Professional Documents
Culture Documents
2011 s4 s430-s438
2011 s4 s430-s438
2011 s4 s430-s438
Technical university Koice, Faculty of Metallurgy, Department of Iron Metallurgy and Foundry, Park Komenskho 14,
040 01 Koice, b Eurocast Koice, 040 01 Koice, Slovakia
alena.pribulova@tuke.sk
2. Realization of experiments
Key words: Hadfields Steel, Chemical Composition, Taughness, Impact Test
Moulding
All experiments were realized for the casting points.
The mould for casting production was made from furan mixture. The opening material was SiO2 sand and it was substituted by chromite in thermal points.
Internal cast iron chills were used in thermal exposed
places. Furan chromite and furan siliceous mixtures were
used for cores production. The cores were reamed and coated
by magnesia siliceous coating.
The charge contained deep-drawing scrap from cold
rolling mill plant, ferroalloys and carburisers. Deoxidation
agent was used Al and for alloying were used: FeMn(c),
FeMn(af), FeCaSi and Al. Melting process was double-slag,
after oxidative period the slag was pulled of the metal surface
because of phosphorus. Then the deoxidation with Al was
made. After deoxidation metal was alloyed with FeMn(c),
FeMn(af) and FeCr. In the ladle metal was deoxided with Al
and then FeCaSi, FeTi and FeZr were added.
Pouring was made with ladle with bottom pouring hole.
Tapping temperature was 1500 C and pouring temperature
was 14351450 C.
After cleaning and blasting the castings were heat
treated.
1. Introduction
Austenitic Hadfields steel containing about 1.2 mass %
C and 12 mass % Mn is known for a high resistance to impact
wear caused by rapid cold work hardening14. This was the
first alloy steel that was extremely hard wearing and proved
the perfect material for early railway track components. Currently it has applications in railway track particularly at crossing where resistance to high metal to metal wear and impact loading is required.
Consequently, it rapidly gained acceptance as a very
useful engineering material. Hadfields austenitic manganese
steel is still used extensively with minor modifications in
composition and heat treatment, primarily in the fields of
earthmoving, mining, quarrying, oil well drilling, steelmaking, railroading, dredging, lumbering, and in the manufacture
of cement and clay products. Austenitic manganese steel is in
equipment for handling and processing earthen materials
(such as rock crushers, grinding mills, dredge buckets, power
shovel buckets and teeth, and pumps for handling gravel and
rocks. Other applications include fragmentizer hammers and
grates for automobile recycling and military applications such
as tank track pads4.
Manganese austenitic steel has some special properties
that make it irreplaceable. In technical practise the hardening
ability by high static or dynamic stress is used. The high hardness of face layers increases the abrasive wear resistance but
because the middle part keeps good toughness, the components support high impact stress.
Many variations of the original austenitic manganese
steel have been proposed5, often in unexploited patents, but
only a few have been adopted as significant improvements.
These usually involve variations of carbon and manganese,
with or without additional alloys such as chromium, nickel,
molybdenum, vanadium, titanium and bismuth.
The basic condition for the chemical composition of
Hadfields steel is ration Mn : C > 10. The upper borderline is
usually 14 % Mn but in technical practice this ration can be
increased to 20 % most of all for thick-walled castings5. The
main reason for using of high content of Mn is to improve the
hardenability.
Melting
All melts were realized in basic electric arc furnace with
volume of 6,5 tons of molten metal. The melts were realized
without alloyed scrap.
Table I
Chemical composition of Hadfields steel via different standarts5,6
Mangaan
steels
Pmax.
0.070
Smax.
1.11.3
max.1,0
12.013.0
0.30.5
0.100
0.040
1.11.4
0.040
STN 422920
STN 422921
standart
A 128, Grade C
1.051.35
G-X 120 Mn 12
STN 417618
Mn
11.013.0
max.1.0
0.100
1.11.5
12.014.0
0.7
0.100
0.050
1.11.5
12.014.0
0.7
0,71,2
0.100
0.050
Table II
Chemical composition of the experimental melts
Chemical composition [mass %]
melt
Si
Mn
Cr
Ni
Nb
Ti
Zr
0.71
13.3
0.24
0.12
0.051
0.006
0.005
0.012
0.16
0.99
0.41
12.8
0.27
0.08
0.042
0.005
0.006
0.01
0.94
0.33
12.4
0.26
0.42
0.044
0.006
0.007
0.01
1.1
0.68
12.5
0.31
0.11
0.042
0.007
0.007
0.012
1.15
0.48
13.2
0.9
0.09
0.044
0.008
0.008
0.009
1.16
0.5
12.3
0.58
0.68
0.042
0.006
0.009
0.01
1.17
0.49
12.7
0.66
0.81
0.047
0.008
0.008
0.01
1.13
0.45
12.5
0.88
0.92
0.051
0.007
0.008
0.01
1.26
0.49
13
0.03
0.08
0.037
0.006
0.01
0.033
0.015
1.23
0.49
13.1
0.003
0.03
0.031
0.007
0.009
0.062
0.031
1.24
0.5
13.1
0.01
0.03
0.032
0.006
0.009
0.018
0.024
1.3
0.5
13.4
0.06
0.06
0.044
0.012
0.006
0.043
1.19
0.45
12.9
0.02
0.04
0.045
0.005
0.01
0.033
1.26
0.43
13.4
0.03
0.04
0.046
0.009
0.007
0.027
1.32
0.5
12.8
0.06
0.05
0.045
0.006
0.004
0.023
1.2
0.48
13.1
0.01
0.04
0.04
0.006
0.008
0.02
Impact test
The impact test is one of the main criterion by evaluation
of quality of casting points. The test specimen for rough bar
with dimensions 30 x 30 and length 200 mm was used for
impact test.
