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Acids in Confections
Acids in Confections
Acids in Confections
F
ood-grade organic acids have diverse
functionality and fulfill several roles.
Acids can enhance or extend flavors,
decrease pH, preserve food and provide
pucker power. In confections, supersour,
flavor enhancement, flavor extension and
nontraditional flavors are all growing trends.
An acids job description is to extend or
enhance tartness or sour perception in addi-
tion to specic functions for gelled confec-
tions. What would orange, cherry, straw-
berry or lemon-lime be without acid as the
star player?
This paper will cover food-grade organic
acids used in confections, their chemical pro-
files, attributes, similarities, differences and
alternative forms of the acid (liquid, powder,
granular and encapsulated). A case study is
presented as an opportunity to explore the
application of acid blends for fruit flavors
since they are found naturally in some fruits.
FUNCTIONALITY OF ACIDS
Taste Modification
Acids are tart by nature. Flavor character-
istics are due primarily to the acids molec-
ular structure, solubility and the level of
buffering in the food or beverage system.
Hard candy, chews, gels and filled gels,
licorice, fruit leathers or panned hard and
soft confections all have different formula-
tions. Use of acids in formulations that are
sensitive to slight variations in pH, or the
presence of components sensitive to acids,
may require buffers to work with the acids
to provide stability. Acids offer ranges in
sourness, intensity and linger. These attrib-
utes impact and help define flavors, balance
sweetness and round out the total taste pro-
file of the flavor in confections.
In addition to taste modification, acids
perform other functional activities in con-
fections. These functional activities include
setting pectin and establishing gel strength
of gelatin gels by impacting pH of the con-
fection.
Sugar Inversion
Another beneficial function of acid is its
utilization to invert sugar. Acids used to
control sugar inversion to make invert sugar
can have dual roles depending on the candy
and pH level. Acid in hard candy contain-
ing high-fructose corn syrup and sucrose in
conventional ratios also functions to cause
low sugar inversion. Invert sugar helps to
prevent recrystallization of sugar crystals.
This helps to minimize grittiness or sandi-
ness in hard candy. Inversion, when uncon-
trolled by correct acid usage levels, can
cause candy to become sticky. Sugar inver-
sion is the hydrolysis of sugar (sucrose)
and results in the component molecules
glucose and fructose (sucrose glucose +
Acids in Confections
Food-grade organic acids in confections offer ranges in sour-
ness, intensity and linger; balance sweetness; and round out
the taste profile; and perform other functions.
Tammy Nash Jarrett
Univar
Tammy Nash Jarrett is
employed at Univar in
its Food Ingredients
division in technical
development. Prior to
Univar she has worked
at The NutraSweet
Co., Chr. Hansen Lab-
oratories and Silesia
Flavors in quality
assurance, research,
product development
and sales.
fructose). The result is cold flow; the
candy becomes hygroscopic and loses its
form/structure (Figure 1).
Impact of pH in Gelled Confections
Gelled confections manufactured with
starch, gelatin or pectin hydrocolloids are
impacted by pH. It is important to maintain
pH control and appropriate acidity levels in
gelled confections to maintain stability. Lack
of pH control may result in variations in the
gel set of pectin. The set may occur too fast
or too slow. For gelatin gels, acidity and pH
impact the strength of the gelatin set and
may degrade it. Too much acid impacts gel-
atin gel strength and decreases firmness. The
gel strength of gelatin decreases at lower
pH levels independent of acid type. A pos-
sible remedy to help gel strength in the pres-
ence of acid is to add buffering salts or
buffered acids in the formulation to help
control pH. Figure 2 illustrates the influence
of pH on gelatin gel strength. This informa-
tion is important when using acid to flavor
the gelled candy as well as acidifying or for-
tifying the candy.
Candy Fortification
Candy fortification represents another
diverse function for acid. Ascorbic acid, also
known as vitamin C, is used in gelled
gummi-type vitamin confections and regu-
lar gummi candy such as fruit snacks. Ascor-
bic acid is an essential nutrient. Ascorbic
acid is synthesized using cost-effective, nat-
ural fermentation of carbohydrates. In for-
mulating confections with ascorbic acid,
dosage levels may need to be optimized to
deliver targeted fortification levels due to
heat, light and oxygen sensitivity of the acid.
