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Acom - 91291757 Steel
Acom - 91291757 Steel
AV E S TA S H E F F I E L D C O R R O S I O N M A N A G E M E N T A N D A P P L I C AT I O N E N G I N E E R I N G
Pressure vessel design rules are changing. The European Directive on pressure
equipment is effective from December 1999. The new harmonised European
code for unfired pressure vessels will later be available for general use, and
gradually replace current national codes.
Design stresses for austenitic grades are based on Rp1.0 yield strength and
Rm tensile strength at the design temperature. Duplex grades follow ferritic
principles with Rp0.2 and RmRT. ASME VIII-1 adopted in July 1999 the
increased stress values from Code Case 2278, where the traditional safety factor
to Rm tensile strength is reduced from 4 to 3.5.
Resulting wall thicknesses are compared for codes and steel grades.
The potential to utilise duplex steel more efficiently is discussed.
INTRODUCTION
New technical rules for pressure vessels
were implemented in Europe in the end
of 1999. They are based on the
Directive on the approximation of the
laws of the Member States concerning
pressure equipment from 1997. Of
particular interest for stainless steel are
the harmonised standards, EN 13445
Unfired pressure vessels and EN
10028-7 Stainless steel flat products
for pressure purposes, which have
been drawn up by standardisation
committees during the 1990s.
1-2000
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adoption of welding processes in the
1930s. Empirical diagrams and
formulas were developed to give
guidance in material selection and
fabrication: The well-known Schaeffler
diagram [5] got many followers [6],
which give popular illustrations to the
composition areas for:
the basic structures: Ferrite (F),
Martensite (M) and Austenite (A)
the dual structures: Semiferrite (fM),
Supermartensite (aM), Unstable
austenite (mA), Duplex (fA)
intended precipitation hardening
(PH), unintended carbide and
intermetallic precipitates
Note that traditional austenitic grades
contain traces of ferrite. Grades without
ferrite are referred to as fully austenitic
(aA), and may be sensitive to
solidification cracking.
The diverse microstructures
determine the wide range of stainless
steel fabrication and use properties. It
would undoubtedly favour their use, if a
globally agreed system for grouping of
stainless steel after microstructure and
chemical composition could be
implemented.
The unique mechanical properties of
austenite were gradually considered in
the pressure vessel codes. In Europe,
safety against brittle fracture was
safeguarded by requirements on other
properties than mere tensile strength.
Material yield or 0.2% proof strength
became controlling. For austenitic
stainless steel there was a change to
1.0% proof strength during the period
196575, in connection to adoption
of the SI-system within steel
standardisation. The earlier unit kg/mm2
was replaced by N/mm2, but
unfortunately not by MPa.
In the 1950s nitrogen was developed
as an alloying element together with
manganese, and in the 60s it was added
to the common 18-8 and 17-10-2 grades
[7]. First added as metal, later as gas.
An addition of 0.1% N will increase the
minimum yield strength with 30%,
from 210 to 280 N/mm2, and improves
the pitting resistance. Furthermore does
nitrogen substitute for carbon and
nickel as austenite stabilisers. New steel
grades developed since then in Sweden
have to a large extent been based on the
ESSENTIAL SAFETY
REQUIREMENTS AND
DESIGN CRITERIA
PED specifies in Annex 1 the essential
safety requirements that shall be met.
They are structured on design,
manufacturing and materials (Table 1).
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The manufacturer shall analyse the
hazards as basis for design and
construction. Design for adequate
strength should consider traditional
factors like internal/external pressure,
ambient/ operational temperature,
reaction forces, corrosion, creep, fatigue
etc. and is made by the methods:
design by formulas (DBF)
design by analysis (DBA)
design by experimental procedure
(DBE)
Table 1.
Overview of essential safety requirements.
Design
Manufacturing
Materials
Procedures for:
forming
joining
non-destructive tests
heat treatment
traceability
Final assessment
insp. of equipment/documents
proof test
Marking and labelling
Operating instructions
Table 2.
Some differences between EN 13445 and ASME VIII-1.
Rule sector
EN
ASME
Design
Units
Allowable stresses calculated by
Ferritic steel factors
applied on
Austenitic steel factors
applied on
C and N/mm2
Designer
1.5
Rp0.2T
and
1.5 or 1.2
Rp1.0T
and
F and ksi
Committee, tables for grades/products
1.5
3.5
Rp0.2RT, Rp0.2T and RmRT, RmT
1.5 or 1.11
3.5
Rp0.2RT, Rp0.2T and RmRT, RmT
Manufacture
Stress at proof test ferritic
austenitic
min. Rp0.2RT/1.05
min. Rp1.0RT/1.05 (max. RmRT/2)
1.5 RmRT/3.5
1.5 RmRT/3.5
Materials
Flat product standard grades
Revision period for standards
New grade approval
Steel data
39 + 9 EN special in EN 10028-7
5 year
EMDS
Newer RT and HT min. values
2.4
RmRT
3
RmT
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ALLOWABLE STRESSES AND
MINIMUM THICKNESSES
Today the designer tries to select the
optimum grade, whereas the possibility
to choose between code systems is
limited. Manufacturers and users
continue with systems they are used to.
Different legal and technical rule
structures, diverse units, designations
and properties complicate comparison.
If we however limit the comparison to
consider primary membrane stresses
and static conditions, the general
tendencies may be shown with the help
of computer conversion. The results for
RT and 200C are given as thickness
index, where the EN thickness for basic
18-8/17-10-2/1.4301/1.4401/304/316 is
set to 10.0 (Table 3).
