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Investigation On Pre Weakening and Crushing of Phosphate Ore Using High Voltage Electric Pulses 2014 Advanced Powder Technology
Investigation On Pre Weakening and Crushing of Phosphate Ore Using High Voltage Electric Pulses 2014 Advanced Powder Technology
a r t i c l e
i n f o
Article history:
Received 19 October 2013
Received in revised form 12 April 2014
Accepted 10 June 2014
Available online 30 June 2014
Keywords:
High voltage electric pulse crusher
Comminution
Phosphate ore
Energy efciency
a b s t r a c t
Mechanical size reduction processes in the mineral processing industry are energy intensive. In this
study, a novel High Voltage Electric Pulses Crusher (HVEPC) was designed and developed to pre-weaken
and crush a phosphate ore. To compare the effectiveness of the new HVEPC in crushing with the conventional crushers, several rock samples of a phosphate ore were used and the effect of the capacitor, the
voltage level and voltage rise time on the phosphate ore breakage was investigated. Comparing the
particle size distribution of the crushed samples using both the HVEPC and the conventional crushers
revealed the difference between their breakage mechanisms. The nal results showed that applying
the high voltage pulses at specic energy of 35 kWh/t could signicantly increase and extend the cracks
and microcrakcs inside the rocks and consequently lead to decline in the Bond crushability and Abrasion
indices of the crushed samples by 10.6% and 28.1%, respectively.
2014 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder
Technology Japan. All rights reserved.
1. Introduction
Comminution, particularly in ner sizes to achieve the required
degree of liberation or specic surface, is a critical unit operation in
terms of energy consumption and process optimization. Several
research have shown that the specic energy consumption in
comminution varies from a few kWh/t for crushing to 1060 kWh/t
for AG/SAG and ball milling, and over 100 kWh/t for ultra-ne
grinding [1]. Sustainable development and use of new raw materials require new, better and more efcient processes. Accordingly,
in the eld of comminution, it is important to consider new
methods based on lower energy consumption and higher degree
of liberation. Studies have shown that conventional mechanical
comminution methods are largely based on application of
compressive force, resulting in high energy dissipation and slime
production. It is known that developing the tensile force based
methods could signicantly decrease the slime production while
reducing energy consumption. Therefore, several novel comminution methods such as High Pressure Grinding Roller (HPGR) [2],
microwaves treatment [3,4], Electro Hydraulic Disintegration
(EHD) [5] and Electrodynamic Disintegration (ED) [6] have recently
been studied and presented.
http://dx.doi.org/10.1016/j.apt.2014.06.010
0921-8831/ 2014 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.
consumption optimization was in JKMRC (Julius Kruttschnitt Mineral Research Center) [1,2426]. The activities of JKMRC have been
conducted in two major areas using high voltage pulses: particle
pre-weakening and mineral liberation which both focused on
improving energy efciency. These studies showed that the ores
treated by high voltage electric pulses with low specic energy
input (a few kWh/t) developed cracks and microcracks in the rock,
and became weaker than untreated particles. Comparison of Bond
work indices showed that the electrical treatment can reduce the
energy consumption in downstream grinding processes by up to
24%. Moreover, research conducted in JKMRC showed that higher
mineral liberation can be achieved in the electrical comminution
[1]. In other words, lower consumption of energy in the electrical
method can result in proper liberated minerals. Wang et al. [24]
studied the factors affecting the electrical grinding for six ores. In
this study, parameters such as feed particle size, undersize
aperture, failure potential and energy input were considered. In
addition, numerical simulations were used to show the distribution and intensity of the electric eld around and within the particles. Accordingly, the electrical comminution is strongly dependent
on the electrical characteristics of the ore. Dal Martello et al. [27]
investigated the effect of the electrical comminution in reducing
impurities in quartz ore to produce silicon for solar cells application. Comparing the magnetic separation efciency of the samples
produced by the mechanical and electrical methods showed a
signicant decrease in iron impurities content of the samples
crushed using the electrical methods.
Dodbiba et al. [28] used both mechanical and electrical comminution for recovery of indium from LCD screens disposed of by
leaching, and reported the results. They concluded that sample
preparation using electrical comminution was more efcient and
environmentally friendly than mechanical comminution.
In this paper, the effect of high voltage electrical pulses on phosphate ore comminution is presented. Phosphate ore was chosen
because its comminution inherently produces a high level of slime
which disrupts the downstream processes and reduces the quality
of the nal product. In this study, a high voltage electrical pulses
unit was designed, developed and tested to investigate the effect
of the instrumental parameters on failure and comminution of
phosphate ore and compare the results with the mechanical
comminution (crushing and grinding).
2. Materials and methods
2.1. Materials tested
The sample used in this study was obtained from the Esfordi
phosphate mining complex located in Bafgh, Iran. About 400 tons
of a representative sample from different zones of the mine were
collected and crushed in the crushing plant. The samples were then
further homogenized in the blending room and approximately 100
tons were sent to IMPRC for the laboratory and pilot scale tests.
