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Jurnal Internasional
Abstract
Dichromatometry
titration
The
effectiveness
of
this
I. INTRODUCTION
solution
(analyte).
determination.
Nov 2011
of
substance
Analyte
ATBAS-60118057Asian-Transactions
with
concentration
known
is
then
Asian Transactions on Basic & Applied Sciences (ATBAS ISSN: 2221-4291) Volume 01 Issue 05
limited
and
organic
indicator [6].
to:
color,
potential,
substances
which
pH
change
color
reaction [2].
agent.
procedure
and
of
dichromate
iron(II)
Nov 2011
which
by
is
widely
potassium
used
Permanganate
ATBAS-60118057Asian-Transactions
instability
(easily
Asian Transactions on Basic & Applied Sciences (ATBAS ISSN: 2221-4291) Volume 01 Issue 05
aquaculture [7].
are
added
(Zimmerman
Reinhardt
reagent).
Potassium
dichromate
solves
the
reaction [4].
indicator
which
might
be
proposed
is
including
variables
of
pH
and
MB
ATBAS-60118057Asian-Transactions
Asian Transactions on Basic & Applied Sciences (ATBAS ISSN: 2221-4291) Volume 01 Issue 05
II. EXPERIMENT
iron(II)
sulfate
potassium
dichromate,
titration.
hexahidrate,
tin(II)
chloride
Merck
For
titration
all
with
analytical
grade.
which
rapidly
disappeared
and
Analysis [1].
The
alternative
dichromatometry
respectively.
and
to
diluted
Nov 2011
using
deionized
water
ATBAS-60118057Asian-Transactions
Asian Transactions on Basic & Applied Sciences (ATBAS ISSN: 2221-4291) Volume 01 Issue 05
However
the
titration experiment
dichromate).
be
MB served as indicator.
Fe added
Fe found
Deviation
No
consumed
in
iron(II)
oxidation
by
MB
(ml)
SA
(gr)
(gr)
(gr)
0.0776
0.0837
0.0061
1M
0.0772
0.0837
0.0066
4M
0.1091
0.1138
0.0047
7M
0.0904
0.0954
0.0050
1M
0.0943
0.1004
0.0061
4M
in 4 6
0.0844
0.0887
0.0043
7M
0.1178
0.1306
0.0128
1M
0.0625
0.0736
0.0111
1M
0.0621
0.0637
0.0016
4M
in 10.5 M
10
0.0735
0.0770
0.0036
4M
11
0.1098
0.1122
0.0024
7M
acid [11].
12
0.1126
0.1155
0.0028
7M
13
0.1306
0.1257
-0.0048
7M
14
0.0887
0.0954
0.0067
7M
and
Reaction 1.
Cr2O72- + 6Fe2+ + 14H+ 2Cr3+ + 6Fe3+ +
7H2O
(1)
Besides, this extremely acid condition
might assist to determine the end point
visually since in extreme acidic solution MB is
Nov 2011
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Asian Transactions on Basic & Applied Sciences (ATBAS ISSN: 2221-4291) Volume 01 Issue 05
semiquinone
of
each titration.
[12].
The
presence
potassium dichromate
summarized in Table 2.
which
results
are
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Asian Transactions on Basic & Applied Sciences (ATBAS ISSN: 2221-4291) Volume 01 Issue 05
terms of reproducibility.
alternative
procedure
due
to
accuracy
Dev. (mg)
MB (mg)
BDS (mg)
Iron sand1
49.088
51.433
2.345
Iron sand2
28.230
23.622
-4.608
Iron stone1
54.449
56.543
2.094
titration
using
alternative
the
end
point
of
the
titration,
MB1 (mg)
Iron sand1
48.083
MB2 (mg)
50.093
(mg)
2.010
27.141
29.319
2.178
Iron stone1
51.433
57.465
6.032
IV. CONCLUSIONS
Redox
titration
using
potassium
Indicators:
Characteristics
and
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Asian Transactions on Basic & Applied Sciences (ATBAS ISSN: 2221-4291) Volume 01 Issue 05
indicators,
Titration
http://wwwchem.uwimona.edu.jm/lab_ma
2011.
of
vanadium
(III)
or
39-76.
Vol. 104.
Photomechanical
phenomena,
IUPAC
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Asian Transactions on Basic & Applied Sciences (ATBAS ISSN: 2221-4291) Volume 01 Issue 05
Nov 2011
ATBAS-60118057Asian-Transactions