FOUNDATION IN SCIENCE

AUGUST 2010 FINAL EXAMINATION

SUBJECT: CHEMISTRY 3
SUBJECT CODE: CH013
TIME ALLOWED: 3 HOURS
(02.00 PM 0.00 PM!
DATE: AUGUST 1"# 2010
INSTRUCTIONS TO CANDIDATE:
1. Answer ALL questions in SECTION A and ANY TWO (2! out of THREE
(3! questions in SECTION B.
INFORMATION TO CANDIDATE:
1. You are permitted to use a non-programmable electronic calculator in this
examination.
SECTION A
A$%&'( ALL )*'%+,-$%
.*'%+,-$ 1
A) Give an I!A" nomenclature for each of the following molecules#
(2 /0(1%!
(2 /0(1%!
(2 /0(1%!

(2 /0(1%!
(2 /0(1%!
2
(2 /0(1%!
(2 /0(1%!
(T-+02: 13 /0(1%!
$) Answer the following questions accordingl%. S+0+' ('0%-$(%! +- 4-*( 0$%&'(. O$' (1!
/0(1 will be given to correct answer and +&- (2! /0(1% for correct reason&s).
i) 'hat is the ma(or product of the following reaction) *tate %our reason clearl%.
(3 /0(1%!

)
A $ " + ,

3
ii) 'hat is the best reagent to ma-e the following product) *tate %our reason
clearl%. &note# . is an% halide atom) (3 /0(1%!
)
A $ " + ,
iii) 'hat is the ma(or product of the following reaction) *tate %our reason clearl%.
(3 /0(1%!
)
A $ " + ,
4
iv) W50+ ,% +5' 6'%+ ('07'$+ +- /01' +5' 8-22-&,$7 9(-:*;+ (X ,% 0$4 502,:'!<
S+0+' 4-*( ('0%-$ ;2'0(24. (3
/0(1%!
)
A $ " + ,

v) W50+ ,% +5' /0=-( 9(-:*;+ -8 +5' 8-22-&,$7 ('0;+,-$< S+0+' 4-*( ('0%-$
;2'0(24.
(3
/0(1%!
)
A $ " + ,
(T-+02: 1 /0(1%!
5
") +etermine whether the following reactions are li-el% to be */10 */10 ,1 or ,1. !rovide
%our reason&s) accordingl%.
(3 /0(1%!
(3 /0(1%!
(3 /0(1%!
(3 /0(1%!
(T-+02: 12 /0(1%!
+) "%clohexene undergoes addition reactions. 'rite equations for each of the addition
reactions of c%clohexene with $r10 2$r0 213 and 21 and clearl% show the reactants0
products and catal%st involved if required.
&T&- (2! /0(1% given for each of correct reaction shown)
(> /0(1%!
,) *how what reagents are needed to prepare the indicated products.
i. 4rom an aldeh%de and a Grignard reagent (3 /0(1%!

6
4) !rovide the I!A" nomenclature of al-%l halides that might be a starting material of the
following products.
(2 /0(1%!
(2 /0(1%!
G) !redict the appropriate alcohol &starting material) and reagent &or catal%st) to prepare the
following products.
(3 /0(1%!
(3 /0(1%!
(3 /0(1%!
2) !redict the product of the following reactions.
7
i)
(2 /0(1%!
ii)
(2 /0(1%!
(T-+02: ?0 /0(1%!
SECTION B
A$%&'( TWO (2! -*+ -8 THREE (3! )*'%+,-$%
8
.*'%+,-$ 3
A) !rovide a detailed mechanism for the h%drol%sis of ester under acidic conditions. *how
the steps involved.
(10 /0(1%!

$) 'rite the 5e-ule structure and give I!A" nomenclature for all al-anes with molecular
formula "6217. ( /0(1%!

(T-+02: 1
/0(1%!
.*'%+,-$
A) *how the al-%nes h%dration mechanism for the following reaction#
(@ /0(1%!
9
$) *tarting with the starting material &8) below0 how would %ou prepare the following
product)
&8)
i.

(2 /0(1%!
ii.
(2 /0(1%!
iii.
(2 /0(1%!
(T-+02: 1
/0(1%!
10
.*'%+,-$ "
A) *how the mechanism for the following esterification reaction. (@ /0(1%!
$) +ifferent classes of compounds are formed when the following al-enes react with hot0
concentrated 59n37. !redict the products obtained. (" /0(1%!
(T-+02: 1 /0(1%!
11
AEND OF .UESTION PAPERA
12