Nama: Nuhammau Nauif

NIN: 1Su121uu


Bome task Buku Bavis

14) Estimate the oxygen uemanu of enuogenous oxiuation of cells (g of 02g
of cells) assuming cell oxiuation can be uesciibeu by Equation 22-21
}awab:
Enuogenous oxiuation equation:
Asumsi
CSB7N02 + S02 ! SC02 + 2B20 + NBS + eneigy
0xygen uemanu = S mol of 02 1 mol CSB7N02
= (S x S2) g of 02 (1 x 11S) g of CSB7N02
= 1.416 g of 02 g of CSB7N02
}aui, uemanu of enuogoneous oxiuation of cells = 1.416 g of 02g of cells



1S) Show by calculation that the oxygen iequiieu foi total oxiuation of
ammonia is 4.S7 g of 02g of N
}awab:
Total oxiuation of ammonia:
Reaction 1: 2 NB4
+
+ S 02 ! 2 N02
-
+ 4 B
+
+ 2 B20
Reaction 2: 2 N02
-
+ 02 ! 2 N0S
-

Peihitungan:
Reaction 1: 0xygen iequiieu foi oxiuation of ammonia
= S mol 02 2 mol N
= (S x S2) g of 02 (2 x 14) g of N
= S.4S g of 02 g of N
Reaction 2: 0xygen iequiieu foi oxiuation of ammonia
= 1 mol 02 2 mol N
= (1 x S2) g of 02 (2x14) g of N
=1.14 g of 02g of N
}aui, total oxiuation of ammonia = S.4S + 1.14 g = 4.S7 g of 02 g of N


16) Show by calculation that 7.14 g alkalinity as CaC0S is piouuceu foi each
giam of ammonia nitiogen (as N) that is oxiuizeu
}awab:
Peisamaan ieaksi:
NB4
+
+ 2 BC0S
-
+ 2 02 ! N0S
-
+2 C02 + SB20
!"# !"#
!
!
!"# !"
!
!
=
! !"#
! !"#

!"##" !"#
!
!
!"##" !
!
! !!"
!"
! !!!"# ! !"#
!
!
!! !

!"##" !"!!
!
!"##" !
=
!"##" !"#
!
!
!"##" !
x
!" !"!!
!
!" !"#
!
!
x
! !"# !"!!
!
! !"# !"#
!
!


!"##" !"!!
!
!"##" !
= 8.714 g BC0S
-
g N x
!""
!"
x
! !"# !"!!
!
! !"# !"#
!
!


!"##" !"!!
!
!"##" !
= 7.14 g CaC0Sg N

17) Evaluate the effects of B0 concentiation on nitiification
}awab:
Pengaiuh konsentiasi B0 paua nitiifikasi uapat uilihat peisamaan
kinetika beiikut:

Baii peisamaan uiatas uipeioleh hubungan antaia B0 uengan kecepatan
laju nitiifikasi. Apabila konsentiasi B0 semakin besai maka kecepatan
laju nitiifikasi pun semakin meningkat.

18) Show by calculation that S.S7 g alkalinity as CaC0S is piouuceu foi each
equivalent of N0S-N) that is ieuuceu
}awab:

}awab: Reaksi uenitiifikasi, menuiut peisamaan 22-S1 hingga 22-SS
untuk tiga uonoi elektion yang umum yaitu:
- Paua aii limbah sebagai uonoi elektion:
C
1u
B
19
0
S
N + 1uN0
S
-
- SN
2
+ 1uC0
2
+ SB
2
0 + NB
S
+ 1u0B
-

- Paua metanol sebagai uonoi elektion:
SCB
S
0B + 6N0
S
-
- SN
2
+ SC0
2
+ 7B
2
0 + 0B
-

- Paua asam asetat sebagai uonoi elektion:
SCB
S
C00B + 8N0
S
-
- 4N
2
+ 1uC0
2
+ 6B
2
0 + 80B
-



Bapat uilihat uaii ketiga ieaksi teisebut, mol N0
S
-
= mol 0B
-
, sehingga:
Nassa N = 1 giam
Nol N = mNi = 114 mol = mol N0S
-
= mol 0B
-

