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Chemistry Exemplar
Chemistry Exemplar
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CHEMIC
AL KINETICS
CHEMICAL
2.
(i)
(ii)
enthalpy of reaction.
(iii)
(iv)
equilibrium constant.
In the presence of a catalyst, the heat evolved or absorbed during the reaction
___________.
(i)
increases.
(ii)
decreases.
(iii)
remains unchanged.
(iv)
(ii)
(iii)
(iv)
using catalyst.
no
3.
4.
(ii)
Fig. 4.1
5.
(iii)
(iv)
pi
2.303
log
pi x
t
(ii)
k=
pi
2.303
log
t
2 pi pt
(iii)
k=
pi
2.303
log
t
2pi + pt
(iv)
k=
pi
2.303
log
pi + x
t
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(i)
6.
(ii)
no
(i)
(iii)
(iv)
48
1
?
T
7.
Consider the Arrhenius equation given below and mark the correct option.
k = A e Ea / RT
9.
(ii)
(iii)
(iv)
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8.
(i)
A graph of volume of hydrogen released vs time for the reaction between zinc
and dil.HCl is given in Fig. 4.2. On the basis of this mark the correct option.
V3 V2
40
(i)
(ii)
V3 V2
40 30
(iii)
V3
40
(iv)
V3 V1
40 20
Fig. 4.2
(ii)
(iii)
(iv)
10. Consider the graph given in Fig. 4.2. Which of the following options does not
show instantaneous rate of reaction at 40th second?
(i)
V5 V 2
50 30
V4 V 2
50 30
(iii)
V3 V2
40 30
(iv)
V3 V1
40 20
no
(ii)
49
Chemical Kinetics
(ii)
(iii)
(iv)
12. Which of the following expressions is correct for the rate of reaction given
below?
5Br (aq) + BrO3 (aq) + 6H (aq) 3Br2(aq) + 3H2O(l)
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(i)
[Br ]
[H+ ]
=5
t
t
(ii)
[Br ] 6 [H ]
=
t
5 t
(iii)
[Br ] 5 [H ]
=
t
6 t
(iv)
[Br ]
[H ]
=6
t
t
(a)
(b)
no
(c)
(i)
(a) only
(ii)
(b) only
(iii)
(c) only
(iv)
50
the same
(ii)
doubled
(iii)
quadrupled
(iv)
halved
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15. Which of the following statements is incorrect about the collison theory of
chemical reaction?
(i)
(ii)
(iii)
(iv)
16. A first order reaction is 50% completed in 1.26 1014 s. How much time
would it take for 100% completion?
(i)
1.26 1015 s
(ii)
2.52 1014 s
(iii)
2.52 1028 s
(iv)
infinite
Initial
concentration
of [B]/mol L1
Initial rate of
formation of
[C]/mol L1 s1
0.30
0.30
0.10
2.
0.30
0.60
0.40
3.
0.60
0.30
0.20
no
1.
(i)
(ii)
(iii)
(iv)
Chemical Kinetics
18. Which of the following statement is not correct for the catalyst?
(i)
(ii)
(iii)
(iv)
19. The value of rate constant of a pseudo first order reaction ____________.
depends on the concentration of reactants present in small amount.
(ii)
(iii)
(iv)
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(i)
20. Consider the reaction A B. The concentration of both the reactants and
the products varies exponentially with time. Which of the following figures
correctly describes the change in concentration of reactants and products
with time?
(ii)
(iii)
(iv)
no
(i)
52
(ii)
it is an elementary reaction.
(iii)
(iv)
(ii)
(iii)
(iv)
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(ii)
the order and the molecularity of slowest step are equal to one.
(iii)
(iv)
(ii)
(iii)
(iv)
(i)
(ii)
(iii)
(iv)
(ii)
(iii)
(iv)
no
(i)
(ii)
Chemical Kinetics
(iii)
(iv)
area under the curve must not change with increase in temperature.
(ii)
(iii)
(iv)
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29. Which of the following statements are in accordance with the Arrhenius
equation?
(i)
(ii)
(iii)
(iv)
(ii)
(iii)
(iv)
31. Which of the following graphs is correct for a zero order reaction?
(ii)
no
(i)
(iii)
(iv)
54
32. Which of the following graphs is correct for a first order reaction?
(ii)
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(i)
(iii)
(iv)
33. State a condition under which a bimolecular reaction is kinetically first order
reaction.
