Combined Sol. Major-2 AITS XII 4-01-2015

CAREER POINT
TS XIV MJ XII -2
TARGET - AIEEE (JEE-Mains)

(ENGINEERING ENTRANCE EXAMINATION)
MAJOR TEST # 2
PHYSICS, CHEMISTRY, MATHEMATICS

Hints & Solutions
PHYSICS
Ques.
10
11
12
13
14
15
Ans.
Ques.
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Ans.
CHEMISTRY
Ques.
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
Ans.
Ques.
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
Ans
MATHEMATICS
Ques.
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
Ans.
Ques.
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
Ans.
PHYSICS
1.[3]
1 + 2 = kl1
21
MR 2
5
1 2 = kl2
1 + 2
l
= 1
1 2
l2
2.[3]
3.[4]
4.[1]
Ni
25 + 26
B= 0 ,r=
2r
2
2R
5.[4]
1
T
2
2
I = I1 + I2 = 2 M R + 2 M R + M (2R ) 2
5 2 5 2
CAREER POINT, CPTower,IPIA,RoadNo.1,Kota(Raj.),Ph:07443040000
Wein's law
mT = b
T=
6
b
= 2892 10 6
m
14.46 10
= 200 K
6.[3]
v
=
7.[3]
Since the ray is totally internally reflected.
v=
c = 5km/s
1
g ( t1 + t 2 + t 3 ) 2
2
for AD, 3h =
t1 : (t1 + t2) : (t1 + t2 + t3) = 1 :
2 :
Thus, t1 : t2 : t3 : : 1 : ( 2 1) : ( 3 2 )
So, 45 > ic
sin 45 > sin ic
1
>
>
8.[2]
15.[2]
16m
4m
V
Point 1, 6 and 8 are same potential similarly

points 2, 4 & 7 are also at same potential
v = eu
A
...(1)
u=
2g16
...(2)
v=
2g 4
...(3)
Circuit can be redrawn as.
e=
3
(1, 6, 8)
2, 4, 7
16.[3]
9.[4]
(VL VC ) 2 + VR2
(30 15) 2 + 20 2 =
Gauss theorem
11.[2]
I = I0et/
12.[1]
Significant figures of volume match with that

of given length.
13.[1]
Fundamental frequency
v
=
4l
19.[1]
N0 = Initial no. of active nuclei

after one mean life no. of nuclei remains =
N0
e
N /e
1
=
Probability of survival = 0
e
N0
225 + 400 = 25 volt
10.[2]
7
= 1.4
5
18.[3]
VR = 20 V
VL = 30 V
VC = 15 V
Vsupply =
2g 4
1
=
2g 16
2
5D
7D
=
d
d
=
R
R
R
5R
RAB =
+
+
3
3
6
6
v
=
u
20.[2]
Let t1, t2 and t3 be the times to cover AB, BC

and CD
1
for AB, h = gt12
2
1
for AC, 2h = g ( t1 + t 2 ) 2
2
X200 A110 + B90 + Energy

7.4 MeV 8.2 MeV 8.2 MeV
B.E.
per
nucleon
Q = (B.E.product B.Ereactant)
Q = (110 8.2 + 90 8.2 200 7.4)
Q = 160 MeV
21.[3]
Diffusion of holes from P side to N side is

found from high concentration to low
concentration.
22.[1]
f=
V
4(0.1 + e)
...(1)
f=
3V
4(0.35 + e)
...(2)
28.[2]
GM 2
a
W = Uf = Ui
U=3
3GM 2
3GM 2
2a
a
3GM 2
2a
e = 0.025
IA
1.4 103 1 m 2
=
= 4.7 106 N
8
c
3 10
5
5
, Cp = R
3
2
29.[2]
F=
Q = nCpT
W = nRT
R
2
.Q=
Q
W=
5
Cp
30.[2]
EP > Ee
24.[1]
No work done in free expansion

W = 0, Q = 0
U = 0
31.[4]
In B2H6 four B-H bonds are normal 2c-2e

bonds the two bridge H-atoms are held by
3c-2e bonds.
25.[2]
Longitudinal strain
32.[3]
4KO2 + 2CO2 2K2CO3 + 3O2

4KO2 + 4CO2+ H2O 4KHCO3+ 3O2
33.[2]
The percentage of carbon is least in wrought

iron.
34.[4]
The reactivity of alkyl halides in SN1 reaction

follow the order : 1 < 2 < 3. Polar protic
solvent increase rate of SN1 reaction.
23.[3]
CHEMISTRY
l stress 10 6
= 105
=
=
L
Y
1011
Percentage increase in length = 105 100

