Revision Date 17/03/2014

Revision 1
SAFETY DATA SHEET
RO lM C346
SECTlON 1: lDENTlFlCATlON OF THE SUBSTANCE/MlXTURE AND OF THE COMPANY/UNDERTAKlNG
1.1. Product identifier
Product name RO lM C346
1.2. Relevant identified uses of the substance or mixture and uses advised against
ldentified uses Corrosion lnhibitor
1.3. Details of the supplier of the safety data sheet
Trading & Development Co. for Machinery And
Equipment
Supplier
Factory for Chemicals
Dammam 2nd lndustrial City
P.O Box: 2923, Al Khobar 31952
Kingdom of Saudi Arabia
(+96613) 812 7775
(+96613) 812 1715
www.redaoilfield.com
1.4. Emergency telephone number
+44 (0)1224 937888
SECTlON 2: HAZARDS lDENTlFlCATlON
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical Hazards Flam. Liq. 3 - H226
Human health Acute Tox. 4 - H302;Acute Tox. 4 - H312;Acute Tox. 4 - H332;Eye lrrit. 2 -
H319;Skin Sens. 1 - H317;Carc. 2 - H351
Environment Aquatic Chronic 2 - H411
Classification (1999/45/EEC) Xn;R20/21/22. Carc. Cat. 3;R40. Xi;R36. R43. N;R51/53. R10.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
2.2. Label elements
Contains FUEL, DlESEL NO 2; GASOlL - UNSPEClFlED
1H-lmidazole-1-ethanamine,4,5-dihydro-,2-(C7-17 and c7-17-unsatd. alkyl) derivs
2-Mercaptoethanol
Label ln Accordance With (EC) No. 1272/2008
Signal Word Warning
Hazard Statements
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H351 Suspected of causing cancer.
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RO lM C346
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements
P501 Dispose of contents/container in accordance with local regulations.
Supplementary Precautionary Statements
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P261 Avoid breathing vapour/spray.
P264 Wash contaminated skin thoroughly after handling.
P370+378 ln case of fire: Use foam, carbon dioxide, dry powder or water fog for
extinction.
P301+312 lF SWALLOWED: Call a POlSON CENTER or doctor/physician if you feel
unwell.
P302+352 lF ON SKlN: Wash with plenty of soap and water.
P303+361+353 lF ON SKlN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P304+340 lF lNHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P305+351+338 lF lN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+313 lF exposed or concerned: Get medical advice/attention.
P312 Call a POlSON CENTER or doctor/physician if you feel unwell.
P330 Rinse mouth.
P333+313 lf skin irritation or rash occurs: Get medical advice/attention.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P403+235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
2.3. Other hazards
This product does not contain any PBT or vPvB substances.
SECTlON 3: COMPOSlTlON/lNFORMATlON ON lNGREDlENTS
3.2. Mixtures
FUEL, DlESEL NO 2; GASOlL - UNSPEClFlED 60-100%
CAS-No.: 68476-34-6 EC No.: 270-676-1
Classification (67/548/EEC)
Carc. Cat. 3;R40
Classification (EC 1272/2008)
Carc. 2 - H351
1H-lmidazole-1-ethanamine,4,5-dihydro-,2-(C7-17 and c7-17-unsatd. alkyl) derivs 10-30%
CAS-No.: 90411-92-0 EC No.: 291-471-3
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RO lM C346
Classification (67/548/EEC)
Xi;R36/38.
R43,R52/53.
Classification (EC 1272/2008)
Skin lrrit. 2 - H315
Eye lrrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Chronic 3 - H412
2-Mercaptoethanol 5-10%
CAS-No.: 60-24-2 EC No.: 200-464-6
Classification (67/548/EEC)
T;R23/24/25.
Xn;R48/22.
Xi;R38,R41.
N;R50/53.
R43.
