Wednesday, February 17, 2010

Rohit Dave
Maintenance may be defined as the upkeep
of the sub stations electrical equipments in
proper working condition and efficient to
derive the following :
# Reliable and efficient operation
# Optimum utilisation
# Availability
# Reduced down time
# Detection of premature faults
# Minimizing revenue loss etc.
To meet the above requirement, the equipment has
to be checked, attended, to trouble-shot and
operated under specified conditions.
The need for maintenance
During the operational life of the electrical equipment,
ageing occurs due to various stresses which is incident
on the equipment both under normal and fault conditions
and result in deterioration of physical and chemical
properties of components making up the electrical
equipment.
The expected performance can not be obtained from the
equipment once it is aged.
The electrical equipment in service are subject to
the following stresses :
Electrical stresses
Thermal stresses
Mechanical stresses
Environmental stresses
Combined stresses
Electrical Stress:
The Insulation of electrical equipment experience the
following voltages :
Continuous normal power frequency rated voltage
Temporary power frequency over voltages due to voltage
regulation, Ferranti effect, and long duration power
frequency over voltages.
Lightning Impulse Voltage Waves (Surges)
Switching Impulse Waves (Surges)
Thermal Stress
Elevated temperatures may be reached during
operation due to dielectric losses, increased I
2
R loss
or by heat absorption from surroundings.
Temperature may increase abnormally due to
sustained short circuit current.
The cooling system failure in power transformers
also stress the windings thermally.
Mechanical Stress
There may be permanent mechanical stress due
to improper installation
Circuit breakers may experience vibration stress
during normal closing/opening and during making /
breaking under fault
The bus bar vibration in rigid bus bar stresses the
bus bar support mechanically
Environmental stress
Environmental factors include pollution, Radiation,
Humidity, dust particles, moisture etc,.
Proximity to chemical industry, sea coast and
intentional damage caused by humans contribute to
ageing and deterioration
Combined stress
In most of the electrical equipment, normally
some of the stress factors as above will be present
Maintenance Schedules for Power Transformers
1. Checking the Color of silica gel in the breather and also oil level of the oil seal. If silica
gel Color changes from blue to pink by 50% the silica gel is to be reconditioned or
replaced.
Daily
2. Observation of oil levels in (a) main conservator tank (b) OLTC conservator (c)
bushings and examining for oil leaks if any from the transformer
Daily
3. Visual check for overheating if any at terminal connections (Red hots) and observation
for any unusual internal noises.
Daily in each shift
4. Checking for noice, vibration or any abnormality in cooling fans & oil pumps of power
transformers standby pumps & fans are also to be run condition to be observed.
Daily
5. Observation of oil & winding temperatures & recording Hourly
6. Visual check of explosion vent diaphragm for any cracks Daily
7. Checking for any water leakage into cooler in case of forced cooling system. Daily
8. Physical examination of diaphragm of vent pipe for any cracks Monthly
9. Cleaning of bushi ngs, inspect for any cracks or chippings of the porcelain and
checking of tightness of clamps and jumpers
Monthly
10. Measurement of IR values of transformer with 2.5 KV megger upto 33KV rating and 5.0
KV megger above 33KV rating. Recording of the values specifying the temperature
which measurements are taken.
Monthly
11. Cleaning of Silicagel breather Monthly
12. Checking of temperature alarms by shorting contacts by operating the knob. Monthly
13. Testing of main tank oil for BDV and moisture content Quarterly
14. Testing OLTC oil for BDV & moisture content Quarterly
15. Testing of Bucholtz surge relays & low oil level trips for correct operation Quarterly
16. Checking auto start of cooling fans and pumps Quarterly
17. Checking of Bucholtz relay for any gas collection and testing the gas collected Quarterly or during fault
18. Checking of operation of Bucholtz relay by air inj ection ensuring actuati on
alaram & trip
Half yearly or during
shutdown
19. Noting the oil level in the i nspection gl ass of Bucholtz relay and arresti ng of oil
leakages if any.
