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Master Thesis/Internship

Topic Guide
2012-2013

Information..........................................................................................................................................................................................1

I.

CMOS Scaling R&D ................................................................................................................. 2


Defect characterization of hetero-epitaxial III-V layers for future high-performance sub-16 nm CMOS
transistors .................................................................................................................................................................................... 2
Random Telegraph Noise (RTN) and the ITRS Roadmap: is it the beginning of the end? ..................................... 3
Deposition and characterization of dielectric barrier films ............................................................................................ 4
Using variational calculus to solve Poisson's and Schroedinger's equations self-consistently within a single
loop: how far can we go? ......................................................................................................................................................... 5
Parallelization of CMOS time-dependent variability measurements............................................................................. 6
Modeling of leakage in very high permittivity dielectrics for DRAM applications..................................................... 7
Low damage etch: use of CF3I as reactant for patterning of 2.0 porous SiOCH materials.................................... 8
Post-etch ULK restoration strategies: effect of H2-CH4-based plasma treatments on dielectric recovery
of 2.0 porous SiOCH materials.............................................................................................................................................. 9
Plasma treatments of model polymers used in EUV lithography: PS and PMMA .................................................... 10
ESD reliability of high mobility FinFET devices for sub-14 nm CMOS....................................................................... 11
Evaluation of photoresist outgassing for extreme ultraviolet lithography ................................................................ 12
Methodologies for memory analysis using C-AFM.......................................................................................................... 13
Carbon nanotube contacts: electrical characterization of CNT Cu damascene contacts ................................14
Graphene synthesis and characterization .......................................................................................................................... 15
Growth of carbon nanotubes for future generations of interconnects..................................................................... 16
Atomic layer deposition for applications in nanotechnology ....................................................................................... 17
XRD study of nano-structured hetero-epitaxial III-V compound semiconductors for VLSI CMOS
applications ................................................................................................................................................................................ 18
Developing in-situ doping of III-V compound semiconductors by hetero-epitaxial MOCVD growth ..............18
Surface preparation and interface passivation of high mobility channel materials for beyond 14 nm
technology nodes ..................................................................................................................................................................... 19
Development of a fixed ramp rate breakdown voltage procedure for gate dielectric testing ............................20
Electrical evaluation and reliability assessment of local interconnects....................................................................... 20
Investigation of advanced resistance-switching (RRAM) memory cells ..................................................................... 21
Investigation and optimization of the electrical switching properties of Conductive Bridging RAM
memory cells (CBRAM) ......................................................................................................................................................... 22
Passivation of Ge for high-performance applications ..................................................................................................... 23
Graphene: device fabrication and characterization ......................................................................................................... 24
Graphene: device fabrication for optoelectronics........................................................................................................... 25
Characterization of ohmic contacts to high-mobility materials (Ge, III-V) ............................................................... 26
Spin transfer torque magnetic random access memory ................................................................................................ 27
Wet processing of high aspect ratio nanostructures...................................................................................................... 28

Master Thesis/Internship Topics 2012-2013

Surface chemistry of III-V semiconductors for cleaning applications ......................................................................... 29


The creation of nanoforces by microbubbles ................................................................................................................... 30
Galvanic corrosion in micro-bump with different bumping metallurgy ..................................................................... 31
Direct heteroepitaxy of III-V semiconductors on silicon mediated by strain-relaxed buffer layers ..................32
3D FIB/SEM structural analysis of nano-electronic devices .......................................................................................... 33
Carrier depth profiling with micro-probes on advanced ultra-shallow high-mobility CMOS semiconductor
structures ................................................................................................................................................................................... 34
Development of a professional data analysis package for the micro-four point probe (M4PP) ..........................35
Development of an industrial analysis-package in Visual C++ for SSRM-measurements ......................................36
Development of probes for nanoscale electrical measurements and manipulation in a nanoprober
system ......................................................................................................................................................................................... 37
Diamond probes more efficient and optimized yield assessment .......................................................................... 38
Advanced materials characterization using ion beam scattering ................................................................................. 39
Ultra high vacuum SSRM nanocontact modeling - Electrical and mechanical impacts of low temperatures
(70K) ........................................................................................................................................................................................... 40
Atomic Layer Deposition of ultrathin metal films for advanced nanoelectronic applications .............................41
In-situ molecular beam passivation of III-Sb compounds ............................................................................................... 42
Developing in-situ doping of III-V compound semiconductors by hetero-epitaxial MOCVD growth................42
Effect of confinement and position of dopants on the ionized impurity scattering limited mobility in a
few-dopant double gate junctionless FET or all-around gate cylindrical nanowire junctionless transistor ......43
Characterization and modeling of the junctionless III-V nanowire for novel device applications .....................44
Remote Coulomb, surface roughness and ionized impurity scattering in novel nanowire all-around gate
FET devices ................................................................................................................................................................................ 45
Symbolic analysis of logic cells for advanced technologies ............................................................................................ 46

II.

CMORE ...................................................................................................................................47
Design and modeling of a single sensor 3-axis gyroscope for IMUs (inertial measurement units) ....................47
Capacitive micromachined ultrasound transducers for imaging, telecom and power transmission
applications ................................................................................................................................................................................ 48
(NANO)PHononicS: MEMS/NEMS acoustic devices and circuits ............................................................................... 49
Nano relays and logic gates: designing at the nanoscale, in presence of nano adhesion forces ..........................50
MEMS-based loudspeaker ...................................................................................................................................................... 51

III. Smart Systems .......................................................................................................................52


Measurement and calibration of models for advanced photovoltaic modules ......................................................... 52
Life-time measurements and modeling of organic photovoltaic solar modules....................................................... 53
Machine learning on low power parallel architectures .................................................................................................. 54
Algorithm and architecture co-optimizations for cost and power constrained Signal processing system .......55

Master Thesis/Internship Topics 2012-2013

Complexity modeling and algorithm transformations for software defined radios................................................ 56


Collaborative spectrum sensing for cognitive radios...................................................................................................... 57
Development of integrated passives for cellular duplexer module in CMOS.......................................................... 58
Analog signal processing for medical signals ..................................................................................................................... 59
Radio-frequency communication with metal-oxide electronics on plastic ............................................................... 60

IV. HUMAN++..............................................................................................................................61
Light up your brain - An intracranial communication network ................................................................................... 61
Towards a non-linear time-varying I-V model for biomedical stimulation electrodes........................................... 62
Investigating the long term behavior of TiN as electrode material for cell interfacing technologies ................63
Localized electrical stimulation of in vitro neurons for guided growth ..................................................................... 64
Signal analysis of recorded electrical activity by advanced microelectrode arrays ................................................. 65
Improving the function, stability, and biocompatibility of carbon nanotube microelectrodes for neuroelectronic applications ............................................................................................................................................................ 66
Development of a test system for standards-compliance measurements for biopotential amplifiers ...............67
Study of effects of thinning & design of test structures for analog chips................................................................... 67
Signal processing algorithms for a neuronal interface chip ........................................................................................... 68
Data acquisition system for integrated cell interfacing systems .................................................................................. 68

V.

Energy......................................................................................................................................69
Degradation mechanisms in organic solar cells................................................................................................................ 69
Solving the Caldeira-Leggett model with balance equations......................................................................................... 70
Modeling ionic diffusion in solid-state materials for energy storage applications.................................................... 71
Bonding of cells to glass for next-generation c-Si PV modules .................................................................................... 72
Radio-frequency communication with metal-oxide electronics on plastic ............................................................... 73
Metal contacts for amorphous Si solar cell applications ................................................................................................ 74
Morphological control of organic bulk solar cells ........................................................................................................... 75
Spectral characterization of organic tandem solar cells................................................................................................. 76
Tunneling barriers for the passivation of metal contacts in silicon solar cells ......................................................... 76
Development of amorphous silicon deposition for silicon heterojunction solar cells........................................... 77
CIGSSe and CZTSSe films formation from selenization/sulfurization of metals and chalcogenide
compounds ................................................................................................................................................................................ 78
Optimization of the optical properties of the layers in a multi-junction solar cell ................................................. 79
Hydrogen generation with III-Nitrides and catalysts ...................................................................................................... 80
Novel semiconductor alloys for optoelectronics of the future ................................................................................... 80
Electrical characterisation of amorphous Si layers for solar cell applications .......................................................... 81
Characterization and power-loss analysis of interdigitated back contact (IBC) silicon solar cells .....................82

Master Thesis/Internship Topics 2012-2013

Reliability testing of c-Si solar cells with Cu plated metallization................................................................................ 83


Copper contact plating for advanced solar cell contacts .............................................................................................. 83
EBIC analysis of thin-film polycrystalline-silicon solar cells ........................................................................................... 84
Raman and EDS analysis for thin-film solar-cell applications ........................................................................................ 85
Organic solar-cell material characterization by TOF-SIMS ........................................................................................... 86
Characterization of organic materials using UHV conductive AFM at low temperatures....................................87
Characterization and modeling of Back-surface field formation in Si-based solar cells ......................................... 88
Initiation of random pyramid formation: impact of contamination and surface roughness ..................................89

VI. INVOMEC ...............................................................................................................................90


Visualisatie van DfX analyse feedback in een elektronisch ontwerp .......................................................................... 90
Pre-routing metal layer estimation ...................................................................................................................................... 91

VII. NERF........................................................................................................................................92
Studying the function of neural circuits.............................................................................................................................. 92
Design, prototyping and testing of miniaturized brain implants .................................................................................. 93

Master Thesis/Internship Topics 2012-2013

Information
Students from universities and engineering schools can apply for a master thesis and/or internship project at imec.
Imec offers topics in engineering and (industrial) sciences in different fields of research.
The topics are arranged according to the imec business programs. You can find more detailed information on each
research program under the heading Research on www.imec.be.
How to apply?
Send an e-mail with your motivation letter and detailed resume to the responsible scientist(s) mentioned at the
bottom of the topic description of your preference. The scientist(s) will screen your application and let you know
whether or not you are selected for a project at imec.
It is not recommended to apply for more than three topics.
For more information, go to the Internship and Master Thesis pages under the Education heading on our website.

1
Master Thesis/Internship Topics 2012-2013

I.

CMOS Scaling R&D


Defect characterization of hetero-epitaxial III-V layers for future high-performance
sub-16 nm CMOS transistors
As the silicon device scaling for future generations becomes increasingly difficult, alternative device structures and
high mobility channel materials like Ge (P-type), InGaAs (n-type), InSb have gained popular research interests.
However owing to high cost of III-V or Ge wafers, the active layers are proposed to be deposited epitaxially on
silicon substrates. This presents itself as a challenge: due to the large lattice mismatch between Si and Ge or III-V
materials, a high density of extended defects like misfit and threading dislocations, stacking faults, twins is created.
Furthermore, the deposition of polar III-Vs on non-polar Si creates additional defects like polar and anti phase
domains. It has been studied that these defects acts as non-radiative recombination centers and limits the electrical
transport of carriers in the device. Therefore, it is important to characterize these defects on the basis of extent of
performance degradation caused by them in the CMOS devices. Subsequently, based on these studies it is desired
to introduce variants in the growth strategies to mitigate the harmful effects or completely eliminate them.
The focus of this internship/thesis would be to study the electrical properties of p-n junction diodes containing
extended defects, fabricated under different processing conditions. This would be done by measuring CurrentVoltage (I-V) and Capacitance-Voltage(C-V) characteristics. Temperature dependent measurements can also be
carried out. The information about the generation and recombination lifetime, ideality factor, activation energy can
be extracted from these measurements which in turn indicate the dominant mechanism (Shockley-Read-Hall, Field
Assisted Tunneling) in the devices.
Additionally, defect characterization which involves identifying and classifying the defects can also be performed
using facilities available at IMEC in close collaboration with its industrial partners.
Type of project: Thesis/internship of 3-4 months.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material science, physics,
electronics.
Responsible scientist(s):
For further information or for application, please contact Eddy Simoen (Eddy.Simoen@imec.be) and Somya Gupta
(Somya.Gupta@imec.be).

2
Master Thesis/Internship Topics 2012-2013

Random Telegraph Noise (RTN) and the ITRS Roadmap: is it the beginning of the
end?
Low-frequency noise is present in all physical, electronic, biological and even societal systems and is for most
experimentalists a source of error. However, it can also provide fundamental information on the basic transport
mechanisms through a semiconductor device, for example. Flicker noise or 1/f noise appears to be universal in
most large systems but breaks down when the dimensions reach the nanoscopic level. In the case of a MOSFET, it
is believed that trapping and de-trapping of charge through many defect states is at the origin of the 1/f noise.
When scaling the device dimensions to the sub-micrometer area, the number of active traps reduces, so that
eventually, only one or a few traps are active and determine the charge transport fluctuations. In practice, this
means that for a small-area device, the current through the channel can switch between a high and a low state,
which is called Random Telegraph Noise (RTN). As the occurrence of a trap and associated RTN is a random
process, this may give rise to significant variation from device to device. As such, RTN is a source of temporal
device variability and may form a performance limitation for 16-nm and below CMOS memories. It is the aim of
the work to study the low-frequency noise and RTN behavior of advanced CMOS technology devices and to
investigate the possible impact of various process options.
At imec, there is a computer-controlled noise measurement system, combined with a 300 mm probe station,
allowing a detailed analysis in function of the gate and drain voltage. As RTN traps may also affect the mobility by
scattering, a correlation with other device parameters, like the threshold voltage and the mobility will be looked
for. It is also possible to study the RTN and noise behavior as a function of temperature. This enables the
determination of the thermal activation of the emission and capture processes underlying the RTN and noise and
provides information on the trap level energy and capture cross section. In a way, RTN allows for trap
spectroscopy in small systems. As there is more and more interest from the industry, this work will be performed
in close collaboration with the imec industrial Partners.
Type of project: Thesis of 3 months.
Degree:
Master in Science or Master in Engineering majoring in e.g. device physics.
Responsible scientist(s):
For further information or for application, please contact Eddy Simoen (Eddy.Simoen@imec.be).

3
Master Thesis/Internship Topics 2012-2013

Deposition and characterization of dielectric barrier films


In copper interconnect technology, typically SiCN films are deposited in-between the low-k dielectric layers,
serving at the same time as a etch stop layer, dielectric Cu barrier, and moisture barrier. Driven by the continuing
scaling, requiring a lower overall k-value of the dielectric stack, alternative materials are investigated. These should
have a lower k-value than SiCN, while maintaining the barrier and etch stop properties, or have similar properties
at a lower thickness.
In this project, the deposition process window is screened for a certain precursor, varying process conditions,
based on literature research. This involves extensive characterization of the deposited films, starting with the
determination of thickness, refractive index, chemical composition through FTIR, stress, Youngs modulus,
hardness, porosity, hydrophilicity, dielectric constant, and leakage of the films. For the most promising films, a
second series of tests which simulate other (former and later) process steps, is performed; this also includes tests
to determine the adhesion to other films, mainly by 4 point bending analysis. Also, a more detailed chemical
analysis, e.g. through XPS and TOFSIMS, will be performed. If all tests are positive, finally, the material is used in
an integration process, resulting in a real test chip and the final electrical characterizations (including reliability
characterizations) are made.
The student will be strongly involved in both the actual deposition of the films and the detailed characterization of
the basic film properties. Hereby (s)he will use state of the art equipment, such as an industrial PE-CVD reactor,
ellipsometers, a Fourier Transform Infrared spectrometer, a high precision mass measurement system, and others.
Furthermore (s)he will also be involved in the next phase of the characterization cycle, as setting up the processes
for the simulation of integration aspects and the electrical characterization on test chips. Also, the student can be
involved in setting up a practical test procedure to measure Cu barrier properties.
Academic and industrial results will be reported in meetings where both imec staff and industrial affiliates
participate.
Type of project: Thesis or internship of minimum 5 months, to start in 2013.
Degree:
Master in

Science

or

Master

in

Engineering

majoring

in

material

science,

physics,

electronics.

Responsible scientist(s):
For further information or for application, please contact Els Van Besien (Els.Vanbesien@imec.be).

