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Magnetic Separation
Magnetic Separation
Magnetic Separation
See also Solid Solid Separation, Introduction
William J. Bronkala, Applied Magnetic Systems, Inc., Greenfield, Wisconsin 53 220, United States
1.
History . . . . . . . . . . . . . . . . . . .
2.
3.
3.1.
1. History
In the mid-1800s, Faraday demonstrated in a
series of experiments that any substance placed
in a magnetic field will either increase or decrease, to a varying extent, the magnetic field
passing through it. This variation in the magnetic
susceptibilities of different materials makes possible the phenomenon of magnetic separation
(see Chap. 2).
Based on its magnetic susceptibility, a material can be classified as ferromagnetic (strongly
attracted magnetically), paramagnetic (attracted
magnetically to some degree), or diamagnetic
(repelled by a magnetic field).
All materials may be termed magnetic, although the relative value of the induced magnetism might be very small. Ferromagnetic materials have magnetic properties similar to iron,
and some ferromagnetic materials will retain
their magnetic properties in the absence of an
applied magnetic field. This phenomenon is
known as remanence. Paramagnetic materials
have a positive magnetic susceptibility (showing
a weak attraction to a magnet), and diamagnetic
materials have a negative magnetic susceptibility (showing a weak repulsion from a magnet).
Ferromagnetic materials are amenable to lowintensity separation and paramagnetic materials
to high-intensity separation.
Since the work of Faraday, numerous magnetic devices have been developed that utilize
differences in magnetic susceptibility to obtain
physical separation of mineral products. The
first successful commercial application of magnetic separators was the separation of iron from
c 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
10.1002/14356007.b02 19
3.2.
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brass in the late 1860s, followed by the separation and concentration of the ferromagnetic mineral magnetite.
Low-intensity electromagnetic separators
of various configurations were developed after
1880 for wet and dry magnetic separation of ferromagnetic materials; these were followed in the
early 1900s by high-intensity magnetic separators and permanent magnet separators. The first
permanent magnet material was an aluminum
nickel cobalt iron alloy designated ALNICO,
which was followed in the 1950s by ceramic
barium and strontium ferrite permanent magnets, and in the 1980s by rare-earth magnets
( Magnets and Magnetic Materials).
High-intensity magnetic separators of several types were developed to separate paramagnetic materials of lower positive magnetic susceptibility. The first high-intensity separators
were largely confined to dry separation, with
subsequent development of high-intensity wettype separators in the early 1960s and the high
gradient magnetic separator (HGMS) in the mid
Magnetic Separation
netic material in practice simply called nonmagnetic, constitutes the tailings (or reject) product.
If liberation is incomplete, a less magnetic (middling) product can result. Each product must be
transported into, through, and out of the magnetic separator. The magnetic and competing
forces (gravitational, frictional, hydrodynamic,
or inertial) tend to reduce the degree of separation.
Definitions (for a more comprehensive treatment, Magnets and Magnetic Materials). A
magnetic field is defined by its magnetic field
strength H (sometimes also called field intensity). The field strength of a homogeneous magnetic field in a solenoid with n turns per meter is
given by
H =nI
=M/H
(2)
B =H
(1)
where M (SI unit A/m) is the induced magnetization of the substance observed whenever it is
placed in a magnetic field.
The magnetic susceptibility of a material,
(volume susceptibility), is dimensionless and is
defined as the ratio of induced magnetization to
magnetic field strength:
Process of Magnetic Separation. Magnetic separation relies on the different behavior of individual mineral particles under the
influence of a magnetic field. Ferromagnetic or
paramagnetic materials are attracted along the
lines of the magnetic force from areas of lower
magnetic field strength to higher field strength.
Diamagnetic particles are repelled from areas of
higher magnetic field strength to those of lower
field strength.
The magnetization of various materials is directly dependent on their degree of magnetic susceptibility and the strength of the applied magnetic field (Eq. 2).