Before test the half rounded notch was pressed on
rough surface of specimen (r = 1.5 mm, h = 1.5 m) that simulated the real conditions of stress.
Main condition was that the specimen had to stand again
3 impacts and the depth of created crack could be max. 7 mm.
4. Obtained results
The chemical composition of the melts was changed
during the tests with goal to find the influence of chromium
s431
5. Evaluation of results
Quality of material used for production of points influences on the safety of transportation on railway therefore the
toughness was tested by impact test and by tension test.
During the tests the content of carbon had escalated to
1.15 %. Content of Mn was adjusted content of carbon to
keep proportion Mn/C.
Influence of molybdenium and vanadium was not in this
case important because of their low content. They were not
put into the melt purposely but they were in the charge. Their
higher content was not suitable because they forming difficult
dissolving carbides.
Grain was refined in four melts by zirconium, since melt
J the melts were alloyed by titanium too. Its content increased
from 0.01 % to 0.04 %.
In first eight melts the content of chromium and nickel
was enhanced to 1 %.
From the results of impact test is visible the negative
influence of chromium and nickel on impact test of material.
The lower values of impact test were observed in melts C, D,
E with high content of Cr and Ni, these samples were broken
after 1 impact. After second impact the samples F, G and H
were broken, they had high content of Cr and Ni too.
After negative results of impact test of melts A H the
chemical composition was changed. The change of chemical
composition was in reduction of Cr, Mo and Ni content.
Only samples J, M, N and P conformed to the test condition (to stand 3 impacts and to have a maximum depth of
6. Conclusions
The chemical composition of melts was changed during
the experiments. 15 melts with different content of Cr, Ni and
with addition of Zr and Ti were tested.
Results of realized experiments show:
Negative influence of the elements formed carbides like Cr
and Ni on impact test of Hadfields steel.
Melts with higher content of Cr and Ni didnt have claimed
toughness and they didnt conformed to impact test.
These results were confirm by tensile test.
For the obtaining of required values of impact test is important to limit the content of chromium to 0.1 % and content of nickel to 0.05 %.
REFERENCES
1.
2.
3.
4.
5.
Table III
Depth of cracks after impact test
Melt
6.
2. impact
3. impact
12
2.63
13
5.85
4.75
7.25
4.375
9.4
3.75
10
2.23
9.6
1.2
2.1
0.7
2.6
4.15
1.75
6.1
8.2
1.8
4.75
8.2
1.75
3.2
5.525
0.5
2.8
6.45
1.675
0.2
2.9
5.35
A. Pribulov, J. Babic, D. Baricov (Technical university Koice, Fakulty of Metalurgy, Department of Iron Metalurgy and Foundry, Koice, Slovakia): Influence of Hadfields steel ChemicalComposition on its Mechanical Properties
The original austenitic manganese steel is still used with
minor modification in composition in the fields of earthmoving, mining, steelmaking and railroading. The goal of this
paper has been an evaluation of influence of chemical composition on quality of Hadfields steel castings. In this case under term quality we can understand first of all the steel toughness which was evaluated by impact test and by tension test.
The quality of Hadfields steel castings was evaluated by next
parameters: chemical analysis of molten metal, impact test
and tensile test. Results of realized experiments showed negative influence of the elements formed carbides like Cr and Ni
on impact test.
1. Introduction
Copper is a traditional material for precise and demanding machine parts like seals, washers, bearing liners, etc. For
these applications properties such as high strength and ductility, fatigue strength, wear resistance, etc., are necessary. In
order to fulfill such requirements an approach of creating
composites using hard dispersoid particles is often used1.
Another way how such desirable properties can be
achieved is creating very fine, submicrocrystalline microstructures2. Such microstructures can be prepared by inducing
severe plastic deformation of the material3. At present very
promising technique for preparing such structures is the
ECAP (Equal Channel Angular Pressing) which allows obtaining the very fine grained microstructure (nanostructure)
by multiple pressings through the die4.
