Professional Documents
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Polymers Libre
Polymers Libre
ENGINEERING POLYMERS
AND SPECIALITY
POLYMERS
TABLE OF CONTENTS
1 COMMODITY POLYMERS
1.1.2 PROPERTIES
1.1.3 APPLICATIONS
1.2.2 PROPERTIES
1.2.3 APPLICATIONS
1.3.2 PROPERTIES
1.3.3 APPLICATIONS
1.4.2 PROPERTIES
1.4.3 APPLICATIONS
1.5.2 PROPERTIES
1.5.3 APPLICATIONS
1.6.2 PROPERTIES
1.6.3 APPLICATIONS
1.7.2 PROPERTIES
1.7.3 APPLICATIONS
1.8.2 PROPERTIES
1.8.3 APPLICATIONS
1.9.2 PROPERTIES
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1.9.3 APPLICATIONS
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10
10
1.10.2 PROPERTIES
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1.10.3 APPLICATIONS
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2 ENGINEERING POLYMERS
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12
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2.1.2 PROPERTIES
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2.1.3 APPLICATIONS
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13
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2.2.2 PROPERTIES
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2.2.3 APPLICATIONS
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2.3 POLYSULFONE
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14
2.3.2 PROPERTIES
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2.3.3 APPLICATIONS
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2.4 POLYOXYMETHYLENE
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15
2.4.2 PROPERTIES
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2.4.3 APPLICATIONS
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16
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2.5.2 PROPERTIES
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2.5.3 APPLICATIONS
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16
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2.6.2 PROPERTIES
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2.6.3 APPLICATIONS
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17
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2.7.2 PROPERTIES
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2.7.3 APPLICATIONS
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18
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2.8.2 PROPERTIES
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2.8.3 APPLICATIONS
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18
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2.9.2 PROPERTIES
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2.9.3 APPLICATIONS
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19
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2.10.2 PROPERTIES
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2.10.3 APPLICATIONS
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3 SPECIALTY POLYMERS
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21
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3.1.2 PROPERTIES
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3.1.3 APPLICATIONS
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22
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3.2.2 PROPERTIES
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3.2.3 APPLICATIONS
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3.3.2 PROPERTIES
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3.3.3 APPLICATIONS
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23
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3.4.2 PROPERTIES
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3.4.3 APPLICATIONS
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24
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3.5.2 PROPERTIES
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3.5.3 APPLICATIONS
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24
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3.6.2 PROPERTIES
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3.6.3 APPLICATIONS
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25
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3.7.2 APPLICATIONS
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3.8 KEVLAR
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3.8.2 PROPERTIES
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3.8.3 APPLICATIONS
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3.9.2 PROPERTIES
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3.9.3 APPLICATIONS
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3.10.2 PROPERTIES
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3.10.3 APPLICATIONS
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4 REFERENCES
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LIST OF FIGURES
FIGURE 1: REPEATING UNIT OF PE _________________________________________________ 2
FIGURE 2: REPEATING UNIT OF PP _________________________________________________ 2
FIGURE 3: REPEATING UNIT OF PS _________________________________________________ 4
FIGURE 4: REPEATING UNIT OF PVC _______________________________________________ 5
FIGURE 5: RECYCLING SYMBOL OF HDPE ___________________________________________ 6
FIGURE 6: REPEATING UNIT OF PMMA ______________________________________________ 7
FIGURE 7: REPEATING UNIT OF PET________________________________________________ 8
FIGURE 8: REPEATING UNIT OF PMA _______________________________________________ 9
FIGURE 9: LLDPE GRANULES ___________________________________________________ 10
FIGURE 10: RECYCLING NUMBER OF LDPE _________________________________________ 11
FIGURE 11: REPEATING UNIT OF UHMW-PE ________________________________________ 12
FIGURE 12: REPEATING UNIT OF POLYTETRAFLUOROETHYLENE __________________________ 13
FIGURE 13: REPEATING UNIT OF POLYSULFONE ______________________________________ 14
FIGURE 14: REPEATING UNIT OF POM _____________________________________________ 15
FIGURE 15: REPEATING UNIT OF PBT______________________________________________ 16
FIGURE 16: REPEATING UNIT OF NYLON 6,6 _________________________________________ 17
FIGURE 17: MONOMERS IN ABS POLYMER __________________________________________ 18
FIGURE 18: REPEATING UNIT OF PPO _____________________________________________ 19
FIGURE 19: REPEATING UNIT OF PET______________________________________________ 20
FIGURE 20 : MOLECULAR STRUCTURE OF LCP VECTRAN _______________________________ 21
FIGURE 21 : MOLECULAR STRUCTURE OF PPV _______________________________________ 22
FIGURE 22: REPEATING UNIT OF PHBV ____________________________________________ 24
FIGURE 23: PREPARATION OF POLYCARBONATE ______________________________________ 25
FIGURE 24: BIODEGRADABLE PLASTIC _____________________________________________ 26
FIGURE 25: KEVLAR ___________________________________________________________ 27
FIGURE 26: POLYHYROXYBUTYRATE ______________________________________________ 28
FIGURE 27: MOLECULAR STRUCTURE OF POLYPYRROLE________________________________ 28
1.1.2 PROPERTIES
It is a high molecular weight, relatively insensitive to most solvent (used for chemical
reaction vessels or pipe).