= 0.001 %.
26.[1]
amax = 2A
1
= 4 (3600)
100
2
= 1442 m/s2
35.[2]
27.[1]
O+
+
T'
H
+ CH3OH
CH3
T
HOCH2COCH3
CH3
T'T5g = 5a
T2g = 2a
given T = 30N
so a = 5m/s2
T' = 105 N
.......(1)
36.[2]
Position 4 is the best one because it is para to

stronger activating group OH at this position
the I effect of OH is minimum.
37.[3]
Cannizaro's reaction.
38.[4]
Soaps are sodium salts of long chain fatty

carboxylic-acids.
For example sodium-oleate C17H33COONa+
soaps form micelle in which there is one
hydrophobic part and another is hydrophillic
part.
48.[4]
r = k [NOBr2] [NO]
From eq. (1)
KC =
[ NOBr2 ]
[ NO][Br2 ]
r = K.Kc [NO] [Br2] [NO]

r = K' [NO]2 [Br2]
Hydrophillic part
Order w.r.t. (NO) is (2)

Hydrophobic
part
39.[4]
40.[3]
49.[1]
OH
The second dissociation constant of maleic

acid is less in comparison to furneric acid.
CH2
H
Number of atoms
8
+ 2 no. of body diagonal
8
=1+24=9
41.[2]
[Co(H2O)5Cl]Cl2.H2O + AgNO3 AgCl

1 mole
excess 2 moles
42.[1]
Ti+4 = [Ar] 4so3do

It has zero unpaired electron.
43.[1]
Fact
44.[2]
Both assertion and reason are true but the

reason is not a correct explanation of the
assertion.
45.[1]
HO
O
H
OH
OH
H
OH
50.[3]
NO
NO+
BO. = 2.5
3
Paramagnetic Diamagnetic
51.[4]
Order of strength of bond is

Ionic > Covalent > Metallic > Vander waal's
force
52.[2]
Na+ > Mg+2 > Al+3 > Si+4

L
Mixture of CuO & Cu2O contains 88% Cu

x
100 x
i.e.
+
= 88
63.5 + 16
2 63.5 + 16
size
for
isoelectronic
1
]
+ ve ch arg e
[size
of
cation
x = 9.06 %
53.[2]
46.[3]
Let in the given compound x mole Sn (II) and

y moles Sn (IV) present.
x + y = 4.44
54.[1]
2x + 4y = 16
or x + 2y = 8
on solving y = 3.56 and x = 0.88
molar ratio of Sn (II) to Sn (IV) is
0.247 : 1 = 1 : 4 (approximately)
47.[1]
55.[1]
At constant pressure
VT
So (10%) increase in temp.
At anode : 2OH O2 + 2H+ + 4e
E
It
F
63.5
1.2 t
0.4 =
2 96500
t = 1013.12 sec
W=
For Ist order reaction

1/ 2
1/ 2
0.05 t
0.025
0.1 t
2t1/2 = 40 min
t
1/2 = 20 min
0.693
min1
20
rate of reaction r = k[A]
k=
0.693
0.01
20
= 0.0003465 M/min
lim
y = x2 +
63.[1]
56.[1]
w = 2.303 nRT log
v1
= 2.303 2 8.314
v2
dy
=
dx
10
20
= 2.303 2 8.314 298 (0 0.3)
= 3423.51 J
= 3.42 KJ
2C
2A + 2B
2A + 2B
2C
64.[1]
P : ( 6 cos ,
C
1/ 2
1
=
25
= 0.2
58.[3]
2 sin)
CP = 6 cos 2 + 2 sin 2 = 2
(where C is the centre of the ellipse)
6(1 sin2) + 2 sin2 = 4
1
3
sin2 = = n or ,
2
4
4 4
1
25
1/ 2
2xy
2xy
=
2
2
y
x
2
y
x2
Any point on the ellipse is
Kc = 25
Kc =
1
y
y2 x2y 1 = 0
298 log
57.[1]
2x
2
=
= 2
cos(sin x ).cos x
1(1)
K"c =
Kc
65.[3]
In =
1
=
5
(ln x)
.1 dx
II
n (ln x)
In = (ln x)n.x
pH = 3 [H+] = 103
When diluted to 10 times, new
10 3
[H ] =
= 104
10
pH = log 104 = 4
n 1
1
. . x dx
x
In = x(ln x)n nIn1

In + nIn1 = x(ln x)n
66.[4]
59.[4]
O
no H
60.[3]
Acid strength Ka
/2
x = 0,
x = 1,
x = 2,
x = 3,
62.[3]
/ 2
1
I power.
pKa
MATHEMATICS
61.[2]
10
5 / 6
(1 cos x) dx +
f(2) = 2 f(0) f(1)

f(2) = 4 3 = 1
f(3) = 2.3 1 = 5
f(4) = 2.1 5 = 3
f(5) = 2.5 ( 3) = 13
function f(x) = x2 2
f (x) = 2x
using L' Hosp.
|f (x)|
(1) dx +
/2
67.[3]
5/6
(2 sin x)dx
5 / 6
1
2
1
f ( x ) f (0)
x0
2
| f (x) | 1
|x|
2
| f(x) |
1
| x | 1 x [0, 2]
2
i.e., | f (x) | 1
68.[4]
At x = 2, function has local minimum

