
l
H
4
[

~
l

i
+
n
+
]
a
l
k
.
d
i
l
.
c
o
l
d
K
M
N
O
4
B
r
2
/
H
2
O
O
3
(
~
i

i
-
)
O
3
(
a
)
+

v
=
+
n
i

i
:

+
N
H
4
O
H
(
b
)
A
g
N
O
3
+
N
H
4
O
H
N
a
-

+
i
=
~
l

i
+
n
+
[
=
i
-
<

H
C
l
+
~

n
i

Z
n
C
l
2
]
f
a

t
+
i

i
+
i
:

~
l

i
l
+

i
-
t
i

+
i
:

~
l

i
l
+

i
-
t
i

+
i
:

~
l

i
l
+

i
-
t
i

+
i
:

~
l

i
l
+

i
-
t
i

n
n
i

n
~
<
z

n
i
n

n
~
<
z

t
i

i
-
i
t

=
O

i
l
n
+
~
-
n
+
i
l
-
n
i

i
t
i
-
i
t

n
i
n
~

-
i

v
i
-
-
t
i
-
i
t

=
+
<
~

-
i

v
i
-
-
t
i
-
i
t

H
2

n
i

l
-
+
n
-
i
t

(
3
)

-
-
+
n
i
-

i
-
=
~
i
-
i
t

(
2

)
5
l
n
-

+
n
i
-

i
-
=
(
1

)
3
0
l
n
-

i
<
+
n
i
-

i
-
=
~
i
-
i
t

i
f
+
4
i
-
-
-
-
-
-
-
-
-
-
-
-
-
-
=
+
<
~

-
i

H
2
C
=
C
H
2
+
O
3
2
H
C
H
O
R

R
'
R
C
O
O
H
+
R
'
C
O
O
H
R

C
H
+
C
u
C
l
R

C
C
u
+
(
n
i
n
)
R

C
H
+
A
g
+
R

C
A
g
+
(
=
+
<
)
2
R
O
H
+
N
a

2
R
O
N
a
+
H
2
|
R

O
H
+
H
C
l
+
H
2
O
c
l
o
u
d
i
n
e
s
s
f
a

~
l
+

i
l
+
-
t
i
:

i
+
=
i
n
z
i
-
(

-
l
+

i
)

i
n
i
-
i
+

i
~
l

i
l
+

i
~
i

i
-
i
+

i
~
l

i
l
+

i
~
i

i
-
i
+

i
~
l

i
l
+

i
=
l
+

+
i
-

l
-

i
l
-
-

+
i
=

i
-
i

i
I
.
-
-
i

+
(
-
+
i
t
n
I
I
.
l
,
-
i

+
(
-
+
i
t
n
I
I
I
.
v
i

i
l
n
+
(
-
+
i
t
n
4
.
2
v
i
4
i
f
n
+
s

t
+
i

i
i

z
i

i
f

i
-
a
f
+
4
i
-

+
u

r
i

+
t
s
r

i
a

"manishkumarphysics.in"
7
CHEMISTRY
f
+
4
i
-

+
u

r
A
r

O
H
l
+
-
i
n
R

C
H
O
R

C
O
C
H
3
o
r
A
r
C
O
C
H
3
o
r
C
H
3
C
H
O
(
-

(
n
i
:

i
+

+
F
e
C
l
3
(
-
<
i
=
i
-
)
2
,
4
-

i
:
-
i
:

i
+
l
-
n
t
i
:

i
-
(
2
,
4
-
D
N
P
)
l

-
+
l
n
n
l

-
A
&
B

i
n
:
-
~
l

i
+
n
+
l
z
i
+
~
l

i
+
n
+
*
I
2
/
N
a
O
H
-
i
n
i
l
n

n
=

z
i
=
i
-
<

N
a
H
C
O
3
l

-
N
a
O
H
,
l
+
-
i
+

i
l
n
-
=
i
-
<

N
a
O
H
,
A
f
a

t
+
i

n
i
-
~

-
i

n
-
i
,
-
i
n
i
,
t

i
)