Amorphous density at 25oC is 0.855 g/cm3.
Crystalline density at 25oC is 1.00 g/cm3.
Tg is -78C and Tm is typically 105-115C.
The thermal conductivity is good, however Tm of PE is low - limited applications at
high temperature.
Considerable stiffness and strength/toughness.
Resistant to chemicals.
Low cost polymer, ease of forming, and permeability to gas and ease of processing.
1.1.3 APPLICATIONS
1.2.2 PROPERTIES
1.2.3 APPLICATIONS
Used in packaging and labeling, textiles (e.g., ropes, thermal underwear and
carpets), stationery, plastic parts and reusable containers of various types,
laboratory equipment, loudspeakers, automotive components, and polymer
banknotes.
Its most common medical use is in the synthetic, nonabsorbable suture Prolene,
manufactured by Ethicon Inc.
Polypropylene has been used in hernia and pelvic organ prolapse repair
operations to protect the body from new hernias in the same location.
Many plastic daily life items are made from polypropylene.
1.3.2 PROPERTIES
1.3.3 APPLICATIONS
1.4.2 PROPERTIES
1.4.3 APPLICATIONS
It is used for sewerage pipes and other pipe applications where cost or vulnerability
to corrosion limit the use of metal.
It is a popular material for window and door frames.
By adding plasticizers, it can become flexible enough to be used in cabling
applications as a wire insulator.
Roughly half of the world's polyvinyl chloride resin manufactured annually is used for
producing pipes for municipal and industrial applications.
1.5.2 PROPERTIES
1.5.3 APPLICATIONS
1.6.2 PROPERTIES
1.6.3 APPLICATIONS
1.7
PMMA is a versatile material and has been used in a wide range of fields and
applications such as: rear-lights and instrument clusters for vehicles, appliances and
lenses for glasses.
PMMA in the form of sheets affords shatter resistant panels for building windows,
skylights, bullet proof security barriers, signs & displays, sanitary ware (bathtubs),
LCD screens, furniture and many other applications.
It is also used for coating polymers.
Methacrylate polymers are used extensively in medical and dental applications.
It may also be referred to by the brand name Dacron; in Britain, Terylene; or, in Russia
and former Soviet Union, Lavsan.
PET is referred to by its common name, "polyester," whereas the acronym "PET" is
generally used in relation to packaging.
1.7.2 PROPERTIES
1.7.3 APPLICATIONS
1.8.2 PROPERTIES
1.8.3 APPLICATIONS
1.9.2 PROPERTIES
1.9.3 APPLICATIONS
It is used for plastic bags and sheets (where it allows using lower thickness than
comparable LDPE), plastic wrap, stretch wrap, pouches, toys, covers, lids, pipes,
buckets and containers, covering of cables and geomembranes.
LLDPE is used in packaging, particularly film for bags and sheets.
Used in agricultural films, saran wrap, and bubble wrap.
Cable covering, toys, lids, buckets, containers and pipe.
BRIEF INTRODUCTION
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1.10.2
1.10.3
PROPERTIES
APPLICATIONS
LDPE is widely used for manufacturing various containers, dispensing bottles, wash
bottles, tubing, plastic bags for computer components, and various molded
laboratory equipment.
Its most common use is in plastic bags.
Trays and general purpose containers
Corrosion-resistant work surfaces
Parts that need to be weldable and machinable.
Plastic wraps
2 ENGINEERING POLYMERS
Engineering polymers are materials with exceptional mechanical properties such as
stiffness, toughness, and low creep that make them valuable in the manufacture of
structural products like gears, bearings, electronic devices, and auto parts. Engineering
polymers are a group of polymers that have better mechanical and/or thermal properties
than the more widely used commodity polymers (such as polystyrene, PVC,
polypropylene and polyethylene).
Being more expensive, engineering polymers are produced in lower quantities and tend
to be used for smaller objects or low-volume applications (such as mechanical parts),
rather than for bulk and high-volume ends (like containers and packaging). These plastics
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normally are not available to the public and frequently are available only to manufacturers
in raw material form in order to be melted and molded into end products.
The term usually refers to thermoplastic materials rather than thermosetting ones.