Aim of this work was to investigate the effect of refining
of microstructure by ECAP process on tribiological behaviour
and wear of Cu-Al2O3 composite at room and elevated temperatures.
2. Experimental
Reaction milling and mechanical alloying was used to
prepare the samples. Cu powder with the calculated addition
of Al was homogenized by attrition in oxidizing atmosphere.
The distribution of the obtained CuO was uniform. A subsequent treatment at 750 C induced the reaction of CuO with
the added Al powder, and led to the formation of Al2O3 particles. The remaining CuO was reduced by attrition in a mixture of H2 + H2O (rate 1:100). The powder was compacted by
cold pressing and hot extrusion at 750800 C.
Microstructured material with 5 vol.% Al2O3 was transformed by the ECAP (Equal Channel Angular Pressing)
method in two passes into a nanocomposite material. The
experimental material was pressed through two right angled
(90) channels of a special die by route C.
The designation of experimental materials is as follows:
Micro Cu-Al2O3 is denoted as Cu1, Nano Cu-Al2O3 is called
Cu2.
s433
coefficient of friction
0.7
0.6
0.5
0.4
0.3
Cu1
Cu2
0
200
400
600
temperature (C)
a
Fig. 1. Coefficient of friction as function of temperature
0.9
0.8
coefficient of friction
0.7
0.6
Cu1-600C
Cu2-600C
Cu1-400C
Cu2-400C
0.5
0.4
0.3
0.2
0.1
0
0
20
40
60
80
100
distance (m)
0.0014
Fig. 4. Example of the wear tracks created at 200 (a) and 400 C
(b) in Cu2. The comparison illustrates the decrease of wear
Cu1
Cu2
0.0012
0.0008
0.0010
0.0006
0.0004
0.0002
0.0000
-0.0002
0
200
400
600
temperature (C)
lead to improvement of the wear properties at lower temperatures where wear resistance of the nanostructured material
was about three times higher than of the micro-Cu. When the
temperature increased up to ~400 C the wear rates decreased
for both materials virtually down to zero. The improvement of
wear rates with temperature is attributed to formation of hard
copper oxides Cu2O on the sample surface.
Table I
Amount of oxygen on the surfaces of the experimental materials found by EDX
Temp.
[C]
20
200
400
600
REFERENCES
1. Besterci M., Kov L.: Int. J. Mater. Product Technol.
18, 26 (2003).
2. Gleiter H.: Nanostruct. Mater. 1, 1 (1992).
3. Valiev R. Z., Krasilnikov N. A., Tsenev N. K.: Mater.
Sci. Eng. A 137, 35 (1991).
4. Besterci M., Kvakaj T., Koiko R., Slleiov K.: Int. J.
Mater. Product Technol. 40, 36 (2011).
5. Hvizdo P., Besterci M.: Chem. Listy, in press (2011).
6. http://www.engineeringtoolbox.com/friction-coefficientsd_778.html
7. Marui E., Endo H.: Wear 249, 582 (2001).
8. Sadykov F. A., Barykin N. P., Aslanyan I. R.: Wear 225
229, 649 (1999).
P. Hvizdoa, M. Bestercia, P. Kulub (a Institute of Materials Research, Slovak Academy of Sciences, b Tallinn University of Technology): Tribological Properties of Cu-Al2O3
Composites at Elevated Temperatures
Fig. 5. Worn caps of the steel balls produced at 200 C (left) and
600 C (right)
4. Conclusions
Two Cu-5%Al2O3 composites with different size of the
matrix grains were prepared. Wear testing was carried out
using pin-on-disc method in the temperature range from 20 C
up to 600 C. Friction and tribological properties of both materials were compared.
It was found that the values of the coefficient of friction
had similar tendency to decrease in the interval between 200
and 400 C. It was shown that refinement of microstructure
s435
Oce
A
B
Hrbk,
[mm]
0,47
0,65
C,
[%]
0,0033
0,0053
Si,
[%]
2,4
0,6
Mn,
[%]
0,23
0,24
P,
Cu, Al,
[%] [%] [%]
0,008 0,013 0,37
0,123 0,014 0,025
1. vod
Izotrpne elektrotechnick ocele /IEO/ sa rozdeuj na
dva zkladn typy a to ocele fini /IEOF/ a semifini /
IEOS/1.Tto klasifikcia je zaloen na spsobe finlneho
tepelnho spracovania. V prpade IEOS vrobca na zver
aplikuje hladiace valcovanie a spotrebite na vystrihnutch
segmentoch realizuje hanie, poas ktorho dochdza
k deformane indukovanmu rastu feritovch zn2,3. IOEF s
u vrobcu kontinulne han na finlnu mikrotruktru, spotrebite vysekan segmenty u neha. Pri finlnom han
IEOS poda EN je z hadiska deformane indukovanho rastu
zn uritou nevhodou, e rchlos ohrevu materilu je limitovan a poas ohrevu priebene dochdza k zotavovacm
procesom, o zniuje inok hnacej sily pohybu hranc ete
pred dosiahnutm teploty ohrevu. Cel proces ohrevu, vdre
na teplote a ochladzovania trv cca 10 hodn4. Pri finlnom
han IEOF materil vstupuje do ohrevu po vysokej deformcii za studena /vye 75 %/, v priebehu krtkodobho hania
dochdza k rekrytalizcii deformovanch feritovch zn.
