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Ethanol Amines
Ethanol Amines
Ethanol Amines
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ETHANOLAMINES
Monoethanolamine
Diethanolamine
Triethanolamine
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CONTENTS
Introduction ...............................................................................................................................2
Ethanolamine Applications.........................................................................................................3
Gas Sweetening ..................................................................................................................3
Detergents, Specialty Cleaners, Personal Care Products.......................................................4
Textiles.................................................................................................................................4
Metalworking ......................................................................................................................5
Other Applications...............................................................................................................5
Ethanolamine Physical Properties ...............................................................................................6
Typical Physical Properties ....................................................................................................6
Vapor Pressure of Ethanolamines (Figure 1).........................................................................7
Heat of Vaporization of Ethanolamines (Figure 2)................................................................7
Specific Heats of Ethanolamines (Figure 3) ..........................................................................8
Comparative Hygroscopicities of Diethanolamine and Triethanolamine (Figure 4) ...............8
Weight Percent Ethanolamine in Aqueous Solutions vs Normality of Solution (Figure 5).....9
pH of Ethanolamine Solutions (Figure 6) .............................................................................9
Partial Pressure of Ethanolamines in Aqueous Solutions at Various Temperatures
(Figure 7, 9, 11) ........................................................................................................10-12
Vapor-Liquid Equilibria of Aqueous Solutions at 760 mm Hg Absolute
(Figure 8, 10, 12) ......................................................................................................10-12
Absolute Viscosities of Aqueous Solutions (Figures 13-15) ................................................13
Freezing Points of Aqueous Ethanolamine Solutions (Figure 16)........................................14
Specific Gravity of Aqueous Ethanolamine Solutions (Figure 17) .......................................14
Weight per Gallon of Aqueous Solutions at Various Temperatures (Figures 18-20)......15-16
Specific Heats of Aqueous Solutions (Figures 21-23) .........................................................17
Storage and Handling ..............................................................................................................18
Shipping Information ...............................................................................................................19
Specifications ...........................................................................................................................19
Product Safety..........................................................................................................................19
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ETHANOLAMINES
Dows versatile family of ethanolamines including monoethanolamine (MEA),
diethanolamine (DEA), and triethanolamine (TEA) offers a broad spectrum of application
opportunities. Triethanolamine is available as TEA, 99% and TEA, Commercial (which contains
nominally 15% diethanolamine). Because ethanolamines combine the properties of amines
and alcohols, they exhibit the unique capability of undergoing reactions common to both
groups. As amines, they are mildly alkaline and react with acids to form salts or soaps. As
alcohols, they are hygroscopic and can be esterified. The chemical structures of the
ethanolamines are:
MEA H NCH CH OH
DEA HN(CH CH OH)
TEA N(CH CH OH)
2
Monoethanolamine
Ethanolamines find uses in such diverse areas as gas sweetening, where they serve as lubricants and scouring agents; detergent and specialty cleaner formulations, in which they are
used to form various amine salts and to control pH; and in a host of other applications
including concrete admixtures, flexible urethane foam catalysts, pharmaceuticals, personal
care products, agricultural chemicals, photographic emulsions, and more.
Diethanolamine
Triethanolamine
TECHNOLOGY LEADERSHIP
Ethanolamines from Dow are backed by approximately 80 years of innovative scientific
research. Since their introduction in the late 1920s, MEA, DEA, and TEA have undergone
extensive commercial development in our laboratories at South Charleston, WV.
