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An Improved Thermocouple Measurement
An Improved Thermocouple Measurement
27
When we use an electrically compensated thermocouple for its frequency response to measure temperatures in
turbulent flames, considerable errors occur due to the temperature- and velocity-dependences of time constant of
response, as well as surface reactions and radiative heat losses. An improved method of reproducing the patterns of
temperature fluctuation was developed, in which a thermocouple was coated to be free from the effects of surface
reactions and its unlinearized output was subjected to the thermal inertia compensation; then the compensated signals
were converted into temperatures following the modified EMF characteristics of the thermocouple. The accuracy was
examined in both a laminar diffusion flame and a turbulent premixed flame.
1. INTRODUCTION
Many researchers have been paying attention to
the measurement of temperature fluctuation in
turbulent reacting flows as a source of information
on the phenomenon. Progress in optical diagnostics has been remarkable in recent years in that
nondisruptive optical techniques, such as Raman
scattering, Rayleigh scattering, and CARS, have
been developed for the purpose. However, their
application is restricted yet to special fields of
research because most of them require a good deal
of experience and are expensive.
The technique of electrical compensation for the
delay of thermocouple response was first developed by Shepard and Warshawsky [1] in 1952.
Since then, it has been used by many investigators
and researchers because of its convenient applicability [e.g., 2-6]. However, a number of questions
have been raised concerning the validity of the
technique. Is the compensated thermocouple technique perfect? As an example, a typical bimodal
probability density function (PDF) of temperature
fluctuations slightly on the burned side in a flame
zone obtained by the technique often suggests that
the temperature of the unburned mixture, corresCopyright 1987 by The Combustion Institute
Published by Elsevier Science Publishing Co., Inc.
52 Vanderbilt Avenue, New York, NY 10017
0010-2180/87/$03.50
28
rc =
l + rc --~
Tj,
(2)
where Tc is the compensated temperature. Assuming that both rj and rc are constant, Laplace
transformation of Eqs. (1) and (2) yields the
following relation:
1 +rS
~[Tc]- - o~ [ Tg].
l+rjS
(3)
rg.
According to Ref. [10], rj is a function of the
temperature, Tf, of the gas layer surrounding the
hot junction defined by the following equation:
T f = ( T g + Tj)/2.
(4)
drj
rj --~- = T g - Tj,
a'
~~
(1)
[es')
ebe~
ej
e,;(e~ e,
e mY
drj de
- T g - Tj.
rJdedt
(5)
[Minicomputer~A/D Converter[
(a) Measuring system A
29
(6)
1500
(7)
1 + Tj,1500/7"j. 0
Tj comes to 750"C for rj,15oo/rj,o = I. Practically,
however, Tj is always higher than 750"C because
30
the ratio, rj.~500/rj.0, is smaller than unity. In other
words, Tj is more likely to indicate the higher
temperature than the time averaged temperature,
Tg, of gases. Irrespective of the wave pattern or
the frequency of the fluctuation of Tg, Tj becomes
higher than Tgg as long as re is held constant.
~ Thermocouple /"
I Vibrator LJF'
< ~.~__~"
II
'
Air Fuel
3. E X P E R I M E N T A L P R O C E D U R E
~ ~ / ~
Unit: mn
00 /\
31
300
O Without coating
With coating
~ I000
200
500
o o
100
O00 ~ ' ~
0A~-I? ~Air0Fuel> 2
I
x mm
5OO
oG
500
1000
Tf
1400
16
t
24
32
ms
32
21
~
0 ~
10
20
30
40
50
60
70
t
ms
c o a t i n g (r,= 9 6 m s )
(a)Without
2ooo[
06
0.4
4OO
800
T+
0 |
1200
I
I
10
20
(b)With
30
40
50
60
70
t
ms
coating('%=118 m s )
~/With
Coating
o2
-400
400
MEASUREMENT OF F L U C T U A T I N G TEMPERATURES
this case because the local gaseous composition is
controlled by molecular diffusion processes and
almost equilibrated. This will be discussed later.