Monthly
20. Checking of all connections on the transformer for ti ghtness such as bushings,
tank earth connection
Quarterly
21. Lubricating / Greasing all moving parts of OLTC mechanism Quarterly or as given in
the manufacturers manual
22. Checking of control circuitry, interlocks of oil pumps and cooli ng fans for auto
start and stop operation at correct temperatures and also for manual operation
Half yearly or during
shutdown
23. Testing of motors, pumps and calibrating pressure gauge Half yearly
24. Pressure testing of oil coolers Half yearly
25. Testing of oil samples for dissolved gas analysis (for 100MVA transformers) Half yearly
26 Testing of oil for di ssol ved gas anal ysis of EHV transformers upto 100KVA
capacity
Once in a year
27. Overhauling of oil pumps and their motors also cooling fans & their motors. Once in a year
28. Testing of oil in main tank for acidi ty, tan delta, interface tension specific
resisitivity
Once in a year
29. Bushing testing for tan delta Once in a year
30. Calibration of oil & winding temperature indicators Repeats
31. Measurement of magnetizing current at normal tap and extreme taps One in a year
32. Measurement of DC winding resistance Once in a year
33. Turns ratio test at all taps Once in a year
34. Inspection of OLTC mechanism and contacts its diverter switch Once in a year or number
of operation as
recommended by
manufacturers are
completed whichever is
35. Overhaul of tap changer and mechanism One in a year
36. Replacement of oil in OLTC Once in year or
whenever number of
operations as
recommended by
manufacturer are
completed whichever
is earlier.
37. Calibration of thermometers (temperature indicators) and tap positi on
indicator.
Yearly
38. Remaining old oil in thermometer pockets, cleaning the pockets and
filing with new oil.
Yearly
39. Checking oil in the air cell (for transformers of 100 MVA & above
capacity)
Yearly
40. Bushings partial discharge test and capacitance (EHV transformers) Yearly
41 Filtration of oil / replacement of oil and filtration Whenever the IR
values of transformer
are below permissible
limits and oil test
results require
filtration / replacement
of oil
42. General overhaul (consi sting 1) Inspection of core & wi ndi ng (2) Through
washi ng of windings (3) Core tightening (4) Check-up of core bolt
insulation (5) Replacement of gaskets (6) Overhaul of OLTC
One in 10 years
1. Cleaning of bushings and external surface of tank cooling pipes Monthly
2. Checking of oil levels in the conservator and gauge glass Monthly
3. Checking of silicased in the breather and replacement is necessary Monthly
4. Checking of oil level in the oil seal of breather & top up if necessary Monthly
5. Checking of HG fuse & LT fuse and renew if necessary (correct
guage shall maintained)
Monthly
6. Checking of vent pipe diaphragm Monthly
7. Checking of terminal loose connections is any and tightening the
same
Monthly
8. Checking for any oil leaks & rectification (including replacement of
oil seals if required)
Monthly
9. Taking long tester reading during peak load hours and remedial
action
Quarterly
10. Noting down neutral currents and load balancing in all the three
phase
Quarterly
11. Measurement of IR Values Half yearl y
12. Testing of oil for BDV, activity Half yearl y
13. Checking of lightening arrestors and replacement is required once
before monsoon)
Half yearl y
14. Measurement of earth resistance checking of earthing system and
rectification if required.
Half yearl y
15. Overhaul of transformer Once in 5 years
Maintenance Schedule of Distribution Transformers
Sl.No Part Defects Causes
1. Tank
a. Leakage of oil
b. Deformation
c. Overheating
Corrosion / mechanical damage Gaskets worn out
excessi ve internal pressure Improper circulation
of cooling oil and / or inadequate ventilation.
2. Radiators
a. Leakage of Oil
b. Deformation
c. Overheating
Corrosion / mechanical damage Gaskets worn out
excessi ve internal pressure Improper circulation
of cooling oil and / or inadequate ventilation.
3. Conservator
a. Leakage of Oil
b. Deformation
c. Overheating
Corrosion / mechanical damage Gaskets worn out
excessi ve internal pressure Improper circulation
of cooling oil and / or inadequate ventilation.
4. Breather
Ineffective Inlet choked Silica gel saturated
5. Explosion
Glass broken Mechanical
6. Core
a. Loose
b. Increased Losses
c. Excess Noise
Bolts l oosening up change in characteristics due
to heating vibration of stampings
7. Winding
a. Short Circuited
b. Loosening
c. Insulation Brittle
d. Open circuited
Overloading Air bubbl es l oss of insulation
shrinkage displacement Overheating
decomposition burn out.
8. Oil
a. Discoloration
b. High Acidity
c. Low BDV
d. Sludge
Contami nation Increased moi sture
Decomposition chemical action with other parts.
