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07 Development of Turbo-Expander Based Liquid Nitrogen Plant - Ranjit Kumar Sahoo
07 Development of Turbo-Expander Based Liquid Nitrogen Plant - Ranjit Kumar Sahoo
NITROGEN LIQUEFIER
By
P f Ranjit
Prof.
R jit Kumar
K
S h
Sahoo
Prof. Sunil Kumar Sarangi
DIRECTOR, NIT ROURKELA
CONTENTS
11. Liquefaction
Liq efaction S
Systems
stems
2. Process Design
3. Major Components of Liquefier
3
4. Design of Heat Exchanger
5. Design of Turboexpander
5
6. Design of JT Valve
7. Design of Phase Separator
8. Assembly of the Liquefier
9. References
9
1. Liquefaction
i
f
i
Systems
S
Linde Cycle
In 1895, Carl Von Linde made this air liquefaction system
Compressor
Heat Exchanger
3
Joule
Thomson
Valve
1
g
Tempera
ature, T
3
Phase
separator
Liquid
f
f
Entropy,s
Fig. 1
Fig. 2
T=const
1
Claude System
In 1902, Georges Claude made an air liquefaction system with an
expansion engine.
engine
2
Temperatture, T
H
Heat
E
Exchangers
h
Compressor
T=const
JT
Valve
g
5
8
Expander
e
Phase
separator
q
Liquid
Entropy,s
Fig. 3
Fig. 4
Kapitza System
In 1939,
1939 Claude cycle is modified by eliminating the third or low
temperature heat exchanger.
Compressor
1
Heat Exchangers
3
7
JT
Valve
3
6
Expander
e
Fig. 5
Phase
Ph
separator
Liquid
Heylandt
y
System
y
In 1949, Davies modified the Claude cycle by eliminating the first heat
exchanger
exchanger.
Heat Exchangers
Compressor
1
3
9
8 7
JT
Valve
6
Expander
e
Fig. 6
Phase
separator
Liquid
2. Process
P
D
Design
i
CASE -1
Pressure
10
20
30
0 93
0.93
0 89
0.89
0 86
0.86
Pinch1
3
3
3
Pinch2
2
2
2
Pinch3
1
1
1
50%
50%
50%
t
m
1
1
1
mf
0.05534 0.07933 0.09567
50
0 83
0.83
3
2
1
50%
1
0.1155
80
0 73
0.73
3
2
1
50%
1
0.142
100
07
0.7
3
2
1
50%
1
0.1521
130
0 67
0.67
3
2
1
50%
1
0.1644
150
0 66
0.66
3
2
1
50%
1
0.171
CASE -2
Pressure
10
20
30
50
80
100
130
0.93 0.89
0.85
0.82
0.71
0.68
0.65
Pinch1
3
3
3
3
3
3
3
Pinch2
1
1
1
1
1
1
1
50% 50%
50%
50%
50%
50%
50%
t
m
1
1
1
1
1
1
1
mf
0.05581 0.0797 0.09579 0.1161 0.1412 0.1517 0.1636
CASE -3
Pressure
10
20
0.14
0.14
Pinch1
3
3
Pinch2
1
1
50%
50%
t
m
1
1
mf
0.003936 0.01319
30
50
80
100
0.15
0.2
0.3
0.35
3
3
3
3
1
1
1
1
50%
50%
50%
50%
1
1
1
1
0.0237 0.04673 0.07726 0.09425
130
0.38
3
1
50%
1
0.1147
150
0.4
3
1
50%
1
0.126
150
0.62
3
1
50%
1
0.17
(At 10 bar)
103.93 K
x=0.3230
127.12 K
300 K
297 K
186 kW
Kapitza cycle (Case-2)
105.34 K
90.45 K
14 kW
103.93 K
x=0.2372
102.93 K
1.4kW
(At 10 bar)
127.09 K
103.93 K
x=0.2355
0 355
300 K
297 K
78.44 K
105.35 K
88 97
88.97
HX-2b
HX-1
HX-2a
Compressor
JT
Valve
Turboexpander
Phase separator
Fig. 8
7 95 bar
7.95
C
1
Make
Up
Fluid
9
Mixer-1
1.1 bar
3
HX-1
7.9 bar
100 2 K
100.2
8
1.15 bar
7.9 bar
100 2 K
100.2
4g
HX-2b
8 bar
310 K
HX-2a
1.1 bar
300 K
4
7
JT
Valve
Mixer-2
1.2 bar
1.2 bar 5g
78.8 K
1.3 bar
1.2 bar
78.8 K
1.15 bar
6
Turboexpander
1.2 bar
78.8 K
Liquid
5f
Phase separator
Effectiveness
Eff ti
off heat
h t exchanger
h
1,1
1 1
Pinch point for heat exchanger 2, p
Efficiency of turbo expander,
Mass flow ratio diverted through Turbo expander,
Initial Values
Yield, y
Enthalpy of cold fluid at outlet of HX1,h9
Unknown Variables:
4g
g
Pinch, p
8
Temperature
Tp = T4 g p
4g
Distance
Fig. 11
Q h 9 = 1h 2 '+ h 8 (1 1 )
h9 = 1h2 '
1
1.