Ekivalen 0B
-
: ekivalen CaC0
S
= 1 : 2, sehingga
mol CaC0
S
= V x 114 mol = 128 mol

NassaCaC0
S
= n x Mr = 1/28 x 100 = 3,57 g
}aui, CaC0
S
sebanyak S,S7 g uihasilkan untuk setiap ekivalen N0
S
-N


19) Evaluate the effects of B0 concentiation on uenitiification
}awab:

B0 uapat menghambat teijauinya uenitiifikasi unegan menekan keija
uaii enzim ieuuksi nitiat. Konsentiasi B0 seienuah u,1S mgL uapat
membuat uenitiifikasi beihenti. Bubungan antaia konsentiasi B0 unegan
laju peitumbuhan, menuiut peisanaan 22-S6, uapat uinyatakan melalui
peisamaan beiikut:












22-S) Beteimine by calculation the alkalinity in g as CaC0Sg of ammonia
nitiogen, as N, that is iequiieu to buffei the total oxiuation ieaction.
}awab:
Reaksi oksiuasi total, menuiut peisamaan 22-24 aualah sebagai beiikut:
NB
4
+
+20
2
-N0
S
-
+2B
+
+B
2
0
Nassa N = 1 g
Nol N=mNi = 114 mol= mol NB
4
+


Sesuai peibanuingan stoikiometii, mol NB
4
+
: mol B
+
= 1 : 2, sehingga:
Nol B
+
=2 114 mol = 17 mol
EkivalenB
+
: ekivalen CaC0
S
=1:2, sehingga
Nassa CaC0
S
= n x Ni = 114 x 1uu = 7.14 giam
}aui, CaC0
S
yang uibutuhkan sebanyak 7,14 g untuk setiap g amonia
nitiogen yang teioksiuasi..

22-6) If the influent ammonium concentiation is 21.8 mgL, estimate the
amount of alkalinity (in mgL) that must be auueu to buffei the oxiuation
ieaction assuming that a iesiuual alkalinity of 8u mgL as CaC0S is
iequiieu to keep the pB at appioximately 7. Assume the influent
alkalinity is 2Su mgL as CaC0S
}awab:

Sebanyak 7,14 g basa yang uibutuhkan pei 1 g amonia nitiogen, sehingga
untuk konsentiasi amonium 21,8 mgL, basa yang uibutuhkan =(21,8
mgL)(7.14 g basag NB4
-
N)= 1SS,6S mgL. 0ntuk menjaga pB, basa
yang uibutuhkan = 1SS,6S + 8u = 2SS,6S mgL Basa paua influen = 2Su
mgL, sehingga tiuak uipeilukan penambahan CaC0
S
.


22-7) If in pioblem 22-6 the amount of alkalinity in the iaw wastewatei is SuS
mgL as CaC0S, what will the pB be aftei nitiification. Assume that the
C02 concentiation in the waste watei iesulting fiom B0Boxiuation anu
ammonia nitiification is 2S mgL. 0se the following equation foi the
estimate:
pB = pK1 -log !
!!!!"!!
!!"#!!!
)
wheie pK1 = 6.S8
}awab:

|C0
2
j =(2S mgL)(44 g.mol x 1u
S
mgg)= S,68 1u
-4
molL
Asumsi: |C0
2
j = |B
2
C0
S
j
Paua Pioblem 22-6, basa beikonsentiasi 1SS,6S mgL uibutuhkan ualam
ieaksi oksiuasi, sehingga basa yang teisisa = SuS - 1SS,6S = 149,SS mgL
}umlah BC0
S
-
= 149,SSx((61 gekivalen BC0S
-
)(Su gekivalen CaC0S) =
182,21 mgL
Konsentiasi BC0
S
-
=
!"#!!"
!"
!
!"
!
!"#
! !"
!
!"
!
= 2,99 x 1u
-S


pB = 6,S8 - log (
!!!" ! !"
!!
!!!! ! !"
!!
) = 6,S8 - (-u,72) = 7,1u
}aui, pB setelah nitiifikasi sebesai 7,1u.