2 2 3 a2 9a 9
a2 9a 10 0
(a 10) (a + 1) 0
+
+
1 10
k 5
h+2
k 2 4
=1
since AD BC
h 1
3
3h 4k + 5 = 0
(1)
5 k 5
again since BE AC =
=1
3
h+2
3h 5k + 31 = 0
(2)
Solving (1) & (2) we get (h = 33, k = 26)
and slope of AC is
a ( , 1] [10, )
69.[4]
dy 2t 1
=
,t>0
dx 2t + 1
Tangent :
73.[1]
2t 1
2
y t2 + t 1 =
(x t t 1)
2t + 1
It passes through (1, 1)
2t 1
. ( t2 t)
t2 + t =
2t + 1
Solving it we get imaginary roots.
70.[4]
AB+ AC 8i 2j + 8k
= 4i j + 4k
=
AD =
2
2
length of median AD
| AD | = 16 + 1 + 16 =
71.[2]
Line AB will be farthest from origin if OP is

right angled to the line drawn.
1
slope of OP =
3
slope of AB = 3
thus the equation of AB is
(y 1) = 3 (x 3)
If D is the mid point of BC then
P (3, 1)
33
10
A = , 0 , B = (0, 10)
3
Given points are (2, 3, 4) and (6, 7, 8) so mid

point is (4, 5, 6)
so, required equation of plane be
4 (x 4) + 4 (y 5) + 4 (z 6) = 0
x + y + z 15 = 0
1
(OA) (OB)
2
1 10
100 50
= .
.10 =
=
2 3
6
3
Area of OAB =
72.[2]
A (h, k)
74.[2]
d=
c1 c 2
a 2 + b2
E
(1, 2) O
B
(4, 3)
C
(2, 5)
Let the third vertex be (h, k)

k2
Now slope of AD is
h 1
5+3
4
=
slope of BC is
24
3
3 2 5
=
slope of BE is
4 1
3
7 45
=4
25 + 144
75.[3]
The line mid parallel to the given lines is

7 + 45
5x + 12y +
=0
2
or 5x + 12y + 19 = 0
76.[1]
If |z| 5, z +
As | z |
2
z
=?
min
2
2
z+
|z|
z
6
77.[1]
78.[3]
x < (25 525 ) or x > (25 + 525 )
23
2
z+
5
z
Given equation is
x2 + px + p3 = 0
we have, + = p, = p3
but 2 =
therefore 3 = p3 = p
and 2 + = p
p2 + p = p p = 2 As p 0
hence = 4, = 2
81.[3]
82.[3]
83.[3]
We have
b
1
f ( x ) dx = b 2 + 1 2
Differentiate both side

1.2 b
f(b) . 1 f(1). 0 =
0
2 b2 + 1
a2
f(b) =
The number of ways to divide n identical

things among
r persons = n + r 1Cr 1 (By multinomial theorem)
n = 30, r = 4
Req. no. of ways = 30 + 4 1C4 1 = 33C3
33 32 31
= 5456
=
3 2
((23)2)7
= (529)7 = (530 1)7
= [7C0(530)7 ....... + 7C6 (530)1 7C7]
= [7C0(530)7 7C1(530)6 .....+ 7C5(530)2]
+ 7 530 1
= 100 [7C0(53)7(10)5 ..... + 7C5(53)2] + 3709
last two digits are 09
b
b +1
2
cos(p d) x cos px cos(p + d) x

sin(p d) x sin px sin(p + d) x
= 1 sin(px + dx px) + a(sin(px dx px dx))

+ a2(sin(px px + dx))
= sin dx a sin 2 dx + a2 sin dx
i.e. independent from p.
80.[3]
x < (25 22.91) or x > (25 + 22.91)

x < 2.09 or x > 47.91
x2
or x 48
(1, 2)
(48, 49, 50, .. 99, 100)
Thus, the favorable number of case is
(2 + 53) = 55
55 11
Hence, the required probability =
=
100 20
As A1 + A2 = a + b
G1 G2 = ab
A1 + A 2 a + b
=
G1 G 2
ab
1
79.[2]
( x 25) < 525 or (x 25) > 525
| z |2 2
2
z+
|z|
z
f(x) =
x
x2 +1
84.[2]
f(0) = c = integer and f(1) = a + b + c = integer.