h8 =
[h 9 (1 y)(1 ) h 2 (1 ) + h 4g (1 ) h p (1 y)]
[( )(1 y)]
[h 4g (1 ) + (1 y)(h 8 h p )]
2.
h3 =
3.
h 9 = 1h 2 '+ (1 1 )h 8
(1 )
Fig. 12
iii. Turbo-expander
From the figure,
From Allprops, find s3, at h3 and p3.
3 6s is the isentropic expansion
3-6s
3-6 is the actual expansion
s 6s = s 3
h6 can b
h6s
be gett ffrom p6s
6 and
d s6s.
6
(h 3 h 6 )
( h 3 h 6s )
Temperatture, T
h 6 = h 3 ( h 3 h 6s )
Entropy,s
Fig. 13
iv. Mixer-2
Applying energy balance equation for the mixer, enthalpy at outlet of mixer is
h7 =
[h 6 + (1 y)h 5g ]
(1 y)
1.3 bar
1.2 bar
1.2 bar
78.8 K
v .Heat Exchanger 2
Fig. 14
h4 =
[h 3 (1 ) (1 y)(h 8 h 7 )]
(1 )
Fig. 15
5g
vi. JT valve
Throttling is an isenthalpic expansion process. Equating the enthalpies
before and after throttling
4
7.9 bar
100.13 K
1.2 bar
78.8 K
h5 = h 4
x5 =
( h 5 h 5f )
( h 5g h 5f )
Fig. 16
vii. Yield
The liliquid
Th
id yield
i ld obtained
bt i d per kkg off gas passing
i th
through
h th
the th
throttling
ttli valve
l
Is (1-x5),
Here (1-) kg of gas passing through the throttling valve is
y = (1 )(1 x 5 )
3
4
4g
6
7
T-S
T
S Diagram
5g
Fig. 18
Parametric Study
Parametric Study
A minimum
i i
effectiveness
ff ti
i
is
present after which the yield
becomes zero.
Requirement
of
high
effectiveness increases with
increase
in
compression
pressure
Fig. 20 Effect of Variation of
effectiveness 1 of HX-1
Parametric Study
Parametric Study
y
yield
increases with increase in
compression pressure.
3. M
Major
j C
Components
t off Li
Liquefier
fi
i.
Compressor
i. Compressor
This
compressor
is
available
in
our
laboratory with oil filter,
pressure controller and
p
pipe layout.
ii Cold Box
ii.
FIN TYPES
120 45 K
120.45
82.22 g/sec
Pressure at inlet
8 bar
0 05 bar
0.05
Cold Fluid
Inlet temperature
100.74 K
Outlet temperature
305 8 K
305.8
Mass flow rate
78.68 g/sec
Pressure at inlet
Allowable pressure drop
1.15 bar
0.05 bar
INPUT :
1 Fin frequency,
1.
frequency f
2. Fin thickness, t
3. Fin length, lf
4. Fin height,
g h
5. Plate thickness, p
714 fins/m
0.2 mm
1.5 mm
6.3 mm
0 8 mm
0.8
CALCULATION :
1. Fin spacing, s =
(1 ft )
f
Fi Parameters
Fin
P
t
S- fin spacing
H- fin height
T- fin thickness
ll- strip length
Geometry of a typical offset strip fin surface
Assume width of heat exchanger, W and No. of layers in hot and cold side, nh and nc.