Examples of engineering plastics include acrylonitrile butadiene styrene (ABS), used for
car bumpers, dashboard trim and Lego bricks; polycarbonates, used in motorcycle
helmets; and polyamides (nylons), used for skis and ski boots.
Engineering polymers have gradually replaced traditional engineering materials such as
wood or metal in many applications. Besides equaling or surpassing them in
weight/strength and other properties, engineering polymers are much easier to
manufacture, especially in complicated shapes.
2.1.2 PROPERTIES
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2.1.3 APPLICATIONS
UHMWPE sheet has been used as synthetic ice in ice rinks where ambient
temperatures or energy costs make it impractical to create and maintain normal ice.
UHMWPE sheet is also cut into small blocks to be used as a brake pad material for
mountain bike trials rim brakes.
UHMWPE is a successful biomaterial for use in hip, knee, and for spine implants.
UHMWPE is also used in the manufacture of Hydraulic Seals and Bearings.
UHMWPE fibers are used in armor, in particular, personal armor and on occasion as
vehicle armor, cut-resistant gloves and bow strings.
2.2.2 PROPERTIES
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2.2.3 APPLICATIONS
2.3 POLYSULFONE
2.3.1 BRIEF INTRODUCTION
Polysulfone describes a family of thermoplastic polymers. These polymers are known
for their toughness and stability at high temperatures. They contain the subunit arylSO2-aryl, the defining feature of which is the sulfone group.
Due to the high cost of raw materials and processing, polysulfones are used in specialty
applications and often are a superior replacement for polycarbonates.
2.3.2 PROPERTIES
Its Tg is 185 C.
Mechanically, polysulfone has high compaction resistance, recommending its use
under high pressures.
These polymers are rigid, high-strength, and transparent.
Polysulfone is highly resistant to mineral acids, alkali, and electrolytes, in pH
ranging from 2 to 13.
Polysulfone has one of the highest service temperature of all melt-process able
thermoplastics.
2.3.3 APPLICATIONS
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2.4 POLYOXYMETHYLENE
2.4.1 BRIEF INTRODUCTION
Polyoxymethylene (POM), also known as acetal, polyacetal and polyformaldehyde is an
engineering thermoplastic used in precision parts requiring high stiffness, low friction and
excellent dimensional stability. As with many other synthetic polymers, it is produced by
different chemical firms with slightly different formulas and sold variously by such names
as Delrin, Celcon, Duracon and Hostaform.
2.4.2 PROPERTIES
2.4.3 APPLICATIONS
The material is widely used in the automotive and consumer electronics industry.
The M16 rifle's stock and other parts are made of it.
Insulin pen and Metered dose inhalers (MDI).
Hardware, locks, handles, hinges.
Packaging: aerosol cans, vehicle tanks.
Clothing: zippers.
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2.5.2 PROPERTIES
2.5.3 APPLICATIONS
2.6.2 PROPERTIES
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2.6.3 APPLICATIONS
2.7.2 PROPERTIES
2.7.3 APPLICATIONS
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It is used for ball bearing cages, electro-insulating elements, pipes, profiles and
various machine parts.
Other popular applications are: carpet fibres, apparel, airbags, tyres, zip ties, ropes,
conveyor belts, hoses and the outer layer of turnout blankets.
Nylon 6-6 is also a popular guitar nut material.
2.8.2 PROPERTIES
2.8.3 APPLICATIONS
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2.9.2 PROPERTIES
2.9.3 APPLICATIONS
PPE blends are used for structural parts, electronics, household and automotive
items that depend on high heat resistance, dimensional stability and accuracy.
They are also used in medicine for sterilizable instruments made of plastic.
BRIEF INTRODUCTION
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It may also be referred to by the brand name Dacron; in Britain, Terylene; or, in Russia
and former Soviet Union, Lavsan.
PET is referred to by its common name, "polyester," whereas the acronym "PET" is
generally used in relation to packaging.
2.10.2
2.10.3
PROPERTIES
APPLICATIONS
3 SPECIALTY POLYMERS
Specialty polymers are polymers having properties and characteristics specially
engineered for specific purposes. They are ranged from mono-functional to
multifunctional polymers. Specialty polymers are specifically designed to serve a specific
purpose.
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They are made by keeping in mind where they are to be used, which chemical and
mechanical properties are to be needed and how they to be shaped are. Every intricate
detail is taken into consideration and their development is very sensitive if we talk about
high end specialty polymers. They can be as cheap as commodity polymers to extremely
expensive ones depending upon their area of application. Main classes of polymers which
fall under the category of specialty polymers are as follows:
Conducting Polymers, Liquid Crystal Polymers, Biodegradable Polymers, Biomedical
Polymers, Polymer Composites, Electroluminescent Polymers and more.
3.1.2 PROPERTIES
LCPs are extremely unreactive and inert, and highly resistant to fire.