Magnetic Separation
Susceptibility
Mineral
Susceptibility
Magnetite
Franklinite
Ilmenite
Magnetic pyrite
Siderite
Hematite
Zircon
Limonite
Corundum
Pyrolusite
Manganite
Garnet
Quartz
Rutile
Pyrite
Zincblende
Dolomite
Apatite
Willemite
Chalcopyrite
Spinel
Galena
0.12 3.07(a)
3.7103 (a)
1.5103 (a)
0.337 5.75103 (a)
8.4104
0.11 1.1103 (a)
1.7107
7 8104 (a)
3.4107 (b)
6.2 7104 (a)
4.9104 (a)
3.75104 (a)
1.75 4.38104 (a)
1.96106
0.2 1.5104 (a)
2.64107 (b)
1106 (b)
2.64106 (b)
1.9104 (a)
8.5107 (b)
0.2107 (b)
3.5107 (b)
Graphite
Fluorite
Aragonite
Calcite
Ruby
Topaz
Beryl
2.2106
2.85107 (b)
3.92107
3.63107
4.7107 (b)
4.2107 (b)
8.26107
3.86107 (b)
2.38105
2.66105
4.27107
3.84107
3.17107 (b)
8.8106 (b)
5.7106 (a)
5.8106 (a)
1.6106 (a)
6106 (a)
4.1105 (a)
3.5104 (a)
8.5107 (a)
0.8
1.2105 (a)
Halite
Celestine
5.0107 (b)
3.42107
3.14107
3.59107 (b)
1.12106 (b)
Tourmaline
Epidote
Augite
Adularia
Diopside
Sapphire
Cobaltite
Feldspar
Limestone
Red serpentine
Green serpentine
Antimonite
Mica, transparent
Ferromagnetic materials are quickly saturated magnetically, and increasing the magnetic
field strength will not increase the magnetization beyond a certain point. For paramagnetic
materials that are difficult to magnetize, the induced magnetization is proportional to the magnetic field strength applied, and some materials,
practically speaking, cannot be saturated.
The efficiency of magnetic separation may
be expressed by both the recovery (i.e., the ratio
of magnetic material in the magnetics relative to
that in the feed) and the grade (i.e., the fraction of
magnetic material in the magnetic concentrate).
Magnetic Separation
Figure 2. Two ways of mounting suspended magnets to remove core nails from foundry sand on a conveyor belt
Magnetic Separation
Magnetic Separation
Magnetic Separation
Magnetic Separation
Figure 9. Magnetic drum separator with radial poles alternating across the face width of the drum
A) Arrangement of poles: a) Drum heads; b) Stationary shaft
B) Principle of operation: a) Revolving cylinder; b) Stationary magnet assembly
Figure 10. Magnetic drum separator with axial poles alternating around the circumference of the drum
A) Arrangement of poles; B) Principle of operation
Magnetic Separation
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Magnetic Separation
4. Applications
The many types of magnetic separators result
in a wide range of applications for these units.
They are used in tramp iron removal, mineral
processing, and iron recovery:
Removal of tramp iron:
Chemicals
Pharmaceuticals
Cooling fluids
Scrap metals
Food processing
Miscellaneous materials
Minerals
(water, glass, cork, textiles)
Mineral beneficiation:
Aluminum
Molybdenum
Barium
Nickel
Chromium
Niobium
Clay
Rare earths
Diamond
Rhenium
Garnet
Talc
Germanium
Tantalum
Hafnium
Tin
Iron
Titanium
Kyanite
Tungsten
Manganese
Yttrium
Recovery of iron:
Solid waste
Heavy media (ferrosilicon)
Magnesium
Mercury
Mica
Platinum-group metals
Radium
Scandium
Silicon
Silver
Sulfur
Tellurium
Thallium
Thorium
Uranium
Vanadium
Zinc
Zirconium
Magnetic Separation
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Chemical processing:
Recovery of paramagnetic fine precipitates:
deposition and recovery of substances on ferromagnetic particles.
The selection of a particular magnetic separator will be influenced by several factors such
as
1) size of feed material,
2) tonnage or capacity to be handled,
3) relative magnetic responsiveness (i.e., susceptibility) of the material to be separated
magnetically,
5. References
1. J. D. Kraus: Electromagnetics, McGraw-Hill,
New York 1953.
2. D. M. Hopstock: Fundamental Aspects of
Design and Performance of Low Density Dry
Magnetic Separators, Trans Soc. Min. Eng.
AIME 258 (1975) 222 227.
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Magnetic Separation