4
Master Thesis/Internship Topics 2012-2013

Using variational calculus to solve Poisson's and Schroedinger's equations selfconsistently within a single loop: how far can we go?
Transport calculations for modern semiconductor devices heavily rely on the local charge distribution and the
related electrostatic potential established inside a device structure. As such, one is bound to solve the
Schroedinger equation self-consistently with Poisson's equation and a number of constitutive equations relating the
electron and hole concentrations to the wave functions of the quantum states and their occupancies. Designing
appropriate numerical code to deal with this task, one is immediately faced with a significant computational burden
due to the highly non-linear and non-local dependence of the charge density on the potential. Moreover, the
necessity of feeding back the charge density into the module that solves Poisson's equation is reflected in the
conventional, double loop that handles the fully self-consistent solution. Recently, an efficient but non-linear
variational principle has been developed that provides a simultaneous solution of all equations involved, while being
carried out merely within a single loop that minimizes a proper action functional. So far however, the necessary
condition that the charge density be a local functional of the potential, has restricted the application of the
principle to cases where the adiabatic approximation or local density approximation leads to an acceptable
description of the quantum mechanical charge density. The purpose of this thesis is to work out the non-linear
variational principle for a number of simple test structures (e.g. planar and/or double-gate MOS capacitors) and to
explore any possible extension of the variational calculus beyond the local density approximation.

Type of project: Thesis of 8 months.


Degree:
Master in Science majoring in physics.
Responsible scientist(s):
For further information or for application, please contact Wim Magnus (Wim.Magnus@imec.be) and Bart Soree
(Bart.Soree@imec.be).

5
Master Thesis/Internship Topics 2012-2013

Parallelization of CMOS time-dependent variability measurements


It is well established that with the size of CMOS devices decreasing to atomic dimensions, the number of dopant
atoms in each device reduces to numerable levels, resulting in increased time-zero (i.e., as-fabricated) variability.
At the same time also the number of defects is decreasing to literally single-digit numbers, resulting in further
variability increase with time (i.e., increased time-dependent variability and thus, further reduced reliability). This
trend has recently lead to a shift in our perception of reliability: the top-down approach (deducing the
microscopic mechanisms behind the average degradation in large devices) is being replaced in deeply-scaled devices
by the bottom-up approach, in which the time-dependent variability is understood in terms of individual defects.
The small ensembles of stochastically behaving individual defects are then responsible for the wide time-dependent
distributions of CMOS device parameters. Understanding these distributions requires electrical measurements on
a large number of devices, necessitating in turn parallel evaluation schemes.
The thesis project will build on a previously-designed on-chip array for parallel device stressing and testing.
Programming of the measurement instruments and the computer-controlled prober will be needed, followed by
statistical analysis of the data, and optionally, designing improved on-chip circuitry. The required skills include
computer programming (Perl), performing electrical measurements and data analysis, and optionally SPICE, and
CAD layout.

Type of project: Thesis possibly with internship of minimum 6 months.


Degree:
Master in Science or Master in Engineering majoring in electrical engineering, physics, nanotechnology, material
sciences.
Responsible scientist(s):
For further information or for application, please contact Ben Kaczer (Ben.Kaczer@imec.be) and Jacopo Franco
(Jacopo.Franco@imec.be).

6
Master Thesis/Internship Topics 2012-2013

Modeling of leakage in very high permittivity dielectrics for DRAM applications


Future dynamic random access memories (DRAM) require metal-insulator-metal capacitors (MIMcaps) with
equivalent oxide thicknesses (EOT) 0.4 nm, necessitating the introduction of dielectrics with very high dielectric
constant (k~100). Furthermore, low leakage current densities ( 10-7 A/cm2) are required for sufficient retention
of charge. Regrettably, high-throughput industrial deposition techniques can result in dielectric films with defects
that can facilitate electronic conduction. Reducing the leakage thus requires thorough understanding of the role of
the defects.
The general aim of the thesis is to interpret the measured leakage and capacitance characteristics (IV and CV at
varying temperature). This will be achieved by modeling trap-assisted leakage mechanisms in MIM structures with
non-uniform electric field due to charge trapped inside the dielectric. Requirements therefore include
understanding of the physics of various conduction mechanisms, self-consistent solving of the Poisson equation,
and optionally electrical IV and CV measurements.
Type of project: Thesis possibly with internship of minimum 6 months.
Degree:
Master in Science or Master in Engineering majoring in electrical engineering, physics, nanotechnology, material
sciences.
Responsible scientist(s):
For further information or for application, please contact Ben Kaczer (Ben.Kaczer@imec.be).

7
Master Thesis/Internship Topics 2012-2013

Low damage etch: use of CF3I as reactant for patterning of 2.0 porous SiOCH
materials
In order to cope with device scaling, inter-line crosstalk and interconnect delays, chip manufacturers are
introducing since a few years low dielectric constant materials (low-ks) as insulating material separating conducting
Cu lines. Currently, targeted k values for 2016 are of the order to 2.0 and below, to be compared with 4.2 for
bulk SiO2 (reference dielectric for the semiconductor industry). In order to achieve such low k value, Si-based
CVD materials are favored, where methyl groups are introduced (less polarizables) together with substractive
porosity. Those materials are referred as p-SiOCH, hybrid dielectrics, or organo-silicon glass (OSG). Current
state-of-the-art synthesis methods allow to reach k values ~ 2.0, with porosity ~ 45% and average pore size ~
2.4nm. Recent studies indicate that those materials can be damaged by plasma processing, leading to methyl group
suppression and loss of hydrophobicity. An option to overcome this issue is to use new plasma chemistries, where
the damaging component has been reduced. One possibility is to replace the conventional fluorocarbon CF4
molecule by trifluoroiodomethane CF3I 1. The objective of this work-package is to evaluate the efficiency of this
solution for plasma etching of a 2.0 porous OSG material, in comparison with conventional CF4-based chemistries.
Starting from pristine blanket low-k films, the vertical damage caused by plasma processing will be evaluated as a
function of various important processing parameters (plasma power, composition, RF driving frequency, pressure,
time). Bulk k-value will be evaluated, as well as structural modifications caused by plasma exposure. Possibly,
pattern tests will be conducted as well, in order to estimate the degree of damage reduction in the transverse
direction (parallel to the wafer surface). Techniques for such a study would be broad and represent a significant
part of the stay: deep understanding of etch tool usage, film characterization (ellipsometry for thickness-n&k, FTIR
or ATR-FTIR for bulk composition, WCA for film hydrophobicity, k-value extraction by C-V measurements on
metal dots). More specific material characterization (XPS, AFM, TOF-SIMS etc...) may be used.
Type of project: Internship or thesis with internship of approx. 6 months full-time.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material sciences, physics,
chemistry, electronics.
Responsible scientist(s):
For further information or for application,
Francois.deMarneffe@imec.be), Laurent Souriau
(Mikhail.Baklanov@imec.be).

please contact Jean-Francois de Marneffe (Jean(Laurent.Souriau@imec.be) and Mikhal Baklanov

E. Soda, S. Kondo, S. Saito, Y. Ichihashi, A. Sato, H. Ohtake and S. Samukawa, J. Vac. Sci. Technol. B 26, 875 (2008)

Master Thesis/Internship Topics 2012-2013

Post-etch ULK restoration strategies: effect of H2-CH4-based plasma treatments on


dielectric recovery of 2.0 porous SiOCH materials
In order to cope with device scaling, inter-line crosstalk and interconnect delays, chip manufacturers are
introducing since a few years low dielectric constant materials (low-ks) as insulating material separating conducting
Cu lines. Currently, targeted k values for 2016 are of the order to 2.0 and below, to be compared with 4.2 for
bulk SiO2 (reference dielectric for the semiconductor industry). In order to achieve such low k value, Si-based
CVD materials are favored, where methyl groups are introduced (less polarizables) together with substractive
porosity. Those materials are referred as p-SiOCH, hybrid dielectrics, or organo-silicon glass (OSG). Current
state-of-the-art synthesis methods allow to reach k values ~ 2.0, with porosity ~ 45% and average pore size ~
2.4nm. Recent studies indicate that those materials can be damaged by plasma processing, leading to methyl group
suppression and loss of hydrophobicity. An option to overcome this issue is low-k restoration, i.e. add a
processing step after plasma etch, that would repair the damaged material (attach new CH3 groups and restore
hydrophobicity of the surface). Currently, we are considering the use of soft plasma processes at low temperature,
based on H2, CH4 and additives. Starting from in-situ damaged low-k films (after etch with 2 typical chemistries, ArCF4-based and N2-CF4-based), the objective of the work-package will be to screen various important process
parameters (plasma power, composition, RF driving frequency, pressure, time), and characterize the level of bulk k
value recovery and material structural modifications. Techniques for such a study would be broad and represent a
significant part of the stay: deep understanding of etch tool usage, film characterization (ellipsometry for thicknessn&k, FTIR or ATR-FTIR for bulk composition, WCA for film hydrophobicity, k-value extraction by C-V
measurements on metal dots). More specific material characterization (XPS, AFM, TOF-SIMS etc...) may be used.
The work-package would also include the optimization of a damage-less photoresist strip process.
Type of project: Internship or thesis with internship of approx. 6 months full-time.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material sciences, physics,
chemistry, electronics.
Responsible scientist(s):
For further information or for application,
Francois.deMarneffe@imec.be), Laurent Souriau
(Mikhail.Baklanov@imec.be).

please contact Jean-Francois de Marneffe (Jean(Laurent.Souriau@imec.be) and Mikhal Baklanov

9
Master Thesis/Internship Topics 2012-2013

Plasma treatments of model polymers used in EUV lithography: PS and PMMA


Nowadays, nano-patterning is facing two main challenges, closely linked together: scaling (dimension reduction) and
line-width roughness (LWR), i.e. sidewall roughness appearing in course of the etch sequence. Advanced
lithography makes use of EUV photo-resist, which is patterned by 13.6nm light. This photo-resist is composed of
two main polymers, PS and PMMA, together with attached groups for protection and de-protection (PAG =
photo-acid generator). Currently, a lot of progress is being made on LWR by performing pre-etch plasma
treatments based on H2. However the precise mechanism of LWR improvement remains not well understood,
especially which photo-resist component is responsible for LWR. In order to clarify this, we propose to study the
effect of plasma treatments (H2, Ar, HBr, He-H2 mainly) on model polymers used in EUV photo-resist, i.e. PS and
PMMA. The objective of the work-package is to perform various plasma treatments (varying plasma power, bias,
composition, exposure time) on PS and PMMA thin films, then perform an in-depth characterization of the
processed films, including ellipsometry (thickness, n & k ()), FTIR or ATR-FTIR (bulk changes), WCA, Tg
measurements). In order to separate the effect of light (VUV, UV, visible), radicals and ion bombardment, the
small-gap technique will be used with MgF2, Fused Silica and BK7 windows.
Type of project: Internship of minimum 3 months.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in materials sciences, physics,
chemistry, electronics.
Responsible scientist(s):
For further information or for application, please contact Jean-Francois
Francois.deMarneffe@imec.be) and Efrain Altamirano (Efrain.Altamirano@imec.be).

de

Marneffe

(Jean-

10
Master Thesis/Internship Topics 2012-2013

ESD reliability of high mobility FinFET devices for sub-14 nm CMOS


In this thesis, the intrinsic ESD robustness of bulk FinFET technology for future CMOS nodes using high mobility
channels and Local interconnect layer will be analysis. Test structures are available to be measured and analyzed.
In the last decade, new processing features have been introduced into VLSI technology: source/drain stressors (90
nm node), high-k dielectrics and metal gate electrodes (45 nm node). Recently, a new transistor architecture
(finFET or multi-Gate FET or 3D-transistor) has been introduced for the 22nm node. The next technology option
to be possibly introduced into the FinFET device architecture is the use of high-mobility (non-silicon) channel
materials. For pFETs, (Silicon)Germanium-based devices are being considered due to their compatibility with the
existing Si technology. For nFETs, III-V alloys such as InGaAs are being investigated. Note that the bulk hole
mobility of Ge (1900 cm2/Vs) is significantly higher than that of Si (450 cm2/Vs). Similarly, the electron mobility in
In0.53Ga0.47As (~12.000 cm2/Vs) is a lot higher than in Si (1400 cm2/Vs).
A key reliability characteristic that needs to be investigated before any commercial product can be shipped, is its
ESD (Electrostatic discharge) reliability. An ESD event on an IC, is a discharge event where up to 10 A of current
over a time span below 100 ns needs to be able to flow through any 2 pin combinations of that IC without
destroying or wounding it. In order to cope with such an event, a pre-designed ESD current path must be
provided on the IC, using dedicated ESD clamps (voltage sensitive switched), which are off during normal
operation and on during an ESD event. Such ESD clamps need to be evaluated in every new CMOS technology,
and if needed to be optimized or altered.
Based on excising test structures, destructive ESD measurements will be performed on various clamps and test
structures. These measurements reveal the high current high voltage behavior which needs to be physically
analyzed; also the failure signatures need to be understood. Once this is understood, ESD FinFET device layout
optimization can be done, and ESD protection strategies developed.
The multi-disciplinary work combines the use of ESD characterization tools, physical analysis of ESD device
operation and the use of TCAD to clarify the underlying physical operation. The student will have to bridge the
fields between advanced technology development, characterization tools, simulation and analog design, joining a
team of imec specialists in this field.
Type of project: Thesis or thesis with internship.
Degree:
Master in Engineering majoring in electronics, nanotechnology.
Responsible scientist(s):
For further information or for application, please contact Geert Hellings (Geert.Hellings@imec.be) and Dimitri
Linten (Dimitri.Linten@imec.be).

11
Master Thesis/Internship Topics 2012-2013

Evaluation of photoresist outgassing for extreme ultraviolet lithography


Extreme Ultraviolet (EUV) light is currently of increased interest in semiconductor processing. EUV Lithography
(EUVL) is the leading candidate for 22nm half-pitch device manufacturing and beyond. One of the concerns of this
process technology is related to outgassing of materials in the vacuum environment e.g. from photoresists ,
which, enhanced by the EUV irradiation, can result in a reflectivity decrease of the optical elements and in other
decrease of exposure tool performance.
In this field the student would work at imec on an experimental outgassing set-up (Fig. 1) to evaluate the EUV
related outgassing and contamination and is involved in outgassing analysis of various photoresist materials. This
will contribute significantly to the understanding how materials and process conditions can impact contamination in
the EUV scanners, and lead to procedures to qualify resist materials before they are used on the EUV scanners.

Fig. 1 : Experimental EUV outgassing set-up at IMEC for investigation of outgassing of lithography materials.

Type of project: Preferably internship of minimum 6 months.


Degree:
Master in Science or Master in Engineering majoring in material sciences, physics, chemistry.
Responsible scientist(s):
For further information or for application, please contact Ivan Pollentier (Ivan.Pollentier@imec.be).

12
Master Thesis/Internship Topics 2012-2013

Methodologies for memory analysis using C-AFM


Conductive bridging resistive RAM memory CBRAM, based on resistance switching mechanisms, is emerging as a
potential replacement for Flash and/or DRAM applications, due to its high scalability potential, for future 20 nm
technology nodes and beyond (fig. A).
Conductive atomic force microscopy C-AFM (fig. B) is a scanning probe microscopy technique, relying on a normal
atomic force microscope equipped with a current sensor capable to measure ultra low currents. C-AFM
represents an invaluable tool in two ways. First it allows examining very small features with nm-scale spatial
resolution (nanoscopic electrical probing), and secondly the tip can be used as a nano sized electrode.
This internship/thesis fits into the characterization framework for CBRAM using C-AFM. You will be trained in the
use of the tool and intensively use it focusing on device de-process methodologies. During the period of the
internship the student will focus on different aspects of this point, using the C-AFM twofold as a microscope and
to de-process memory devices in situ. The data analysis and interpretation will cover an important part of the
work; you will apply statistical principles in data collection and will be asked to rule out your results. You will work
in an international R&D team; a good command of English language is required.

The detailed content of the work will be defined in detail at the moment of starting this project.

Type of project: Thesis or internship of 6 months.


Degree:
Master in Science or Master in Engineering majoring in physics, electrical engineering, material science, chemistry.
Responsible scientist(s):
For further information or for application, please contact Umberto Celano (Umberto.Celano@imec.be).