Another trend to consider with acids in
candy applications is acid sanding. This is
the application of acids to the outer layer of
the candy. Sanding the outer layer of gelled
confections has increased with the demand
for more sour taste.
Supersour Taste
Supersour taste appears to embrace the
more sour the better theme. Surface sour-
ness is meeting consumers demand for
more sourness and manufacturers uti-
lization of more acid. To accomplish
increased sourness, manufacturers are
sanding the outer surface of candy with
acid or acid-containing blends and avoid-
ing degradation of the candy. The quality of
the sanded candy depends on the steam
temperature for a sticky candy surface.
Steam for the surface should be hot and
dry for good adherence to the surface. Typ-
ically, acid is added as part of a dry-mix
blend for sanding. Blends may also include
encapsulated acids, buffering salts con-
taining acids or lower-solubility acids like
fumaric acid. A key factor to avoid product
loss is proper time, temperature and
humidity when drying the candy.
Acids in Confections
A possible remedy
to help gel strength
in the presence of
acid is to add
buffering salts or
buffered acids in
the formulation to
help control pH.
The Manufacturing Confectioner March 2012 59
Acid Benet
Citric acid Natural; impacts citrus avors
refreshing; low cost in use
Lactic acid Natural; mild and lingering; good
for creamy avors with fruit notes;
enhances mint and eucalyptus
avors
Fumaric acid More sourness than other
acidulants; may help acid-coated
candy due to low solubility
Malic acid Mellow, smooth, persistent
sourness; enhances flavor profile;
can mask some flavors; works well
with high-intensity sweeteners
Figure 3
Acids Features and Benets
Similarities
Can modify avors
Adjust pH
Modify sourness
Modify sweetness
Differences
Strenth/intensity, type of avor
Cost in use
Solubility and hygroscopic tendencies
Synthesis/structure/forms/molecular weight
Figure 4
Acids Similarities and Differences
Ascorbic Acid C
6
H
8
O
6
Lactic Acid C
6
H
10
O
3
Citric Acid C
6
H
8
O
7
Fumaric Acid C
4
H
4
O
4
Tartaric Acid C
4
H
6
O
6
Figure 5
Acidulants for Confections: Attributes
HO
HO
HO
O
O
OH
H
HO
HO
O
O
OH
OH
O
Molar weight: 192g mol
-1
Melting point (MP): 153C
Solubility: 57.6% (wt/wt)
Synthesis: fermentation
Physical appearance: solid (granular,
ne granular, powder)
Anhydrous
Monohydrate
Taste: strong tart; gives an immediate
sharp reaction
Acidity (pK
a
): 3.13, 4.76, 5.4
Molar weight: 176.12g mol
-1
Appearance: white or light yellow solid
(granular or ne granular)
Melting point (MP): 190-192C; 463-
465K; 374-378F (decomp.)