The particle size distribution of this sample showed that 80% of
particles were smaller than 9.6 mm, 25% were ner than 150 lm
which is the acceptable size for the downstream process and
11.5% were ner than 38 lm.
Mineralogical studies were done on the thin-smooth polished
sections prepared from the main sample and analyzed using a
polarizing optical Zeiss Axioplan 2 microscope with light reection
and transmission. These studies showed that the major minerals
present in the sample are apatite, hematite and quartz. Hematite
is mostly inter-locked by contact and in some cases as 0.1
0.01 mm inclusions in other minerals. Apatite is interlocked with
hematite, calcite and quartz mainly of double type and less frequently triple type which decreased with particle size. The result
of the XRF analysis done on the sample using Fillips Magic_pro
instrument is given in Table 1.
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Table 1
Chemical analysis of phosphate ore sample.
Composition
Fe2O3
P2O5
SiO2
CaO
MgO
Al2O3
K2O
SO3
Cl
Y2 O3
L.O.I
Mass (%)
42.50
15.74
14.27
19.60
3.97
1.01
0.17
0.15
0.11
0.08
2.40
Table 2
Empirical equations correcting with Ai to estimate rod, ball and mill liner wear.
Rod mill
Wet
Ball mill
Wet
Dry
before the spark gap which had a direct relation with the discharge
pulse. The capacitor was slowly charged from a DC source until the
spark gap broke down. This spark gap acted as a voltage-limiting
and voltage-sensitive switch of which its ignition time (time to
voltage breakdown) was very short.
The second part of the HVEPC, indicated as EPC in Fig. 1, was
the crushing chamber consisting of a rod-shaped copper electrode. In addition, the electrical disintegration system had also a
current transformer and a coil type amperemeter that was connected to the oscilloscope and a computer. The voltage between
the generator and ground electrode made of a steel plate was
measured by a probe connected to the oscilloscope. The ground
electrode consisted of circular apertures to pass the crushed
particles and prevent over-crushing. The sample was immersed
in the water in the chamber between two electrodes and then a
high-voltage pulse was directly discharged to disintegrate the
sample.
The third part was related to the safety accessories. Considering
the safety issues in all cases of using high voltage power supplies
was a crucial part of this study to design and install the necessary
safety equipment.
The energy of discharged electrical pulse was calculated by
Eq. (2):
E 1=2CV max 2
Fig. 1. High voltage pulse electric crushers schematic diagram and circuit.
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No. of pulses
Capacitor (nF)
Voltage (kV)
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
6000
2667
1500
960
667
4500
2000
1125
720
500
3600
1600
900
576
400
750
480
334
30
30
30
30
30
40
40
40
40
40
50
50
50
50
50
60
60
60
20
30
40
50
60
20
30
40
50
60
20
30
40
50
60
40
50
60
6
13.5
24
37.5
54
8
18
32
50
72
10
22.5
40
62.5
90
48
75
108
0.008
0.019
0.033
0.052
0.075
0.011
0.025
0.044
0.069
0.100
0.014
0.031
0.056
0.087
0.125
0.067
0.104
0.150
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.100
Fig. 3. Effect of specic energy of the pulse in J/cm on 3 fractions of 12.519, 6.35
12.5 and 3.356.35 mm phosphate ore crushing.
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Fig. 4. Relationship between the minimum specic energy of pulse and particle size
of phosphate ore.
Fig. 6. Average particle size distribution of jaw crushing (JC) and HVEPC in 2 forms:
cumulative passing and retained on sieve (normal).
Fig. 5. Waveshapes of discharge voltage in two conditions: C:40 nF, V:20 kV and C:10 nF, V:40 kV.
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Non-treatment
3 kWh/t
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
3.07
5.32
5.67
5.86
6.23
6.35
6.56
6.66
6.75
7.16
7.68
7.72
8.05
8.23
8.60
10.90
14.73
15.23
18.75
20.78
2.67
5.25
5.58
5.66
5.72
5.78
6.10
6.29
6.82
6.98
7.08
7.36
7.51
8.26
9.17
10.71
12.52
15.07
16.23
16.46
2.18
4.52
5.27
5.28
5.64
5.77
5.84
6.20
6.29
6.40
6.91
7.05
7.29
7.74
8.88
11.08
14.12
14.98
15.21
16.65
9.02
0
8.32
7.8
8.06
10.6
Average
Relative difference (%)
5 kWh/t
Table 5
Wear rate (kg/kW-h) of rod, ball and mill liner by phosphate ore prepared by conventional mechanical comminution and electrical comminution.
RodMill
Wear rate (kg/kW-h)
Rod
Mech. comminution
HVEPC comminution
0.1135
0.1054
7.1574
Ballmill (wet)
Liner
Ball
Ballmill (dry)
Liner
Ball
Liner
0.0097
0.0087
0.0905
0.0801
0.0072
0.0064
0.0104
0.0089
0.0010
0.0009
10.2265
11.5086
10.2265
15.1483
15.1483
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