13
Master Thesis/Internship Topics 2012-2013

Carbon nanotube contacts: electrical characterization of CNT Cu damascene


contacts
Carbon Nanotube (CNT) interconnect devices are being processed and electrically evaluated at imec in Leuven
(Belgium). The processing and electrical evaluation of the 150nm diameter CNT contacts on TiN proceeds at full
wafer level in the imec cleanrooms and testing facilities. All the integration steps for the CNT integration, the steps
for patterning the Cu damascene top contact, and the mask set used are compatible with 130nm device
technologies on 200mm wafers.[1,2] These CMOS-compatible processes were optimized previously on 300nm via
test structures, with the optimization mostly concerning the CNT growth.[3] This new platform is designed for
automatic electrical testing using Kelvin vias, parallel vias or other probing pads. It allows for fast and quantitative
comparison using automatic probing of 200mm wafers. The high yield that we can obtain, and the agreement
between the single contact resistances measured from Kelvins and the parallel contacts indicate that the process is
stable.
Our work is focusing on improving the CNT quality to reduce the contact resistance. In parallel, splits in the
integration module on the top contact are included to obtain more insight in the CNT-to-metal contact. In
addition, we are searching for CNT growth methods from catalysts compatible with future interconnect
substrates. Here, the underlayer specs may go beyond the CoSi2 or NiPtSi2 era. We will have wafers with CNT
interconnects available processed under different conditions. Electrical measurements can be performed at imec
for: (1) Obtaining a better understanding of the behavior of the CNT interconnect under stressed conditions (high
frequency, breakdown, aging, reliability...), supported by theoretical modeling. (2) Developing a theoretical model
that can be validated experimentally to distinguish the Rc-bottom contact (between CNT and bottom contact).
The electrical performance studies have the objective to obtain a detailed understanding of the CNT interconnect
and find ways to improve the CNT interconnect performance. The CNT growth and integration work is realized
in a cross-functional team bridging the two groups of Prof. Dr. S. De Gendt (team Nano Applications Materials
Engineering) and Dr. Zs. Tkei (team InterConnect Integration).
[1] N. Chiodarelli et al., IEEE IITC conf. proc. (2011) 153155. [2] M.H. van der Veen et al., Electrical Characterization of CNT contacts with Cu
damascene Top Contact, Microelectron. Eng., submitted (2012). [3] N. Chiodarelli et al. Nanotechnology 22 (2011) 085302.

Cross-section of the electrical structure showing four 150nm contact holes


filled with CNT and metallized with Cu single damascene top contact.

Type of project: Thesis or internship.


Degree:
Master in Science or Master in Engineering majoring in physics, electronics, material sciences, nanotechnology.
Responsible scientist(s):
For further information or for application, please contact Yohan Barbarin (Yohan.Barbarin@imec.be) and Marleen
van der Veen (Marleen.vanderVeen@imec.be).

14
Master Thesis/Internship Topics 2012-2013

Graphene synthesis and characterization


Graphene is a 2D, semi metallic, one-atom-thick sheet of sp2-bonded carbon atoms.[1] Graphene synthesis by
means of mechanical exfoliation gives highest quality graphene but is not a CMOS compatible process due to (1)
randomness of flake deposition (2) low yield. Growth on metal films (CVD graphene) or by annealing of SiC
crystals (epitaxial graphene) still need high T budgets.[2] Although graphene is intrinsically compatible with CMOS
processing because of its planar nature and transferability, technology will need a CMOS compatible synthesis
method. Synthesis from solid carbon sources offers a clean method that is potentially compatible with front end of
line processing, tools and scaling.[3]
The objective of this internship is to develop processes to synthesize graphene by means of anneal-type of solid
stated reactions using SiC-based film stacks and by means of epitaxial growth from crystalline SiC. The candidate
will also learn how to manipulate graphene in order to transfer it to alternate supports with the objective to
fabricate and characterize devices.[4] Part of the work will entail the manipulation of graphene produced by
mechanical exfoliation, for benchmarking purposes. The challenges involved are:
1.
2.
3.
4.

Fine tuning of process parameters to control the number of graphene layers grown.
Investigation of the influence of the substrate texture/crystallinity on the properties and quality of
synthesized graphene.
Study of the interfacial reactions between the substrate and graphene.
Post-processing of as-grown graphene (e.g., transfer, modification, device design).

The work will start from earlier findings within the graphene team[4] and is conducted in the group of Prof. Dr. S.
De Gendt.
[1] Novoselov et al, Science 306 (2004) 666. [2] de Heer et al., Solid State Communications 143 (2007) 92. [3] Juang et al., Carbon 47 (2009)
2026. [4] Nourbakhsh et al, PSS 6 (2012) 53.

Type of project: Thesis or internship.


Degree:
Master in Science majoring in material sciences, nanotechnology, chemistry.
Responsible scientist(s):
For further information or for application, please contact Marleen van der Veen (Marleen.vanderVeen@imec.be)
and Inge Asselberghs (Inge.Asselberghs@imec.be).

15
Master Thesis/Internship Topics 2012-2013

Growth of carbon nanotubes for future generations of interconnects


Due to their remarkable electrical, thermal and mechanical properties, carbon nanotubes (CNT) have been
considered for various applications in different fields of research. One particular application, situated in the world
of integrated circuits, is a CNT based interconnect.
In the literature, various reports exist where the growth of carbon nanotubes with a
high quality is demonstrated. However, most of these results are obtained under
process conditions that are not fully CMOS compatible and hence cannot be used in a
back-end-of-line process.
The aim of this project therefore is to investigate and develop a CMOS compatible
growth process that results in high quality CNTs. In addition to this, the CNTs need to
be grown in very small via features (sub 22 nm), as is projected for future generations of
interconnects (Figure 2). The major restrictions for the process are:
1) Process temperature has to be below 400 C.
2) Achieve CNT growth directly on conductive substrates.
3) CNT (shell) density has to be sufficiently high.

Figure 1: CNTs grown on TiN

The student will be involved in experimental work, focusing on catalyst


deposition techniques for CNT growth (such as electrochemical deposition of
catalytic nanoparticles) as well as studying the CNT growth process itself.
The work will start from earlier findings within the CNT team and is conducted
in the group of Prof. Dr. Stefan De Gendt.

Type of project: Thesis or internship.


Degree:
Master in Science majoring in material sciences, nanotechnology, chemistry.
Responsible scientist(s):
For further information or for application, please contact Marleen van der Veen (Marleen.vanderVeen@imec.be)
and Johannes Vanpaemel (Johannes.Vanpamel@imec.be).

16
Master Thesis/Internship Topics 2012-2013

Atomic layer deposition for applications in nanotechnology


Atomic Layer Deposition (ALD) is an advanced technique to deposit thin films on a substrate from gas phase
precursors. The film is deposited layer by layer through a cyclic process of self-limiting surface reactions. The use
of self-limiting surface reactions results in a number of unique features, such as growth control at the atomic level
and conformal deposition on extremely complex nanostructures.
Thanks to the process control at the atomic level, ALD has applications in nanotechnology. For example, the
performance of computer chips and memory cells can be improved by introducing novel materials deposited by
ALD, for example high-k dielectric oxides. A new potential application is energy storage in supercapacitors with
nanostructured materials. ALD can also be used to increase the efficiency of solar cells, e.g. by introducing a
passivation layer.
This thesis or internship topic frames in the research and development of ALD processes of metal oxides (e.g.
Al2O3, HfO2, SrTiO3 , TiO2 ). The ALD process parameters need to be optimized in order to achieve uniform
(nanometer thin) films with optimized properties. For example, the self-limiting aspect of the surface reactions is
examined as it provides the basis for the process control at atomic level. The deposition temperature can affect
the amount of impurities in the film and its phase. For deposition of metal oxides, the oxidant precursor (H2O, O3
) also plays an important role. Insight in the surface chemistry (ligand exchange reactions or oxidation reactions)
can provide a substantial contribution to the optimization of the process.
In order to characterize the nm-thin films, complementary measurement techniques are applied, such as
spectroscopic ellipsometry, X-ray photoelectron spectroscopy, Secondary Ion Mass Spectroscopy
Type of project: Thesis and/or internship of approx. 6 months.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in chemistry, physics, material
sciences.
Responsible scientist(s):
For further information or for application, please contact Annelies Delabie (Annelies.Delabie@imec.be) and Sven
Van Elshocht (Sven.VanElshocht@imec.be).

17
Master Thesis/Internship Topics 2012-2013

XRD study of nano-structured hetero-epitaxial III-V compound semiconductors for


VLSI CMOS applications
Since a few years, III-V compound semiconductors such as InGaAs, InP and InAlAs are being researched by the
micro-electronics community as candidate materials for replacing silicon in the most advanced CMOS generations
for 2020 and beyond. Due to the lattice mismatch and chemical differences, the epitaxial growth of these III-V
materials on Si substrates requires specific approaches to control defect formation, which is lethal for highly
performing circuits. Therefore, it is critically important being able to measure and analyze not only the thickness of
these layers and their exact composition, but also such parameters as crystalline quality, defects and defect density.
One of the most important techniques to assess the crystalline quality of semiconductor layers is X-ray diffraction,
but in principle this technique is only applicable on bulk materials or blanket films. The purpose of this work is to
develop measurement routines which allow to analyze nano-size structures by means of advanced XRD-tools,
featuring thin film diffraction, grazing incidence X-ray diffraction, high-resolution X-ray diffration, X-ray pole figure
analysis and/or X-ray rocking curve analysis.
Type of project: Thesis and/or internship.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material science, physics,
electronics, ...
Responsible scientist(s):
For further information or for application, please contact Clement Merckling (Clement.Merckling@imec.be) and
Weiming Guo (Weiming.Guo@imec.be).

Developing in-situ doping of III-V compound semiconductors by hetero-epitaxial


MOCVD growth
The epitaxial growth of III-V compound semiconductor on silicon substrate as channel material is a very promising
method for future CMOS device fabrication because of their high electron mobility. Their implementation in
conventional MOS structures requires thin III-V layers to be grown on a silicon substrate with shallow, abrupt and
well-controlled doping profiles.. The doping efficiency is influenced by many growth conditions such as precursors,
the growth temperature, annealing treatments etc. This work focuses on the doping of III-V thin layers (typically
InGaAs, InAlAs) during MOCVD growth, by using different doping elements such as carbon and silicon. The aim is
to develop effective and reproducible growth processes so that the doping concentration and diffusion of the
doping elements can be tightly controlled.
Type of project: Thesis and/or internship.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material science, physics,
electronics, ...
Responsible scientist(s):
For further information or for application, please contact Clement Merckling (Clement.Merckling@imec.be) and
Weiming Guo (Weiming.Guo@imec.be).

18
Master Thesis/Internship Topics 2012-2013

Surface preparation and interface passivation of high mobility channel materials for
beyond 14 nm technology nodes
The continuous demand for downscaling pushes the Si transistor towards its physical limits. Therefore, new
materials need to be introduced as channel materials. Possible candidates are SiGe, Ge, and III/V (e.g. InGaAs and
InP). These materials exhibit high bulk mobilities. However, in order to fulfill their high expectations, the interface
between the channel and the high-k needs to be passivated. Simply stated, a good passivation preserves the bulk
properties throughout the interface between the channel material and the high-k oxide. In order to achieve this,
we need to start from a defect free surface and the subsequent high-k deposition should not introduce new
defects. Therefore, the first step is to control the surface chemistry of the channel material. This can be done by a
wet chemical treatment or by a gas phase treatment prior to the high-k deposition.
The goal is to study the resulting surface chemistry by highly advanced analysis techniques such as AR-XPS (Angle
Resolved X-Ray Photo-electron Spectroscopy), TXRF (Total X-Ray Reflection Fluorescence), SIMS (Secondary Ion
Mass Spectroscopy) ... .
The next step is to study the influence of the surface chemistry on the high-k deposition by ALD (Atomic Layer
Deposition) and hence the passivation of the interface created. Again, several analysis techniques need to be used
in order to unravel the chemical bonding at the interface. Additionally, electrical characterization is needed to
study the passivation of the interface formed.
In the end, we need to come to a high quality interface with low defect densities in order to allow the introduction
of these new materials in the next technology nodes.
Type of project: Thesis and/or internship.
Degree:
Master in Science or Master in Engineering majoring in chemistry, material sciences.
Responsible scientist(s):
For further information or for application, please contact Sonja Sioncke (Sonja.Sioncke@imec.be).

19
Master Thesis/Internship Topics 2012-2013

Development of a fixed ramp rate breakdown voltage procedure for gate dielectric
testing
CMOS scaling is not only concerned with the reduction of the channel length and channel width, but also the
scaling of other transistor parameters such as the gate dielectric thickness. The long-term reliability of these ultrathin layers is of major concern. Several critical reliability mechanisms are identified and under investigation. Some
of these tests however are quite time-consuming.
The main aim of this thesis/internship is to develop a fixed ramp rate breakdown voltage procedure for fast gate
dielectric testing. This includes the selection of the proper measurement tools, the implementation of the test
software within our measurement environment, the demonstration of the finished routine and the electrical testing
of advanced gate stacks.
Type of project: Thesis or internship of 6 months.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in electronics.
Responsible scientist(s):
For further information or for application, please contact Thomas Kauerauf (Thomas.Kauerauf @imec.be).

Electrical evaluation and reliability assessment of local interconnects


In future CMOS technologies the individual transistors will be connected through local interconnects in order to
increase the device density and to reduce the metal one complexity. These local interconnects however have to
fulfill the same strict reliability specification as the other chip components and a thorough understanding of the
potential degradation mechanisms is needed.
The main aim of this thesis/internship is the electrical characterization of these local interconnects. This includes
the evaluation of various newly designed test structures, the comparison of different local interconnect processes
and the investigation of potential reliability issues.
Type of project: Thesis or internship of 6 months.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in electronics.
Responsible scientist(s):
For further information or for application, please contact Thomas Kauerauf (Thomas.Kauerauf @imec.be).

20
Master Thesis/Internship Topics 2012-2013

Investigation of advanced resistance-switching (RRAM) memory cells


Resistive Random-Access-Memory (RRAM), based on resistance switching mechanisms, is emerging as a potential
nonvolatile memory candidate for below-20nm technology nodes, due to its better scalability, beyond the limits
currently predicted for NAND Flash.
10nm-small RRAM cells are shown to have low voltage operation, very fast switching time, in the order of ns and
below, small energy consumption per switching and good reliability. To take on the benefits of these excellent
attributes to circuit level and enable high density memory array implementation, additional self-rectifying
functionality is required for the resistive switching stack.
The main task of this internship/thesis is to investigate RRAM cells that show self-rectifying characteristics, with the
aim of understanding the switching behavior, relate it to intrinsic performance and identify paths for further
improvement/optimization.
You will be involved in electrical characterization, focusing on either performance or reliability aspects. You will be
using state-of-the-art instrumentation and you will apply statistical principles in data collection using in-house
developed characterization methodologies, so as to ensure a short response time in characterization. You will
process data and assist in their interpretation. Feedback for process improvement is a key point.
You must have a good background in semiconductor physics and knowledge of CMOS technology. You must be
fluent in at least one programming/data analysis environment such as Matlab or similar and familiar with LabView
and basic instrumentation for electrical testing. You will work in an international R&D team; a good command of
English language is required.
The detailed content of the work will be defined in detail at the moment of starting this project.
Type of project: Thesis or internship of 4-6 months.
Degree:
Master in Science or Master in Engineering majoring in electronics, electrical engineering, physics.
Responsible scientist(s):
For further information or for application, please contact Bogdan Govoreanu (Bogdan.Govoreanu@imec.be).

21
Master Thesis/Internship Topics 2012-2013

Investigation and optimization of the electrical switching properties of Conductive


Bridging RAM memory cells (CBRAM)
The Resistance RAM is a new class of memories emerging as serious candidate for future memory replacement, in
particular for high-density memory application. Resistance RAM cells typically consist of an insulator material
sandwiched between two metal electrodes, and exhibiting resistive-switching properties, that is to say the
application of an electrical current/voltage to the cell induces reversible changes of the cell resistance, which allows
thus programming different memory states.
The Conductive Bridging RAM (CBRAM) is a sub-class of RRAM, for which one of the electrode contains mobile
elements (usually Cu or Ag) and which is based on the following switching mechanism: (1) applying a positive
voltage to the Cu- or Ag-containing electrode activates the formation of a conductive bridge (or filament) in the
insulator, resulting in the switching of the cell to a low resistance state (LRS); (2) on the other hand, a negative
voltage activates the dissolution of this filament and thus the return to the high resistance state (HRS) (see Fig.1).

