Oil Chem

TECHNOLOGIES

Surfacttants Bringing Chemical IOR

TO THE NEXT GENERATION

Oil Chem
TECHNOLOGIES

Surfacctants Bringing
g g Chemical IOR
TO THE NEXT GENERATION

Our Company

Oil Chem Te
echnologies
g
No. 38 Overa
all in 2009
No. 2 in Energy Area

OilChem
mNetwork
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siness Strategy
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Marketing & sales

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Techno
ologies

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O
Produ
ucers

Local Partners /
Toll Manufactures

Patented Products & Processes

for IOR

State-of-the-art Patented
d Technology for EOR
Description

Patent No.

New Anionic Surfactants for Large Qua

antity

6,043,391

Anionic ASP Composition

6 022 834
6,022,834

Sulfonated Phenolic Resins for Low Ad

dsorb

6,736,211

Viscoelastic Surfactants for EOR

7,373,977

Alcohol Ether Sulfonates for Hi Temp/H

Hi TDS

7,427,588

Organic Alkali for Hard Waters

11/811,786

Amphoteric Surfactants for High Temp

p/Hi TDS

7,556,098

High MW Anionic Surfactants

11/895,497

I t
Internal
l Ol
Olefin
fi Eth
Ether S
Sulfonates
lf
t for
f Hi Temp/Hi
T
/Hi TDS

12/009 429
12/009,429

Oil Chem
TECHNOLOGIES

Surfaactants Bringing
g g Chemical IOR
TO THE NEXT GENERATION

Field Exp
perience

ASP, SP Field Flood Since 1995

Instow
Warner

Crowsnest

Gull Lake

Karamay

Daqing
Tanner
Gudong

Pelican Lake (4)

Mellott
Range

Countess

Ad
Adena

Shengli

Suffield
Cypress

Sho-VelTum

Bridgeport

Viraj

Diadema

ASP-others
ASP, SP- Oil Chem

Surtek. Chemical Enhanced Oil Recovery

Daqing ASP Pilot Production

ASP flood
fl d
decline
waterflood
decline

Oil Recoveryy
MT
T/Day
s/Day
Tons

ASP PROJECT
T USING ORS-41
ORS 41TM
IN DAQING, CHINA
20
15

BEFORE ASP
AFTER ASP

10
5
0
1

2
3
4
Well Number
N

SPE 36748 (1996)

HuskyTab
berASPProject
12

2500
4/2008
2087 bbls/day

10

4/2008
10.2% oil cut

2000

Begin ASP 6/2006

1500

6
4

300

1000

00
500

2
0

bbls
oil/day

% Oiil Cut

1.7% oil cut

Oil Cut
Oil
Production

Tanner, WyomiingASPProject
Tanner,Wyomi
ing ASP Project

SPE 100004

ShoVelTum FiieldASPProject
j
On
Onproduction>40yrs
production > 40 yrs,extensivewaterflood,
extensive water flood
produced4bbl/day
ASP started on 2/98 ussingNa
sing Na2CO3 andORS
and ORS62
62
ASPstartedon2/98,us
Totalincrementaloil>1
10,444bblin1.3years
35
30

So%PV

25
20
15
10
5
0
0

10
15
20
25
30
(SurfactantConcentration%)(ASPSlugSize)

35

SPE 84904

NorthAmericaSPProject

Heavyoilfield
H
il fi ld
Underpolymerflood
Added0.1%surfactanttwithpolymer
~3monthslater,thew
watercutreducedfrom97%
to58%

Big Sinkingg,Kentucky
BigSinking
g, Kentucky
Chemicalinjected:0.8%N
NaOH +0.1%ORS162HF
Problemsovercome:

IFTloweredfrom23.6to0
0.001mN/m
Poorwaterinjectivity
Highwatercuts
220%increaseininjectivityy

SPE 89384

SurfactantFloodForrLowPermFormation
BHT~56C
Producedbrineisusedtoreiinject
TDS~195,000ppm,Ca,Mg
pp
g ~2
2500ppm,sour,highFe
pp
g
contain
Hadtroubleinjectingwater
Using0.1%SS780since2003
3in2fields successfully
increasedtheoilproduction