Environments that deteriorate the polymers are high-temperature steam,
concentrated sulfuric acid, and boiling caustic materials.
LCPs have a high mechanical strength at high temperatures, extreme chemical
resistance, inherent flame retardancy, and good weatherability.
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3.1.3 APPLICATIONS
LCPs are useful for electrical and mechanical parts, food containers, and any other
applications requiring chemical inertness and high strength.
LCP is particularly attractive for microwave frequency electronics due to low relative
dielectric constants, low dissipation factors, and commercial availability of laminates.
Packaging Micro-electromechanical systems (MEMS) is another area that LCP has
recently gained more attention.
They are incorporated into various objects to enhance Fire retardant properties.
A
A
Figure 21 : Molecular Structure of PPV
3.2.2 PROPERTIES
It is diamagnetic in nature & has a very low thermal conductivity (10 13 S/ cm).
Tg is 85C and Tm is 285C.
It is water soluble, but its precursors can be manipulated in aqueous solution.
3.2.3 APPLICATIONS
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3.3.2 PROPERTIES
Lower densities.
Excellent resistance to corrosion & chemicals.
They show applications in limited temperature range as Polymer matrix flows at high
temperature.
High tensile strength & impact resistance.
3.3.3 APPLICATIONS
They are used in automobile parts, storage tanks, industrial flooring, plastic pipes,
etc.
They are extensively used in automobiles to reduce vehicle weight & boost fuel
efficiency.
3.4.2 PROPERTIES
Low density.
Resistance to high temperature.
Excellent resistance to corrosion.
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3.4.3 APPLICATIONS
They are used as structural components (like wings, body, stabilizers, etc.) of
aircrafts & helicopters.
They are used in making sports goods (rackets, archery, racing bicycles, etc.),
laptops, fishing rods, musical instruments, etc.
O
A
CH
CH2
O
O
CH2
CH
A
n
CH3
CH3
Figure 22: Repeating Unit of PHBV
3.5.2 PROPERTIES
PHBV is a thermoplastic polymer. It is brittle, has low elongation at break and low
impact resistance.
Primitive mechanical properties.
It is expensive and has low thermal stability.
3.5.3 APPLICATIONS
PHBV are used for controlled drug delivery as they are biocompatible &
biodegradable. Also it is non-toxic.
PHBV can be used as a sole structural material or as a part of degradable
composites.
PHBV can be used for films, blow molded bottles & as a coating on paper.
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3.6.2 PROPERTIES
Its Tm is 265C.
It has a good resistance (up to 140C) and has thermal stability.
High impact strength & tensile strength.
It has a tendency to yellow with long term ultraviolet exposure.
3.6.3 APPLICATIONS
They can be used for making electrical insulators, industrial plugs, sockets, switches,
covers of cell phones, laptops, papers, etc.
The production of CD, DVDs, and Blue ray Disc by injection molding of
polycarbonate.
It is also used for widescreens for motorcycles, golf carts, small planes & helicopters.
It can also be used for electronic display for use in mobile and portable device for
some LCD screens.
It can be laminated to make bullet-proof glass.
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inorganic salts. These polymers are found both naturally and synthetically made, and
largely consist of ester, amide, and ether functional groups.
3.7.2 APPLICATIONS
It can be used in food packing, foam for industrial packaging, film rapping, disposable
plastic packing material such as single serve cups, disposable food service items,
etc.
Polymers like Polylactic acids are used in controlled drug delivery because of
biocompatibility & biodegradability.
Cell transplantation using biodegradable polymers scaffolds offers possibility to
create completely natural new tissues & replace organ function.
These polymers are used as time release coating for fertilizers & pesticides, making
films for moisture & heat retention.
3.8 KEVLAR
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O
A
NH
NH
O
A
C
n
3.8.2 PROPERTIES
3.8.3 APPLICATIONS
Kevlar is often combined with carbon fibers & embedded in epoxy resins to form
hybrid composite that have the ability to withstand catastrophic impact.
It can also be used in light weight boat hulls, high performance race cars.
It can be used as cables for mooring lines, offshore drilling platforms, for parachute
lines, fishing lines, mountaineering ropes & pulley ropes.
It can be used in protective clothing & body armor.
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3.9.2 PROPERTIES
3.9.3 APPLICATIONS
PHB can be used for films, blow moulded bottles & as a coating on paper.
PHB are used for controlled drug delivery as they are biocompatible &
biodegradable. Also it is non-toxic.
PHB can be used as a sole structural material or as a part of degradable composites.
BRIEF INTRODUCTION
3.10.2
PROPERTIES
28
PPy is an insulator.
3.10.3
APPLICATIONS
PPy and related conductive polymers have two main application in electronic devices
and for chemical sensors.
PPy is also potential vehicle for drug delivery.
The polymer matrix serves as a container for proteins.
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4 REFERENCES
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