Fig1. Current-voltage switching traces and schematic of filament formation due to electrochemical dissolution and growth of the electrode
metal element (from R. Waser et al., Adv. Mater., 21, 2009)

At imec, we started a project aiming to develop Cu-based CBRAM cells. We fabricate cells consisting of different
materials for the Cu-based electrode (pure Cu, or Cu-alloys) and for the insulator (binary oxides, nitrides, ...). The
purpose of the thesis is to study the resistive-switching properties obtained for different stacks and to relate these
switching characteristics to the physical properties of the used materials. The gained understanding of these
relationships will allow to (1) better understand the switching mechanism, and (2) identify optimum material stack
characteristics improving the memory parameters of the cell.
To this aim the study will mainly consist in electrical measurements using conventional Current-Voltage
measurements, as well as pulse-programming testing for scaled devices. Specific measurements like temperaturedependent I-V or impedance measurements may also be required.
The study will be carried out within a project team consisting of experts in different fields (processing, integration,
physical characterization, modeling ...), and in close collaboration with industrial partners.
Type of project: Thesis or internship of minimum 5 months.
Degree:
Master in Science or Master in Engineering majoring in material sciences, physics, electronics.
Responsible scientist(s):
For further information or for application, please contact Ludovic Goux (Ludovic.Goux@imec.be).

22
Master Thesis/Internship Topics 2012-2013

Passivation of Ge for high-performance applications


Since several decades, the semiconductor material of interest to fabricate computer chips and other electronic
devices has been Si. In the near future however, such high-performance applications may require a different type of
semiconductor because Si does not fulfill the needs anymore. Due to its higher intrinsic carrier mobility and hence
the possibility to operate at higher speed, Ge is being considered as a potential candidate to replace Si. A critical
issue for the successful integration of Ge devices on the other hand is the electrical passivation of the Ge surface.
This passivation is mandatory because defects like dangling bonds at the Ge/gate stack interface are able to trap
charges and as such decrease the carrier mobility.
This thesis or internship topic frames in the research and development of an optimal passivation of the Ge surface,
resulting in the highest feasible carrier mobility. We will focus on GeO2 as this type of passivation has shown to be
promising. Also, the integration of GeO2 is quite straightforward since it can be obtained by oxidation of the Ge
semiconductor surface. The quality of the GeO2 layer however will depend largely on the preparation method.
Therefore, we will evaluate several techniques in order to obtain GeO2 of the best quality and a defect-free
Ge/GeO2 interface. The physical quality of the GeO2 passivation layer will be examined by means of several
measurement techniques like Spectroscopic Ellipsometry, X-Ray Photoelectron Spectroscopy and Atomic Force
Microscopy. Capacitance-Voltage and Current-Voltage measurements will be applied for electrical evaluation. This
electrical evaluation will first be done on capacitors, which consists of a Ge semiconductor substrate, a GeO2
passivation layer, a high-k dielectric layer and a metal gate. At the final stage, the passivation layer will be evaluated
on transistors, resembling the eventual electronic device.
Type of project: Thesis and/or internship.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in chemistry, physics, material
sciences, electrical engineering.
Responsible scientist(s):
For further information or for application, please contact Laura Nyns (Laura.Nyns@imec.be) and Sven Van
Elshocht (Sven.VanElshocht@imec.be).

23
Master Thesis/Internship Topics 2012-2013

Graphene: device fabrication and characterization


Graphene, an atomically-thin sheet of carbon atoms arranged in a sp2 honeycomb lattice, has been successfully
isolated for the first time only in 2004 [Novoselov et al, Science 306 (2004) 666.]. The peculiar electronic
properties of graphene arise mainly from the configuration of its energy band structure, which, combined with the
intrinsically low occurrence of defects and the stiffness of its lattice, allows for the featuring of intriguing 2-D
physical phenomena. Graphene has been proposed as a candidate for CMOS and post-CMOS electronics.
However, in order to make electronic applications of graphene realistic, one has to necessarily tune its electronic
properties, so that, for example, a bandgap is introduced. The realization of a proper bandgap is critical for the
device performance. Most recently, the research team has demonstrated the tuning of single-layer graphene by pand n- doping due to engineering the interactions with the SiO2 support [Nourbakhsh et al, PSS 6 (2012) 53.].

Figure: (a) Transfer characteristics and (b) transconductance of SLG-FETs fabricated on pristine and silanized Si/SiO2 substrates. The latter
sample is then treated in basic (red) and acidic (blue) solutions to turn the behavior from n- to p-type.[Figure taken from: Nourbakhsh et al, PSS
6 (2012) 53.] (c) image of a graphene device.

The candidate will learn how to manipulate and functionalize graphene, to characterize the doping level and the
bandgap formation. Therefore, he/she will be involved in the design, fabrication, and characterization of graphene
devices. Part of the work will entail the manipulation and functionalization of graphene produced by both
mechanical exfoliation and synthetically grown graphene, for benchmarking purposes. The challenges involved are:
The study of the interfacial reactions between the substrate, graphene and doping layer;
Post-processing of as-grown graphene (e.g., transfer, modification, device design);
Device fabrication by lithography;
Electrical device characterization.
The work will start from earlier findings within the graphene team and is conducted in the group of Prof. Dr. S. De
Gendt.
Type of project: Thesis or internship.
Degree:
Master in Science or Master in Engineering majoring in material sciences, nanotechnology, chemistry, physics.
Responsible scientist(s):
For further information or for application, please contact Inge Asselberghs (Inge.Asselberghs@imec.be).

24
Master Thesis/Internship Topics 2012-2013

Graphene: device fabrication for optoelectronics


Graphene, an atomically-thin sheet of carbon atoms arranged in a sp2 honeycomb lattice, has been successfully
isolated for the first time only in 2004 [Novoselov et al, Science 306 (2004) 666.]. The peculiar electronic
properties of graphene arise mainly from the configuration of its energy band structure, which, combined with the
intrinsically low occurrence of defects and the stiffness of its lattice, allows for the featuring of intriguing 2-D
physical phenomena. With respect to optoelectronic device performances, the high transparency in the visible-light
range and the low resistivity of graphene sheets are the most attractive features, which makes graphene an ideal
candidate to explore further its potential as a transparent electrode.
The goal of this project is to study the layer interactions between substrate, graphene and optical active materials
(e.g. quantum dot interactions), to characterize device performances and by molecular fine-tuning increase the
optoelectronic device performance.

(a)

(b)

(c)

Figure: (a) Schematic of the QD-treated graphene transistor in the typical measurement configuration employed in this work. (b) Transfer
characteristics Ids vs. Vg of a SLG FET in pristine conditions, after QD deposition, and during QD excitation (532 nm laser). The inset shows an
optical microscope image of the 2-probe graphene device (scale bar: 2 m). (c) Energy level diagram of the CdSe/ZnS QDs in contact with
SLG.[Pictures taken from: Klekachev et al, Physica E: Low-dimensional Systems and Nanostructures (2011) 43(5) 1046-1049]

During the internship/master thesis you will learn how to manipulate and functionalize graphene, to characterize
the doping level and the bandgap formation. Therefore, you will be involved in the design, fabrication, and
characterization of graphene optoelectronic devices. The challenges involved are:
The study of the interfacial reactions between the substrate, graphene and doping layer;
Post-processing of as-grown graphene (e.g., transfer, modification, device design);
Device fabrication by lithography;
Electrical and optical device characterization
The work will start from earlier findings within the graphene team and is conducted in the group of Prof. Dr. S. De
Gendt.
Type of project: Thesis or internship.
Degree:
Master in Science or Master in Engineering majoring in material sciences, nanotechnology, chemistry, physics.
Responsible scientist(s):
For further information or for application, please contact Inge Asselberghs (Inge.Asselberghs@imec.be) and
Alexander Klekachev (Alexander.Klekachev@imec.be).

25
Master Thesis/Internship Topics 2012-2013

Characterization of ohmic contacts to high-mobility materials (Ge, III-V)


In near future, CMOS technology will have to implement novel semiconductors materials in the existing Si-based
platform. This will allow maintaining good performances while scaling the CMOS features dimensions. Highmobility materials, like Ge and III/V compounds (GaAs, InGaAs, InAs...) are considered the best candidates to
replace Si. In order to be able to implement these materials, contact schemes need to be developed to obtain low
resistive ohmic contacts to Source and Drain areas of MOSFET devices. This needs also to be achieved working
out integratable solutions. Fabrication and characterization (electrical and physical) of Metal/high-mobility materials
test structures allows for extraction of specific contact resistivity values, which combined with thermal stability
studies can lead to determination of proper contact scheme to satisfy ITRS requirements for sub-22 nm node.
The candidate will start by studying the theory of ohmic contacts and metal/semiconductor systems. He/she will
get familiar with state-of-the-art solutions for contacts on high mobility materials. He/she will follow closely the
fabrication steps of test structures and perform electrical characterization, backing the results theoretical studies
and simulations of Metal-Semiconductors systems.
Type of project: Internship or thesis with internship of 3-6 months.
Degree:
Master in Science or Master in Engineering majoring in physics, electronics, material sciences (focusing
semiconductors materials).
Responsible scientist(s):
For further information or for application, please contact Andrea Firrincieli (Andrea.Firrincieli@imec.be) and Jorge
Kittl (Jorge.Kittl@imec.be).

26
Master Thesis/Internship Topics 2012-2013

Spin transfer torque magnetic random access memory


As the demand for faster, smaller and more power-efficient devices is increasing, the present memory
technologies, such as DRAM, SRAM, and NAND Flash are reaching their limits in terms of scalability beyond the
16-nm generation. Alongside the thriving effort to push further the boundaries of current technologies, new
emerging memories have been developed and the spin-transfer torque magnetic random access memory (STTMRAM) is considered the most promising replacement. This is the next generation of consumer mass-scale
application of spintronics, following the widespread read head technology that hard drives use nowadays, which
could open the way to a new era in which nano-spintronics complements or even replaces nano-electronics in a
broad scale.
STT-MRAM is a type of non-volatile memory, it retains the information even when is not powered. It is based on
magnetic materials, more specifically on magnetic tunnel junctions (MTJ), a sandwich composed of two
ferromagnetic electrodes separated by an oxide barrier. The information in these devices is stored given the
relative orientation of the ferromagnetic layers. A high resistive state is found when they are antiparallel and a low
resistive state when both ferromagnets are pointing towards the same direction. The control of the magnetization
is done via the spin-transfer torque effect (STT) that enables to manipulate magnetizations by applying electrical
currents that become spin-polarized when traveling through the ferromagnets.
Imec is implementing a very exciting and challenging program on the development of STT-MRAM devices on the
300-mm platform, aiming ultrafast devices at the smallest possible technology nodes.
Several possibilities for master thesis and internships are possible. Experimental studies will be carried out on the
magnetic properties of novel materials with perpendicular magnetic anisotropy. This will be carried out via
combinatorial sputtering deposition (outsourced), electrical (transport) and optical (MOKE) characterizations. To
support the experimental findings, micromagnetic simulations will be investigated on distinct properties. For
example, to predict the magnetization behavior during the write process is crucial to reduce the necessary write
current. This reduction in current also depends on the optimization of key parameters such as magnetic damping
and anisotropy energies.
Knowledge on magnetism is an asset.
Type of project: Thesis and/or internship.
Degree:
Master in Science or Master in Engineering majoring in material sciences, physics.
Responsible scientist(s):
For further information or for application, please contact Mauricio Manfrini (Mauricio.Manfrini@imec.be), Sven
Cornelissen (Sven.Cornelissen@imec.be) and Jorge Kittl (Jorge.Kittl@imec.be).

27
Master Thesis/Internship Topics 2012-2013

Wet processing of high aspect ratio nanostructures


In semiconductor manufacturing, two critical issues in the wet processing of nanostructures with high aspect ratio
are incomplete wetting and pattern collapse. The contact angle that a liquid drop makes with an ideally flat surface
depends mainly on surface chemistry. Amplification of hydrophobicity by surface patterns is frequently seen in
nature (e.g. so-called lotus effect) and is illustrated in Figure 1 for flat and nano-patterned silicon surfaces.
Development of superhydrophobic behavior can lead to processing defects from incomplete wetting in between
nanostructures. On the other hand, as the critical dimensions of structures scale down, capillary force can cause
significant deflection of high aspect ratio structures and pattern collapse can occur after complete drying. Figure 2
shows the SEM images of free standing nano pillars before a wet treatment (a), and self organized patterns formed
after pillars are brought together by capillary forces (b & c). These pattern collapses should be prevented in
industrial fabrications.
In this project we investigate the wetting behavior of solutions on nanostructures with different surface
chemistries and the parametric dependence of pattern collapse on the wetting properties of the structure material
as well as structure dimensions. The student will have access to imecs state-of-the-art cleanroom facilities and get
hands on experience of contact angle measurement, Fourrier transform infra-red spectroscopy (FTIR), electroless
metal deposition and surface modification by adsorption.

(mirror image)

Figure 1. Water droplets on flat (left) and nano-patterned (right) silicon surfaces.

(a)

(b)

(c)

Figure 2. Top-down SEM images of (a) free standing pillar structures with high aspect ratio; (b) and (c) self-organized collapsing patterns formed
after a wet processing.

Type of project: Thesis or internship of minimum 3 months.


Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material sciences,
chemistry, physico-chemistry.
Responsible scientist(s):
For further information or for application, please contact Guy Vereecke (Guy.Vereecke@imec.be) and XiuMei Xu
(XiuMei.Xu@imec.be).
28
Master Thesis/Internship Topics 2012-2013

Surface chemistry of III-V semiconductors for cleaning applications


In order to meet the future demands imposed by the scaling roadmap, the heart of the transistor, the channel,
needs to be replaced by a new material in which the mobility of the charge carriers is higher than for silicon.
Semiconductor compounds based on group III and V elements of the periodic system e.g. InP and InGaAS meet
these requirements.
The III-V materials are grown in transistor structures through the gas phase with epitaxial and atomic layer
deposition techniques. A critical factor controlling deposition is the starting condition of the surface as this
influences the nucleation and properties of the grown layer. When contamination is present in the form of native
oxides, metals and particles, or when dangling bonds are not fully passivated, defects will be introduced in the
deposited layer or at the interface. Such defects are usually electronically active and reduce the efficiency of the
transistor. Minimizing defect densities in transistor structures is essential and can be achieved with controlled
chemical surface treatments.
In order to design wet chemical solutions that lead to an appropriate surface pre-conditioning and allow for nanoscale processing of these III-V materials, a thorough understanding of the interactions between the substrate and
the chemical solutions is needed and the basic etching mechanism needs to be investigated on a (sub) nanometer
level.
The goal of this project is to find a suitable chemistry which leads to selective contaminant removal and controlled
etching of the substrate in order to guarantee removal of surface defects in the crystal lattice. This (sub)nanometer
etching should be independent of crystal orientation in order to keep the surface stoichiometry intact. After
contamination and defect removal reoxidation of the surface poses a problem and can be minimized by sulfur
based passivation. At present we are screening various sulfur chemistries and we are characterizing the passivation
process.
For this research the following techniques are important:
ICP-MS to determine the amount of dissolved III-V material (ppb-ppt level)
TXRF to measure metallic contamination on III-V surfaces
Electrochemistry to study kinetics of etching and metal deposition
Photoluminescence to obtain insight in surface passivation and defect levels
XPS to measure surface composition
Atomic Force Microscopy to measure surface roughening at the atomic scale.
We are looking for enthusiastic and motivated students majoring in chemistry, material sciences or related field
with a strong interest in chemistry/physics of semiconductors and analytical chemistry. The duration of this project
is 2-12 months (assuming full time presence).
Type of project: Internship with thesis (2-12 months full-time).
Degree:
Master students majoring in chemistry, material sciences.
Responsible scientist(s):
For further information or for application, please contact Dennis van Dorp (Dennis.vanDorp@imec.be).