In order to confirm the above interpretations we
predicted the compensated wave patterns of Tc by
numerical simulations. The predicted wave patterns in Fig. 10 exhibit the same discrepancy
between bottom temperatures for the coated and
uncoated cases, as seen between Figs. 8 and 9,
even though surface reactions are neglected in the
simulation. Time constants of frequency response
of the hot junction, rj, exposed to the prescribed
temperature fluctuations in Fig. 5 were obtained
from the solid curve in Fig. 6, and the compensating time constant, re, was assumed to be constant
in the calculation of Eqs. (1) and (2). Although we
cannot estimate the exact values of radiative heat
transfer, the approximate increase in radiative heat
loss due to coating can be evaluated from experiments or the literature, referred to in section 4.2.
The decrease in Tj by radiative heat loss is
assumed to be zero for the uncoated junction and
60C for the coated one, respectively, in the
present simulation, because the emissivity of silica
is larger than that of platinum. The assumed values
of 7c to make the peaks of Tg and Tj coincide are
given in Fig. 10. As long as the normalized time
constants of frequency response have the same
temperature dependence, the absolute value of rj
does not affect the results of simulations, as
described in section 4.1. In the present simulation,
therefore, the values of rj for the uncoated junction
were used throughout. That is the reason why the
difference in rc values for both cases is slightly
smaller than that in Fig. 8.
From these facts we can conclude that the
observed difference in bottom temperature of
fluctuations in Figs. 8 and 9 has almost nothing to
33
06-'b
2'o ~'o~'o
t
"o ~'o-'-7o
ms
2000r
I Without coating(~=lO5ms)
I000
16
ms
24
32
re "C
34
2000 -- -1500
t~
~3
0 2
-400
(b)
400
(a)
300
2000
600
15O0
(~)s~t~ A w~tt~t~t~rq
,_1000
400.~ "~I000
5OO
o,,
00
10
r rnm
500
O~
L
5
I0
~00
2O0
I~50
r mm
-- Ideal bimodal P O F
(a)System A wilhout coating
(c)S~tem B with coating
0.~
)
i i
i i t i i
0.5
ff-TL)/(T. -TO
i i
nnnl
I
I
I
- vv~0
20
40
60
80
t ms
(a) System A without Coating (T~=10 ms)
20001
- 100001
20
40
60
80
t ms
(b)System A with Coating (~ =13ms)
2000/
_ooo! 2'0
t ms
()System 8 with Coating ('~=14ms)
Fig. 16. Fluctuating wave forms of compensated temperatures
in a turbulent flame obtained by three combinations of coating
and compensating systems.
35
5. C O N C L U S I O N S
The causes of error in temperature measurements
by a fine thermocouple were discussed. A simple
improved technique for measuring fluctuating
temperatures has been proposed to minimize the
influences of surface reaction, radiative heat transfer, and temperature dependence of time constants
of frequency response. Applying the technique to
both laminar and turbulent flames, the accuracy of
the method was discussed and the following
conclusions have been obtained:
1. Time constants of frequency response of a
thermocouple decrease with the increase in gas
film temperature surrounding the hot junction.
2. The time averaged temperature of the hot
junction is considerably higher than that of
gases due to the temperature dependence of
time constants of the thermocouple.
3. The inappropriate compensation at low temperatures can be eliminated by the proposed
compensation technique, in which the compensation is applied directly to the output signal of
a thermocouple prior to the voltage-temperature conversion according to the modified EMF
curve.
4. Catalysis-proof coatings enlarge the time constants of frequency response due to the increase
in thermal resistance. However, the temperature dependence of the time constants remains
the same as that for an uncoated one. This
indicates that the temperature fluctuations of
gases can be reproduced, without being affected by coating, by adopting larger time
constants in compensation.
5. The increased radiative heat transfer caused by
the coating reduces the mean temperature of
the hot junction, which cancels the influence of
temperature dependence of time constants and
results in the improvement of compensation at
low temperatures.
6. By combining the effects of (3) and (5), the
influences of catalysis and radiative heat losses
are eliminated; hence fluctuating temperatures
can be properly compensated over the whole
temperature range.
7. Catalysis is negligible in laminar diffusion
flames. In turbulent premixed flames, how-
36
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
REFERENCES
1.
2.
3.
14.
15.