9. Terminal
Bushing
a. Breakage
b. Leakage of Oil
Strain Gasket Worn out Loose fit.
10 Tap Switch
a. Inoperative Broken lever
b. Burnt Contact
c. Short Circuit
Maloperation Insulati on failureFailure of
operation mechanism overheating
Common Defects noticed and the cause
Run to failure Maintenance
( Corrective Actions Only )
Time directive maintenance
( Preventive Maintenance )
Condition Directive Maintenance
( Predictive )
Repair and restoration of equipment/component
that have failed or malfunctioning and are not
performing their intended function
Periodic and Planned maintenance actions
taken to maintain a piece of equipment within
the expected operating conditions. It extends
the equipment life and is performed prior to
equipment failure to prevent it. This includes
technical specification surveillance, in service
inspection and other regulatory forms of
equipment maintenance.
MAINTENANCE
Approach Strategies
The continuous or periodic monitoring and
diagnosis in order to forecast component
degradation so that as needed planned
maintenance can be performed prior to
equipment failure. Not all equipment conditions
and failure modes can be monitored therefore,
predictive maintenance must be selectively
applied.
Time directive maintenance
( Preventive Maintenance )
Inspection of Transformer
O/H of OLTC
Checking of Protection Circuit
DGA
Earth Test
BDV of Oil
Cleaning
Working of Fire Protection Equipment
Painting
Transformer Testing
Run to failure Maintenance
( Corrective Actions Only )
Failure of gasket
Failure of Bushing
Failure of PT / CT
Oil Leakage
Burning of Jumpers
Winding / insulation Failed
OLTC Problem
Condition Directive maintenance
( Predictive )
Filtration of Oil
Drying of Transformer
Based on DGA / Transformer Testing
During Inspection
Oil Leakage from any Parts of
Transformer
Painting/Cleaning Required
Oil Level
Silica J ell degraded
All indicating lamps
Condition of
Radiator
Hot/Cold
All Doors &
inspection
window glass
Unwanted materials
Core
Winding
Over heating breakdown in core plate insulation leads
to circulating currents & usually sparking at fault.
Major Failures
Overheating due to poor joints is common fault in any parts
of the electrical circuit. Breakdown of inter-strand insulation
results in circulating current causing overheating of
insulation and hot spots at point of fault
Poor joints
OLTC
Most common problem observed in OLTC
1. Mechanical Problem
1. Failure of AC Supply
Tripping Motor MOCB
LT Cable Fault
Motor Failure
Failure of declutching switch
2. Mechanical Problem
Braking of shear Pin
Failure in friction device
2. Electrical Problem
Wear & Tear on Fixed/Moving contact
Resistance Open
Tracking on phase board
J umper burnt
Braking of Barrier board
The OLTC provides uninterrupted
voltage regulation of transformers
under load.
The voltage is regulated by changing
the voltage ratio. This is done in steps.
The transformer is equipped with a tap
winding whose tapping are connected
with the tap selector of the OLTC
Changing Voltage Ratio
a. Linear Voltage Regulation
b. Reversing Voltage Regulation
c. Coarse & fine Voltage regulation
Step Voltage
is 200 Volt/tap
Normal Taping from Winding
Linear Voltage Regulation
We have two different make OLTC
1. Crompton
1. F33
2. AT
2 CTR
Reversing Voltage Regulation
We have different makes OLTC
Flange Mounted OLTC
Crompton AT
NGEF
In Tank
(A)With Pre-Selector Switch
(B)Without Pre-Selector Switch
Easun
(A)
BHEL
(B)
Pre-Selector Switch
Diverter switch
Compartment in OLTC
Flange Mounted OLTC
Driving Mechanism
High Speed Selector switch
Selector switch is capable of making &
Breaking load in addition to selecting tap
A chamber houses the motor
and driving mechanism
Compartment in OLTC
In Tank V type
Driving Mechanism
Selector Switch
Inside the
Main Tank
Transmission Shaft
Top Plate
Compartment in OLTC
In Tank D type
Main Tank
Top Plate
Pre-Selector Switch
Diverter switch inner
Diverter switch Oil Vessel
OSR
Operation in OLTC
Pennant Cycle
Tap is changing from No.1 to No.2
Operation in OLTC
Flag Cycle
R2 contact fixed contact 4.