i
n
i
-
i

n
i
~

-
i

n
i
n
~

-
i

+
i
n
i
~

-
i

~
i

-
v
l
-
l

n
n
i

n
-

-
-
C
H
I
3
+
i

i
n
i
~

-
i

(
~
i

i
+
i
n
)
-
i
n
i
l
n

n
=
n
i
n
l
n

n
=

z
i
n

<
n

i
-
i
t

l
-
+
n
-

n
n
-

n
n
i

n




+
n
n

~
<
z

N
H
3
+
i
n

i
f
+
4
i
+
H
2
H

+
(

i
n
i
-
i

n
i
~

-
i

)
R
C
H
O
+
C
u
+
2

R
C
O
O
H
+
C
u
2
O
+
+
2
H
2
O
+
l
n
n
l

-
.
n
i
n
R
C
H
O
+
A
g
+

R
C
O
O
H
+
2
A
g
(

-
<

i
)
H
2
O
+
C
O
2
|
R
C
O
O
R

+
N
a
O
H
+
l
+
-
i
+

i
n
i
-
(
n
n
i

i
)
R
C
O
O
H
+
R

O
H
(

n
t
i
-
l

-
)
R
C
O
N
H
2
+
N
a
O
H
R
C
O
O
N
a
+
N
H
3

|
f
a

:
-
i
-
=
(

l
+
-
i
n
+
i

i
-
i

i
D
N
P
-

i
-
i

i
+
l
n
n

i
-
i

i
n
:
-

i
-
i

i
~
i

i
+
i
n

~
l

i
l
+

i
l
n

n
=

i
-
i

i
=
i
l

i
:
+
i

i
-

i
-
i

i
l
z
i
+
~
l

i
+
n
+
:
p
-

i
l
=
l
-
l
n
-
t
i
:

i
+
n
i

i
:

S
O
2
=

=
-
-
-
t
,
:
=
l
n

n
t
i
-
t

R
C
H
O
.
,
i

i
n
n
i

i
-
-
t
i
-
i
t

"manishkumarphysics.in"
8
CHEMISTRY
f
+
4
i
-

+
u

r
-
i
:

i
l
n
+
(
R
C
H
2
N
O
2
)
o
r
A
r
N
O
2
v
i

i
l
n
+
(
n
i
-
R
N
H
2
(

i
n
l

+
(
n
i
-
A
r
N
H
2
R
2
N
H
l
,
-
i

+
(
n
i
-
+
i

i
t
i
:

(
n
i
-
i

~
-
n

i
+

+
n
l
n
+
-
=

i
-
i

i
C
H
C
l
3
,
K
O
H
H
N
O
2
(
N
a
N
O
2
+
H
C
l
)
H
N
O
2
(
N
a
N
O
2
+
H
C
l
)
+
|
-
-
+

i
i
n
(
i
)
N
a
N
O
2
+
H
2
S
O
4
(
i
i
)
l
+
-
i
n
n
i
l
n
z
i
~
l

i
+
n
+
(
1
0
%
(
-
+
i
t
n
n

|
-
-
+

i
i
n
)
l
-
-
t
i
:
l

-
~
l

i
+
n
+
(
0
.
2
%
s
o
l
.
n
)
f
a

t
+
i

i
+
i
n
i
~

-
i

l
-
+

i
(
+
i

i
n
(
n
i
-
)
N
2

n
i

l
-
+
n
-
i
t

-
i

n
i
n
i
n

n
+
i

i
:

(
d
y
e
)

-
-
i
t

n
i
n

n
-

-
-
t
i
-
i
(
l
n

n
i
-

i
-
i

i
)
n
i
n

n
-
i

n
-

-
-
t
i
-
i
t

n
-
i

i
f
+
4
i
A
r
N
H
O
H
A
g
A
g
+
R
N
H
2
+
C
H
C
l
3
+
3
K
O
H
R
N
C
+
3
K
C
l
+
3
H
2
O
R
N
H
2
+
H
O
N
O
R
O
H
+
N
2
+
H
2
O
f
a