29
Master Thesis/Internship Topics 2012-2013

The creation of nanoforces by microbubbles


Bubbles can be created in fluids and are used for a broad range of
applications. Under the influence of pressure variations, bubbles can
implode which is shown in figure 1. The last few years, the research in
microbubbles has been ramped up, because imploding microbubbles can
be used in biomedical applications. An example is the implosion of
microbubbles near a cancer cell, which result in the perforation of the cell
membrane. Once the cell membrane is open, the injection of medicine is
facilitated. The ruptured membrane of living cells usually heals within a
time span of a few minutes. An example of a ruptured cell is shown in
figure 2. In the semiconductor industry, oscillating bubbles are used to
Figure 1 Implosion of a bubble
remove contaminants or nanoparticles from fragile structures. By using
ultrasound or, in other words, the same sound field for visualizing fetuses, small bubbles can be created. These
microbubbles oscillate with the same rhythm as the sound field. If the sound pressure is high enough, the bubbles
will oscillate very strong and they can even collapse. Such a collapsing bubble will remove nanoparticles from a
surface. Currently the implosion is not very well controlled and also results in damaged fragile structures. More in
depth research is necessary to control the nanoforces created by the imploding microbubbles.
The final goal of the work is to control the microbubble size
and to facilitate bubble nucleation. Several aspects need to be
investigated, including the effect of charge, surface tension,
spatial distribution of microbubbles, changes in the sound field...
The experimental tools which can be used for this type of work
are sonoluminescence tests, cavitation noise measurements,
damage and particle removal tests... The latter experiments are
closely related with the practical cleaning process.
Nanoparticles will be deposited on a surface in a controlled
way, which will be measured with light scattering techniques.
Figure 2 Cell ruptured by an imploding bubble
Next, these particles will have to be removed with the
microbubbles that are created during the application of ultrasound. During an intensive training period, the student
will learn how to operate the tools and interpret results.
Type of project: Thesis of minimum 4 months (full-time) and maximum 1 year.
Degree:
Master in Science or Master in Engineering majoring in physics, chemistry, material sciences.
Responsible scientist(s):
For further information or for application, please contact Steven Brems (Steven.Brems@imec.be).

30
Master Thesis/Internship Topics 2012-2013

Galvanic corrosion in micro-bump with different bumping metallurgy


The electronics industry is increasingly looking into 3D integration in order to address the ever continuing product
needs of miniaturization and performance increase for future generation of ICs. This result in high speed
interconnects with reduced noise and crosstalk as compared to wire bonded assemblies. 3D integration requires a
physical stacking such as die to die (D2D) or die to wafer (D2W) while forming a permanent electrical and
mechanical connection between the input/output pins of the devices. Fine pitch micro-bump connection is
considered as a promising approach for making die to die interconnections due to its lower bonding temperature.
A micro-bump consists of a solder bump and an Under-Bump-Metallisation (UBM) on the die. The reaction
between solder and UBM results in intermetallic formation and hence the top and bottom dies are connected. This
UBM must meet several requirements. First it must provide a strong, stable, low resistance electrical connection
to the underlying metal such as aluminum and Cu. Then it must adhere well both to the underlying metal and to
the surrounding IC passivation layer. The UBM must also provide a strong barrier to prevent the diffusion of other
bump metals into the IC. Finally the UBM must be readily wettable by the bump metals, for soldering.
Continuous downscaling in the micro-bump pitch requires new materials to meet all the afro-mentioned
requirements. However, the compatibility between the new material and the existing technology needs to be
evaluated.
For this specific topic the applicant would be required to investigate galvanic corrosion in multi-layer UBM system.
He will be also asked to investigate polarization behavior of different metals in a few Cu etchants and study the
galvanic corrosion tendency based on experiments. Moreover, he is asked to integrate the possible solutions to
reduce galvanic corrosion. Finally, the impact of galvanic corrosion on 3D chip stacking and electrical performance
such as electro-migration, thermal cycling and high temperature storage will be evaluated. He should be able to
execute appropriate DoEs under the guide of his mentor. During the execution phase he will be supported by
imec experts and allowed to use imec advanced facility.
Type of project: Thesis with internship of 6 months-1 year.
Degree:
Master in Science or Master in Engineering majoring in chemistry (preferred), material sciences, physics,
electronics.
Responsible scientist(s):
For further information or for application, please contact Wenqi Zhang (Wenqi.Zhang@imec.be) and Philippe
Vereecken (Philippe.Vereecken@imec.be).

31
Master Thesis/Internship Topics 2012-2013

Direct heteroepitaxy of III-V semiconductors on silicon mediated by strain-relaxed


buffer layers
High mobility III-V semiconductors are an increasingly hot topic of research in the semiconductor industry. Their
use for high performance, low power logic devices has been envisioned, in the International Technology Roadmap
of Semiconductors (ITRS), for the 11-nm node and beyond. So far, the growth of III-V structures has been almost
exclusively carried out on lattice-matched III-V substrates (i.e. In53%GaAs or In52%AlAs lattice-matched to InP
substrates), to ensure that a defect-free, device-quality III-V active layer is achieved. The monolithic integration of
III-V materials onto a Si-based platform would bring a number of advantages: no need for large-size, expensive III-V
substrates; CMOS compatible processing; possibility to integrate different functional blocks monolithically onto the
same Si platform, such as logic/switching circuitry, high-frequency circuitry, and even optical interconnects.
However, the challenge of monolithic III-V integration onto Si poses tremendous challenges both at the
processing/integration level, and at a more fundamental material level.
The latter aspect arises from the considerable difference in lattice mismatch between Si and some of the III-V
materials considered as candidates for III-V high mobility channels (e.g. a formidable 8% between Si and In53%GaAs).
The lattice mismatch makes it difficult to achieve the growth of a defect-free III-V epitaxial layer directly on Si.
Additionally, the generation of polar/non-polar interfaces between a group-IV semiconductor (Si) and a III-V
material can result in the formation of antiphase boundaries (APBs), considered detrimental for correct device
operation. In order to mitigate the issues aforementioned, one of the approaches currently evaluated by the
scientific and industrial community entails the growth of a Strain Relaxed Buffer (SRB) between the Si substrate
and the III-V device layer. Data show that this route allows for a drastic reduction of the number of defects
reaching the active III-V device layers.
The project focus is to investigate the SRB structure dependence on a number of process parameters. The
structures will be grown by Metal-Organic Chemical Vapor Deposition (MOCVD). Concurrently, the candidate is
expected to characterize the stacks grown, both structurally (X-ray diffraction, electron and optical microscopy)
and electrically (Hall and sheet resistivity measurements on the active device layer). The candidate should also be
able to interpret the data collected and extract meaningful correlations.
Type of project: Internship of minimum 3 months.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material sciences.
Responsible scientist(s):
For further information or for application, please contact Mirco Cantoro (Mirco.Cantoro@imec.be).

32
Master Thesis/Internship Topics 2012-2013

3D FIB/SEM structural analysis of nano-electronic devices


Cross-sectional structural analysis of devices is important to control and optimize the processing, e.g. by measuring
layer thickness, etch depth and profile, trench filling or contact morphology. The combination of focused ion beam
milling (FIB) with scanning electron microscopy (SEM) in a dual-beam FIB/SEM is a major metrology tool for
these applications. To cross the point of interest, generally a manual sequential slice (i.e. ion beam milling) and
view (SEM image) approach is needed.
Topic for the internship is to investigate the use of automated slice and view routines for application to small
device structures as well as large volumes. Based on the obtained set of images a 3D reconstruction of the device
volume can be made with dedicated software. Subsequently this can be cut in any given direction. With the
electron and ion beam conditions the information depth in the images and the step between the subsequent slices
can be varied. The combination of both will determine the resolution of the 3rd dimension in the reconstructed
volume.
The work will involve: get acquainted to acquire high-quality SEM images, to explore the capabilities of the
automated slice-and-view image acquisition software and to establish best procedures for small or very large
volumes, to study the best experimental conditions for the milling and imaging, and 3D reconstruction of the set of
images. Applications will be e.g. metallization structures on devices, through-silicon-vias (TSV), neuron cells on
nano-devices.
Type of project: Internship of 3-6 months.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material sciences, physics,
electronics.
Responsible scientist(s):
For further information or for application, please contact Hugo Bender (Hugo.Bender@imec.be).

33
Master Thesis/Internship Topics 2012-2013

Carrier depth profiling with micro-probes on advanced ultra-shallow high-mobility


CMOS semiconductor structures
As CMOS devices get smaller with each technology node, the processes needed to fabricate and characterize
these also become more and more complex. Moreover, the fast introduction of new high mobility materials (Ge,
III-V) additionally complicates the electrical analysis of these new structures. Crucial technological parameters
which directly relate to the performance of the final devices are the sheet resistance of the involved ultra-shallow
junctions (USJs) and the detailed shape of their carrier depth profile.
Historically conventional four-point probes (with mm separation and 100 g load) have been used (and still are) for
the determination of the sheet resistance. The Spreading Resistance Probe (SRP) has been used for carrier depth
profiling of USJs on Silicon and Germanium and Electrochemical Capacitance Voltage on III-V materials. As new
high mobility materials are, however, introduced and USJ become shallower (sub-50 nm), these conventional tools
become basically useless (too high probe penetration, too large contacts, large correction factors, insufficient
depth control, etc.).
Recently two promising new tools have become available, i.e. the micro-four point probe (M4PP) and the
NanoProber (NP). The main strength of the former is accurate, absolute, zero-penetration, sheet resistance
measurement (within 0.1%), the strength of the latter is measurements in vacuum with highly flexible positioning of
the micro-probes. Both tools can be applied to the new high-mobility materials needed today and have probe
contact sizes small enough for sub-50 nm depth profiling. The main goal of this work is to investigate and compare
in detail the two- (=spreading resistance) and four-point (=sheet resistance) based capabilities of M4PP and NP to
accurately extract carrier profiles along a slanted (beveled) surface for sub-50 nm ultra-shallow junctions in high
mobility materials and to develop a physical understanding for the observed differences (noise behavior, shape
calibration curves, sampling volume, etc.).
The major steps in this work will be: (i) Familiarizing oneself with all the tools involved in this work (M4PP, NP
(+SEM), profilometers, polishing tools, Labview and Tivoli software, etc.), (ii) Enhancing the NP software to allow
for two (four) point resistance depth profiling, (iii) Performing M4PP and NP measurements (iv) Investigate the
impact of different measurement parameters (pitch, pressure) on the accuracy of the extracted carrier profiles, (v)
Developing physical understanding for the observed experimental results, (vi) comparing results with other
techniques such as Scanning Spreading Resistance Microscopy (SSRM), SRP and Secondary |Ion mass Spectrometry
(SIMS) data.
Type of project: Thesis of 6 months.
Degree:
Master in Science or Master in Engineering majoring in physics, electrical/electronic engineering, material science.
Responsible scientist(s):
For further information or for application, please contact Trudo Clarysse (Trudo.Clarysse@imec.be) and Kai
Arstila (Kai.Arstila@imec.be).

34
Master Thesis/Internship Topics 2012-2013

Development of a professional data analysis package for the micro-four point probe
(M4PP)
The micro-four point probe (M4PP) is an electrical technique that allows for the very accurate measurement of the
(sheet) resistance of a very thin (sub-100 nm) highly conductive semiconductor layer on top of a substrate of
opposite impurity type (n- or p-type) (by pushing a current through the outer two probes and measuring the
resulting voltage difference between the inner two probes). In 2009 such a M4PP tool has been installed at imec.
The tool came with commercial software (from Denmark) for the sheet resistance raw data collection, but not for
the data manipulation of the many different data files or consequent data interpretation.
When applying this technique to a bevelled surface (slanted), one can generate a sheet resistance versus depth
profile, from which the underlying carrier depth profile can be extracted. The latter is of crucial importance for the
development of future state-of-the art transistors. In 2010-2011 an initial version of a brand new M4PP data
treatment software package named Tivoli has been implemented. During the next (second) academic year Tivoli
was enhanced among others with improved smoothing capabilities, a graphics overlay module and printing
capability.
The goal of the third working year of this project is, to continue the development of the Tivoli package for both
surface sheet resistance+mobility and carrier depth profiling analysis. The programming environment is Microsoft
Visual C++, with the Trolltech/Nokia Qt4 class libraries and Qwt graphics libraries. Issues involved in this work
will be: (i) For surface analysis, making different types of result plots/maps (resistance/voltage versus position, twodimensional 200- and 300 mm resistance contour maps, etc.) and implementing support for a new micro-probe
CIPTech tool allowing to extract mobility data from the measurements, (ii) For carrier depth profiling,
implementing probe pitch correction algorithms and adding support for two point (so called spreading resistance)
measurements, which have a smaller sampling volume, (iii) Adding further support for making overlays with profiles
from other dopant and carrier characterization techniques, (iv) Eventually semi-automatically generation of analysis
results reports (in MS Word or PDF format).
It is not the aim of this work to develop new data treatment algorithms. This subject is, however, a challenge for
those who wish to specialise themselves in all aspects and capabilities of object-oriented Windows programming
within the Visual C++ environment with a signal-slot architecture (Qt) environment, focussing on a truly userfriendly graphical user interface (GUI).
Type of project: Thesis of 6 months.
Degree:
Master in Industrial Sciences majoring in electrical/electronic engineering, option information- and communication
techniques (ICT).
Responsible scientist(s):
For further information or for application, please contact Trudo Clarysse (Trudo.Clarysse@imec.be).

35
Master Thesis/Internship Topics 2012-2013

Development of an industrial analysis-package in Visual C++ for SSRMmeasurements


The goal of this project is to develop and to implement in the Microsoft Visual Studio C++ 2008 (v9) programming
environment in combination with the Microsoft Foundation Class (MFC) libraries, Windows XP/Vista/7 compatible
software for the analysis of SSRM-measurements, which has been named MicroQuanti (MQ). This thesis is part of
a long-term project.

Figure 1. Screenshot of the MicroQuanti software illustrating the area detection and the quantification procedures for a classical planar
MOSFET.

SSRM (Scanning Spreading Resistance Microscopy) is an AFM (Atomic Force Microscopy) based technique
developed a few years ago that makes use of a very small conducting probe (nm scale) to measure the local
resistance of a small piece of conducting material along its cross-section. This delivers a two-dimensional
resistance image where the colour of every pixel is corresponding to the magnitude for the measured resistance
(see Figure1). The SSRM resistance picture has then to be converted as accurately as possible into a carrier
concentration image where every pixel indicates the number of carriers (electrons and/or holes) present at every
position. The aspects that will be investigated in this thesis are the improvement of the two-dimensional smoothing
procedure for the resistance pictures (suppression of noise in the measurements) and the introduction of a twodimensional quantification procedure based on a new type of calibration structure (from resistance to carrier
concentration). Furthermore, a new graphics user interface will have to be developed to allow the end-user more
control over a large number of critical parameters.
Type of project: Thesis of 6 months.
Degree:
Master in Industrial Sciences majoring in electrical/electronic engineering, option information- and communication
techniques (ICT).
Responsible scientist(s):
For further information or for application, please contact Trudo Clarysse (Trudo.Clarysse@imec.be) and Pierre
Eyben (Pierre.Eyben@imec.be).

36
Master Thesis/Internship Topics 2012-2013

Development of probes for nanoscale electrical measurements and manipulation in


a nanoprober system
Imecs nanoprober consists of an electron microscopy (SEM) system which is equipped with up to four
nanomanipulators
and electrical measurements units. It allows for dedicated nanoscale manipulation,
measurement and characterization tasks. Various add-on components have been added to the nanoprober such as
an energy dispersive X-ray spectroscopy (EDS) unit, a heating stage, a micro-gripper, an electron beam induced
current (EBIC) module, and a micro-gripper which are extending the application range. It is used for example for
electrically probing nanostructures such as nanowires and carbon nanotubes, for characterizing localized thin-film
stacks, and for manipulating nanostructures using a pick-and-place approach.
Electro-chemically etched tungsten wire needles are commonly used as tips in the nanoprober. They are manually
made and suffer from oxidation and suffer from low sharpness of typically 50-100 nm. Furthermore, tungsten is
not well suited for all measurements and alternative tip materials are highly desirable. Therefore, we have
demonstrated in a first step micro-fabricated in-plane diamond tips and evaluated them in the nanoprober. Besides
their in-plane tip geometry, the probes are similar to common scanning probes used in atomic force microscopy
(AFM). Unfortunately, this probe configuration is too cumbersome to use in a nanoprober setup. It is therefore
the aim of this internship to develop and test a dedicated probe configuration for the nanoprober. For this,
micro-fabricated tips in metal and doped diamond will be assembled to dedicated nanoprober probes and will be
then mechanically and electrically evaluated inside the nanoprober. The student will optimize the probe assembly
and configuration. He/she will learn to work with SEM, to carry out micro-assembly, and to manipulate and
electrically measure on the nanometer scale.
Type of project: Internship of 3-6 months.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material sciences, physics,
electrical engineering, ...
Responsible scientist(s):
For further information or for application, please contact Thomas Hantschel (Thomas.Hantschel@imec.be).

