Hydroquinone

Formula: C H O
6

Molecular weight: 110.1106

IUPAC Standard InChI:
o

InChI=1S/C6H6O2/c7-5-1-2-6(8)4-3-5/h1-4,7-8H

Download the identifier in a file.

IUPAC Standard InChIKey: QIGBRXMKCJKVMJ-UHFFFAOYSA-N

CAS Registry Number: 123-31-9

Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript.
Other names: 1,4-Benzenediol; p-Benzenediol; p-Dihydroxybenzene; pDioxybenzene; p-Hydroquinone; p-Hydroxyphenol; Arctuvin;
Benzohydroquinone; Benzoquinol; Diak 5; Eldopaque; Eldoquin;
Hidroquinone; Hydroquinol; HE 5; Phiaquin; Quinol; Tecquinol; Tenox HQ;
1,4-Dihydroxybenzene; 4-Hydroxyphenol; p-Dioxobenzene; Hydrochinone;
Benzene, p-dihydroxy-; Black and White Bleaching Cream; Derma-Blanch;
Hydrochinon; Hydroquinole; Idrochinone; NCI-C55834; Tequinol; USAF EK356; 1,4-Dihydroxy-benzeen; 1,4-Dihydroxy-benzol; 1,4-Dihydroxybenzen;
1,4-Diidrobenzene; UN 2662; Dihydroquinone; Aida; Eldopacque; Eldopaque
forte; Eldoquin forte; Solaquin forte; p-Dihydroquinone; Black & White
Bleaching Cream; 1,4-Benzenediol (hydroquinone)
Permanent link for this species. Use this link for bookmarking this species for
future reference.

 Information on this page:

o Phase change data
o References
o Notes / Error Report
Other data available:
o Gas phase thermochemistry data
o Condensed phase thermochemistry data
o Reaction thermochemistry data
o Henry's Law data
o Gas phase ion energetics data
o IR Spectrum
o Mass spectrum (electron ionization)
o UV/Visible spectrum
o Gas Chromatography
Data at other public NIST sites:
o X-ray Photoelectron Spectroscopy Database, version 4.1
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Phase change data

Go To: Top, References, Notes / Error Report
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights
reserved.
Data
compiled
BS R.L.
TRC - Thermodynamics Research
AC W.E.
ALS H.Y.
Afeefy,
DRB DH - E.S. Domalski and E.D. Hearing

Quantity
T

Value

as
indicated
in
comments:
Brown
and
S.E.
Stein
Center, NIST Boulder Laboratories, M. Frenkel director
Acree,
Jr.,
J.S.
Chickos
J.F.
Liebman,
and
S.E.
Stein
D.R.
Burgess

Units Method

Reference

Comment

boil

558.2

N/A

Aldrich Chemical
Company Inc.,
BS
1990

boil

558.2

N/A

Krupatkin and
Rozhentsova,
1971

Quantity

Value

Units Method

Uncertainty assigned by
TRC = 1. K; TRC

Reference

Comment
Crystal phase 1 phase;
Uncertainty assigned by
TRC = 0.6 K; TRC

fus

445.0

N/A

Bret-Dibat and
Lichanot, 1989

fus

445.

N/A

Buckingham and
Donaghy, 1982

BS

N/A

Krupatkin and
Rozhentsova,
1971

Uncertainty assigned by
TRC = 0.3 K; TRC

fus

Quantity
T

triple

443.5
Value
445.98

Units Method
K

N/A

Reference
Sabbah and
Buluku, 1991

Comment
Uncertainty assigned by
TRC = 0.03 K; TRC

445.5

triple

Quantity

Value

84.4 0.7 kJ/mol

Quantity

Value

vap

94.1 kJ/mol

94.1 0.5 kJ/mol

sub

Reference
Verevkin and
Kozlova, 2008

N/A

Units Method

94.13 0.53 kJ/mol

sub

N/A

Units Method

H
sub

Uncertainty assigned by
Andrews, Lynn, et TRC = 0.3 K; obtained
al., 1926
from cooling curve in
absence of air; TRC
Comment
AC

Reference

Comment

Sabbah and
Buluku, 1991, 2

Hfusion =21.090.4
kJ/mol; ALS

N/A

Sabbah and
Buluku, 1991, 2

DRB

Sabbah and
Buluku, 1991, 2

AC

99.2 1.7 kJ/mol

Magnus, 1956

Reanalyzed by Cox and

Pilcher, 1970, Original value
= 104. kJ/mol; ALS

103.76 kJ/mol

Coolidge and
Coolidge, 1927

ALS

sub

sub

Reduced pressure boiling point

T (K)
boil

Pressure (bar)

558.2
558.

Reference

Comment

0.973 Weast and Grasselli, 1989

BS

0.973 Buckingham and Donaghy, 1982

BS

Enthalpy of vaporization
H (kJ/mol) Temperature (K) Method
vap

70.5

448. - 559.

Antoine Equation Parameters

Reference
Stephenson and Malanowski,
1987

Comment
AC

log (P)

10

P
T = temperature (K)

(B

/
vapor

(T
pressure

C))
(bar)

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Temperature
(K)

Reference
von Terres,

Comment
Coefficents calculated by
NIST from author's data.

432.3 - 559. 5.8947 3049.481 -40.485 Gebert, et al.,

1955

Enthalpy of sublimation
H (kJ/mol) Temperature (K) Method
sub

100.6 1.3

325. - 339.

93.7 0.5

334.

101.3

341. - 400.

104. 1.

N/A

Reference
Chen, Oja, et al., 2006

AC

Sabbah and Buluku, 1991, 2

AC

GS

Bender, Bieling, et al., 1983

AC

342. ME,TE de Kruif, 1981

103.8

298. - 346.

99. 2.

351.

103.8

326. - 345.

Comment

N/A

AC

Magnus, 1956

AC

Wolf and Weghofer, 1938

ALS

QF

Coolidge and Coolidge, 1927

AC

Enthalpy of fusion
H (kJ/mol) Temperature (K) Method
fus

Reference

Comment

26.500

444.95

N/A

Bret-Dibat and Lichanot, 1989, 2 DH

27.23

445.1

N/A

Verevkin and Kozlova, 2008

26.48

453.

N/A

Bret-Dibat and Lichanot, 1989, 2 AC

27.110

445.5

N/A

Andrews, Lynn, et al., 1926, 2

DH

27.11

445.1

Andrews, Lynn, et al., 1926, 2

AC

AC

Entropy of fusion
S (J/mol*K)
fus

Temperature (K)

Reference

Comment

59.

444.95 Bret-Dibat and Lichanot, 1989, 2

DH

60.9

445.5 Andrews, Lynn, et al., 1926, 2

DH

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