Poas vdre na teplote u nie je mon vyui mechanizmus
deformane indukovanho pohybu hranc zn. V prci sme sa
zamerali na vyuitie mechanizmu deformane indukovanho
pohybu hranc poas dynamickho kontinulneho hacieho
procesu IEO s cieom dosiahn hrubozrn mikrotruktru so
zvenou intenzitou kubickej, resp. Gossovej textrnej zloky.
3. Vsledky
Mikrotruktra vchodzieho stavu skmanch ocel ,
teda stavu po finlnom han v prevdzkovch podmienkch
je uveden na obr. 1 a, b. Stredn rozmer feritovho zrna
ocele A je d = 79 m a stredn rozmer ocele B d = 38 m. Na
obr. 2 uvdzame nameran hodnoty strednej vekosti feritovch zn v zvislosti od stupa deformcie, pre teploty hania 900 C a 950 C. Oce A dosahuje maximlnu hodnotu
vekosti zrna d = 420 m po han pri 950 C po deformcii
4 %, oce B dosahuje maximlnu hodnotu vekosti zrna
d = 380 m po deformcii 6 % a teplote hania 950 C. Poas hania pri teplote 900 C feritov zrno rastie v rmci
celho skmanho rozsahu deformcii . Pri teplote hania
950 C po prekroen kritickho stupa deformcie /4 % resp.
6 %/ dochdza v dsledku iastonej rekrytalizcii k poklesu
a
2. Experiment
Ako experimentlny materil sme pouili dve vkuovan
IEOF s chemickm zloenm uvedenm v Tab. I, v stave po
finlnom kontinulnom han v prevdzkovch podmienkch.
Materil bol nsledne spracovan v laboratrnych podmienkch. Plech bol ohriaty na teplotu 250 C a bezprostredne /do 2 sec./ valcovan s jednm berom v rozsahu 2 %,
4 %, 6 % a 8 %. Vyvalcovan materil bol han v atmosfre
H2 dynamickch podmienkch pri teplotch 850 C, 875 C,
900 C, 925 C, a 950 C s dobou vdre na teplote 180 seknd. Na tepelne spracovanch vzorkch bola meran koercivita Hc v jednosmernom magnetickom poli na vzorkch
30x10 mm, pomocou koercimetra KPS Ic. Metalografickou
analzou bol pre jednotliv truktrne stavy stanoven stredn rozmer feritovho zrna. Na deformovanch vzorkch bola
meran mikrotvrdos po hrbke plechu. Pomocou nanoinden-
s436
strednej vekosti zrna. Na obr. 3 s pre oce A aj oce B zobrazen nameran hodnoty koercitvnej sily v zvislosti od
stupa deformcie a teploty hania. Minimlna hodnota koercitvnej sily v prpade ocele A bola Hc = 14 A/m a v prpade
ocele B Hc = 8 A/m. Znamen to podstatn znenie
v porovnan s vchodzm stavom 47 A/m resp. 82 A/m.
Na obr. 4 s pre oce B zobrazen nameran hodnoty
mikrotvrdosti HV 10 po hrbke plechu po valcovan berom
6 % a predohriati materilu na 250 C. Na obr. 5 s zobrazen
vsledky z EBSD meran, charakterizujce zastpenie jednotlivch prednostnch krytalografickch orientcii v oceli B
v dodanom stave, na obr. 6 po han pri 950 C a predchdzajcej deformcii 4 %. Dolo k zveniu intenzt kubickej
(100)[0vw] a Gossovej (110)[001] a (111)[0vw] je potlaen.
4. Diskusia
Podstata predloenho postupun tvorby mikrotruktry
a krytalografickej textry je zaloen na vyuit deformane
indukovanho pohybu hranc zn feritu pri kontinulnom
s437
HV
285
280
275
270
265
260
I.
II.
III.
IV.
V.
VI.
VII.
VIII.
IX.
X.
5. Zver
vzdialenos od povrchu ( m)
Obr. 4. Zvislos rozloenia mikrotvrdosti v materiali B po hrbke plechu po valcovan berom 6 % a predohriati materlu na
250 C
s438