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MODUL KIMIA SPM 2014/2015 Kertas 2: Chapter 2: Carbon Compound Sebatian Karbon
MODUL KIMIA SPM 2014/2015 Kertas 2: Chapter 2: Carbon Compound Sebatian Karbon
KELAS INTENSIF
Sekolah Kluster Kecemerlangan
Kimia A+
MODUL 2 TINGKATAN 5
CHAPTER 2: CARBON COMPOUND
SEBATIAN KARBON
MODUL 2 TINGKATAN 5
Activity 1
Carbon is located in group ... . A carbon atom contain .. electrons, therefore the
electronic configuration is ..
Karbon terletak dalam kumpulan ..................... . Atom karbon mengandungi ........ elektron, oleh itu
konfigurasi elektronik ialah.................
It has valance electrons in the outermost orbital.
Atom karbon mempunyai ............ elektron valens di orbit terluar.
In order to achieve a stable outer octet of electrons, it forms four .. bonds.
Untuk mencapai oktet terluar untuk stabil elektron, ia membentuk empat ikatan ..................
Each carbon atom is tied to other atoms through four covalent bonds. All the four covalent bonds may
exist in three forms as shown below:
Setiap atom karbon terikat kepada atom lain melalui empat ikatan kovalen. Semua empat ikatan kovalen boleh
wujud dalam tiga bentuk seperti yang ditunjukkan di bawah:
Organic / Organik
Found in, produced by, or derived from
living elements.
Dijumpai dalam, yang dihasilkan oleh, atau
diperolehi dari unsur-unsur hidup.
Example:
MODUL 2 TINGKATAN 5
Meaning / Maksud
Hydrocarbons where all its
carbon atoms are tied to each
other through single covalent
bond only
Hidrokarbon ialah semua atom
karbon yang terikat antara satu
sama lain melalui ikatan kovalen
tunggal sahaja
Hydrocarbons which contains at
least one double covalent bond
among its carbon atoms
Hidrokarbon yang mengandungi
sekurang-kurangnya satu ikatan
kovalen ganda dua antara atom
karbon.
Examples:
Unsaturated Hydrocarbon
Reaction
with
potassium
anganite(VII) solution
Tindak balas dengan larutan kalium
manganat (VII)
MODUL 2 TINGKATAN 5
B
ALKANES / ALKANA
Activity 3
(a) Complete the table below:
Number
of
Carbon
1
Structural formula
Molecular formula
Name of
alkane
Condition at
room temperature
CH4
Methane
Gas
3
4
7
C7H16
C8H18
10
MODUL 2 TINGKATAN 5
b.
Explain why on going down the alkane series, the melting and boiling point increase?
Terangkan apabila siri alkana menurun, lebur dan takat didih meningkat?
On going down the alkanes series, the ..increases caused by the
increase in molecular size.
Apabila siri alkana menurun,disebabkan oleh peningkatan dalam saiz
molekul.
When the molecular size increases, the melting and boiling point... This is because
the larger the molecular size, the stronger the .. forces of attraction between
the molecules. Thus more energy is needed to . the forces of attraction during
melting or boiling.
Apabila saiz molekul meningkat, peleburan dan takat didih . Hal ini kerana saiz molekul
lebih besar, semakin kuat .. daya tarikan antara molekul. Oleh itu lebih banyak tenaga
diperlukan untuk mengatasi . semasa takat lebur atau takat didih.
[3 marks]
c.
Ethane and propene burn in excess of oxygen gas. Balance the chemical equation of the
combustion of these hydrocarbons.
Etana dan propena membakar melebihi gas oksigen. Imbangkan persamaan kimia bagi pembakaran
hidrokarbon ini.
(i)
C2H6 (g)
O2 (g)
CO2 (g) +
(ii)
C3H8 (g)
O2 (g)
H2O (l)
[2 marks]
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MODUL 2 TINGKATAN 5
Activity 4
a) Name the compound a, b, c, d, e, and f.
(a)
(c)
b)
Complete combustion
with excess O2
pembakaran lengkap
dengan lebihan O2
Methane
Incomplete
Combustion (limited O2)
Pembakaran tidak
lengkap
(O2 terhad)
Substitution reaction
(chlorination)
Excess chlorine
Sunlight or heat
klorin berlebihan
Cahaya matahari atau haba
(d)
(b)
(e)
(f)
State the uses of methane in everyday life/Nyatakan kegunaan metana dalam kehidupan seharian
i ..
ii .
iii ..
iv ..
c)
Explain how methane can cause fire in landfills and peat swamps
Terangkan bagaimana metana boleh menyebabkan kebakaran di tapak pelupusan dan paya gambut
...