37
Master Thesis/Internship Topics 2012-2013

Diamond probes more efficient and optimized yield assessment


Boron-doped diamond tips have become the ultimate choice for performing electrical measurements on the
nanometer scale with ultra-high spatial resolution. In contrast to other diamond applications where it faces a
strong competition from other materials, doped diamond is the only material which can withstand the extremely
high pressures (in the GPa range) needed to establish a good electrical contact on silicon and germanium. The solid
diamond tips are made by so-called molding whereby first a pyramidal pit is etched, then it is filled up with
diamond and finally the mold is etched away. The pyramidal tip is attached to the end of a metal cantilever beam.
Using such probes advanced nanoelectronics device structures (e.g. planar field-effect transistors (FETs), FinFETs,
tunnel-FETs (TFETs), solar cell structures) are routinely measured in scanning spreading resistance microscopy
(SSRM) with a spatial resolution of 1 nm. However, the fabrication yield for such tips is still very limited to only
about 30-50%. A tedious and time consuming probe evaluation procedure is therefore in place to determine the
yield for a fabricated probe wafer (~45 minutes per probe, ~15 hours per wafer). The measurements results are
important feedback for further process optimization. Another drawback of the existing evaluation procedure is
that there is an observation gap between the tests done on the calibration structures and on real-life device
structures.
The goal of this internship is therefore the development of an improved probe qualification methodology. This
involves the critical assessment of the existing testing procedure with respect on how it can be improved towards
a better match with device measurement observations and the reduction of probe testing per probe and wafer
respectively. For this, also more advanced calibration structures will be studied and novel approaches for probe
yield determination will be assessed. The student will be trained in the use of atomic force microscopy (AFM), in
particular the use of the SSRM method. He/she will learn and carry out probe mounting and testing of in-house
fabricated full-diamond tips. After having gained practical experience in the use of the existing methodologies, the
student will work towards a more efficient and predicting probe qualification process.
Type of project: Internship of 6 months.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material sciences, physics,
electrical engineering, ...
Responsible scientist(s):
For further information or for application, please contact Thomas Hantschel (Thomas.Hantschel@imec.be).

38
Master Thesis/Internship Topics 2012-2013

Advanced materials characterization using ion beam scattering


This topic is an opportunity to learn about fundamental materials characterization techniques in a state-of-the-art
nanoelectronics research center. You will be exposed to challenges in current and future CMOS technology.
Novel materials processing techniques and characterization approaches have boosted the nanoelectronics industry
dramatically. We have witnessed the introduction of high-k materials (e.g. HfO2) replacing the SiO2 insulator in
advanced transistors, and metals (e.g. TiN) replacing poly-Si as a gate material. Yet, the introduction of novel
materials is expected to be even more essential in the future. Research is ongoing to replace Si by alternative
materials that exhibit a higher mobility. Finally, new materials are also needed for the realization and optimization
of new devices such as resistive memory (RRAM) cells, conductive bridge resistive memory (CBRAM),
photovoltaic (PV) cells, nano-batteries, micro-electromechanical systems (MEMS), light emitting diodes (LEDs) etc.
The development of new materials at imec builds also upon the experience and expertise of the materials and
component analysis (MCA) department.
One of our major tools is an ion accelerator (maximum 2 Mega Volt) with two dedicated end stations; one for
Rutherford Backscattering spectrometry (RBS), and another for Elastic Recoil Detection (ERD) experiments. In
RBS, essential information from the sample is gained from the residual energy of the scattered projectiles. In ERD,
the information comes from the energy of the recoiled target atoms. To attain the best possible detection
resolution, the acceleration voltage and the projectile species need to be properly chosen in relation with the
nominal sample structure and the known detection schemes.
The focus of your work will be to investigate novel materials, e.g. GaN, using Elastic Recoil Detection experiments.
Till now, at imec, we have been employing mostly a 6 MeV Cl beam for the ERD analysis of thin films. It may be
expected that projectile beams other than Cl (e.g. Cu, Br, I) and primary energy other than 6 MeV are more
effective in the analysis of certain thin films. Through simulations (software available) and practical experiments,
you will investigate the capabilities of various ion species and acceleration voltages towards the analysis of new
materials.
Type of project: Internship or thesis of 6 months.
Degree:
Master in Science or Master in Engineering majoring in material sciences, physics, chemistry, electronics.
Responsible scientist(s):
For further information or for application, please contact Johan Meersschaut (Johan.Meersschaut@imec.be).

39
Master Thesis/Internship Topics 2012-2013

Ultra high vacuum SSRM nanocontact modeling - Electrical and mechanical


impacts of low temperatures (70K)
SSRM (Scanning Spreading Resistance Microscopy) is an AFM (Atomic Force Microscopy) based technique
developed a few years ago that makes use of a very small conducting probe (nm scale) to measure the local
resistance of a small piece of conducting material.

Figure 2. UHV-AFM system equipped


with SEM column and liquid nitrogen
cooling system.

Figure 3. Transport processes in a forward-biased


Schottky barrier

Figure 4. Electron mobility as a


function of temperature for
various impurity
concentrations

Working at room temperature, an electro-mechanical modeling of the nanocontact between the probe and the
semiconductor to be analyzed has been proposed for silicon and validated experimentally. It has been
demonstrated that the high-pressure (around 10 GPa) tip-silicon SSRM nanocontact was a Shottky contact
impacted by surface states for lowly doped material and by the tunneling through the barrier potential for highly
doped material. The current transport in metal-semiconductor contacts is dominated by majority carriers (in
contrast to p-n junctions) and in forward bias conditions four transport processes are taking place : (a) the
transport of electrons from the semiconductor over the potential barrier into the metal, (b) the quantummechanical tunneling of electrons trough the barrier (that is important for heavily doped semiconductors), (c) the
recombination in the space-charge region, and (d) the hole injection from the metal to the semiconductor (Fig 2).
For low temperatures, its known that the emission of electrons from the semiconductor over the top of the
barrier into the metal is reduced. Hence the tunneling current will dominate at higher dopings. As observed
experimentally and modeled in the Unified Mobility model, the mobility within the semiconductor is also affected
when the temperature is lowered (Fig. 3). Moreover, the lowering of the temperature is also impacting the
mechanical properties of the material to be analyzed (hardening of metal, modification of semiconductor phase
transformations involved in SSRM,...). Using a UHV AFM system equipped with a SEM column (Fig. 1) to perform
point-contact measurements (I-V and force curves) as well as scan analysis on dedicated p- and n-type staircase Si
test-structures, the student will have to study the impact of temperature (ranging down to 70K) on the electromechanical SSRM nanocontact and consequently on the SSRM performances.
Type of project: Thesis of 6 months.
Degree:
Master in Industrial Sciences majoring in electrical/electronic engineering.
Responsible scientist(s):
For further information or for application, please contact Pierre Eyben (Pierre.Eyben@imec.be).
40
Master Thesis/Internship Topics 2012-2013

Atomic Layer Deposition of ultrathin metal films for advanced nanoelectronic


applications
Ultrathin metal films play an increasingly important role in advanced microelectronics, e.g. as gate electrodes in
transistors and capacitors and as diffusion barriers and seed layers in interconnect applications. For dielectric thin
films, the most customary deposition method is atomic-layer deposition (ALD) because of the possibility of
depositing high-quality films at low temperature. By contrast, the deposition of metallic thin films by ALD has been
studied much less. Recently, there is high interest in the ALD of elementary metals such as ruthenium, aluminum,
tantalum... .
The ALD of metals encounters several challenges. First, a very long growth inhibition is often observed, i.e. the
deposition starts only after a certain time span, during which the surface is exposed to the precursors but no film
is deposited. The growth inhibition often implies a rough, island-like film growth. That is highly unwanted because
for all applications, ultrathin (< 5 nm), smooth and continuous metal films are required. Second, in many cases of
metal ALD, plasma is used during the ALD process. The latter is called plasma-enhanced ALD (PE-ALD). PE-ALD
often results in improved growth and better properties of the deposited metal, such as conductivity, purity.
However, the plasma however, can also detrimentally impact the substrates properties due to exposure of the
substrates surface to the plasma species at the initial stage of the growth.
The student will conduct experiments on state-of-the-art (PE)-ALD equipment in order to deposit ultra-thin,
continuous metal films. The focus will be on the understanding and characterization of the initial growth of the
films with the aim to improve the nucleation and the film properties. To study the film properties, he will use
various techniques such as ellipsometry, X-ray-reflectivity and -diffraction measurements, resistivity by 4-points
probe measurements, rutherford backscattering spectrometry,... Furthermore, he will be involved in the
integration of the deposited layers in nanoelectronic devices to assess its impact on device level.
Type of project: Thesis and/or internship.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in physics, chemistry, material
sciences.
Responsible scientist(s):
For further information or for application, please contact Johan Swerts (Johan.Swerts@imec.be) and Sven Van
Elshocht (Sven.VanElshocht@imec.be).

41
Master Thesis/Internship Topics 2012-2013

In-situ molecular beam passivation of III-Sb compounds


Further scaling of CMOS High Performance devices and circuits for logic applications along the lTRS roadmap
guidelines asks more and more for high carrier mobility channel materials. The antimonide-based III/Vs are known
to have even higher mobilities, up to 77000 cm2/V.s for InSb. The most exciting aspect of the III/Vs however could
be that also pFETs could become in reach if we look into strained antimonides, with mobilities even higher than
these of germanium. Two major problems with antimonides is i) how to fabricate these materials on our standard
large size silicon substrates, and ii) how to passivate the gate oxide/channel interface. With respect to the first
problem, the most straightforward solution is to grow these materials on the silicon substrate. Two issues have to
be taken into account, which is the huge difference in lattice size (almost 16 % for InSb), and the strong tendency
to segregation and facet formation. Concerning the second problem: in order to suppress gate leakage, one has to
make use of a thin high-k dielectric layer between the channel and the metal gate. But passivation of this interface
between the compound semiconductor and a high-k dielectric is known to be a huge problem. In this context, an
appropriate passivation techniques have to be developed (in-situ oxide deposition, H2S-H2Se interlayers, ...), keeping
in mind that the equivalent oxide thickness (EOT) must be controlled down to ~0.5 nm.
The purpose of this work is to study physically and electrically the in-situ passivation of III-Sb semiconductors with
different passivation schemes and high-k oxide by the means of molecular beam epitaxy techniques.
Type of project: Thesis and/or internship.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material science, physics,
electronics, ...
Responsible scientist(s):
For further information or for application, please contact Clement Merckling (Clement.Merckling@imec.be).

Developing in-situ doping of III-V compound semiconductors by hetero-epitaxial


MOCVD growth
The epitaxial growth of III-V compound semiconductor on silicon substrate as channel material is a very promising
method for future CMOS device fabrication because of their high electron mobility. Their implementation in
conventional MOS structures requires thin III-V layers to be grown on a silicon substrate with shallow, abrupt and
well-controlled doping profiles. The doping efficiency is influenced by many growth conditions such as precursors,
the growth temperature, annealing treatments etc. This work focuses on the doping studies (growth and advanced
characterizations) of III-V thin layers (typically InP, InGaAs, InAlAs) during MOVPE growth, by using different
doping elements such as carbon and silicon. The aim is to develop effective and reproducible growth processes so
that the doping concentration and diffusion of the doping elements can be tightly controlled.
Type of project: Thesis and/or internship.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material science, physics,
electronics, ...
Responsible scientist(s):
For further information or for application, please contact Clement Merckling (Clement.Merckling@imec.be).

42
Master Thesis/Internship Topics 2012-2013

Effect of confinement and position of dopants on the ionized impurity scattering


limited mobility in a few-dopant double gate junctionless FET or all-around gate
cylindrical nanowire junctionless transistor
As nanowire dimensions are scaled down the number of dopants in the nanowire becomes small. Even for a
relatively large doping density of 1019 cm-3 a cylindrical nanowire with radius 5 nm and channel length 10 nm will
only contain about 7 dopants. As a result, the usual method of impurity averaging does not work and the discrete
nature of dopants needs to be taken into consideration. In this thesis the student is expected to calculate the
electrostatic potential of a single Coulomb charge in a nanowire surrounded by a dielectric and metal gate. The
Coulomb field of a charge residing in a semiconducting nanowire or double gate structure is determined by the
boundary conditions imposed on the electrostatic potential of this charge. In a semiconducting nanowire
junctionless FET with surrounding dielectric and gate or a double gate FET structure with dielectric and metal gate,
the electrostatic potential is determined by solving Poissons equation for a single charge with appropriate
boundary conditions. For a double gate junctionless FET the presence of the planar dielectric and metal gates will
also determine the electrostatic potential of the Coulomb charge. The obtained electrostatic potential is used to
calculate the scattering rate for ionized impurity scattering using the Boltzmann equation in the relaxation time
approximation together with Fermis golden rule. The student is expected to investigate the effect of confinement
(wire radius, gate voltage) and of dopant position in the wire on the low-field mobility.
The candidate should have a strong background/interest in solid-state physics, quantum mechanics and
computational physics.
Type of project: Thesis
Degree:
Master student majoring in physics, electrical engineering, nanoscience, nanotechnology.
Responsible scientist(s):
For further information or for application, please contact Bart Soree (Bart.Soree@imec.be).

43
Master Thesis/Internship Topics 2012-2013

Characterization and modeling of the junctionless III-V nanowire for novel device
applications
A junctionless nanowire FET is a novel device invented in imec which is uniformly doped throughout source,
channel and drain. It has been shown that the junctionless transistor offers the promise of superior scaling to sub22 nm dimensions compared to regular transistors. Originally, the junctionless nanowire transistor was designed to
avoid detrimental surface interactions which have a negative impact on the transport properties of charge carriers
inside the channel of the device such as surface roughness or remote phonon scattering. The uniform doping
throughout source, channel and drain greatly simplifies the fabrication process due to the absence of doping
junctions. The current-voltage characteristics of this novel device are very similar to a conventional inversion
mode (MOSFET) device. The current in this device is carried by the majority carriers delivered by the dopants. In
order to switch off the current, an all around gate must deplete the doped channel by applying a gate voltage (field
effect). Moreover, the junctionless nanowire transistor can also be used in the low-temperature regime to possibly
create a superinsulator which is a material with infinite resistance. Such material should (in analogy to a
superconductor) show a phase transition with respect to temperature and/or applied voltage [1]
The student is expected to measure the electrical properties of single III-V nanowire devices by means of
conventional probe stations, with and without cryogenic capability, for which he will be adequately trained. The
data collected (current vs. voltage characteristics) will be organized and plotted to extract the quantities of
relevance and interest. The student is also expected to interpret the characterization results by modeling the
junctionless pinch-off transistor. Here, the student can make use of the expertise available in the physics, modeling
and simulation group. Analytical modeling can be performed by using an existing model in which the material
parameters are adjusted to handle III-V materials, and if feasible and/or desirable quantum mechanical modeling of
the transport properties of charge carriers in the III-V nanowire can also be performed by the student.
[1] "Superinsulator and quantum synchronization", V. M. Vinokur, T. I. Baturina, M. V. Fistul, A. Y. Mironov, M. R. Baklanov and C. Strunk,
Nature 452, 613616 (2008).

Type of project: Thesis


Degree:
Master student majoring in physics, electrical engineering, nanoscience, nanotechnology.
Responsible scientist(s):
For further information or for application, please contact Bart Soree (Bart.Soree@imec.be), Mirco Cantoro
(Mirco.Cantoro@imec.be) and Wim Magnus (Wim.Magnus@imec.be).

44
Master Thesis/Internship Topics 2012-2013

Remote Coulomb, surface roughness and ionized impurity scattering in novel


nanowire all-around gate FET devices
In nanowire MOS field-effect transistors (FETs) degradation of the low-field mobility due to interactions occurring
at or near the interface between the substrate and the insulator are important in the strong inversion regime. In
this strong inversion regime, the electrons are mainly residing near the interface which results in a stronger
coupling of the electrons with interactions which are localized near or at the substrate-insulator interface.
The working principle of the novel junctionless pinch-off transistor does not require a strong inversion regime, but
is based on current carried by majority carriers flowing throughout the entire volume of the channel. As a result
one expects a lower impact of the detrimental surface interactions.
On the other hand, the junctionless pinch-off nanowire transistor requires doping, which in turn will depress the
low-field mobility due to ionized impurity scattering. In order to calculate the low-field mobility one needs the
scattering rates obtained from the Boltzmann transport equation in the relaxation time approximation in
combination with Fermis golden rule together with the energy spectrum and group velocities obtained from a selfconsistent Poisson-Schrodinger solver.
The student is expected to derive the scattering rates for the scattering mechanisms mentioned above and to
numerically implement these into an existing Poisson-Schroedinger solver for an all-around gate nanowire FET.
The student will compare the obtained results for such a device when operating in inversion mode (MOSFET) and
operating as a junctionless transistor. The candidate should have a strong background/interest in solid-state
physics, quantum mechanics and computational physics.