R1 contact fixed contact 3
Main moving is floating
R1 leave fixed contact 3,
R2 contact fixed contact 4
Load is carried by resistor R2
Tap change is completed
Normal
Main moving contact
left fixed contact. Load
is carried by resistor R1
OLTC with Pre-selected switch (NGEF, Esson)
Flag Cycle
Parts in OLTC
Main Shaft
Phase Board
Fixed Contact
Resistance
Roller Contact
Jumpers
connected
to Tapping
Current Plate
Fixed Contac
Main Moving Contact
Roller Contact
Barrier Plate
J umper coming
from Xmer
Phase Board
Resistance
Driving Mechanism
DSS
Tap indicator
Motor
Counter
Raise Lower Contactor
Motor Protection Relay
AVR mounted on RTCC
Automatic Voltage Regulating Relay (AVR):
AVR is used to maintain secondary voltage (11KV) of power
transformer by operating primary side (22/33KV) OLTC Tap.
Input to AVR is secondary side of 11000/110V Potential
transformer directly connected on secondary side of Power
Transformer (Circuit PT or Transformer PT).
EMCO, NMC, Pradeep and accord make AVRs are in service.
Typical settings of AVRs
Auxiliary supply = 110V AC
Nominal Voltage = 110V AC (From 11000/110V PT)
Raise Operation : V <108V
Lower Operation : V >112V
Time Delay = 120 Sec.
Directional Sequence Switch (DSS):
DSS is cam operated multiple contact switch used to maintain OLTC motor supply to
during operation and cut-off after completion of OLTC operation.
Switron, Shirke Electricals, Recom make
DSS are in service.
Typical DSS contacts and their application
is as follows.
OLTC Timer Scheme Timer scheme will
operate if motor supply is continuous for more
than set time (Set time=2*time for one operation)
and avoids high/lower voltages during DSS and
contactor mal-operation .
Motor Protection Relay
(MPR) Driving motor is
protected for overload by
MPR which isolates it
under fault condition.
Directional Raise Limit switch Blocks
electrical raise operation when tap at
maximum position (Tap15 or 16).
Directional Lower Limit switch Blocks
electrical lower operation when tap at
minimum position (Tap1).
Electrical Interlocks And Protection:
Hand Interlock Switch (HIS)
HIS isolates electrical supply
during manual crank handle is
in. Ensures safety to operating
personal.
Protection for OLTC
OSR
Motor Stuck up Alarm
Motor Supply Failed Alarm
OLTC PRV
On RTCC
Over hauling of OLTC
Washing
Over-hauling of OLTC
Cleaning
CONDITION MONITORING OF
TRANSFORMER OIL
Parameters for condition monitoring of oil service
Two ways are available to an operating engineer
1.To make periodic oil tests to establish trends and classify
them.
2.To conduct dissolved gas analysis to assess the internal
condition of transformers
PARAMETERS TO BE CHECKED ARE:
1. FLASH POINT
2.DIELECTRIC DISSIPATION FACTOR
3.SPECIFIC RESISTANCE
4.NEUTRALISATION.
5.MOISTURE CONTENT
6.SLUDGE %
7.BREAK DOWN VOLTAGE
8.D.G.A.
PHYSICAL CONTAMINATION
1.Dust, fiber, metallic, particles, other solid impurities.
2.Dissolution of varnish.
3.Free and dissolved water.
CHEMICAL DETERIORATION
Oxidation resulting in acids sludge and polar
impurities.
CONTAMINATION OF GASES
a) Dissolved air from atm. Nitrogen, co2
b) Generated in oil, methane, ethane, acetylene,
ethylene etc. Before the oil is put in the
transformer, its properties should be fully
ensured.
Interpreting Transformer Oil Test Data
There is classic relationship between the transformer
insulating oil tests neutralization or acid number (NN) and
interfacial tension (IFT). Several independent studies
have shown that an increase in NN should normal be
followed by a characteristic drop in IFT. When test results
for a given oil sample do not fall between the range shown
on either side of median line, further investigation is
necessary.
Sample of
transformer
oil illustrating
seven color
classification
CHEMICAL DECOMPOSITION OF HYDROCARBONS
Sr. No.
TESTS INFORMATION PROVIDED BY TESTS
1 Interfacial Tension Sludge present in the oil.
2 Neutralisation Number Acid present in the oil .
3 Moisture content (ppm) Reveals total water content or cellulosic deterioration.
4 Flash point Sudden drop in flash point indicates of unsatisfactory
working condition of transformer.
