NARAYANA JUNIOR COLLEGE

Kothapet, Disukhnagar, Hyderabad

SENIOR INTERMEDIATE (FTB)

LT FTB ASSIGNMENT 28
CHEMISTRY
27.11.08
ORGANIC CHEMISTRY (ALDEHYDS & KETONES)
1
Which of the following aldehydes does not show Aldol condensation
1)CH3CHO
2)(CH3)3C-CHO
3)(CH3)2CH-CHO
4)CH3CH2CHO
X
2.
R-CO-R+[H]
Alkane , then x is
1)P2O5
2)HCl+Zn
3)Zn-Hg+HCl
4)LiAlH4
CH MgI
LiAlH
3.
CH3-CO-CH
3
3
4 X
Y , Then Y , is
1)CH3CH2OH
2)CH3COOH
3)CH3CO-CH3 4)CH3CHO
4.
5.

6.
7.

8.

9.
10.

11.
12.

13.

CaCO
CHCl
HgSO
(O )

4 A B 3 C D 3 E,

C2H2 H

SO

,Then E is a/an

1)Antiseptic
2)Anti freezer
3)Explosive compound 4)Hyphotic drug
The number of Ether and Alcohol isomers of a compound with the molecular formula
C4H10O is
1)3,3
2)3,4
3)4,3
4)4,4
CH MgI
LiAlH
Cu
3
4 C , Then isomeric of C is

A
B
CH3CHO
o
H O
300 c
2
1)CH3CH2CH2CH2-OH 2)CH3CH2-O-CH3 3)C2H5-O-C2H5
4)1 and 3
Which is Redox reaction
NH
1) CH3CHO+AgNO3
2)CH3CHO+CuO
3

NaOH
3) HCHO
4)All

(CH COO) Mn
Ca (OH )
ConH SO
CH3CHO
2 B C
2 4 D, Then D is

3

2
A
homologue of
1)Mesitylene
2)Ethyl Benzene
3)Xylene
4)2 and 3
Which of the following reacts with Tollens reagent
1)CH3CHO
2)CHCl3
3)HCOOH
4)All
2
2
Al O
aq KOH
dil. NaOH
2 3 B Pd Cu
C H Cl

A
C
D
2 5
o
360
then which of the following conversions is incorrect
1) A B is dehydration
2) B C is wackers reaction
3) A C is reduction
4) C D is addition and condensation
Which does not give chloroform , when distilled with Bleaching powder
1)CH3CHO
2)C2H5OH
3)CH3CH2CHO
4)CH3CO-CH3
X and Y are Isomers. X gives Iodoform test. But not Y. Both on reduction with
Zn-Hg+Con HCl form propane. The X and Y are respectively.
1)Acetaldehyde, Vinyl alcolhol
2)Acetaldehyde, Acetic acid
3)Acetone, propanal
4)Propanal, Acetone
Which is not properly arranged
Compound
Reagent
Use
1.
CH3CHO
NH3
Rubber accelerator
2.
CHCl3
Acetone
Hypnotic drug
3.
C2H5OH
Ether
Substitution for petrol
4.
Diethyl ether
CO2
Natalite

14.

CH3COCH3

Cl
aqKOH
2 X Y .
NaOH

Y is

1)Acetic acid
3)Potassium formate
15.

16.

17.
18.
19.

20.

2)potassium acetate
4)Alcohol
C H
H O
SOCl
6 6 D ZnHg E ,
2 C

2 B
CH3Cl+KCN A
E also
NaOH
AlCl
HCl
3
obtained when Benzene reacts with X in prosence of AlCl3, Then X is
1)Aniline
2)Ethyl Benzene
3)Ethyl alcohol
4)Ethyl chloride
When ethylene is passed through acidified solution of PdCl2 in the presence of copper
chloride , it forms X . X on reduction with LiAlH4 forms Y.Both X and Y answer iodoform
test .X and Y are
1)Ethanol ,Ethanal
2)Propanone,Proponal
3)Ethanol , propanal
4)Ethanal , Ethanol
Which of the following is used as rubber accelerator
1)CH3CH(OH)NH2
2)CH3CH=N-OH
3)(CH3)2C=N-NH.C6H5
4)CH3CHOH(CN)
CH3CHO is obtained on the hydrolysis of
1)CH2CI-CH2Cl
2)CH3-CHCl2
3)CH3-CCl3
4)CH3COCl
C2H5OH+CaOCl2CHCl3 + X
CH3COCH3+CaOCl2CHCl3+Y
,
X+YZ . Then Z is uses as
1)Hyprotic drug
2)Solid fuel
3)Antiseptic
4)Antipyretic
Ethyl chloride KCN
X H 2O
Y LiAIH
4 Z Where Z is
1)1o ROH

21.

22.

23.

25.
26.

3) propane

4)Mixed ether.

Ethyl chloride forms a pair of homologues on/by the actions of

1)Reduction, Wurtz reaction

2)KCN, AgCN

3)KNO2, AgNO2

4)Aq KOH, alc. KOH

Chloroform on strong heating with Ag metal forms X. X on hydration under given suitable
conditions gives Y. If Y is heated with I2 and NaoH, Z is formed X, Y&Z are respectively.
1)Ethane, ethanol, Iodoform

2)Ehyne, acetone, iodoform,

3)Ehyne, Ethanal, iodoform.

