Professional Documents
Culture Documents
Review
Review
Review
3 hours
Answer any 4 out of 5 problems:
conceptual questions and calculations
Screw dislocation
Applied tensile
stress: s = F/A
R s cos cos
In general for cubic unit cells, an angle
between directions 1 and 2,
represented by [u1v1w1] and [u2v2w2],
respectively, is given by:
= cos
-1
u1u 2 v1v2 w1 w2
(u12 v12 w12 )(u 22 v22
w22 )
R s cos cos
crss y coscos
crss
y
(cos cos ) max
Conditions for slip
R CRSS
5
Slip System
Slip System: combination of slip plane and slip direction
Slip plane - plane on which slippage occurs
Highest planar densities (and large interplanar
spacings)
Slip directions - directions of movement
Highest linear densities
Metals
Slip Plane
Slip
Direction
No. of Slip
Systems
{111}
110
12
{110}
1 11
12
-Fe, W
{211}
1 11
12
-Fe, K
{321}
1 11
24
{0001}
101 0
101 1
1120
1120
1120
6
7
Strengthening Mechanisms
Dislocation motion
Precipitation strengthening
Strain hardening
Hall-Petch Equation:
syield so k y d
1 / 2
10
11
Ao Ad
%CW
x 100
Ao
sy
1
sy
Strain hardening
e
13
14
TR
15
16
17
Large
Moderately
Ductile
Brittle
Moderate
Small
Ductile:
%AR or %EL
Warning before
fracture
Brittle:
No
warning
18
19
(between grains)
Transgranular/Intragranular
(through grains)
20
S = stress amplitude
Fatigue
smax
smin
Sfat
Fatigue limit
safe
10 3
10 5
10 7
10 9
N = Cycles to failure
S
time
S = stress amplitude
sm
unsafe
case for
steel (typ.)
unsafe
case for
Al (typ.)
safe
10 3
10 5
10 7
10 9
N = Cycles to failure
21
Creep
Sample deformation at a constant stress (s) vs. time
s,e
Primary Creep
Secondary Creep
Tertiary Creep
22
Phase Diagrams
23
primary
eutectic
eutectic b
24
25
Solubility
Limit
80
60
40
(liquid solution
i.e., syrup)
L
(liquid)
+
S
(solid
sugar)
20
40
60 65 80
100
C = Composition (wt% sugar)
Sugar
20
Water
Temperature (C)
Solubility Limit:
Maximum concentration for
which only a single phase
solution exists.
26
Pure Cu
cooling
cooling
heating
+ b
27
28
T(C)
1600
1500
Cu-Ni
phase
diagram
L (liquid)
1400
1300
1200
(FCC solid
1100
1000
solution)
0
20
40
60
80
100 wt% Ni
29
3032 35
CL C0
40 4 3
50
C wt% Ni
30
tie line
1300
L (liquid)
B
TB
(solid)
1200
R
20
3 0CL
C0 4 0 C
wt% Ni
WL
ML
50
Adapted from Fig. 9.3(b),
Callister & Rethwisch 8e.
C C0
ML
S
ML M R S C CL
M x S ML x R
W
C CL
R
0
R S C CL
31
C changes as we solidify.
Cu-Ni case: First a to solidify has C = 46 wt% Ni.
Last a to solidify has C = 35 wt% Ni.
Slow rate of cooling:
Fast rate of cooling:
Equilibrium structure
Cored structure
Uniform C:
35 wt% Ni
First a to solidify:
46 wt% Ni
Last a to solidify:
< 35 wt% Ni
32
Binary-Eutectic Systems
In eutectic systems, there is
partial solubility in the solid
state. (Cu-Ag and Pb-Sn alloy
systems)
Eutectic point.
Eutectic temperature TE
Eutectic composition CE.
(CE) + b(CbE)
cooling
TE 800
Liquidus
L+
Solidus 779C
8.0
E L+b
b
71.9 91.2
600
Solvus
400
200
20
+ b
40
Solvus
100
60 CE 80
C , wt% Ag
heating
33
Temperature C
Temperature C
Binary-Eutectic Alloy
of eutectic composition
Tm
Time
Pure metal
Melting temperature
range
Time
Alloy
34
Region II:
L L +
+b
Pb-Sn
system
T(C)
300
Region III:
L+b
Region IV:
L L + + b
L (liquid)
200
L+
18.3
100
61.9
97.8
+ b
0
primary
eutectic
eutectic b
L+b b
183C
20
100
60
80
C, wt% Sn
35
T(C)
200
L+
L +b b
TE
+ b
(Pb-Sn
System)
100
C, wt% Sn
0
hypoeutectic:
C0 = 50 wt% Sn
20
40
60
80
eutectic:
C0 = 61.9 wt% Sn
b
b
175 mm
100
hypereutectic:
(illustration only)
b
b b
b
160 mm
eutectic micro-constituent
36
37
Nonferrous Alloys
Cu Alloys
Al Alloys
Refractory metals
Noble
metals
vs 7.9 for steel
-Nb, Mo, W, Ta
-reactive at high Ts -Ag, Au, Pt
-oxid./corr. resistant
-space applic.