5 Sludge Indicated deterioration.
6 Dielectric Dissipation Reveals presence of moisture, resins, varnishes or
their products of oxidation in oil.
7 Dielectric strength Conductive contaminants and moisture present in the
oil.
8 Resistivity Indicative of conducting impurities.
9 Dissolved Gas Analysis Reveals ppmof combustible gases dissolved in the oil
to assess the internal condition of the transformer.
SERVICE OIL TESTS
The service oil tests to be conducted are furnished below:
Service oil tests as per IS: 1866 2000
GROUP III OILS:
To categorize under group III, the parameters should be
well beyond the limits proposed in table IV. Such oils
should be initially filtered under vacuum and
temperature to verify whether the properties improve or
not. If properties like Dielectric Dissipation Factor,
Interfacial Tension do not improve on filtration, then
there is a case for oil to be replaced.
Transformer Oil Filtration
Transformer oil filtration is carried out with
oil filter machine of adequate capacity.
The oil filtration plant is designed to remove
dissolved moisture, dirt, air and other gases
from the transformer oil.
This two stage plant operates on the principle
of Low Temperature and High Vacuum.
This term contains in general: the heatup of oil, removal
of solid particles of more than 3 m size from the oil,
vacuum degasification and drying of oil.
Unfiltered oil is taken in to the system through the inlet valve. Then the oil is
pumped to the system through positive displacement pump. Preliminary filters
protect the pump by entering solid and magnetic particles up to 1 mm size. The oil
is heated up to 60C. After heating the oil passes through the cartridge filters
where the particles up to 5 microns are filtered. Then the oil is passed through a
specially designed vacuum chamber, where the moisture, air and other gases are
extracted from the oil. The vacuum chamber is designed in such a way that the oil
is spread out and is allowed to fall by gravity over the media inside, forming a thin
film of oil providing a large surface area exposed to vacuum. With this exposure,
the dissolved moisture and gases are evacuated to improve the insulating
properties of transformer oil.
In the course of oil filtration clean oil in the transformer
vessel becomes mixed with the original filling and,
consequently, a few cycles are necessary for the oil filling to
achieve the performance required.
The filtration, however, is carried through for a period until it
achieves the parameters necessary (which happens already
after four circulations, but sometimes 10 circulations are
necessary).
During the filtration solid particles are removed from the
transformer oil which entered it as a consequence of wear,
chemical and heat decomposition of solid particles, but also by
loosened rust and suspended sludges.
During the oil drying it is to reckon with water contained in
fixed insulation material. It is known that of the total volume of
water in the transformer up to 97 per cent is stored in the wood
pulp.
When drying a water affected transformer with the help of oil
the curve of water removal from the oil is a significantly different
one.
After Filtrations
Before Filtrations
Vacuum Chamber
Heater
Compressor
Dehydration of Core Coil assembly of the transformer.
Active part of the transformer is heated and then evacuated for
removal of moisture from the insulation.
Core coil assembly is heated by hot oil circulation or induction heating
system.
Drying of Transformer
This includes reconditioning of transformer
windings, insulation, gasket sealing and removal
of moisture.
Such overhauling is carried out at site with adequate
lifting and handling facility.
Transformers are dried using the oil-spray method. The principle consists in
heating up the transformer by spraying hot transformer oil on the internal
parts of the transformer structure. As soon as the required temperature of
the active part of transformer is achieved the vacuum degassing follows.
Vapours of water are sucked off from the machine at the operating pressure
of 5 -10 mbar and the temperature of 60 - 80 C. Normally the capacity of
vacuum pumps is 100 - 500 m3 of gases and vapours per hour, which for
the initial efficiency of 30 per cent means that up to 2 liters of water are
removed from the transformer in one hour. The efficiency, however, drops
gradually down to approx. one tenth of the value, depending on the
moisture degree. The process is then stabilized by hot oil which continues
to be sprayed into the internal area of the transformer. Since the
temperature at the point of spraying decreases considerably due to the
evaporation of water, and the propagation of heat in vacuum is heavily
constrained, it is necessary to heat up the internal parts of the transformer.
This is done by ventilating of the transformer interior and heating up the
same with hot oil mist. In such a way about 50 to 100 litres of water are
removed from the transformer during the drying. The time necessary to dry
out a transformer is about 10 days.
Drying of transformers
Transformers are dried using the oil-spray method.
