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Thermally Stimulated Depolarization Currents in Tri-Ethyleneglycol Doped Poly (Methyl Acrylate) Film Electrets
Thermally Stimulated Depolarization Currents in Tri-Ethyleneglycol Doped Poly (Methyl Acrylate) Film Electrets
Thermally Stimulated Depolarization Currents in Tri-Ethyleneglycol Doped Poly (Methyl Acrylate) Film Electrets
1. INTRODUCTION
Polymer materials have long been
considered to be good insulators, because
their predominant covalent bonds exhibit
low electroconductivity. However, in the
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79
1.2E-12
TSD CURRENT(AMP)POSITIVE
5 MV/m
10MV/m
15 MV/m
1E-12
8E-13
6E-13
4E-13
2E-13
0
0
20
40
60
80
100
120
140
160
TEMPERATURE ( C)
Fig 1- Thermally Stimulated depolarization Current thermograms for doped PMA at constant polarising
temprature(Tp=40oC) with various polarizing fields (05,10 and 15 MV/m)
80
5.00E-07
Tp=40C
4.00E-07
Tp=60C
3.50E-07
Tp=80C
Tp=90C
3.00E-07
2.50E-07
2.00E-07
1.50E-07
1.00E-07
5.00E-08
0.00E+00
125
-5.00E-08
150
175
200
225
250
275
300
TEMPERATURE ( C)
-11.8
-12
-peak
-peak
log I (Amp)
TSD CURRENT(AMP)POSITIVE
4.50E-07
-12.2
-12.4
-12.6
-12.8
0
0.5
1.5
2.5
3.5
1/2
(Ep) (MV/m)
1/2
4.5
81
-11.65
-11.7
-peak
log I(Amp)
-11.75
-peak
-11.8
-11.85
-11.9
-11.95
-12
-12.05
-12.1
0
10
12
14
16
Ep (MV/m)
270
-peak
265
260
255
250
245
40
50
60
70
80
90
Poling Temprature(Tp) C
Fig 5: Poling temperature(Tp) versus maximum peak temperature(Tm) for doped PMA
100
82
0
-1
Ep=100kv/cm
-2
log (Siemens/cm)
-3
-4
-5
-6
-7
-8
-9
-10
2.4
2.5
2.6
2.7
3
10 /T
2.8
2.9
-1
(K )
Fig 6: Arrhenius plot(Temprature dependance of conductivity for doped poly methyl acrylate(PMA)
at given field
83
Fig 8: SEM images of doped Poly Methyl Acrylate (PMA) thin film
Wave Frequency
Fig. 9 : Infrared Spectroscopy of doped poly(methyl acrylate) (PMA) film.
Nano Vision, Vol.1, Issue 2, 30 June, 2011, Pages (54-100)
Fig 10: NMR Spectroscopy of doped Poly Methyl Acrylate (PMA) (Chemical shift in PPM)
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Table-1: Depolarization kinetic data for doped PMA samples at 40oC with various polarizing
fields. Sample thickness 25m for Al-Al System
Polarizing
Field
-peak
-peak
(Ep)
MV/m
Peak
Current
(Amp.)
Peak
Temp.
(oC)
05
5.1x10-13
50
10
1.09x10-12
15
6.5x10-13
Activation
Energy
(eV)
Relaxation
Time()
(sec)
Charge
Released
Coul.(Q)
Peak
Current
(Amp.)
Peak
Temp.
(oC)
Activation
Energy
(eV)
Relaxation
Time()
(sec)
Charge
Released
Coul.(Q)
0.234
2.8x105
8.6x10-9
9.2x10-13
140
0.563
8.7x106
7.4x10-8
50
0.233
1.6x106
6.6x10-8
1.07x10-12
120
0.524
2.7x107
6.8x10-7
50
0.232
6.2x105
7.8x10-8
8.3x10-13
120
0.509
4.9x106
5.9x10-7
Table-2: Depolarization kinetic data for doped PMA samples at a polarizing field 10MV/m
with various polarizing temperatures i.e. 40, 60, 80 & 90C respectively.
Sample thickness 25m for Al-Al System
Peak
temperature
Tm(C)
Activation
energy
E(eV)
Charge
released
Q(C)
Relaxation
time
(s)
Peak
current
Im
(A)
----245
-----0.596
-----4.5x10-9
-----2.1x104
-----3.16x10-7
60
205
255
0.290
0.581
1.6x10-9
3.3x10-8
1.8x104
5.1x104
6.6x10-8
3.96x10-7
10
80
---260
-----0.573
-----6.2x10-8
-----7.5x104
-----3.14x10-7
10
90
205
265
0.280
0.554
5.3x10-8
8.9x10-8
2.3x104
7.8x104
1.07x10-7
4.17x10-7
Polarizing field
Ep(MV/m)
Polarizing
temperature
Tp(C)
10
40
10
Peaks
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Table 3 : Electrical Parameter i.e Electrical Conductivity & Activation Energy of doped
PMA film atvarious temperatures & constant polarizing field Ep=10MV/m
Temperature
(oC)
Electrical Conductivity
()(Siemens/cm)
Activation Energy(Ea)
(ev)
341
1.95x10-9
0.64
343
7.08x10-9
0.59
347
2.56x10-8
0.52
355
6.26x10-8
0.49
371
1.37x10-7
0.46
403
2.85x10-7
0.42
407
3.03x10-7
0.37
REFERENCES
1. Pavan Khare & A.P. Srivastava, Indian J
Pure & Appl Phys, 29, 410 (1990).
2. H. C. Sinha & A. P. Srivastava, Indian J
Pure & Appl Phys, 17, 726 (1979).
3. A. R. Tiwari, S. K. Srivastava, K. K.
Saraf & A. P. Srivastava, Thin Solid
Films, 70, 191 (1980).
4. S. C. Chakraborty, N. B. Palit, S. K. Das
& S. Basu, Indian J Pure & Appl Phys,
29, 478 (1991).
5. Prashant Shukla & M. S. Gaur, Iranian
Polymer Journal, 17(3), 184 (2008).
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