+
i

i
n
(
n
i
-
~
l

i
l
+

i
-
i

i
l
-
-
t
i
:
l

i
-
i

i
N
a
N
O
2
+
H
C
l
N
a
C
l
+
H
N
O
2
+
H
N
O
2
+
2
H
2
O
N
H
2
.
H
C
l
N
2
C
l
N
=
N
-
C
l
+ O
H
O
H
N
=
N
-
i

n
i
n
i
n

i
:

i
-

i
:
(

i
l
-

n
+
n
i

i
:

-
+

i
i
n
+
H
2
N
.
C
H
R
.
C
O
O
H
(
~
n
i
-
i

~
-
n
)
C
O
C
O
C
O
H
O
H
(
l
-
-
t
i
:

i
-
)
C
O
C
O
(
-
i
n
i

n
)
C
O
C
=
N

C
CO
H
+
R
C
H
O
+
H
2
O
+
C
O
2
-
i
n
i

n
"manishkumarphysics.in"
9
CHEMISTRY
MISCELLANEOUS SOLVED PROBLEMS (MSPS)
1. Identify X, Y & Z with the help of following reactions.
(X)
) n Hydrocarbo
Saturated (
) H C (
18 9

u h / Cl
2
Single monochloro structural product
(Y) (C
8
H
18
)

u h / Cl
2
Single monochloro structural product
(Z)
) n Hydrocarbo
Saturated (
) H C (
14 7

u h / Cl
2
Two monochloro structural productss
l--- ~lil+i~i +i =ti+-i = X, Y ( Z +i t-il-
(X)
) (
) H C (
18 9
ksdkcZu M lar`Ir gkb

u h / Cl
2
(+ ni-i+nii =--in+ -i<
(Y) (C
8
H
18
)

u h / Cl
2
(+ ni-i+nii =--in+ -i<
(Z)
) (
) H C (
14 7
ksdkcZu M lar`Ir gkb

u h / Cl
2
<i ni-i+nii =--in+ -i<
Ans. C, D.
Sol. X = or Y =
3 3
3 3
3 3
CH CH
| |
CH C C CH
| |
CH CH
Z = ,
"manishkumarphysics.in"
10
CHEMISTRY
2. X(C
8
H
10
) (Aromatic)

v h / Cl
2
Twomonochloro (structural)
Y(C
8
H
10
) (Aromatic)

v h / Cl
2
One monochloro (structural)
X(C
8
H
10
) ((inl+)

v h / Cl
2
<i ni -i+nii (= --in+)
Y(C
8
H
10
) ((i n l+)

v h / Cl
2
(+ ni -i+ni i (= --in+)
Ans.
(X) (Y)
3. An organic hydrocarbon on oxidative ozonolysis produces oxalic acid and butanedioic acid. Its structure is
(+ +i l-+ ti:i+i - ~i+=i+ - ~ii-i+i +- ~i+= ln+ ~-n ( - i:~i:+ ~-n <-i t -i :=+i
=--i =zi ti ni
(A) (B) (C) (D*)
Sol.
Oxidation
O
3

4. An optically active acyclic compounds X (molecular formula C
5
H
9
Br) give following reactions
(+ +ilzi+ =l+ ~-l+ iln+ X (~i=zi C
5
H
9
Br) l--- ~lil+i <-i t -i -
The incorrect statements about 'X' are:
'X' + ln( ~= +i- ti n -
(A*) It has two stereoisomers (B*) It gives an achiral product (Y) on ozonolysis
(C*) It has two asymmetric carbon atoms (D) It has four stereoisomers and all are optically active
(A*) :=+ <i lziln =nii t (B*) t ~i i -i+i +- ~l+ n i ln+ (Y) < -i t
(C*) :=n <i ~=nln- +i - nii t
(D) :=+ -i lziln =nii tin ~i =ii +ilzi+ =l+ t
Sol.