34. Write the rate equation for the reaction 2A + B C if the order of the reaction
is zero.
35. How can you determine the rate law of the following reaction?
2NO (g) + O2 (g) 2NO2 (g)
36. For which type of reactions, order and molecularity have the same value?
no
40. For a certain reaction large fraction of molecules has energy more than the
threshold energy, yet the rate of reaction is very slow. Why?
55
Chemical Kinetics
41. For a zero order reaction will the molecularity be equal to zero? Explain.
42. For a general reaction A B, plot of concentration of A vs time is given in
Fig. 4.3. Answer the following question on the basis of this graph.
(i) What is the order of the reaction?
(ii) What is the slope of the curve?
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Fig. 4.3
43. The reaction between H 2(g) and O2(g) is highly feasible yet allowing the gases
to stand at room temperature in the same vessel does not lead to the formation
of water. Explain.
44. Why does the rate of a reaction increase with rise in temperature?
45. Oxygen is available in plenty in air yet fuels do not burn by themselves at
room temperature. Explain.
46. Why is the probability of reaction with molecularity higher than three
very rare?
47. Why does the rate of any reaction generally decreases during the course of
the reaction?
48. Thermodynamic feasibility of the reaction alone cannot decide the rate of the
reaction. Explain with the help of one example.
no
49. Why in the redox titration of KMnO4 vs oxalic acid, we heat oxalic acid solution
before starting the titration?
50. Why cant molecularity of any reaction be equal to zero?
51. Why molecularity is applicable only for elementary reactions and order is
applicable for elementary as well as complex reactions?
52. Why can we not determine the order of a reaction by taking into consideration
the balanced chemical equation?
56
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Column I
(i)
(ii)
(a)
Ist order
(iii)
(b)
Zero order
no
(iv)
(i)
(ii)
Column II
(a)
(b)
Chemical Kinetics
(iii)
(iv)
e a
Energetically favourable reactions
(v)
E /R T
(d)
(e)
(f)
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(vi)
Column II
(i)
Diamond
(a)
(ii)
Instantaneous rate
(b)
(iii)
Average rate
(c)
Column II
(i)
(a)
rate constant
(ii)
(b)
rate law
(iii)
(c)
order of
slowest step
(iv)
(d)
rate of a reaction
no
(ii) Both assertion and reason are correct but reason does not explain
assertion.
58
57. Assertion
Reason
58. Assertion
Reason
59. Assertion
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Reason
60. Assertion
Reason
61. Assertion
Reason
62. All energetically effective collisions do not result in a chemical change. Explain
with the help of an example.
63. What happens to most probable kinetic energy and the energy of activation
with increase in temperature?
64. Describe how does the enthalpy of reaction remain unchanged when a catalyst
is used in the reaction.
65. Explain the difference between instantaneous rate of a reaction and average
rate of a reaction.
no
66. With the help of an example explain what is meant by pseudo first order
reaction.
59
Chemical Kinetics
ANSWERS
I. Multiple Choice Questions (Type-I)
1. (iii)
2. (iii)
3. (ii)
4. (i)
5. (ii)
6. (i)
7. (iv)
8. (iii)
9. (iii)
10. (ii)
11. (i)
12. (iii)
13. (i)
14. (ii)
15. (iii)
16. (iv)
17. (ii)
18. (ii)
19. (ii)
20. (ii)
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34.
35.
36.
37.
38.
[R] = [R]0 kt
t=
39.
[R ]0
k
no
40.
Apart from the energy considerations, the colliding molecules should also
have proper orientation for effective collision. This condition might not be
getting fulfilled in the reaction.
41.
60
43.
This is because activation energy for the reaction is very high at room
temperature.
44.
45.
46.
47.
48.
49.
The reaction between KMnO4 and oxalic acid is very slow. By raising the
temperature we can enhance the rate of reaction.
50.
51.
52.
Balanced chemical equation often leads to incorrect order or rate law. For
example the following reaction seems to be a tenth order reaction.
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42.
no
(i) (a)
(ii) (b)
(iii) (b)
(iv) (a)
54.
(i) (c)
(ii) (a)
(iii) (d)
(iv) (f)
(v) (b)
(vi) (e)
55.
(i) (b)
(ii) (a)
(iii) (c)
56.
(i) (b)
(ii) (a)
(iii) (d)
(iv) (d)
61
Chemical Kinetics
58. (v)
59. (i)
60. (v)
61. (iii)
63.
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66.
no
65.
62