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Ethanolamine Applications
Typical Applications
MEA
Adhesives
Agricultural Chemicals
DEA
TEA,
Commercial
TEA, 99%
Gas Treating
Metalworking
Photographic Chemicals
Rubber
Textile Finishing
Urethane Foams
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Triethanolamine
H2NCH2CH2OH
61.08
HN(CH2CH2OH)2
105.14
N(CH2CH2OH)3
149.19
1.017
0.00080
1.092(a)
0.00065(b)
1.126(f)
0.00059
170.4
101
71
268(c)
182
150
335(c)
245(c)
205
<1
<0.01
<0.001
10.5 (50.9)
24.1
16.2
28.0 (82.4)
380
21.6 (70.9)(e)
921(f)
404
Solubility at 20C, % by wt
In Water
Water In
Complete
Complete
Complete(f)
Complete(f)
Complete(f)
Complete
0.6
0.1
0.7
0.1
Complete
Complete(f)
0.03
0.01
0.5
0.03
Complete(f)
Complete
2
Complete
2
<0.03
Complete
48.3(d)
1.4539
0.00034
48.5(g)
1.4747(g)
0.00027(b)
48.9(d)
1.4852(f)
0.00020
96 (205)(h)
191 (375)(h)
208 (407)(h)
(a) At 30/20C
(b) At 35 to 65C
(c) Extrapolated (decomposes)
(d) At 25C
NOTE
This table sets forth typical properties of Monoethanolamine, Diethanolamine, and
Triethanolamine based upon analysis(ses) of commercial product or purified sample, etc.;
however, Dow does not analyze each shipment of product for all of these properties. Dow
warrants only that, at the time of delivery, product will conform to Dows standard specifications as then in effect.
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Figure 1
Vapor Pressure of Ethanolamines
Temperature, F
70
1000
600
400
90
120
160
200
240
320
400
480
800
500
300
Vapor Pressure, mm Hg
200
100
60
40
80
50
30
20
MEA
10
6
4
DEA
TEA
8
5
3
2
1
20
40
60
80
120
Temperature, C
160
200
240
Figure 2
Heat of Vaporization of Ethanolamines
Temperature, F
150
250
350
450
550
650
440
410
MEA
380
350
320
DEA
290
260
TEA
230
200
50
100
150
200
250
Temperature, C
300
350
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Figure 3
Specific Heat of Ethanolamines
40
80
Temperature, F
120 160 200 240 280 320 360
0.84
0.82
0.80
0.78
Specific Heat, Cal/g-C
0.76
MEA
0.74
DEA
0.72
0.70
TEA
0.68
0.66
0.64
0.62
0.60
0.58
0.56
0.54
0
20
40
60
Figure 4
Comparative Hygroscopicities of Diethanolamine and Triethanolamine from 75 to 80F
100
80
60
DEA
40
TEA
20
10
8
6
4
1
10
20
30
40
50
60
Relative Humidity, %
70
80
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Figure 5
Weight Percent Ethanolamine in Aqueous Solutions vs Normality of Solution
70
TEA
DEA
60
MEA
50
40
30
20
10
0
0
6
9
12
Normality of Amine Solution
15
Figure 6
pH of Ethanolamine Solutions
40
20
TEA, 99%
10
TEA,
Commercial
4
2
1
DEA
MEA
.4
.2
.1
.04
.02
.01
8
10
11
pH at 20C
12
13
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Figure 7
Partial Pressure of Monoethanolamine in Aqueous Solutions at Various Temperatures
Temperature, F
40
10
60
80
100
120
MEA
% by wt
100
95
90
80
60
40
30
20
0.1
0.01
10
5
10 -3
10 -4
0
10
20
30
Temperature, C
40
50
Figure 8
Vapor-Liquid Equilibria (T-x-y) of Aqueous Monoethanolamine Solutions at 760 mm Hg Absolute
180
170
340
160
320
300
140
280
130
260
120
240
110
220
100
Liquid Phase
90
180
80
0
10
200
10
20 30 40 50 60 70 80 90 100
Monoethanolamine, Percent by Weight
Temperature, F
Temperature, C
Vapor Phase
150
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Figure 9
Partial Pressure of Diethanolamine in Aqueous Solutions at Various Temperatures
Temperature, F
60
80
0.1
100
120
140
DEA
% by wt
0.01
100
95
10-3
80
60
40
10-4
20
10
10
-5
10-6
15 20 25
30 35 40 45 50 55
Temperature, C
60 65
70
Figure 10
Vapor-Liquid Equilibria (T-x-y) of Aqueous Diethanolamine Solutions at 760 mm Hg Absolute