[2 marks]
MODUL 2 TINGKATAN 5
C
ALKENES/ALKENA
Activity 5
(a) Complete the table below:
Number of
Carbon
2
Structural formula
Molecular
formula
Name of
alkane
Condition at
room temperature
5
6
7
C7H14
10
MODUL 2 TINGKATAN 5
Activity 6
(a)
CH3
Cl
CH3
CH3
(b) Construct the structural formula for/ Bina formula struktur bagi:
(i)
C5H10
(iv)
2-methylbut-2-ene
(ii)
2-chlorolpropene
(v)
3-methylbutene
(iii) pent-2-ene
MODUL 2 TINGKATAN 5
Activity 7
Write the molecular formula or structural formula of the product for every reaction of propene below
Tuliskan formula molekul atau formula struktur hasil bagi setiap tindak balas propena bawah
a)
b)
excess O2,
heat
h)
limited O2
heat
c)
acidified
KMnO4 (aq)
Propene
Pronena
H2 / Ni
.180o C
Addition
polymerization
H2O(g)
300 C,60 atm,
H3PO4
g)
Cl2(aq)
d)
HCl (g)
f)
e)
Activity 8
(a)
Table below shows the reactions to compare the chemical properties of alkane and alkene.
Complete the table.
Jadual di bawah menunjukkan tindak balas untuk perbandingkan sifat-sifat kimia alkana dan alkena.
Lengkapkan jadual ini
Reaction/Tindak balas
Observation/Pemerhatian
Hexane
Hexene
Reaction with oxygen
Hexane burns with a yellow
Tindak balas oksigen
sooty flame
terbakar dengan api kuning hitam
Reaction with bromine Water
No visible change
Tindak balas air bromin
Tiada perubahan
Reaction with acidified potassium No visible change
Tiada perubahan
manganate(VII) solution
Tindak balas dengan larutan kalium
manganat (VII) berasid
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MODUL 2 TINGKATAN 5
(b)
hexane
(ii) hexene
(c)
(d)
(i)
(ii)
(iii)
(iv)
Aspect/ aspek
Alkane
Alkane
Sootiness of flame
Kejelagaan nyalaan
Bromine water
Air bromin
Acidified KMnO4
Keasidan KMnO4
MODUL 2 TINGKATAN 5
D ISOMERS
Activity 9
a) Draw the structural formula and give name to all isomers of
Lukiskan formula struktur dan namakan semua isomer
(i) C4H8
(ii)
C4H10
(iii)
C5 H12
ALCOHOLS/ Alkohol
Activity 10
The general formula for alcohol is .
Formula am bagi alkohol adalah
(a)
i) Name :
ii) Name:
iii) Name:
MODUL 2 TINGKATAN 5
iv) structural formula
Name : Propan-2-ol
Name : Butan-1-ol
Name : Pentan-2,3-diol
(b) Draw the structural formula and give names to all isomers of
Lukiskan formula struktur dan namakan semua isomer
(i)
propanol (C3H7OH)
(ii)
butanol (C4H9OH)
Activity 11
(a)
Description/keterangan
MODUL 2 TINGKATAN 5
(b)
(iii)
State the temperature, catalyst and other condition needed for fermentation process.
Nyatakan suhu, pemangkin dan keadaan lain yang diperlukan untuk proses penapaian.
...
...
(iv)
(c)
Hydration process involves hydration of ethene. Ethene is obtained from the cracking of
petroleum fractions.
Proses penghidratan melibatkan penghidratan etena. Etena diperolehi daripada keretakan pecahan
petroleum.
(i)
Write the chemical equation for hydration process.
Tuliskan persamaan kimia bagi proses penghidratan.
...
(ii)
State the temperature, pressure and catalyst needed for hydration process.
Nyatakan suhu, tekanan dan pemangkin yang diperlukan untuk proses penghidratan
MODUL 2 TINGKATAN 5
Activity 12
a) Complete the table below
1
Draw and label the set of apparatus to show the dehydration process of propanol.
Lukis dan labelkan set radas untuk menunjukkan proses penyahhidratan propanol
MODUL 2 TINGKATAN 5
F
CARBOXYLIC ACIDS/ ASID KARBORSILIK
Activity 13
(a) Complete the diagram below.
Uses/kegunaan:
Functional group/ kumpulan
fungsi:
a
b
c
d ..
General formula:
CARBOXYLIC ACIDS
..
b ..
names end with/ berakhir dengan
.. . Eg. ethanoic acid.
(b)
c
d ..
e ..
Ethanoic acid
Propanoic acid
Butanoic acid
2-methylbutanoic acid
MODUL 2 TINGKATAN 5
(c)
A carboxylic acid, X has an empirical formula CH2O. Experimental determination shows that it has
a molar mass of about 59 g mol-1
Asid karboksilik, X mempunyai formula empirikal CH2O. Eksperimen menunjukkan bahawa jisim molar
ialah 59 g mol-1.
(i)
What is the general formula of carboxylic acid?