Type of project: Thesis


Degree:
Master in Science or Master in Engineering majoring in physics, electrical engineering, nanoscience,
nanotechnology.
Responsible scientist(s):
For further information or for application, please contact Bart Soree (Bart.Soree@imec.be).

45
Master Thesis/Internship Topics 2012-2013

Symbolic analysis of logic cells for advanced technologies


Growing complexity of logic design at nodes below 14nm forces to adopt a design style that can embrace the
simplicity required to enable manufacturing, along with a process technology that can be finely tuned to the desired
performance constraints. The co-optimization of allowable track budgets in standard cell library for power
delivery, layout patterns, active area analysis, and circuit design strategies would enable economical trade-offs at
the advanced technology nodes for 20 nm and beyond.
The candidate for this position will be responsible for developing a fully automated framework to combine both
lithography and electrical constraints of an advanced technology node to optimize the performance of a standard
cell library. The candidate should formalize the constraints on design rules for future technology. The outcome of
this analysis would be the bottleneck evaluation and characterization for the enablement of design at a particular
technology node. The framework should be able to evaluate the proposed optimizations at a cell library level.
During the execution phase, he/she will be supported by imec experts and will use the existing infrastructure
available at imec.
Skills needed:
Circuit design responsibilities require proficiency in analog, high-speed digital, and/or RF circuit design. The
candidate should have previous experience with Cadence and Mentor Graphics EDA tools. Proficiency with one or
more of the following software platforms /tools is highly desirable: MatLab, C/C++, Perl.
The day-to-day contact with people from all over the world makes fluency in English a necessity.
Type of project: Thesis with internship of minimum 3 months (6 months preferable)
Degree:
Master in Electrical/Computer Engineering.
Responsible scientist(s):
For further information or for application, please contact Arindam Mallik (Arindam.Mallik@imec.be) and Mustafa
Badaroglu (Mustafa.Badaroglu@imec.be).

46
Master Thesis/Internship Topics 2012-2013

II.

CMORE
Design and modeling of a single sensor 3-axis gyroscope for IMUs (inertial
measurement units)
Inertial measurement units (IMUs) appeared in consumer applications (gsm's, laptops, camcorders, ...) thanks to
their miniaturization and according small price. Nowadays, the trend in IMU development is to further miniaturize
them, to make them even cheaper and to increase their functionality by grouping more sensors in order to
broaden their application areas.
At imec, the SiGe-MEMS platform provides a good opportunity to realize a single chip, multi-sensor inertial unit. A
single chip solution is very appealing as the area of the total system can be optimized to achieve a high
performance system at a competitive price point.
Gyroscopes constitute a key element of an IMU. These are indeed an order of magnitude more complex than
other sensors present in IMUs, e.g. accelerometers, pressure sensors, magnetometers, .... They typically require
large sensor/readout areas and account for the main power consumption of IMUs. Traditionally, 3 separate
gyroscope sensors are used for a 3-axis sensing and reuse of readout circuit blocks is minimal. Recently a single
mass 3-axis gyroscope topology was introduced, which allows reuse of circuit blocks; hence reduce the area and
the power consumption of the sensor, which are both very appealing for the consumer market.
Throughout this study, the candidate is expected to examine this existing single sensor 3-axis sensing gyroscope
topology and model it using our current SiGe technology parameters. He/she is also expected to come up with
similar but different approaches/topologies for 3-axis single sensor gyroscopes. If time allows, he/she will design
such a gyroscope using our internal SiGe runs, and test the performance of the realized devices.
Type of project: Thesis and/or internship.
Degree:
Master in Science or Master in Engineering majoring in mechanics, physics, electronics, ...
Responsible scientist(s):
For further information or for application, please contact Akif Erismis (Akif.Erismis@imec.be) and Xavier
Rottenberg (Xavier.Rottenberg@imec.be).

47
Master Thesis/Internship Topics 2012-2013

Capacitive micromachined ultrasound transducers for imaging, telecom and power


transmission applications
Microelectronics experiences since the early seventies a period of sustained run-away development. Researchers
strive to keep up with and fulfill Moore's law by scaling transistors down thus cramming always more circuits,
more computing power and more functions on a chip always smaller and faster. However, this More of Moore era
is said to be coming to an end.
The past decade has seen the start of a paradigm shift. Acknowledging the limitations of the scaling model for
microelectronics, the emergence of novel technology drivers and appearance of new usage scenarios, e.g. low
power, nomadism, health care and health monitoring, ..., researchers started exploring alternative technological
paths. This defines the so-called More than Moore approach that departs from the one technology fits all approach
and aims at developing a plurality of diverse ad-hoc technologies and according interfacing solutions. RF-MEMS is
one of these technologies.
High-frequency MEMS resonators are the basic building blocks for embedded ultrasound systems. With their high
Q-factor, high-level of integrability, MEMS devices allow to define arrays of ultrasound sources and receivers onwafer, with their CMOS drivers and readouts. Besides the obvious extension of the well-known concept of
echography, such systems are promising alternative solutions for example to the problems of in-vivo power
delivery to implanted devices.
The objective of this work is to design and characterize MEMS-based ultrasonic sources and receivers. These
devices will have to be optimized for example for power-delivery. Major attention will be laid on the isotropic
power-scavenging ability of the receiver and increased directivity of the source obtained through appropriate
arraying. Required simulations will be performed in COMSOL and/or ANSYS (with hands-on training).
Type of project: Thesis and/or internship.
Degree:
Master in Science or Master in Engineering majoring in mechanics, physics, electronics, ...
Responsible scientist(s):
For further information or for application, please contact Xavier Rottenberg (Xavier.Rottenberg@imec.be) and
Harrie Tilmans (Harrie.Tilmans@imec.be).

48
Master Thesis/Internship Topics 2012-2013

(NANO)PHononicS: MEMS/NEMS acoustic devices and circuits


Microelectronics experiences since the early seventies a period of sustained run-away development. Researchers
strive to keep up with and fulfill Moore's law by scaling transistors down thus cramming always more circuits,
more computing power and more functions on a chip always smaller and faster. However, this More of Moore era
is said to be coming to an end.
The past decade has seen the start of a paradigm shift. Acknowledging the limitations of the scaling model for
microelectronics, the emergence of novel technology drivers and appearance of new usage scenarios, e.g. low
power, nomadism, health care and health monitoring, ..., researchers started exploring alternative technological
paths. This defines the so-called More than Moore approach that departs from the one technology fits all approach
and aims at developing a plurality of diverse ad-hoc technologies and according interfacing solutions. RF-M/NEMS is
one of these technologies.
Guided wave acoustic devices, e.g., resonators, transmission lines, filters, , are key building blocks for future
telecommunication systems. Indeed, with their extremely high Q-factors and linearity, these devices promise
making the natural trade-offs of system design obsolete.
The objective of this work is to design and characterize multi-stage acoustic filters, delay lines, oscillators or
acoustic black holes and cloaking structures. Using the technology available at imec, and especially the sub-micron
gap feature of our SiGe-MEMS technology, the candidates will endeavor in the booming field of phononics while
enjoying the opportunity of realizing transducers, drivers and sensors, with high electrostatic transduction
efficiency. Required simulations will be performed in COMSOL, Coventorware, MEMS+ and/or ANSYS (with
hands-on training).
Type of project: Thesis and/or internship.
Degree:
Master in Science or Master in Engineering majoring in mechanics, physics, electronics, ...
Responsible scientist(s):
For further information or for application, please contact Xavier Rottenberg (Xavier.Rottenberg@imec.be) and
Harrie Tilmans (Harrie.Tilmans@imec.be).

49
Master Thesis/Internship Topics 2012-2013

Nano relays and logic gates: designing at the nanoscale, in presence of nano
adhesion forces
Conventional logic switching is done by CMOS-based transistors, but these suffer from energy-efficiency
limitations imposed by the finite sub-threshold slope (large leakage current) in the CMOS transistors (especially for
sub 90nm CMOS). Purpose of this thesis topic is to replace the MOS transistor-based logic gates by NEMS
transistor-based logic gates thereby exploiting the low effective threshold voltage and zero leakage achievable with
these NEMS switching devices. These NEMS-based logic gates are expected to approach the ideal logic gate
behavior, which is characterized by two clearly distinct binary output levels (the 1 and the 0), by a minimum
(ideally zero) power consumption, by an abrupt transition between states at the output for a certain applied
input signal level, and, by a negligible time delay between the input transition and the output transition. A typical
implementation of a NEMS transistor is that of a NEMS relay. It is a nano-scale version of a conventional
electromechanical relay. Realizing these NEMS logic devices in imecs SiGe NEMS technology, under
development at the moment, allows integration of the NEMS logic devices above standard CMOS logic circuits,
thereby co-designing CMOS-to-NEMS.
The candidate will study and investigate the various typical NEMS logic implementations. In practice, (s)he will
optimize the design of NEMS relays taking into account the impact of nanoscopic forces, e.g. Casimir and van der
Waals forces, on the actuation characteristics of the devices, e.g. actuation voltages, response times, ... . Next,
(s)he will devise (novel) concepts for NEMS logic gates, along with a conceptual NEMS process flow (and choice of
materials). The focus will be on the detailed design, model and simulation of the performance of these NEMS logic
gates.
Type of project: Thesis and/or internship.
Degree:
Master in Science or Master in Engineering majoring in physics, mechanics, electronics, ...
Responsible scientist(s):
For further information or for application, please contact Xavier Rottenberg (Xavier.Rottenberg@imec.be),
(Harrie Tilmans (Harrie.Tilmans@imec.be) and Veronique Rochus (Veronique.Rochus@imec.be).

50
Master Thesis/Internship Topics 2012-2013

MEMS-based loudspeaker
A typical loudspeaker is an electromechanical transducer that converts electrical audio signals (20Hz to 20kHz) at
its input into sound waves generated at its output due to changes in the air pressure in the vicinity of the
loudspeaker. Conventional loudspeakers typically rely on the electro-dynamic (moving-coil) principle.
Microspeakers are (miniaturized) loudspeakers fabricated using micromachining or MEMS technologies and offer
small size and low weight. Compared to electrodynamic loudspeakers, electrostatic loudspeakers appear more
amenable to miniaturization and to MEMS fabrication. Down scaling the size (of the speaker diaphragm) however
has a degrading effect on the loudness of the speaker (becoming more severe for the lower frequencies).
Conventional speakers are always of the analog type. A novel speaker concept is based on so-called Digital
Sound Reconstruction (DSR). DSR is a process by which discrete acoustic pulses of energy created from an array
of speakers (or speaklets) are summed to produce a time-varying sound (pressure) waveform. As such, the
acoustic output (sound) is provided directly from a digitally-encoded signal. From first studies it appears that DSR
based speakers suffer much less when downscaling the system and thus offer potential for ultra-slim, small
loudspeakers.
The candidate will study and investigate the various typical MEMS loudspeaker implementations (both of the analog
and the digital type) and more in particular (s)he will explore the impact of down scaling (miniaturizing) and
ultimate size limits of the speaker (application dependent). A (performance) comparison will be made of the
different electromechanical transduction mechanisms. Next, (s)he will devise (novel) concepts for MEMS
loudspeaker, analog as well as digital (thereby implementing the most effective transducer), along with a conceptual
MEMS process flow (and choice of materials). The focus will be on the detailed design, model and simulation of the
performance of these MEMS loudspeakers.
Type of project: Thesis and/or internship.
Degree:
Master in Science or Master in Engineering majoring in physics, electronics, ...
Responsible scientist(s):
For further information or for application, please contact Xavier Rottenberg (Xavier.Rottenberg@imec.be) and
Harrie Tilmans (Harrie.Tilmans@imec.be).

51
Master Thesis/Internship Topics 2012-2013

III.

Smart Systems
Measurement and calibration of models for advanced photovoltaic modules
Photovoltaic solar panels provide a very attractive solution for future clean energy provision on site. Today's
panels provide a relatively high efficiency under optimal conditions and when just fabricated. However, when
external temperature, radiation angle, and radiation concentration conditions are varying, also the power efficiency
fluctuates quite heavily. Moreover, aging effects do play a role in both the panels and the convertor of the solar
energy system. The range of these effects heavily depends on the context in which these panels are used and on
the type of technology used.
We will mainly focus on crystalline silicon flat-plate modules using the most cost-effective solar cells.
In this thesis, we want to measure the characteristics of flat-plate modules. Both electrical and thermal effects will
be included. The measurements will also be used to calibrate 3D finite-element models. This will contribute heavily
to improve the energy-yield efficiency over the entire life time of the future solar system. That will result in a large
practical impact of the work in this thesis.
Profile: strong interest in measurement setups and hardware, basics of electrical SPICE-level modeling, basics of
thermal modeling.
Type of project: Thesis of minimum 6 months (full-time, at Leuven).
Degree:
Master in Engineering majoring in micro- or nano-electronics.
Responsible scientist(s):
For further information or for application, please contact Jonathan Govaerts (Jonathan.Govaerts@imec.be) and
Francky Catthoor (Francky.Catthoor@imec.be).

52
Master Thesis/Internship Topics 2012-2013

Life-time measurements and modeling of organic photovoltaic solar modules


Organic photovoltaic solar cells provide a very cheap and attractive solution for future clean energy provision on
remote sites. Today's cells and materials provide a reasonable efficiency but due to various degradation
mechanisms (induced by the exposure to air, water, heat) they rapidly fail.
Insight into these steady-state mechanisms has been developed and is also part of an ongoing research at imec.
Contrary to laboratory ageing in real-life context, especially outside, weather conditions are constantly evolving
(clouds, shadow, light, heat etc.).
This does not only lead to fluctuation in power conversion efficiency but also has considerable influence on device
degradation. These rapid changes may even aggravate device failure, but for the moment they are not well studied.
However, theoretical models suggest that device degradation could be effectively mitigated by dynamically adjusting
device operation in correlation with the changes of the environment. For example, in case of partial shadowing of
the solar cell, it may be beneficial to suspend device operation momentarily. Otherwise even short-term
overheating accelerates device failure and considerably reduces device lifetime on the long-term. Such a smart
control can be realized at a minimal hardware cost but could substantially improve device lifetime i.e. considerably
reduce its final device cost. Hence this works bears the promise of important practical implications.
This thesis comprises both a practical and a theoretical part.
The practical part involves adaption of an existing device lifetime measurement system to record dynamic
changes of device performance and environmental conditions. For this work a basic knowledge of especially
electrical measurement and partly also semiconductor device physics is required. Knowledge of Labview is a
plus. As a result of this work the student will record the dynamic electrical response of the solar cells and
could later verify the impact of the simulator.
The theoretical part of the work comprises the investigation of the impact of various dynamic parameters and
means to mitigate them by controlling and interacting with the devices. This part of the work will be only
worked out at the initial stage (continued in follow-up activities).
It will most likely be performed at Matlab level so some knowledge of Matlab or other script languages is desirable.
Combination of the two parts will demonstrate the future potential of smart PV controllers.
In this first thesis, we plan to mainly focus on the practical part. The theoretical part will be further elaborated
especially in follow-up work.
Type of project: Thesis of minimum 6 months (full-time at Leuven). Earliest possible start date for this project is
October 2012.
Degree:
Master in Engineering majoring in micro- or nano-electronics.
Responsible scientist(s):
For further information or for application, please contact Eszter Voroshazi (Eszter.Voroshazi@imec.be), Jan Genoe
(Jan.Genoe@imec.be) and Francky Catthoor (Francky.Catthoor@imec.be).