275
495
Vapor Phase
235
455
215
415
195
375
175
335
155
295
135
255
115
Note: Ethanolamines can
undergo decomposition
at temperatures above
approximately 200C
Liquid Phase
215
95
175
75
0
11
10
20 30 40 50 60 70 80 90 100
Diethanolamine, Percent by Weight
Temperature, F
Temperature, C
255
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Figure 11
Partial Pressure of Triethanolamine in Aqueous Solutions at Various Temperatures
Temperature, F
120
140
0.1
160
180
200
TEA
% by wt
0.01
100
95
1 0 -3
80
60
1 0 -4
40
10
20
10
-5
5
1 0 -6
1 0 -7
45 50 55 60
65 70 75 80 85
Temperature, C
90 95 100
Figure 12
Vapor-Liquid Equilibria (T-x-y) of Aqueous Triethanolamine Solutions at 760 mm Hg Absolute
380
360
680
340
640
320
600
560
Vapor Phase
280
520
260
480
240
440
220
200
400
180
360
160
320
140
280
120
240
100
Liquid Phase
80
0
12
10
20 30 40 50 60 70 80 90 100
Triethanolamine, Percent by Weight
200
Temperature, F
Temperature, C
300
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Figure 13
1 30C (86F)
2 50C (122F)
3 75C (167F)
4 100C (212F)
100
60
40
20
10
6
4
2
1
0.6
0.4
0.2
0.1
1
2
3
4
0 10 20 30 40 50 60 70 80 90 100
Monoethanolamine, Percent by Weight
Figure 14
1 30C (86F)
2 50C (122F)
3 75C (167F)
4 100C (212F)
1000
400
200
100
40
20
10
4
2
1
0.4
0.2
0.1
1
2
3
4
10 20 30 40 50 60 70 80 90 100
Diethanolamine, Percent by Weight
Figure 15
1 30C (86F)
2 50C (122F)
3 75C (167F)
4 100C (212F)
1000
400
200
100
40
20
10
4
2
1
0.4
0.2
0.1
1
2
3
4
0 10 20 30 40 50 60 70 80 90 100
Triethanolamine, Percent by Weight
13
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Figure 16
Freezing Points of Aqueous Ethanolamine Solutions
140
60
120
40
100
20
Diethanolamine
60
40
20
0
-20
-20
Note: Freezing point data
for 70% to 90%
Diethanolamine in water are
extrapolated
-40
-40
-60
Monoethanolamine
-60
0
20
40
60
80
Ethanolamine, Percent by Weight
100
Figure 17
Specific Gravity of Aqueous Ethanolamine Solutions at 20/20C
1.13
1.12
1.11
Triethanolamine
1.10
1.09
Freezing
Point
1.08
1.07
1.06
Diethanolamine
1.05
1.04
1.03
Monoethanolamine
1.02
1.01
1.00
0
14
10
20 30 40 50 60 70 80
Ethanolamine, Percent by Weight
90 100
Freezing Point, F
Freezing Point, C
80
Triethanolamine
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Figure 18
Weight per Gallon of Aqueous Monoethanolamine Solutions at Various Temperatures
9.2
Freezing Point Curve
9.0
0F
8.8
30F
60F
8.6
90F
120F
8.4
150F
180F
8.2
210F
8.0
7.8
0
20
40
60
80
Monoethanolamine, Percent by Weight
100
Figure 19
Weight per Gallon of Aqueous Diethanolamine Solutions at Various Temperatures
9.4
9.2
30F
60F
90F
0 F
9.0
Pounds per Gallon
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120F
150F
8.8
180F
210F
8.6
240F
8.4
Boiling Point
8.2
8.0
0
15
20
40
60
80
Diethanolamine, Percent by Weight
100
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Figure 20
Weight per Gallon of Aqueous Triethanolamine Solutions at Various Temperatures
9.6
9.4
30F
60F
90F
120F
150F
180F
210F
240F
0F
9.2
Pounds per Gallon
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9.0
8.8
8.6
8.4
Boiling Point
8.2
8.0
7.8
0
16
20
40
60
80
Triethanolamine, Percent by Weight
100
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Figure 21
Specific Heats of Aqueous Monoethanolamine Solutions Temperature, F
40
1.1
80
120
160
200
240
Cal/g-C
MEA % by Wt
1.0
0.9
25
0.8
50
75
0.7
100
0.6
0
20
40
60
80
Temperature, C
100
120
Figure 22
Specific Heats of Aqueous Diethanolamine Solutions
1.1
40
Temperature, F
120
160
200
240
DEA % by Wt
1.0
Cal/g-C
80