3
O
(X)

2
H
"manishkumarphysics.in"
11
CHEMISTRY
5. A set of reagents (1 to 8) are successively reacted with the following compound
1. NaHCO
3
2. 2, 4, DNP 3. Na metal
4. AgNO
3
+ NH
4
OH 5. Fehlings solution 6. Cu
2
Cl
2
+ NH
4
OH
7. Br
2
/ H
2
O 8. NaNO
2
+ HCl
The reagents which give positive test with the given compound are :
(A) 1, 2, 3, 4, 5 (B) 3, 4, 5, 6, 8 (C) 1, 2, 3, 4, 8 (D*) All reagents except 1 and 8
~li+n + (1 to 8) +i (+ = -i l--- i ln+ + =ii ~lil+i +- t
1. NaHCO
3
2. 2, 4, DNP 3. Na ii-
4. AgNO
3
+ NH
4
OH 5. +tlnn ln- 6. Cu
2
Cl
2
+ NH
4
OH
7. Br
2
/ H
2
O 8. NaNO
2
+ HCl
-i+- iln+ + =ii +i -= ~li+n + i-in+ i-ii < - t
(A) 1, 2, 3, 4, 5 (B) 3, 4, 5, 6, 8 (C) 1, 2, 3, 4, 8 (D*) 1 ( 8 + ~nii =ii
Sol. There is no COOHgroup or NH
2
group.
Regents 1 and 8 will fail to give test.
Sol. i ln+ n COOH=n t ~i NH
2
=n t -l-i- -ti t
~li+n+ 1 ( 8 -i +- i-ii -ti < n
6. Compounds I and II can be distinguished by using reagent.
(I) (II)
4-Amino-2-methylbut-3-en-2-ol 4Amino2,2-dimethylbut- 3-yn-1-ol.
(A) NaNO
2
/ HCl (B) Br
2
/ H
2
O
(C*) HCl / ZnCl
2
(anhydrous) (D) Cu
2
Cl
2
/ NH
4
OH
l+= ~li+n + + -i n ,ii i ln+ I ~i II +i li < l+i i =+-i t
(I) (II)
4-(ni-i-2-n lin -3-: --2-~in 4(ni-i2,2-i:nlin- 3-~i:--1-~in
(A) NaNO
2
/ HCl (B) Br
2
/ H
2
O
(C*) HCl / ZnCl
2
(l-ni) (D) Cu
2
Cl
2
/ NH
4
OH
Sol. Moderate
(I) gives immediately turbidity by Lucas reagent and (II) does not give turbidity appriciably.
"manishkumarphysics.in"
12
CHEMISTRY
1. NaHCO
3
2. 2, 4, DNP 3. Na ii-
4. AgNO
3
+ NH
4
OH 5. +tlnn ln- 6. Cu
2
Cl
2
+ NH
4
OH
7. Br
2
/ H
2
O 8. NaNO
2
+ HCl
-i+- iln+ + =ii +i -= ~li+n + i-in+ i-ii < - t
(A) 1, 2, 3, 4, 5 (B) 3, 4, 5, 6, 8 (C) 1, 2, 3, 4, 8 (D*) 1 ( 8 + ~nii =ii
Sol. There is no COOHgroup or NH
2
group.
Regents 1 and 8 will fail to give test.
Sol. i ln+ n COOH=n t ~i NH
2
=n t -l-i- -ti t
~li+n+ 1 ( 8 -i +- i-ii -ti < n
6. Compounds I and II can be distinguished by using reagent.
(I) (II)
4-Amino-2-methylbut-3-en-2-ol 4Amino2,2-dimethylbut- 3-yn-1-ol.
(A) NaNO
2
/ HCl (B) Br
2
/ H
2
O
(C*) HCl / ZnCl
2
(anhydrous) (D) Cu
2
Cl
2
/ NH
4
OH
l+= ~li+n + + -i n ,ii i ln+ I ~i II +i li < l+i i =+-i t
(I) (II)
4-(ni-i-2-n lin -3-: --2-~in 4(ni-i2,2-i:nlin- 3-~i:--1-~in
(A) NaNO
2
/ HCl (B) Br
2
/ H
2
O
(C*) HCl / ZnCl
2
(l-ni) (D) Cu
2
Cl
2
/ NH
4
OH
Sol. Moderate
(I) gives immediately turbidity by Lucas reagent and (II) does not give turbidity appriciably.