Classification (EC 1272/2008)
Acute Tox. 3 - H301
Acute Tox. 3 - H311
Acute Tox. 2 - H330
Skin lrrit. 2 - H315
Eye Dam. 1 - H318
Skin Sens. 1 - H317
STOT RE 2 - H373
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown are in accordance with the latest EC Directives.
SECTlON 4: FlRST AlD MEASURES
4.1. Description of first aid measures
General information
Get medical attention. Perform artificial respiration if breathing has stopped. Show this safety data sheet to the doctor in attendance.
lnhalation
Remove victim immediately from source of exposure. Provide fresh air, warmth and rest, preferably in a comfortable upright sitting
position. lf breathing stops, provide artificial respiration.
lngestion
DO NOT lNDUCE VOMlTlNG! lf vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Never give liquid to
an unconscious person. Get medical attention.
Skin contact
Remove contaminated clothing and flush with plenty of water until pain disappears. lf discomfort persists transport to hospital and bring
these instructions.
Eye contact
lmmediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. lmmediately transport to
hospital or eye specialist.
4.2. Most important symptoms and effects, both acute and delayed
General information
lf adverse symptoms develop as described the casualty should be transferred to hospital as soon as possible.
lnhalation
Respiratory irritant effects that impair function with symptoms such as cough, pain, choking, and breathing difficulties.
lngestion
Harmful if swallowed.
Skin contact
Skin irritation. Prolonged or repeated contact with used oil may cause serious skin diseases, such as dermatitis.
Eye contact
May cause severe irritation to eyes.
4.3. lndication of any immediate medical attention and special treatment needed
No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. lf in
doubt, GET MEDlCAL ATTENTlON PROMPTLY!
SECTlON 5: FlREFlGHTlNG MEASURES
5.1. Extinguishing media
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RO lM C346
Extinguishing media
Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.
Unsuitable extinguishing media
Water jet.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
During fire, toxic gases (CO, CO2) are formed. Sulphurous gases (SOx).
Unusual Fire & Explosion Hazards
FLAMMABLE.
Specific hazards
When heated and in case of fire, harmful vapours/gases may be formed. Closed containers can burst violently when heated, due to
excess pressure build-up.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Spillages or uncontrolled discharges into watercourses must be lMMEDlATELY alerted to the Environmental Agency or other appropriate
regulatory body.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTlON 6: ACClDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
For personal protection, see section 8. Do not breathe vapour. Do not smoke, use open fire or other sources of ignition. Take
precautionary measures against static discharges.
6.2. Environmental precautions
Do not allow ANY environmental contamination. Do not discharge into drains, water courses or onto the ground. Contain spillages with
sand, earth or any suitable adsorbent material. Use appropriate containment to avoid environmental contamination. Ensure electrical
continuity by bonding and grounding (earthing) all equipment.
6.3. Methods and material for containment and cleaning up
Contain spillage with sand or earth. Self-contained breathing apparatus with full facepiece. Containers with collected spillage must be
properly labelled with correct contents and hazard symbol. Do not flush road with water. Contain contaminated water/ firefighting water For
waste disposal, see section 13.
6.4. Reference to other sections
For personal protection, see section 8. For waste disposal, see section 13.
SECTlON 7: HANDLlNG AND STORAGE
7.1. Precautions for safe handling
Keep away from heat, sparks and open flame. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is
above accepted level. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the
work site. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Avoid spilling, skin and eye contact.
Flammable/combustible material.
7.2. Conditions for safe storage, including any incompatibilities
Avoid inhalation of vapours and contact with skin and eyes. Store in tightly closed original container in a dry, cool and well-ventilated place.
Drums should be stacked to a maximum of three high. Store in a demarcated bunded area to prevent release to drains and/or
watercourses. Vapours are heavier than air and may travel along the floor and in the bottom of containers. Contaminated rags and cloths
must be put in fireproof containers for disposal. Avoid exposure to high temperatures or direct sunlight. Do not use compressed air or
oxygen for filling, discharging or handling. May explode in a fire. Keep containers tightly closed. Suitable containers: mild steel,
stainless steel. Do NOT use container made of: Rubber, neoprene or PVC. Do not subject to grinding/shock/friction.
