Chem p2 Final 2013

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1

SULIT
4541/2
Chemistry
Paper 2
Nov 2013
2 jam

NAMA CALON

TINGKATAN

SEKOLAH MENENGAH KEBANGSAAN AMINUDDIN BAKI


KUALA LUMPUR

PEPERIKSAAN AKHIR TAHUN


2013
PERCUBAAN SPM TAHU7
CHEMISTRY
FORM 4
Paper 2
2 hours 30 minutes
JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU
DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO
1.

Tuliskan nama dan kelas anda pada ruangan


yang disediakan.

2. Calon dikehendaki membaca maklumat di


halaman BELAKANG.

Bahagian

B
C

Soalan
1
2
3
4
5
6
7
8
9
10
Jumlah

Markah Markah
Penuh Diperoleh
09
09
09
10
11
12
20
20
20
20

Kertas soalan ini mengandungi 17 halaman bercetak


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For
Examiners
Use

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SECTION A
[ 60 marks ]
Answer all questions in this section.
1. Diagram 1 shows part of Periodic Table of Elements.
A, B, C, D, E, F and G do not represent the actual symbol of the elements.

Diagram 1
Using the letters in above Periodic Table of Elements, answer the following questions.
(a) Draw the electron arrangement of atom F
1(a)
1

[1 mark]

(b) Which of the element exist as monoatomis gas?


1(b)
...........
[1 mark]
(c) Element E is more electronegative than element D. Explain why
...........

[3 mark]

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1(c)
1

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(d) State one special characteristic of element G

1(d)

...........
[1 mark

(e) Element A reacts with element B to form an ionic compound


(i) State one property of the compound formed

1(e)(i)

...........
[1 mark]
(ii) Write the chemical equation of the reaction.

1(e)(ii)

...........
[2 mark]

Total A1
10

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2. Diagram 2.1 shows the heating curve of solid Q at room condition.

Diagram 2.1
(a) (i). What is the melting point of substance Q?
2(a)
..........
[1 mark]
(ii) What is the physical state of substance Q from point S to T?

1
2(b)

...........
[1 mark]
(iii) Explain why there is no change in temperature from S to T?

...........

[2 marks]
(d) Draw the arrangement of particles of substance Q from point T to U.

2(c)
2(d)

[1 mark]
2(e)
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(b) Table 2.2 shows the proton number and nucleon number of elements W, X, Y
and Z
Element
W
X
Y
Z

Proton number
6
8
8
15
Table 2.2

For
Examiners
Use

Nucleon number
12
16
17
31
2(f)

(i) What is the meaning of nucleon number?


...........
[1 mark]

1
2(g)

(ii) Which atoms are isotopes?

.............
[1 mark]
(iii) Explain your answer in b(ii)
...........
...
[1 mark]

(iv) Compare atomic size of Y and Z.


......
[1 mark]
(v) Give reason for your answer in 3(c)(i).
..
..
[1 mark]

Total A2
10

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3. Diagram 3 shows a series of reactions for the production of magnesium nitrate and
substance G with magnesium as the initial reactant.

For
Examiners
Use

Diagram 3
(a) Name the solution E and substance G
Solution E

: .

Substance G

: .
[2 marks]

(b) Name gas R and explain how to identify the gas?


..
..
[2 marks]
(c) In phase I, 20 cm3 of hydrochloric acid 1.0 mol dm-3 is reacted with excess of
magnesium powder.
(i) Write the chemical equation for this reaction.

[2 marks]

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(ii) Calculate the maximum amount of volume of gas R that can be produced at
room condition.
[Molar volume at room condition : 24 dm-3 mol-1]

[2 marks]
(d) Name the type of reaction that took place in phase II
..
[1 mark]
(e) Explain how you can separate substance G from the product mixture.
.
.
[2 marks]

Total A3
10

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4. Two elements X and Y can be reacted to form a compound. Figure 4 shows the
electron arrangement of the particle in the compound.

Figure 4

(a) What is the type of particle of this compound?

5(a)(i)

..............
[1 mark]
(b)

What is the proton number of element Y?

.
[1 mark]
(c)

Write the formula of the compound.

.
[1 mark]
(d)

Element Y can react with Lithium to form a compound.


(i) What type of chemical bond formed?

.
[1 mark]
(ii) Draw the electron arrangement of the compound formed.
[Proton number of lithium : 3]

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[2 marks]

(iii) Compare the electrical conductivity of compound formed between element


and Y with compound formed between Lithium and element Y.

For
Examiners
Use

.
.
[2 mark]

5(d)(i)

(iv) Explain your answer in d (iii)

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...........
...
5(d)(ii)
..
1

..
[2 marks]

Total A4
10

For
Examiners
Use

5. Hydrochloric acid is a strong acid. Table 5 shows two solution of hydrochloric acid
P and Q with different concentration.
Hydrochloric acid solution
P
Q
Table 5

Concentration (mol dm-3)


0.100
0.001

(a) State the meaning of an acid.

