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Reduction of Graphene Oxide Via - Ascorbic Acidw
Reduction of Graphene Oxide Via - Ascorbic Acidw
COMMUNICATION
www.rsc.org/chemcomm | ChemComm
Received (in Cambridge, UK) 27th August 2009, Accepted 4th December 2009
First published as an Advance Article on the web 24th December 2009
DOI: 10.1039/b917705a
We demonstrated that the individual graphene oxide sheets can
be readily reduced under a mild condition using L-ascorbic acid
(L-AA). This simple approach should nd practical applications
in large scale production of water soluble graphene.
Ever since the discovery of the advantageous properties of
graphene, the challenge has been to produce individual
graphene sheets in a bulk quantity.15 In the last few years,
several approaches, such as micromechanical exfoliation of
graphite,1 chemical vapor deposition,26 and solution-based
chemical reduction of graphene oxide (GO) to graphene,710
have been developed. Among these methods, one may mention
the solution-based chemical reduction of GO because it has
advantages of low-cost and bulk-scale production. However,
the low solubilities of the chemically reduced graphene oxide
(CR-GO) sheets in water and most organic solvents, and the
strong pp stacking tendency between CR-GO sheets lead to
the formation of irreversible agglomerates unless the capping
reagents (polymers or surfactants) are used. On the other
hand, the capping reagents may aect the properties of the
graphene sheets, accordingly limited their practical applications.
Additionally, in the most successful cases, the chemical reduction
of the GO was conducted using hydrazine or hydrazine
hydrate as the reducing agent. However, because hydrazine
and hydrazine hydrate are highly poisonous and explosive,11
precautions must be taken when large quantities of hydrazine
or hydrazine hydrate are used. Consequently, a new approach
for eectively converting GO into stable graphene sheets
under mild conditions needs to be explored.12,13
L-Ascorbic acid (L-AA), having a mild reductive ability and
nontoxic property, is naturally employed as a reducing agent
in living things,1416 and has also been used as a primary
reductant in the laboratory.1720 Herein, we present a facile
approach for reducing GO sheets using L-AA as a reductant in
an aqueous solution at room temperature. As will be shown,
besides the pronounced reduction capability to GO, the
oxidized products of L-AA may also play a role as a capping
a
Fig. 2 FT-IR (a) and Raman (b) spectra of GO before (1) and after
being reduced via L-AA for 12 (2), 24 (3), and 48 (4) hours.
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