Therefore, a + b = integer
85.[1]
When the first row has exactly one zero, the

total number of cases is 6.
When the first row has two zeros, we get
more cases. In total we get more than seven
cases.
86.[1]
If a fix number is added as subtracted from

the given set of number. Then it's standard
deviation will not change.
87.[3]
Proposition p (q r) is false, then the truth

values of p, q, r are respectively T, F, F.
88.[2]
100
> 50
x +
x
(x 25)2 > 525
p q p q (p q ) p
T T
T
T
T F
F
T
F T
F
T
F
(p q) p is tautology
7
89.[1]
lim
tan
2r 1
1 + 2 2 r 1
r =1
2 r 2 r 1
tan 1
r r 1
1 + 2 .2
r =1
n
= lim
= lim
{tan
(2 r ) tan 1 (2 r 1 )}
r =1
= lim (tan1 2n tan1 2)

n
= tan1 2 tan1 1 = tan1 tan1 1

= =
2 4 4
90.[4]
Q 3 = 1 + 1 + 12
7 = 1 + 2 + 22
13 = 1 + 3 + 32
--------------------------------------------------- cot1 3 + cot1 7 + cot1 13 + .......
n
= lim
cot
tan
2
1+ r + r
r =1
n
= lim
(1 + r + r 2 )
r =1
n
= lim
tan
r =1
(r + 1) r
1
+ r (r + 1)
= lim
[tan
(r + 1) tan 1 r ]
r =1
= lim [tan1(n + 1) tan1 1]

n
= tan1

= =
4 2 4 4

Combined Sol. Major-2 AITS XII 4-01-2015

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CAREER POINT

TARGET - AIEEE (JEE-Mains)

PHYSICS, CHEMISTRY, MATHEMATICS

CAREER POINT, CPTower,IPIA,RoadNo.1,Kota(Raj.),Ph:07443040000

Since the ray is totally internally reflected.

t1 : (t1 + t2) : (t1 + t2 + t3) = 1 :

Point 1, 6 and 8 are same potential similarly

Circuit can be redrawn as.

Significant figures of volume match with that

N0 = Initial no. of active nuclei

225 + 400 = 25 volt

Let t1, t2 and t3 be the times to cover AB, BC

CAREER POINT, CPTower,IPIA,RoadNo.1,Kota(Raj.),Ph:07443040000

X200 A110 + B90 + Energy

Diffusion of holes from P side to N side is

No work done in free expansion

In B2H6 four B-H bonds are normal 2c-2e

4KO2 + 2CO2 2K2CO3 + 3O2

The percentage of carbon is least in wrought

The reactivity of alkyl halides in SN1 reaction

Percentage increase in length = 105 100

Position 4 is the best one because it is para to

CAREER POINT, CPTower,IPIA,RoadNo.1,Kota(Raj.),Ph:07443040000

Soaps are sodium salts of long chain fatty

r = K.Kc [NO] [Br2] [NO]

Order w.r.t. (NO) is (2)

The second dissociation constant of maleic

[Co(H2O)5Cl]Cl2.H2O + AgNO3 AgCl

Ti+4 = [Ar] 4so3do

Both assertion and reason are true but the

Order of strength of bond is

Na+ > Mg+2 > Al+3 > Si+4

Mixture of CuO & Cu2O contains 88% Cu

Let in the given compound x mole Sn (II) and

CAREER POINT, CPTower,IPIA,RoadNo.1,Kota(Raj.),Ph:07443040000

At anode : 2OH O2 + 2H+ + 4e

For Ist order reaction

w = 2.303 nRT log

Any point on the ellipse is

In = x(ln x)n nIn1

f(2) = 2 f(0) f(1)

CAREER POINT, CPTower,IPIA,RoadNo.1,Kota(Raj.),Ph:07443040000

At x = 2, function has local minimum

Line AB will be farthest from origin if OP is

If D is the mid point of BC then

Given points are (2, 3, 4) and (6, 7, 8) so mid

Let the third vertex be (h, k)

The line mid parallel to the given lines is

CAREER POINT, CPTower,IPIA,RoadNo.1,Kota(Raj.),Ph:07443040000

x < (25 525 ) or x > (25 + 525 )

Differentiate both side

The number of ways to divide n identical

cos(p d) x cos px cos(p + d) x

= 1 sin(px + dx px) + a(sin(px dx px dx))

x < (25 22.91) or x > (25 + 22.91)

( x 25) < 525 or (x 25) > 525

f(0) = c = integer and f(1) = a + b + c = integer.

When the first row has exactly one zero, the

If a fix number is added as subtracted from

Proposition p (q r) is false, then the truth

(x 25)2 > 525

CAREER POINT, CPTower,IPIA,RoadNo.1,Kota(Raj.),Ph:07443040000

= lim (tan1 2n tan1 2)

= tan1 2 tan1 1 = tan1 tan1 1