Dissolved Gas Analysis is widely accepted as the most reliable tool
for the earliest detection of incipient faults in transformers and tap
selector units. Hydrocarbon (mineral-based) oils and silicones are
used as insulation fluids in transformers because of their high
dielectric strength, heat transfer properties and chemical stability.
Under normal operating conditions very little decomposition of the
dielectric fluid occurs. However, when a thermal or electrical fault
develops, dielectric fluid and solid insulation will partially
decompose. The low molecular weight decomposition gases include
hydrogen, methane, ethane, ethane, acetylene, carbon monoxide
and carbon dioxide. These fault gases are soluble in the dielectric
fluid. Analysis of the quantity of each of the fault gases present in
the fluid allows identification of fault processes such as corona,
sparking, overheating and arcing.
Dissolved Gas Anal ysis
DGA
ANALYSIS
Relative Solubility as a function of Temperature
Structure of insulating oil & fault gases
Gas Normal(<) Abnormal(>) Interpretation
H2 150ppm 1500ppm Corona, Arcing
CH4 25ppm 80ppm Sparking
C2H6 10ppm 35ppm Local Overheating
C2H4 20ppm 150ppm Severe Overheating
C2H2 15ppm 70ppm Arcing
CO 500ppm 1000ppm Severe Overheating
CO2 10,000ppm 15,000ppm Severe Overheating
Flag Point ( Key Gas) Method
Rogers Ratios
Duval Triangle
Area Diagnosis
PD
Partial Discharges
D1
low energy discharging-
sparking
D2
High Energy Discharge.
T1
Thermal Fault (< 300deg.C)
T2
Thermal Fault ( 300deg.C
700deg.C)
T3
Thermal fault greater than
700 deg.C.
Diagnostic results using
Duval Triangle Method
DT
Indeterminate-thermal fault or
electrical discharge
% Correct
Diagnoses
% Unresolved
Diagnoses
% Wrong
Diagnoses
IEEE Key Gas
Method
42 0 58
IEEE Rogers
Ratios
62 33 5
Doernenburg Ratios 71 26 3
IEC Basic Gas
Ratios
77 15 8
IEC Duval Triangle 96 0 4
The accuracy of the methods used has been evaluated
CH4/H2 1092/95 11.4 1
C2H6/C
H4
576/1092 0.527 0
C2H4/C
2/H6
2033/576 3.526 1
C2H2/C
2H4
0.21/2033
0.0001
0
1 0 1 0 Circulating /
Overheated Joint
C2H2/C2H4 33.04/750.76 0.044 0
CH4/H2 530.22/99.6 5.323 2
C2H4/C2H6 750.76/253.24 2.965 1
0 2 1 indicate thermal fault(>700*C);Over heating of Copper
CH4/H2 844.58/482.92 1.75 1
C2H6/CH4 219.3/844.58 0.26 0
C2H4/C2H6 1528.31/219.3 6.97 1
C2H2/C2H4 66.53/1528.31 0.044 0
1 0 1 0 Circulating currents and /
or overheating joints.
Rogers Ratio
Bucholz gas analysis (IS 3638)
Colour of gas Identification
Colorless Air
White Gas of decomposed paper and cloth insulation
Yellow Gas of decomposed Wood insulation
Grey Gas of overheated oil due to burning of iron
Black Gas of decomposed oil due dielectric arc
Combustible gas indicates decomposed insulation and oil vapour
Combustibility
Chemical test
Method 1 Method 2
Solution 1
5 g AgNO3 dissolved in 100 ml
of distilled water
Aqueous solution of
Ammonia
Solution 2
A weak solution of Ammonia in
water is slowly added to 100 ml
of solution 1 until a white ppt
which forms first, disappears in
mixture
100 mg Palladous
chloride (PdCl) dissolved
in 100 ml of distilled
water
Method 1 Observation Identification
Both solution
Both solution clear.
No PPT
The Gas is Air
Solution 1
White ppt turning brown
on exposed to sunlight
Gas of Oil Dissociation
Solution 2
Dark brown ppt Gas of decomposed paper,
cottonor wood insulation
Method 2 Observation Identification
Both solution
Both solution clear.
No PPT
The Gas is Air
Solution 1
Brick red ppt Gas of Oil Dissociation
Solution 2
Black ppt in 2 to 3
minutes
Mere darkening
Gas of decomposed paper,
cottonor wood insulation
Small concentration but
positive presence of gas of
decomposed solid insulation.