Storage Class
Flammable liquid storage.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTlON 8: EXPOSURE CONTROLS/PERSONAL PROTECTlON
8.1. Control parameters
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RO lM C346
Contains no substances with occupational exposure limit values.
8.2. Exposure controls
Protective equipment
Process conditions
Use engineering controls to reduce air contamination to permissible exposure level. Provide eyewash station.
Engineering measures
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not
exceeded.
Respiratory equipment
ln case of inadequate ventilation and work of brief duration, use suitable respiratory equipment.
Hand protection
Neoprene, nitrile, polyethylene or PVC. Nitrile gloves are recommended, but be aware that the liquid may penetrate the gloves. Frequent
change is advisable.
Eye protection
Goggles/face shield are recommended. Contact lenses should not be worn when working with this chemical!
Other Protection
Wear suitable protective clothing as protection against splashing or contamination.
Hygiene measures
Observe good chemical hygiene practices.
Skin protection
Wear apron or protective clothing in case of splashes.
SECTlON 9: PHYSlCAL AND CHEMlCAL PROPERTlES
9.1. lnformation on basic physical and chemical properties
Appearance Dark coloured liquid.
Colour Yellow. to Dark. Amber.
Odour Characteristic.
Solubility lnsoluble in water Soluble in: Hydrocarbons. Miscible with water
lnitial boiling point and boiling range (C)
Not determined.
Melting point (C)
Not available.
Relative density 0.82 - 0.90 at 20C
Vapour density (air=1)
Not available.
Vapour pressure
Not available.
Evaporation rate
Not available.
pH-Value, Conc. Solution
Not applicable.
pH-Value, Diluted Solution
Not available.
Viscosity
Not available.
Decomposition temperature (C)
Not available.
Odour Threshold, Lower
Not available.
Odour Threshold, Upper
Not available.
Flash point (C) >52.0C minimum CC (Closed cup).
Auto lgnition Temperature (C) 257C
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RO lM C346
Flammability Limit - Lower(%)
Not available.
Flammability Limit - Upper(%)
Not available.
Partition Coefficient
(N-Octanol/Water)
Not available.
Explosive properties
Not available.
Oxidising properties
Not available.
9.2. Other information
No information required.
SECTlON 10: STABlLlTY AND REACTlVlTY
10.1. Reactivity
No specific reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use. Extinguish all ignition sources. Avoid sparks, flames, heat and
smoking. Ventilate.
10.3. Possibility of hazardous reactions
No hazardous reactions when stored and handled according to instructions.
Hazardous Polymerisation
Will not polymerise.
10.4. Conditions to avoid
Avoid heat, flames and other sources of ignition.
10.5. lncompatible materials
Materials To Avoid
Strong oxidising substances.
10.6. Hazardous decomposition products
During fire, toxic gases (CO, CO2) are formed.
SECTlON 11: TOXlCOLOGlCAL lNFORMATlON
11.1. lnformation on toxicological effects
Acute toxicity:
Acute Toxicity (Oral LD50)
> 490.0 mg/kg Rat
Acute Toxicity (Dermal LD50)
> 2500.0 mg/kg Rabbit
Acute Toxicity (lnhalation LC50)
> 340.0 mg/l (vapours) Rat 1 hour
SECTlON 12: ECOLOGlCAL lNFORMATlON
Ecotoxicity
The product is mildly toxic to aquatic organisms.
12.1. Toxicity
Acute Fish Toxicity
Toxic to aquatic organisms.
Acute Toxicity - Fish
LC50 96 hours ~ 35.0 mg/l Pimephales promelas (Fat-head Minnow)
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RO lM C346
EC 50, 48 Hrs, Daphnia, mg/l No data available.
lC 50, 72 Hrs, Algae, mg/l No data available.