11. Total area between plates, Afr = b n W
12. Total free flow area, Aff = Afrf
m
13. Core mass velocity, G =
Aff
14. Reynolds number, Re = GDe
For Re>Re*,
j = 0.18(Re)
(R ) 0.42 ( ) 0.288 ( ) 0.184 ( ) 0.005
f = 0.32(Re) 0.286 ( )0.221 ( ) 0.185 ( ) 0.023
F R
For
Re<Re*,
R *
j = 0.36(Re) 0.51 ( ) 0.275 ( ) 0.27 ( ) 0.063
f = 4.67(Re) 0.70 ( )0.196 ( ) 0.181 ( ) 0.104
Where
h
s
l
=
s
t
=
s
[1 + 5.269 10
[1 + 7.669 10
Where
s
h
t
=
l
De =
t
s
2shl
2(hl + ht + sl ) + ts
0.1
0.1
For Re <Re
<Re* (Laminar Flow)
( 2 * hc )
(K f * t )
f =
(G j c )
(Pr)0.667
tanh( Ml )
( Ml )
A
20. Surface effectiveness, o = 1 ( f A ) (1 f )
o
21 Overall
21.
O
ll h
heatt ttransfer
f coefficient,
ffi i t
1
1
pAo
(A /A )
=
+
+ oc ohh
U o oh hh KW AW
oc hc
1 ( Af / Ao )
UoAo
23. Heat transfer area may now be calculated as Ao =
Uo
De * Ao
4 * Aff
1
1 CR .
ln
(1 CR ) 1
(UA)lc
U
(1 Cr )
(1 Cr )(1 + y )
(1 + )y
1 (1 + )y
15. -
= ( y /(1 + y )1 / 2
16. -
(1 + )
(1 )
(1 Cr ) * N.T .U
1 + NTU Cr
(1 Cr )
18. Ineffectiveness (1 ) =
exp(( r1 ) Cr
17 17.
19. Effectiveness = [1 (1 )]
r1 =
M
Manglik
lik
Joshi
J
hi &
Webb
Core length
2002
1888
2277
Core width
180
180
180
Core Height
165
165
165
10
10
10
Cold fluid
Inlet temperature
Outlet temperature
Mass flow rate
Pressure at inlet
Allowable pressure drop
91.38 K
100.81K
78 68 g/sec
78.68
1.2 bar
0.05 bar
5. Design Turboexpander
Nitrogen
124 K
7.97 bar
1.2 bar
76.46 g/s
NIT ROURKELA
Brake compressor
Shaft
Turbine Wheel
Turboexpander Assembly
Brake
Brake nozzle compressor
shaft
Nozzle
Tilting Pad
Bearing
Aerostatic
thrust Bearing
g
NIT ROURKELA
Turbine wheel
Diffuser
NIT ROURKELA
ds
ns
Specific speed and specific diameter of the turbine wheel are calculated
by
Q3
s =
(1)
3/ 4
(hin3s )
D2 ( hin 3 s )1 / 4
ds =
Q3
Where
Q3 = k1 * Qex
(2)
(3)
(4)
Dtip
=
= 0.6
D2
(5)
D hub
=
= 0.425
Dtip
(6)
Power produced,
produced
(7)
Number of blades=10
Thickness of blades= 0.6 mm
Blade height at inlet,
b
( D
m tr
Z tr t tr ) 2C
((8))
m 2
: 1,38,778 rpm
: 17.8 mm
8.9 mm
Number of blades
10
Thickness of blades
: 0.6 mm
NIT ROURKELA
Velocity Triangle
C2
187.38
C3
110.31
W2
94 48
94.48
W3
152 97
152.97
U2
215.11
U3
96.8
60.38o
45.92o
26o
95o
NIT ROURKELA
Air/Nitrogen
pressure
Inlet total p
: 4.1 bar
: 300 K
Expected efficiency
: 60%
NIT ROURKELA
Specific
p
speed
p
and Specific
p
diameter are g
given by
y
s =
Q1
hs
(9)
3/ 4
D h
ds = 2 s
Q1
1/ 4
(10)
(11)
= power input
i
t ffactor
t
=1
1.02
02
sf = Slip factor = 0.9
NIT ROURKELA
(12)
15 mm
Diameter at outlet
33.7 mm
3 mm
Number of blades
12
Thickness of blades
0.75 mm
NIT ROURKELA
: 14534 rad/sec
Dimensions of Nozzle
Wt = Throat width
Dt = Throat diameter
Dn = Nozzle diameter
D2 = Turbine inlet diameter
Cn = Chord length
m tr
= 1 . 84 mm
Width at throat
throat, w t =
Z n bt t C t
((13)
3)
Cmt
0
tan
=
29
.