4)Ethyne, benzene, iodobenzene.

Chloretone is
1) An alcohol

24.

2)3o ROH

2) A ketone

3) An Ester

HCl
aqKOH
Y
Z , Then Z is
(excess )
2)CH3CH2OH
3)CH3CHO

CH3CHO+CuO

CH COOH

X , Then X is
3
1)Cu2O
2)Cu
3)CuSO4
PBr
H
SO
/H O
AlcKOH
C2H5OH
2 4
2

3
X

Y
Z
1)Na
2)CH3MgX
3)CH3CH2Cl

4) A hydrocarbon

Ag
CHI3 X

1)CH3COOH

4)C2H2
4)All
X

A H 2 , Then X is
4)NaOH

27.

K Cr O / H
X
2 2 7
1)CH3CHO

28.
29.

(O)

CH COOH , Then Y is
3
2)CH3CH2-CHO
3)CH3-COCH3 4)1 and 3
Y

In which of the following reagents, ethyl alcohol undergoes C OH bond cleavage

1) CH3 MgBr
2) CH3COOH
3) HNO3
4) Lucas reagent
Cu
Y , Then Y is used in the preparation
CH3CHO+CH3MgCl X
300o c
1)Nail polish remover 2)Cordite

30.
31.

32.

33.
34.
35.

36.

37.

3)Acetylene storing

4)All

Glucose X
C2H5OH , Then X is
1)Invertase
2)Zymase
3)Diastase
4)Maltase
Acetaldehyde can be oxidised to acetic acid by
1)Tollens reagent
2)Fehlings reagent
3)Manganese acetate
4)All
H O
Ba (OH )
Cu
2 C , Then C is
2

A
B
CH3CHO+CH3MgBr
o
300 c
1) 4-Methyl, 3 hydroxy , 2 pentanone
2) 4-methyl-2hydroxy-3 pentanone
3) 4 hydroxy , 4 methyl, 2 pentanone
4) 4 hydroxy 3 methyl 2 pentanone
Which of the following does not give precipitate with Alkaline I2 solution
1)C2H5OH
2)C2H5-CO-C2H5
3)CH3CHO
4)CH3-CO-CH3
KMnO
Zn Hg

PDC
4 A, , Then A is



X
Y
Z
C2H5OH
HCl
H O
2
1) Acetaldehyde
2) Acetic acid
3) Ethylene glycol
4) Ethyl alcohol
C2H5O C2H5 + cold HI X + Y
X + (CH3CO)2O Z + A
Y + CH3COOAg Z
What are X, Y, Z
1) X = C2H5I , Y = C2H5OH , Z = CH3COOC2H5
2) X = C2H5OH , Y = C2H5I , Z = CH3COOC2H5
3) X = C2H5I , Y = C2H5I
, Z = CH3COOC2H5
4) X = C2H5I , Y = CH3COOH , Z = CH3COOC2H5
Match the following
Reaction
Catalyst

C2H5O C2H5 + CH3COCl

CH3COOC2H5 + C2H5Cl
a) Cu
1)
CH3CH2OH CH3CHO
b) MnO
2)

CH3COOH
CH3COCH3
c) KOH
3)
CH3COCH3 + CHCl3 Chlorotone
d) ZnCl2
4)
e) AlCl3
1) 1d , 2a , 3 b, 4 d 2) 1e, 2a, 3b, 4c
3) 1d, 2a, 3b, 4c
4) 1a, 2b, 3e, 4c
Assertion (A) : Ethers behave as bases in the presence of mineral acids
Reason (R) : Ethers form a dative bond with proton of acid
1) Both A and R are correct, R is the correct explanation of A
2) Both A and R are correct, R is not the correct explanation of A
3) A is correct, but R is wrong

4) A is wrong, but R is correct

38.

Assertion (A) : Alkynes give aldehydes and ketones on hydrolysis

Reason (R) : Both aldehydes and ketones are functional isomers
1) Both A and R are correct, R is the correct explanation of A
2) Both A and R are correct, R is not the correct explanation of A
3) A is correct, but R is wrong

39.

40.

4) A is wrong, but R is correct

Which of the following statements is / are correct

a) Tollens reagent is used to distinguish aldehydes and ketones
b) Iodoform test is used to distinguish ethyl alcohol from methyl alcohol
c) Grignard reagent gives primary alcohol with aldehydes and secondary alcohols with
ketone
d) 2, 4 DNPH is used to distinguish aldehydes and ketones
1) a, b
2) b, c
3) a, b & d
4) a, b & c
In which of the following reagents acetaldehyde undergoes only addition reaction
1) dil. NaOH
2) NH2OH
3) HCN
4) 2, 4 DNPH
***
CHEMISTRY

1) 2 2) 3 3) 4
11) 3 12) 3 13) 4
21) 1 22) 3 23) 1
31) 4 32) 3 33) 2

4) 4
14) 3
24) 3
34) 3

5) 2
15) 4
25) 1
35) 2

6) 2
16) 4
26) 1
36) 3

7) 4
17) 1
27) 4
37) 1

8) 4
18) 2
28) 4
38) 2

9) 4
19) 3
29) 4
39) 1

10) 3
20) 1
30) 2
40) 3