Apakah formula am asid karboksilik?
(ii)
(iii)
Activity 14
a) Figure shows a series of conversion starting from ethene to ethyl ethanoate.
Rajah menunjukkan satu siri penukaran bermula dari etena kepada etil ethanoate.
Ethene
Ethanol
II
Ethanoic acid
b)
Reaction I
Reaction II
MODUL 2 TINGKATAN 5
c)
Observation/Pemerhatian
Inference/ inferens
ESTER
Activity 15
(a) Name the following esters and give the alcohols and carboxylic acids required to synthesise
the esters name.
Namakan ester berikut dan berikan alkohol dan asid karboksilik yang diperlukan untuk mensintesiskan
nama ester.
Formula
Name
Carboxylic acid
Alcohol
Example :HCOOC2H5
Ethyl methanoate
Methanoic acid
Ethanol
a) CH3 COOCH3
b) CH3 COOC3H7
c) C2H5 COOCH3
MODUL 2 TINGKATAN 5
b) Draw the structural formula for the compound form in the reaction between alchol and carboxylic acid
below.
Lukiskan formula struktur bagi bentuk sebatian dalam tindak balas antara alkohol dan asid karboksilik
di bawah.
(i)
methanol and propanoic acid
(ii)
(iii)
MODUL 2 TINGKATAN 5
Activity 16
(a)
Product of an .
reaction between a carboxylic
acid and an alcohol.
contain ,
and
.
the functional
group is COO- or
. group
ESTERS
uses of ester/kegunaan ester,
a) ..
b) ..
c)
d)
2.
3.
4.
5.
b) Write the fruit flavour for each of the ester below/Tulis rasa buah-buahan bagi setiap ester di bawah
(i)
n-pentyl ethanoate : .
: .
: .
MODUL 2 TINGKATAN 5
Order in homologous series/ Order dalam siri homolog
Activity 17
Butan-1-ol
C4H9OH
Porcelain chips
Serpihan perselin
II
Compound P
Sebatian P
IV
Hydrogen
Compound Q
Sebatian Q
chloride
I
Acidified potassium
dichromate(VI) solution
Compound R
Sebatian R
III
Compound S
Sebatian S
ethanol
a)
b)
Butan-1-ol
: ..
(ii)
Compound P
: .
(iii)
Compound R
(iv)
Compound S
: ..
(i)
compound P
(ii)
compound Q :
(iii)
compound R : ..
(iv)
compound S : .
MODUL 2 TINGKATAN 5
H
FATS/LEMAK
Activity 18
Compare fats and oils/ Perbandingan lemak dengan minyak
Comparison/bandingan
Oils/minyak
Fats/lemak
Source/ sumber
Melting point/ takat lebur o C
Physical state at room
temperature
Keadaan fizik pada suhu bilik
Cholesterol content kandungan
kolesterol
Examples
Contoh
< 20 / lower
> 20 / higher
Butter
Mentega
Molecular structure
struktur molekul
(III) Write the Similarities of fats and oils/ Tuliskan persamaan lemak dengan minyak
In terms of/ dalam bentuk
Similarities/persamaan
Molecular formula
Formula molekul
Type of compound
Jenis sebatian
Type of bond
Jenis ikatan
MODUL 2 TINGKATAN 5
Activity 19
a) Complete the flow chart below to show the Extraction Process of Palm Oil.
Lengkapkan carta aliran di bawah untuk menunjukkan proses pengekstrakan minyak sawit.
Sterilization
Pengsterilan
Stripping
Penanggalan
Digestion
Penghadaman
Pressing
Penekanan
Purification
Penurunan
MODUL 2 TINGKATAN 5
I NATURAL RUBBER/ GETAH ASLI
Activity 20
a) Give explanation for every situation below/Berikan penerangan bagi setiap keadaan di bawah:
i)
ii)
When 20 cm3 latex is added with 5 cm3 methanoic acid, latex coagulate rapidly.
Apabila 20 cm3 getah ditambah dengan 5 cm3 asid metanoik, getah membeku dengan cepat.
iii)
When 5 cm3 ammonia solution is added to latex, latex does not coagulate.
Apabila 5 cm3 larutan ammonia ditambah kepada susu getah, getah tidak membeku.
Unvulcanised rubber
Getah tak tervulkan
Vulcanised rubber
Getah tervulkan
Oxidation
Pengoksidaan
Resistance of heat
Ketahanan terhadap haba
Strength
Kekuatan
Elasticity
Kekenyalan
MODUL 2 TINGKATAN 5
Diagram shows the structural formulae of compound M and compound N. Both compound M and
compound N are isomers of a carbon compound.
Rajah menunjukkan formula struktur bagi sebatian M dan sebatian N. Kedua-dua sebatian M dan sebatian N
adalah isomer satu sebatian karbon.