06
=
Throat angle,
g , t
C
t
(14)
(15)
Dt + wt 2 wt Dt Cos t = 29 .8 mm
2
(16)
2 u S
u
z 1 + cot +
sin s
NIT ROURKELA
2
2
= 4 .4
mm
(17)
Design of Diffuser
1 Kinetic energy at the rotor outlet should be recovered using a
1.
diffuser.
2. The best suited diffusing
g angle
g
which minimizes the loss in
pressure recovery is 5o-6o
Aex =
Qex 0.0148
=
= 0.00087
0 00087 m 2
17
C ex
(18)
Design Of Shaft
We have chosen the diameter of the shaft and checked for maximum
stress and critical speed .
Di
Diameter
t off the
th shaft
h ft = 16 mm
The length of the shaft and dimension of the collar depends upon the
dimensions of the bearings.
Length of the shaft
= 108.1
108 1 mm
NIT ROURKELA
(14534.67 0.036)
= 116.27 m/s
2
1
2
=
Vsurf
= 225 < 230 MPa
Stress at the root of the collar,
Vsurf = d 2 =
(19)
(20)
f = 0 .9 d l
1.80 1011
= 6650.09 Hz
8440
=3,99,005 rpm
Which is below the operating speed of 1,38,778 rpm
NIT ROURKELA
(21)
ii.
iii.
Thrust
ust Foil
o Bearing
ea g
B. Journal Bearings
NIT ROURKELA
i.
ii.
iii.
iv.
Neutral
Upper Thrust Plate
Thrust Collar
Shaft
Lower Thrust Plate
W
NIT ROURKELA
NIT ROURKELA
Bump Foil
Advantages:
Bearing
Housing
1 Self-acting.
1.
Self-acting
2. Rotor dynamically stable.
3. Accommodate thermal growth.
4. Accommodate Misalignment.
5. High ability to damp.
6. Better wear resistant.
T FFoilil
Top
Aerodynamic
A
d
i
pressure
determines
the
load
carrying capacity of shaft
and it deforms the top foil
and bump foil to prevent
contact between rotor and
bearing, which results zero
wear of the bearings.
Bearing Block
Modification in Turboexpander
Present Model
Modified Model
Supporting structures
NIT ROURKELA
Supporting structures
A Cold
A.
C ld end
d casing
i
1. The cold end housing is the lower
mostt partt which
hi h is
i capable
bl to
t hold
h ld the
th
Teflon insulation rings so that the heat
could not enter into itit.
2. It contains nozzle diffuser centrally.
3 It takes the process gas inside and
3.
cooled gas comes out centrally from
the diffuser.
NIT ROURKELA
Supporting structures
B. Bearing block
The bearing housing is the central
component providing support to the
t
two
j
journal
l bearings
b i
and
d the
th two
t
thrust bearings.
NIT ROURKELA
Supporting structures
C Warm end housing
C.
1. The warm end housing has a nozzle to
p
which is fitted
the brake compressor
above brake compressor by shrink fit
operation.
2. There is an inlet and exit tube through
which air is sucked in and compressed
air goes out.
out
NIT ROURKELA
Turbine wheel
Brake compressor
Shaft
NIT ROURKELA
Nozzle Diffuser
N
Nozzle
l cover
Spacer
Compressor end
NIT ROURKELA
B i bl
Bearing
block
k
C
Cold
end housing
v. J
JT Valve
a e
3D model of Liquefier
Liq. Nitrogen exit
Turboexpander
Exit to the Compressor
Inlet to the HX1
HX2
Cold Box
HX1
Phase separator
NIT ROURKELA