12.2. Persistence and degradability
Degradability
There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative potential
The product contains potentially bioaccumulating substances.
Partition coefficient
Not available.
12.4. Mobility in soil
Mobility:
No data available.
12.5. Results of PBT and vPvB assessment
This product does not contain any PBT or vPvB substances.
12.6. Other adverse effects
Not applicable.
SECTlON 13: DlSPOSAL CONSlDERATlONS
General information
Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority.
13.1. Waste treatment methods
Dispose of waste and residues in accordance with local authority requirements. Hazardous waste landfill in sealed containers.
Environmental manager must be informed of all major spillages.
SECTlON 14: TRANSPORT lNFORMATlON
14.1. UN number
UN No. (ADR/RlD/ADN) 1268
UN No. (lMDG) 1268
UN No. (lCAO) 1268
14.2. UN proper shipping name
Proper Shipping Name PETROLEUM DlSTlLLATES, N.O.S., or PETROLEUM PRODUCTS, N.O.S. (Diesel, Fuel)
14.3. Transport hazard class(es)
ADR/RlD/ADN Class 3
ADR/RlD/ADN Class Class 3: Flammable liquids.
ADR Label No. 3
lMDG Class 3
lCAO Class/Division 3
Transport Labels
FLAMMABLE
LIQUID
3
14.4. Packing group
ADR/RlD/ADN Packing group lll
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RO lM C346
lMDG Packing group lll
lCAO Packing group lll
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
14.6. Special precautions for user
EMS F-E, S-E
Emergency Action Code 3Y
Hazard No. (ADR) 30
Tunnel Restriction Code (D/E)
14.7. Transport in bulk according to Annex ll of MARPOL73/78 and the lBC Code
No information required.
SECTlON 15: REGULATORY lNFORMATlON
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Health and Safety at Work Act 1974. The Control of Substances Hazardous to Health Regulations 2002 (S.l 2002 No. 2677) with
amendments.
Guidance Notes
Workplace Exposure Limits EH40. CHlP for everyone HSG(108).
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC)
No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of
substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
with amendments.
15.2. Chemical Safety Assessment
No chemical safety assessment has been carried out.
SECTlON 16: OTHER lNFORMATlON
lssued By HS&E Manager.
Revision Date 17/03/2014
Revision 1
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RO lM C346
Risk Phrases ln Full
Flammable. R10
Harmful by inhalation, in contact with skin and if swallowed. R20/21/22
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53
Harmful: danger of serious damage to health by prolonged exposure if swallowed. R48/22
lrritating to eyes and skin. R36/38
lrritating to eyes. R36
lrritating to skin. R38
Limited evidence of a carcinogenic effect. R40
May cause sensitisation by skin contact. R43
Risk of serious damage to eyes. R41
Toxic by inhalation, in contact with skin and if swallowed. R23/24/25
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R50/53
Hazard Statements ln Full
Causes serious eye damage. H318
Causes serious eye irritation. H319
Causes skin irritation. H315
Fatal if inhaled. H330
Flammable liquid and vapour. H226
Harmful if inhaled. H332
Harmful if swallowed. H302
Harmful in contact with skin. H312
Harmful to aquatic life with long lasting effects. H412
May cause an allergic skin reaction. H317
May cause damage to organs <<Organs>> through prolonged or repeated exposure. H373
Suspected of causing cancer. H351
Toxic if swallowed. H301
Toxic in contact with skin. H311
Toxic to aquatic life with long lasting effects. H411
Very toxic to aquatic life with long lasting effects. H410
Very toxic to aquatic life. H400
Disclaimer
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials
or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However,
no warranty guarantee or representation is made to its accuracy, reliability or completeness. lt is the user's responsibility to satisfy himself as to the
suitability of such information for his own particular use.
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