EN will allow 20% lower wall
thickness (25% higher stress) than
ASME for RT design with traditional
grades. The difference is reduced with
increasing temperature, to nil at 400C.
The EN advantage is even more
pronounced for nitrogen grades and the
newer austenitic and duplex grades,
where the difference in thickness is
35% at RT and 020% at 300/400C.
Within the code systems, EN gives
greater advantage for the newer grades
(2035% thinner) than ASME (035%
thinner).
EN maximum design stresses for
austenitic grades are based on the
traditional formula Rp1.0/1.5 but allows
for grades with elongation over 35%
also the lower of Rp1.0/1.2 and Rm/3.
This new principle gives generally
higher stresses, which are in the
range 10% to +20% of current stresses
in national codes.
The new design stresses according to
EN 13445 and ASME VIII-1 are
compared in Figure 1.
In the long perspective it is likely
that harmonising developments will
reduce differences between the systems.
Initiatives have also lately been taken
within ISO to investigate the
possibilities for international
recognition of regional and national
codes.
Table 3.
Resulting wall thicknesses (index) according to EN 13445 and ASME VIII-1.
Steel type
Austenitic
Cr-Ni-Mo
Temp.
EN
ASME
EN vs ASME
18-8/17-10-2
RT
200C
10.0
10.0
12.5
10.2
20% thinner
2%
RT
200C
8.2
8.9
12.5
10.2
35%
15%
20-18-6
RT
200C
7.6
7.1
9.3
7.9
20%
10%
22-5-3
RT
200C
6.5
6.3
9.8
8.0
35%
20%
17-10-2
RT
200C
Do. + Nitrogen
New austenitic
Duplex
Coldstretched
POTENTIAL
DESIGN STRESSES
FOR DUPLEX GRADES
The austenitic grades eventually got
special criteria for allowable stresses
that took advantage of their specific
non-brittle and work hardening
behaviour.
Today duplex grades are evaluated
according to ferritic grade criteria.
Their behaviour is however more
similar to austenitic grades, with energy
absorbed before ductile fracture that is
twice the common ferritics. Can
austenitic criteria be justified for
duplex grades?
Two basic questions then have to be
answered:
maximum allowed stresses for
prevention of brittle fracture
maximum allowed stresses for elastic
behaviour.
Requirements for prevention of
brittle fracture is treated by the EN
code in Annex D. Methods are defined
to establish impact energy
requirements. A model may be made
for empirical relations between fracture
toughness, yield strength, wall
thickness and temperature [14].
Elastic and plastic behaviour may be
measured in biaxial loading of
cross-shaped specimens. Established
stress-strain response is then applied to
a newly developed constitutive model,
to define the grade specific parameters
[15]. The constitutive model is used in
(6.2)
(6.4)
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300
300
CSD
EN - spec.
250
250
EN
18-8 + Coldstretched
VIII-1 rev.
MPa
VIII-1
200
200
150
150
100
100
18-8 + Nitrogen
18-8
50
50
MPa
100
200
300
400
500
300
300
250
250
200
200
150
150
100
100
20-18-6 + Nitrogen
100
200
300
400
500
400
500
50
50
0
0
100
200
300
Temp. (C)
400
500
100
200
300
Temp. (C)
Figure 1.
Maximum allowed design stresses in EN and ASME between RT and 400C for:
Austenitic 18-8, 18-8 +Nitrogen, 20-18-6 +Nitrogen and Duplex 22-5-3 +Nitrogen.
Comparison with 18-8 according to the Swedish Cold-stretching Directions (CSD).
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Table 4.
Standard and potential properties for duplex 22-5-3. Resulting wall thickness (index).
Standard
Steel
Product
EN 10028-7
1.4462
ASTM A240
S31803
CR strip
HR plate
CR/HR
CR/HR strip
Potential
CONCLUSIONS
Wall thickness, RT
EN
ENalt ASMErev
max. 6 mm
max. 75 mm
max. 50 mm
480
460
450
max. 8 mm
500
580
660
640
620
20
25
25
6.5
750
25
5.5
REFERENCES
1. MARTIN D BERNSTEIN. Design
criteria for boilers and pressure vessels
in the USA. 6th Int. Conf. on Pressure
Vessel Technology, Beijing, 1988,
p 111 136
2. WERNER E HOFFMANN. Design
criteria of boilers and pressure vessels
in the Federal Republic of Germany.
6th Int. Conf. on Pressure Vessel
Technology, Beijing, 1988, p 1731
3. J H G MONNYPENNY. Stainless iron
and steels. Chapman & Hall, London
1926, p 215 and 254
4. MATS LILJAS. Superaustenitic
stainless steels: development,
fabrication and use. Scandinavian
Journal of Metallurgy 1998;27
5. A L SCHAEFFLER. Selection of
austenitic electrodes for welding of
dissimilar metals. The Welding Journal
1947;10, p 601 620
6. MANFRED SCHIRRA. Die historischempirische Entwicklung des
Gefgediagrammes der CrNi-Sthle.
Stahl und Eisen 1992; 10, p 117120
7. MATS LILJAS, JAN-OLOF NILSSON.
Development of commercial nitrogenrich stainless steels. 5th Int. Conf.
on High Nitrogen Steels. EspooStockholm, 1998
8. JAN JONSON. Coldstretched austenitic
stainless steel pressure vessels. 2nd Int.
Conf. on Pressure Vessel Technology,
San Antonio, USA, 1973, p 11571165
9. CSD. Cold-stretching directions.
SIS-Pressure vessel commission, 1991
10. VdTV WB 411 Kaltgestreckte
nichtrostende Sthle. Verband der TV,
1995
5.6
9.8
5.2
8.1