0.9
25
0.8
50
0.7
75
100
0.6
0
20
40
60
80
Temperature, C
100
120
Figure 23
Specific Heats of Aqueous Triethanolamine Solutions
1.1
40
Temperature, F
120
160
200
240
TEA % by Wt
1.0
Cal/g-C
80
0
0.9
25
0.8
50
0.7
75
0.6
100
0.5
0
17
20
40
60
80
Temperature, C
100
120
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STORAGE TEMPERATURES
Ethanolamines require heated and insulated storage and transfer facilities. Ethanolamines
darken, however, at temperatures above 140F (60C).
Storage
Temperature, F
Approximate
Viscosity, cP,
30C (86F)
Monoethanolamine
10.5 (50.9)
65-95
15
Diethanolamine
28.0 (82.4)
95-120
380
Triethanolamine, Commercial
15.8 (60.4)
75-110
400
Triethanolamine, 99%
21.6 (70.9)
85-110
400
18
(a)
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Shipping Information
For your convenience in ordering, Dow markets ethanolamines both direct and through an
effective network of distributors. Less than full tank car or tank truck quantities can be
delivered most rapidly through a Dow distributor. Consult your Dow representative for the
name of the distributor nearest you.
For delivery of large volume orders, ethanolamines are stocked in terminals throughout the
world.
Triethanolamine, Triethanolamine,
Commercial
99%
8.47
1.015
9.10 (30C)
1.088 (30C)
9.37
1.123
9.38
1.124
Coefficient of Expansion
at 55C, per C
0.00081
0.00060
0.00049
0.00053
96 (205)
191 (375)
194 (382)
208 (407)
(a) Determined by ASTM Method D 93, using the Pensky-Martens Closed Cup
Specifications
Specifications for DOW Ethanolamines are available on request from your Dow sales
representative.
Product Safety
When considering the use of any Dow products in a particular application, you should
review Dows latest Material Safety Data Sheets and ensure that the use you intend can be
accomplished safely. For Material Safety Data Sheets and other product safety information,
please contact us using the numbers on the back cover of this brochure. Before handling
any other products mentioned in the text, you should obtain available product safety information and take necessary steps to ensure safety of use.
No chemical should be used as or in a food, drug, medical device, or cosmetic, until the
user has determined the suitability and legality of the use. Since government regulations
and use conditions are subject to change, it is the users responsibility to determine that this
information is appropriate and suitable under current, applicable laws and regulations.
Dow requests that the customer read, understand, and comply with the information
contained in this publication and the current Material Safety Data Sheet(s). The customer
should furnish the information in this publication to its employees, contractors, and
customers, or any other users of the product(s), and request that they do the same.
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NOTICE: No freedom from any patent owned by Seller or others is to be inferred. Because use conditions and applicable laws may differ from one location to
another and may change with time, Customer is responsible for determining whether products and the information in this document are appropriate for
Customers use and for ensuring that Customers workplace and disposal practices are in compliance with applicable laws and other governmental enactment.
Seller assumes no obligation or liability for the information in this document. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED.
Published January 2003
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