6(a)
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.............
.
[1 mark]
(b) Why hydrochloric acid is a strong acid?

6(b)

.............

...
[1 mark]
(c) Which solution with gives a lower pH values?

6(c)

..............
[1 mark]
(d) Give one reason for your answer in (c)

1
6(d)

..............

..
[1 mark]
(e) Figure 5.2 shows four test tubes contain dry glacial ethanoic acid, aqueous
solution of ethanoic acid, and dilute hydrochloric acid.

6(e)

Figure 5.2
(i) State the colour change of litmus paper in test tube Q and R.
..............
[1 mark]
(ii) Is there any change of colour of the litmus paper in test tube P? Explain why.
.

[2 marks]
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(iii) Write the formula of ion that caused the colour changed of the litmus paper.

[1 mark]
(iv) Calcium carbonate powder is added into test tube R. Write the chemical
equation of the reaction that take places

6(f)(i)
1

..............
[2 marks]

For
Examiners
Use

6. Diagram 6 shows the process to industrially manufacture of ammonia.

Diagram 6
(a) Name the process that produce ammonia
.
[1 mark]
(b) Write the chemical equation for the process in (a)
..
[1 mark]
(c) What are the conditions for this process to produce maximum of ammonia?
Catalyst

: .

Temperature : .
Pressure

: .
[3 marks]

(d) Ammonia gas can react with sulphuric acid to produce a salt fertilizer.
Name the salt produce

[1 mark]

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(e) Write the chemical equation to produce salt in (d)

[2 marks]
(f) The reaction between ammonia and carbon dioxide produce urea, CO(NH2)2 and
water.
Calculate the percentage of mass of nitrogen in the urea.
[Relative Atomic Mass: H; 1, C; 12, N; 14, O; 16]

[2 marks]

Total A6
12

(a) What is the name of the process to produce sulphuric acid?


..
[1 mark]

Section C
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( 20 marks )
Answer any one questions from this section

(a)

Table 9 shows the chemical symbols which represent three elements,


X, Y and Z with proton number and nucleon number.

Elements

Proton number

Nucleon number

X
Y
Z

11
17
6

23
35
12

Table 9
(i)

Write the electron arrangement of atoms X and Y.


[ 2 marks ]

(ii)

The reaction between atoms of X and Y forms an ionic compound


whereas the reaction between atom of Y and Z forms a covalent compound.
Based on the above statement, explain how these are formed.
[ 12 marks ]

(iii)

Give three differences between a covalent compound and an ionic


compound.
[ 6 mark ]

10 Explain the changes in the properties of period 3 elements across the period from left to
right with reference to
(a) metallic nature
[ 6 marks ]
(b) electronegativity
[ 6 marks]
(c) basicity and acidity of their oxides
[ 8 marks]

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MAKLUMAT UNTUK CALON


1.

Kertas soalan ini mengandungi tiga bahagian: Bahagian A, Bahagian B dan Bahagian

C.
2. Jawab semua soalan dalam Bahagian A. Tulis jawapan bagi Bahagian A dalam ruang
yang disediakan dalam kertas soalan.
3. Jawab satu soalan daripada Bahagian B dan satu soalan daripada Bahagian C.
Tuliskan jawapan bagi Bahagian B dan Bahagian C pada halaman bergaris di
bahagian akhir kertas soalan ini. Jawab Bahagian B dan Bahagian C dengan terperinci.
Anda boleh menggunakan persamaan, gambar rajah, jadual, graf dan cara lain yang
sesuai untuk menjelaskan jawapan anda.
4. Tunjukkan kerja mengira, ini membantu anda mendapatkan markah.
5. Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu.
6. Rajah yang mengiringi soalan tidak dilukis mengikut skala kecuali dinyatakan.
7. Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam
kurungan.
8. Masa yang dicadangkan untuk menjawab Bahagian A ialah 90 minit, Bahagian B ialah
30 minit dan Bahagian C ialah 30 minit.
9. Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan.
10. Serahkan semua kertas jawapan anda di akhir peperiksaan.
INFORMATION FOR CANDIDATES
1.
2.
3.

4.
5.
6.

This question paper consists of three sections: Section A, Section B and Section C.
Answer all questions in Section A. Write your answers for Section A in the spaces
provided in the question paper.
Answer one question from Section B and one question from Section C.
Write your answers for Section B and Section C in the lined pages at the end of the
question paper. Answer questions in Section B and Section C in detail. You may use
equations, diagrams, tables, graphs and any other suitable method to explain your answer.
Show your working in calculations, it may help you to get marks.
If you wish to cancel any answer, neatly cross out the answer.
The diagrams in the questions are not drawn to scale unless stated.
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7.
8.

Marks allocated for each question or parts are shown in brackets.


The time suggested to complete Section A is 90 minutes, Section B is 30 minutes and
Section C is 30 minutes.
9. You may use a non-programmable scientific calculator.
10. Hand in all your answer sheets at the end of the examination.

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