Solubility in water: 33g/100ml
Synthesis: fermentation
Acidity (pK
a
): 4.10 (rst), 11.6 (second)
O
O
OH
OH
H
3
C
O
OH
OH
HO
O OH
OH
O
P
O
OH
OH
OH
O
O
HO
OH
OH
OH
Molar weight: 116.07g mol
-1
Melting point (MP): 286C
Solubility: 0.61% (wt/wt)
Synthesis: synthetic
Form: white, crystalline
Taste: tart
Acidity (pK
a
): 3.03, 4.47
Molar weight: 90.08 g mol
-1
Melting point (MP): 53C
Solubility: soluble
Synthesis: fermentation (mix w/L- form)
Taste: mild
Form: liquid (88%); also available as
powder
Acidity (pK
a
): 3.86
Molar weight: 134.09
Melting point (MP): 130C
Solubility: 25C ~58% (wt/wt)
Synthesis: synthetic
Taste: smooth, tart
Form: granular
Acidity (pK
a
): 3.40, 5.05
(not typically in confections)
Molar weight: 98.00
Melting point (MP): 41C
Solubility: miscible
Source: minerals
Taste: sharp and bland
Form: liquid (75%+)
Inorganic
Acidity (pK
a
): 2.15, 7.20, 12.35
Phosphoric Acid H
3
PO
4
D,L Malic Acid C
4
H
6
O
5
Molar weight: 150.1 g mol
-1
Melting point (MP): 206C/403F
Solubility: 58% (wt/wt)
Synthesis: natural (L+)
Taste: strong/tart
Form: solid, ne granular
Acidity (pK
a
): 3.02, 4.34
Chemical structures and analytical char-
acteristics of acids (e.g., form, solubility,
molecular weight) impact the choice of
acid used for various profiles in confec-
tions. The strength of the acid impacts the
intensity of sourness observed in confec-
tions. Acid strength is measured by disso-
ciation the measurement of release of the
hydrogen ion. Hydrogen ion dissociation
is represented by dissociation constants
(K
a
) and reported as K
a
values. The val-
ues are established experimentally and
found in technical literature.
For example, high K
a
values represent
strong acids. Some acids have more than one
hydrogen ion to contribute and may have
more than one K
a
value. Figure 6 is a chart of
common acids showing the number of hydro-
gen ions available for dissociation.
Acid choice for confections may be influ-
enced by storage conditions available to
manufacturers. Some acids are hygroscopic
and will harden at inappropriate tempera-
tures and humidity levels during storage.
Ingredients that compact, become hard or
lack flow properties have a negative impact
on manufacturing. It is difficult to resolve
issues if equipment or conditions are not
available to grind or solubilize the ingredi-
ent for processing. In some cases, liquid acid
solutions are available for manufacturing.
One typical solution for confections is 50
percent citric acid. Lactic acid is also avail-
able as a solution (Figure 7).
Acid Profiles
As available acidulants at manufacturing
sites and formulations evolve with new
trending candy types, consideration must
be given to the acids sourness for the
desired sweetness and flavor profiles. Acid
sourness can vary with each respective acid.
Acids also have different sourness/tartness
intensities, taste perception and linger. Some
organic acids like those used in confections
offer quick sour sensation and dissipate
quickly. Examples would be citric acid and
tartaric acid. Acids like fumaric, malic and
lactic may linger longer depending on other
formulation parameters. These attributes
could be helpful with sweeteners and fla-
vors to balance the overall taste profile.
Sweeteners and flavors should work
together. Acid selection may help with bal-
ancing the profile. For example, if a sweet-
ener lingers longer in taste, organoleptically
it may be better for the flavor to extend
with the sweetener. In this situation it may
be more advantageous to use an acid with
a longer linger to balance the profile. As a
case in point, consider nonsucrose confec-
tions with bulking agents and high-inten-
sity sweeteners or consider candy formula-
tions with alternative sweeteners having
different sweetness onset and linger. It may
be favorable to use the traditional acid for
the flavor with an additional acid to com-
plement the overall taste of the confection.
In the example with the sweetener having
a longer linger, one may consider using
Acids in Confections
Acid choice for
confections may
be influenced by
storage conditions.
Some acids are
hygroscopic and
will harden at
inappropriate
temperatures and
humidity levels
during storage.
The Manufacturing Confectioner March 2012 61
Acid Storage/handling
Citric Hygroscopic solid
Available as 50% solution
Fumaric Nonhygroscopic solid
Malic Hygroscopic solid
Lactic Liquid, powder, buffered*
(*form used in candy)
Tartaric Hygroscopic
Phosphoric
Inorganic Corrosive
Figure 7
Acids Storage/Handling
Protons Acid
1 Lactic
Acetic
2 Fumaric
Malic
Tartaric
3 Citric
Phosphoric
Figure 6
Hydrogen Ions in Common Acids
Acids in Confections
Use of acids in
candy should be
optimized to deliver
flavor or broaden
the flavor profile in
the presence of
sweetness and
complementing
target flavor.
62 March 2012 The Manufacturing Confectioner