38
Ferrous alloys
Metal Alloys
Ferrous
Steels
Steels
<1.4wt%C
<1.4
wt% C
Nonferrous
Cast Irons
Cast
Irons
3-4.5 wt%C
3-4.5
wt% C
T(C)
1600
1400
1200
austenite
+L
4.30
1000
800
ferrite
600
400
0
(Fe)
L+Fe3C
1148C
727C
Eutectoid:
0.76
Eutectic:
+Fe3C
Fe3C
cementite
+Fe3C
3
Iron:
Commercial pure iron
contains less than 0.008
wt. % C
Steel:
Ferrous alloy
containing between
0.008 and 2.14 wt.% C
Cast Iron:
Ferrous alloys
containing between 2.14
and 6.7 wt.% C
6.7
Co , wt% C
39
1400
1200
+L
(austenite)
1148C
+Fe3C
1000
727C = Teutectoid
800
+Fe3C
600
400
0
(Fe)
Fe3C (cementite)
Ferrite, : BCC
Austenite, : FCC
d-Ferrite: BCC
Cementite, Fe3C
1600
6.7
C, wt% C
40
41
+ Fe3C
6.7 wt% C
0.76 wt% C
0.022 wt% C
T(C)
1600
1200
1000
L+Fe3C
1148C
+Fe3C
Equil. Cooling: Ttransf. = 727C
Eutectoid:
600
400
0
(Fe)
727C
DT
+Fe3C
Undercooling by Ttransf. < 727C
0.76
800
0.022
ferrite
+L
(austenite)
Fe C (cementite)
1400
6.7
C, wt%C
42
Classification of Steels
T(C)
1600
L
+L
(austenite)
+Fe3C
800
2.14
(Fe)
+ Fe3C
0.008
400
727C = T eutectoid
- Eutectoid (B):
600
L+Fe3C
1148C
1000
0.76
1200
Fe3C (cementite)
1400
+Fe3C
4
6.7
C, wt% C
43
moderate
cool
slow
cool
Pearlite
Bainite
( + elong. Fe3C particles)
( + Fe3C layers + a
proeutectoid phase)
Martensite
T Martensite
bainite
fine pearlite
coarse pearlite
spheroidite
General Trends
Martensite
(BCT phase
diffusionless
transformation)
reheat
Ductility
Strength
reheat
rapid
quench
Spheroidite
( + spherical
Fe3C particles)
Tempered
Martensite
( + very fine
Fe3C particles)
44
Ceramic Materials
45
AX Crystal Structures
ZnS
(zinc blende)
Coordination# = 4
NaCl
(Rock salt)
Coordination# = 6
CsCl
(cesium chloride)
Coordination# = 8
46
Fluorite structure
Perovskite structure
47
Silicate Ceramics
Si4+
O2-
Crystalline SiO2
Amorphous SiO2
Na +
Si 4+
O2 -
glass
48
Graphite
Graphene
Fullerene
Carbon nanotube
49
Frenkel
Defect
50
Mechanical Properties
Ceramic materials are more brittle than metals.
In highly ionic solids, dislocation motion is difficult
few slip systems
resistance to motion of ions of like charge (e.g.,
anions) past one another
Mechanical properties of ceramic are usually determined
using bending
Both the flexural strength and modulus of elasticity of
ceramic materials decrease with increasing volume fraction of
porosity
51
Polymers
52
Molecular characteristics
Chemistry
(repeat unit
composition)
Size
(molecular
weight)
Shape
Structure
(chain twisting,
entanglement)
Linear
Branched
Cross-linked
Network
Isomeric states
Geometrical
isomers
Stereoisomers
Isotactic
Syndiotactic
Atactic
Cis
Trans
53
Saturated hydrocarbons
H
Unsaturated hydrocarbons
H C C H
C C
Double bond
Triple bond
Polymerization
+
fr e e r a d ic a l
R C
R C
H H
mo n o me r
( e th y le n e )
in itia tio n
repeat
unit
R C
d ime r
p r o p a g a tio n
54
random
alternating
block
graft
55
56
Polymer Crystallinity
Polymers rarely 100%
crystalline
Semi crystalline
crystalline
region
rc > rs > ra
Chains are more closely
packed together in
crystalline polymer
amorphous
region
57
Diffusion in Polymers
Rates of diffusion are greater through amorphous regions
than through crystalline regions.
Rate of diffusion is influenced by:
a.Foreign molecule size the smaller the size, greater the
diffusion rate
b.Chemical property of the foreign molecule molecules that
are chemically inert with the polymer diffuse faster than those
that react with the polymer
58
Crystalline polymer
Amorphous polymer
59