Note: Producer is not revealed due

d to customer confidentially

South America
a SP Project

DIADEMA and SINDICATO (CAPSA)

AGUA DEL CAJON AREA (CAPEX)

KM20 y OTROS (CAPSA)

2005 03 04 1139.dwg

Offshore AS
A Project
Sea water is softened on the platform

Single well test succeessfully performed

using SS 6-72LV injec
cted with NaOH

SPE 100943, 109033

Oil Chem
TECHNOLOGIES

Surfacctants Bringing
g g Chemical IOR
TO THE NEXT GENERATION

Producct Lines

Oil Chem IOR Product Lines

New Generation of IOR Surfactants:
GreenSurfTM - Bio-Based low adsorption
surfactant

ORS Series - Pioneer ASP

surfactants > 60 Millions
surfactants.
pounds at 0.2% successfully
implemented
Cold Heavy Oil Recovery
No steam or solvent is
needed

Visco-elastic Smart
Surfactant to provide low
IFT and viscosity

NanoSurf 969 100% Green

based micro emulsion for gas
shale

Green aromatic solvent

replacement

ORSSurfacttantsforASP
>>60millionpoundswereinjec
60 million pounds were injecctedsince1995withtotal
cted since 1995 with total
success
q
Lowconcentrationrequired
Nocosurfactant,solvent,salttoptimizationrequired
Fieldprovensuccess
Field proven success

GreenSurfTM fo
or SP and ASP
State of the Art,Bio
StateoftheArt
Biobase
baseedsurfactants
ed surfactants
ToleranttohighTDS,Ca,M
Mg
Hightemperaturestable
i h
bl
Lowadsorption
GreenSurfAdsorption
mgsurfactantadsorbe
ed/gbereasand

7
6
5
4
3

GreenSurf

Control

1
0
0

0.05

0.1

0.15

0.2

Surfactantwt%

0.25

0.3

Cold Heavyy Oil Recoveryy

Heavy oil recoveryy by modifying
the apparent
pp
viscosityy of the oil with
small amount of the surfactant
No steam or solve
ent is required

HeavyOilinBrine Control

HeavyOilRecovery
y
y 0.1%Surfactant@
AmbientTeemperature

Wettabilityy Alteration

IFT > 1 mN/m

0.1% SS-87
70
IFT = 10-33 mN/m
m

IFT = 10-1 mN/m

NanoSurf 969 MicroEmulsionfor

M
UnconventionaalGasReservoir
l

100%Green
100%
Green environm
mental friendly
mentalfriendly
ReducePhasetrapping
Improvewaterrecovery
Increasegasregainedpermeability
Lowpourpoint< 20F

Nanosurf 969forSShaleGasRecovery
RelativePermeabilityvs
ResidualFluidSaturation

RegainedPermeabilityIncrease
Permeability,mD
P

Regained
dPermeability,%

40
35
30
25
20
15

0.25
0.2
0.3%Nanosurf969

0.15

WithoutNanosurf969

01
0.1
0.05

10
5

30
0

2
3
GasDrivePressure,MPa

35

40

45

50

4
ResidualFluidSaturation,%

55

60

65

Green Aromatic So
olvent Replacement
GreenSolv Wellbore Cle
eaner
GreenSolv Rig Wash
GreenSolv Aromatic Re
eplacement
GreenSolvAromaticRep
placementSolvency
100
RelativeAssphalteneSolvencyy
(tolu
uene=100%)

90
80
70
60
50
40
30
20
10
0
Toluene

Xylene

GreenSolvAromatic
Replacement

Oil Chem
TECHNOLOGIES

Surfacctants Bringing
g g Chemical IOR
TO THE NEXT GENERATION

Services Available

Servicess Available
Complimentary surfactan
nt screening/optimzation
Complimentary chemical EOR surfactant consultation
Custom surfactant design
Local manufacturing ava
ailable
Field experiences to sha
are