H
H
C = C
= C
Compound M
Sebatian M
H
Compound N
Sebatian N
Diagram
Rajah
(a) (i) State the meaning of isomer.
Nyatakan maksud isomer.
...
[1 mark]
(ii) Write the molecular formula for the carbon compound in Diagram.
Tulis formula molekul bagi sebatian karbon dalam Rajah.
[1 mark]
(iii) State the names of compound M and compound N using IUPAC nomenclature.
Nyatakan nama sebatian M dan sebatian N dengan menggunakan penamaan IUPAC.
Compound M :..
Sebatian M
Compound N :
Sebatian N
[2 marks]
(iv) Draw the structural formula for another isomer of the carbon compound.
Lukis formula struktur untuk satu lagi isomer bagi sebatian karbon itu.
[1 mark]
MODUL 2 TINGKATAN 5
(ii) State the name of the process for the conversion of compound M to the alcohol.
Nyatakan nama proses penukaran bagi sebatian M kepada alkohol itu.
..
[1 mark]
(iii) State two of the conditions used in the conversion.
Nyatakan dua keadaan yang digunakan dalam penukaran itu.
1...
2
[2 marks]
MODUL 2 TINGKATAN 5
Boiling point (o
C)
Preparation
Oxidation product
Penyediaan
Hasil pengoksidaan
Ethanol
Etanol
Ethanoic acid
78
C2H4 + H2O
C2H5OH
Propanol
Propanol
Asid etanoik
Propanoic acid
97
C3H6 + H2O
C3H7OH
Asid propanoik
Butanol
Butanol
Butanoic acid
118
C4H8 + H2O
C4H9OH
Asid butanoik
Table
Jadual
Based on Table, state and explain five characteristics of a homologous series.
Berdasarkan Jadual 7, nyatakan dan terangkan lima ciri siri homolog.
[10 marks]
(b) The following information is about an organic compound X.
Maklumat berikut adalah mengenai suatu sebatian organik X.
Empirical formula is CH2O
Formula empiric ialah CH2O
Relative molecular mass is 60
Jisim molekul relatif ialah 60
Reacts with calcium carbonate to produce a type of gas that turns lime water chalky
Bertindak balas dengan kalsium karbonat untuk menghasilkan sejenis gas yang mengeruhkan air kapur.
Based on the information given:
Berdasarkan maklumat yang diberi:
(i) Determine the molecular formula of X.
(Relative atomic mass: C =12, H =1, O = 16)
Tentukan formula molekul X.
(Jisim atom relatif: C =12, H = 1, O = 16)
[2 marks]
(ii) State the name of the homologous series for X and explain your answer.
Nyatakan nama siri homolog bagi X dan terangkan jawapan anda.
[2 marks]
(iii) Write a balanced chemical equation for the reaction of compound X with calcium carbonate.
Tulis persamaan kimia seimbang untuk tindak balas sebatian X dengan kalsium karbonat.
[2 marks]
MODUL 2 TINGKATAN 5
= C
H
H
Compound P
Sebatian p
Compound Q
Sebatian Q
Diagram
Rajah
Compare and contrast these two hydrocarbons based on their structures.
Banding dan bezakan kedua-dua hidrokarbon ini berdasarkan strukturnya.
[4 marks]
MODUL 2 TINGKATAN 5
Diagram shows the conversion of an organic compound from one homologous series to another. Rajah
Rajah menunjukkan penukaran sebatian organik daripada satu siri homolog kepada yang lain.
Hydration
Oxidation
Penghidratan
Pengoksidaan
Compound W
Sebatian W
Alkene Q
Alkena Q
Diagram
Rajah
Compound X
Sebatian X
Ester A
Ester A
(a) The possible relative molecular masess of alkene Q are 28, 42 or 56.
By choosing any one of the relative molecular masses,
determine the molecular formula for the alkene
draw the structural formula and state the name of the alkene.
[Relative atomic mass: H = 1; C = 12]
Jisim molekul relatif yang mungkin bagi alkena Q adalah 28, 42 atau 56.
Dengan memilih salah satu daripada jisim molekul relative itu,
tentukan formula molekul bagi alkena itu
lukiskan formula struktur dan nyatakan nama bagi alkena itu.
[Jisim atom relative: H =1; C =12]
(b)
[4 marks]
(c) By using compound W and compound X that obtained in (b), describe hoe ester A can prepared in
the laboratory. In your description, include:
List of materials and apparatus
Procedure
Observation
Chemical equation
Name of ester
Dengan menggunakan sebatian W dan sebatian X yang diperoleh di (b), huraikan
bagaimana ester A boleh disediakan di makmal.Dalam huraian anda,sertakan:
Senarai bahan dan radas
Prosedur
Pemerhatian
Persamaan kimia
Nama bagi ester A
[10 markah]
Copy Cikgu Marzuqi Mohd Salleh