53
Master Thesis/Internship Topics 2012-2013

Machine learning on low power parallel architectures


Machine learning techniques are more and more used in our everyday environment to track untypical behavior or
predict possible events. These solutions more and more rely on the use of embedded, low power sensor nodes
that are hidden in our environment and execute the machine learning algorithms locally based on a limited
computational power. While machine learning research was traditionally focused on finding better algorithms to
predict the possible events, it is now becoming important to focus also on the computational efficiency of those
algorithms, and implementation feasibility on embedded low power processors.
To cope with the increasing computational complexity, at acceptable power cost, the trend is to go towards more
parallel architectures for embedded applications. For instance, data level parallelism which we find in SIMD
architectures, or instruction level parallelism which we find in VLIW architectures. These architectures however
come with many specific constraints related to the data flow. Many emerging machine learning kernels are designed
with sequential processing in mind, and are hence inherently incompatible with those architectures. If these
problems are not eliminated at high level, i.e., at functionality level, no low level compiler transformations will
allow to achieve acceptable results. This results in very inefficient resource utilization on parallel architectures, and
hence low energy efficiency.
At imec, we want to tackle this opportunity to study how we can improve the algorithms so that they map
inherently more efficient on SIMD or VLIW architectures. In this master thesis, we will start from a bottleneck
algorithm in the context of machine learning. For choosing the algorithm there are two options: First option is to
analyze two simple algorithms like decision tree learning and nave Bayes (NB). Since these algorithms have
opposite characteristics for the two separate phases in machine learning (learning and inference) they are ideal for
a comparison. Second option is to investigate one algorithm that is more involved like full Bayesian networks, a
Hidden Markov model (HMM), or a Gaussian Mixture Model (GMM). Then, algorithm transformations can be
proposed that improve the algorithm in terms of computational complexity.
The student will first have to carry out an extensive literature study related to machine learning and existing
implementations and bottlenecks. Then, the machine learning algorithm will be implemented on an embedded
parallel processor. To improve the efficiency of the implementation, possible algorithmic transformations will be
proposed.
The topic is proposed as master thesis possibly combined with an internship. The internship will focus on the study
of the algorithm. The master thesis will focus on the algorithm transformation so that it can be implemented on a
parallel architecture.
Type of project: Thesis and/or internship.
Degree:
Master in Science or Master in Engineering majoring in electrical engineering, computer science.
Responsible scientist(s):
For further information or for application, please contact Sofie Pollin (Sofie.Pollin@imec.be) and Wannes Meert
(Wannes.Meert@cs.kuleuven.be).

54
Master Thesis/Internship Topics 2012-2013

Algorithm and architecture co-optimizations for cost and power constrained Signal
processing system
Many fundamental innovations in ICT are driven by advanced signal processing systems and their efficient
implementations. As an example, wireless baseband signal processing is one of the key enablers for affordable Gbps
wireless communications. There are many other examples in areas such as computer vision, machine learning and
biomedical engineering.
As one of the key challenges in such innovation, cost and power of signal processing implementations need to be
minimized whereas application level requirements are not scarified. To achieve this goal, co-optimizations of the
following two will be essential:
Signal processing algorithms that extract useful information from raw data via various mathematical
transformations and searching operations.
Signal processing architectures that execute the above mathematical transformations and searching operations.
In the proposed thesis, the student will work on concrete cases such as:
MIMO detectors optimized for LTE and LTE-Advanced radio systems
Channelization for software defined radio receivers
Scale-invariant feature transform for computer vision applications
For each of the topics, the work will consist first of an extensive literature study of the involved algorithms. Next,
and algorithm will be selected with the help of the experienced imec researchers in the field. Finally, an efficient
implementation should be derived. To achieve this, possible algorithm or architecture optimizations will be
needed. The student will learn the respective application domain (e.g., MIMO detectors for LTE) as well as
embedded software design and computer architectures. As a result, this topic provides a good training for
industry-relevant skills as well as innovative algorithms and architectures.
Type of project: Thesis possibly with internship of total duration of 6 months.
Degree:
Master in Science or Master in Engineering majoring in electrical engineering, computer science.
Responsible scientist(s):
For further information or for application, please contact Sofie Pollin (Sofie.Pollin@imec.be) and Min Li
(MinLi@imec.be).

55
Master Thesis/Internship Topics 2012-2013

Complexity modeling and algorithm transformations for software defined radios


To keep improving spectral efficiency, future wireless standards will employ more and more advanced modulation,
coding and multiple-antenna schemes. To cope with their increasing computational complexity, at acceptable
power cost, the trend is to go towards more parallel architectures. For instance, data level parallelism which we
find in SIMD architectures, or instruction level parallelism which we find in VLIW architectures. However, these
architectures come with many specific constraints related to the data flow. Many emerging baseband processing
algorithms are designed with sequential processing in mind, and are hence inherently incompatible with those
parallel architectures. If these problems are not eliminated at high level, i.e., at functionality level, no low level
compiler transformations will achieve acceptable results. This leads to very inefficient resource utilization on
parallel architectures, and hence low energy efficiency.
At IMEC, we want to tackle this opportunity to study how we can improve the algorithms so that they map
inherently more efficiently on SIMD or VLIW architectures already during the algorithm design in Matlab. We need
therefore to define appropriate complexity measures for good algorithm design. With the establishment of good
metrics, it will be possible for algorithm developers to compare different algorithms with respect to
implementation friendliness. Typically, complexity is only available after the algorithm has been transformed and
compiled on the SDR (Software Defined Radio) processor, which is a costly task. The goal of this thesis is to
derive a method for complexity verification already in Matlab.
In this master thesis, we will start from a set of algorithms that were implemented on the imec SDR processor in
the context of LTE-advanced and WLAN standards. This can be soft MIMO equalizer computation and advanced
signal detection or channel processing of Hybrid ARQ. For these algorithms, that are available both in Matlab and
implemented on a parallel processor, a complexity estimate for implementation will be derived such that it can be
computed from the Matlab representation of the algorithms. Then, algorithm transformations can be proposed
that reduces the implementation complexity of those algorithms.
The student will first have to carry out a literature study related to both computer architectures and wireless
baseband algorithms. Then, the reference implementations of the imec wireless baseband will be studied. Finally, a
method will be derived to compute the complexity from the Matlab representation, and compared with the
reference implementation complexity. Many tools are available at imec for determining such a cost model, and the
student will have to select which one is most appropriate within the time constraints. A second goal of the
research would be to change the bottleneck algorithm so that an improvement is achieved on implementation
complexity.
The topic is proposed as internship combined with a master thesis, or a master thesis only. The internship will
focus on the modeling and metric definition. The master thesis will focus on the algorithm transformation. If
master thesis only, then the master thesis will focus on modeling and metric definition.
Type of project: Thesis or internship with thesis.
Degree:
Master in Science or Master in Engineering majoring in electrical engineering, computer science.
Responsible scientist(s):
For further information or for application, please contact Sofie Pollin (Sofie.Pollin@imec.be) and Claude Desset
(Claude.Desset@imec.be).

56
Master Thesis/Internship Topics 2012-2013

Collaborative spectrum sensing for cognitive radios


Spectrum is becoming a major resource constraint when designing radio systems. More and more wireless
technologies are being developed, resulting in a very heterogeneous mix of devices sharing the crowded spectrum.
This increasing success of wireless communication is likely to cause huge spectrum congestion problems in the
near future, similar to the well-known traffic jams caused by congestion or our roads. New paradigms for
efficiently exploiting the spectrum are clearly needed in this context. The need for a more flexible use of the
spectrum is currently recognized and investigated by the major regulatory/standardization bodies (IEEE, ITU, ETSI,
FCC, EC). Worldwide, we currently see some frequency bands opening up (e.g., TV spectrum) for more flexible
access. But similar to traffic congestion problems, it is not only required to provide more spectrum, but also to
make more efficient use of the available resources.
This has lead to the concept of cognitive radio. In its most general definition, a cognitive radio aims at sensing
and learning the environment to autonomously adapt its transmission parameters in order to improve the use of
network/spectrum resources. This requires the receiver to be able to scan the whole band, searching for
optimal transmit opportunities. Indeed, information about instantaneous spectrum occupancy can lead to a
spectacular better usage of the available capacity. Current radio architectures, which are focused on the reception
of a predefined channel are not able to proceed to this kind of scan operation in a timely, cost and energy effective
way. Therefore, a specific component must be added into the reception path. The latter, so-called sensing engines,
has to analyze the band occupation without necessarily recovering the information. Hence, its signal processing
functionality can be relaxed, leading to fast, cost effective and energy efficient implementation. Innovative sampling
schemes can be considered, to achieve this new sensing functionality.
Next to the local sensing, that is done by each wireless device, it is required to combine the sensed information to
obtain a global view of spectrum use in certain area. Because of the wireless propagation nature, it is indeed
required to obtain a more distributed view. However, local measurements tend to be noisy and inaccurate. Also
inconsistencies arise because of the presence of buildings causing very irregular propagation patterns.
The proposed activity consists in several tasks that can be carried out by several master or PhD thesis students in
the cognitive radio architecture and functionality team:
Building or adding sensing functional blocks to a detailed Matlab model to determine the performance of
sensing algorithms for target technologies such as WLAN, LTE, DVB-T,
Proposing extensions to existing sensing schemes to improve the sensing performance.
The algorithms complexity will be assessed and reduced in view of low power/low cost implementation.
Integrating the sensing engine in a network for collaborative sensing. Solutions to combine local measurements
into a consistent view of spectrum use.
Type of project: Thesis
Degree:
Master in Science or Master in Engineering majoring in electrical engineering, digital signal processing.
Responsible scientist(s):
For further information or for application, please contact Sofie Pollin (Sofie.Pollin@imec.be) and Peter Van
Wesemael (Peter.VanWesemael@imec.be).

57
Master Thesis/Internship Topics 2012-2013

Development of integrated passives for cellular duplexer module in CMOS


Reconfigurable radio platforms for 4G
in 40nm CMOS target more concurrent streams, higher rates and
flexibility, at low cost and power. Imecs reconfigurable radio front-end research focuses on scalable transceivers in
cost-effective digital CMOS technology, targeting low power, low cost, high linearity and multimodeoperation. In
addition, digital RF and surface acoustic wave (SAW)-less transceivers are being investigated.
In cellular handsets, duplexers are used in various frequency division duplexing (FDD) standards such as HSDPA
and LTE, where three-way filtering is required between the antenna, transmitter (TX) and receiver (RX). The lownoise amplifier (LNA) in the RX must be isolated by the duplexer from the large power amplifier (PA) signal to
circumvent compression, while at the same time allowing signals to transfer from PA to antenna and antenna to
LNA. To address modern multi-standard, multi-band integrated radios, a flexible duplexer would be desired over a
set of multiple fixed-frequency surface acoustic wave (SAW) duplexers, to lower board area and bill-of-materials
for cellular handsets. Integration of these modules onto the CMOS die is one of the final frontiers towards true
SAW-less radios. Several performance challenges arise with the implementation of such duplexers, which consist
of tunable passive components. Linearity, automated tuning and high-voltage sustainability are only a few of many
concerns.
In this project, imec is looking for a motivated MSc student to perform his/her thesis work on the development of
integrated passives on CMOS. The goal of the project is to design high quality passives for use in duplexer modules
for front-ends in future 4G cellular handsets. During this project, the student will investigate system-, circuit- and
component level issues related to the integration of duplexers. Furthermore, the student will perform the design
of critical passives in sophisticated EM simulation software. Depending on the available time and progress, a tapeout opportunity may allow the student to verify the designed passives on silicon during measurement.
Good communicative and planning skills are a must to complete the project within time.
Type of project: Internship of 6 months.
Degree:
Master in Science in Electrical Engineering majoring in micro-electronics or electromagnetism.
Responsible scientist(s):
For further information or for application, please contact Barend van Liempd (Barend.vanLiempd@imec.be),
Jonathan Borremans (Jonathan.Borremans@imec.be) and Jan Craninckx (Jan.Craninckx@imec.be).

58
Master Thesis/Internship Topics 2012-2013

Analog signal processing for medical signals


The ever increasing interest towards smarter, smaller, and autonomous wearable health monitoring for medical
and lifestyle applications is driving the research for the realization of ultra-low-power and wireless sensor nodes.
These sensor nodes will be responsible for extracting medical signals from the patient and process them to detect
the presence medical disorders.
One of the problems in digital signal processing of medical signals is the vast amount of data allocations extensive
DSP memory and leading to large power dissipations. An emerging approach to this problem is to shift some of the
signal processing from digital domain to analog. In order to realize this goal filters with special transfer functions
are required. The topic of this thesis will focus on the implementation of these analog filters first in Matlab and
then in transistor level.
Following skills are required for the applicants
a)
b)
c)
d)
e)

Excellent grades in courses Analog Integrated Circuit Design and/or Analog Filter Design
Strong background in Linear Algebra
Strong background in analog filter design
Experience with MATLAB
Experience with Cadence Design
Environment

Type of project: Thesis or internship of minimum 6 months.


Degree:
Master in Electrical and Electronics Engineering.
Responsible scientist(s):
For further information or for application, please contact Refet Firat Yazicioglu (Refet.Firat.Yazicioglu@imec.be).

59
Master Thesis/Internship Topics 2012-2013

Radio-frequency communication with metal-oxide electronics on plastic


In recent years, fast progress was made in the technology of thin-film semiconductor devices based on organic
semiconductors (such as pentacene and derivatives) and oxides, such as Indium-Gallium-Zinc-Oxide (GIZO). In
particular this latter semiconductor offers over amorphous silicon the advantages of a much higher carrier
mobility, of the order of 10 cm2/Vs, and room temperature processing, making it fully compatible with plastic
substrates. This new technology opens the way to circuits and systems fabricated directly on flexible plastic foil.
RFID transponders and tags are one type of application that will greatly benefit from this opportunity.
The crucial component of a passive RFID tag is the rectifier, which must operate at HF (13.56MHz) or more
preferable at UHF (869MHz). The diodes must follow the high-frequency input signal, still providing enough power
supply for the tag circuitry, which is accomplished only by optimized devices with low leakage current and charge
transient time. These devices can have mainly two topologies: the Schottky and transistor connected diodes.
Transistor-diodes are based on a shorted gate-drain transistor configuration. In this configuration, the gate-drain
electrode and the source act as the injector and the blocking electrode, respectively. The main advantage of such
topology is the integration with other circuitry, as exactly the same process technology as for standard transistors
can be used for its fabrication. Their main drawback, on the other hand, is the relatively long minimal channel
length that can be achieved with standard photolithographic processes.
The main task of the student is to investigate the effects of GIZO deposition on the transistor-diode
characteristics, in order to achieve high on/off drain currents and high electron mobility, targeting mainly the
transistor onset voltage control. This activity includes the fabrication of devices within imec clean room and our
laboratories using mainly two deposition techniques: RF sputtering and thermal evaporation. The second step will
be to integrate these single devices in a rectifier with integrated capacitances and characterize its frequency
response. Initially, the devices will be fabricated on a hard substrate such as silicon, but the final device should be
completely realized on a flexible plastic carrier. In order to develop insightful ideas about the diode performance,
all experimental work will be followed by analytical and SPICE model.
Type of project: Thesis or internship of 6 months.
Degree:
Master in Science or Master in Engineering majoring in material physics, electronics, nanotechnology.
Responsible scientist(s):
For further information or for application, please contact Adrian Chasin (Adrian.Chasin@imec.be).

60
Master Thesis/Internship Topics 2012-2013

IV.

HUMAN++
Light up your brain - An intracranial communication network
Reading your mind has applications in safety, medical diagnostics and treatment, and entertainment. For safety and
entertainment, non-invasive solutions based on caps and headsets are used. Non-invasive imaging provides useful
help for diagnosing brain diseases. But for treatment, medical staff uses invasive devices for a more resolved
picture of your brain activity, allowing them to zoom in millimeter-size brain areas. To go even further and touch
on individual cells, we may need to bring in many devices in the various regions of interest and that without
damaging the brain.
Tiny implants can be envisaged and are made possible by the downscaling of micro- and nanoelectronics. Such
devices must operate at ultra-low power while sensing their environment, communicating data between each
other and to a central hub, and being provided by energy remotely. Different physical principles can be used for
energy and data transfer: electromagnetic, magnetic, optical, ultrasonic,
The purpose of the work is to build a computational model of such a multi-node network. A high-level power and
communication model of each node and its surroundings shall be developed based on literature and existing
modules. For lower level physical modeling, computational frameworks based on Monte Carlo or finite-element
simulation shall be used, and high-level models shall be extracted. The final model shall allow trading off system
parameters such as node distances, node autonomy, aggregate data rate, and energy consumption and facilitate the
design of the nodes and the hub.
The actual work involves physical modeling & simulation, model extraction, high-level system modeling and
simulation. Matlab/Simulink is the target tool for the high-level system model. Several tools are available for
physical modeling & simulation. Programming skills are a clear asset.
Type of project: Thesis and/or internship of 6 months full-time.
Degree:
Master in Engineering or Master in Science majoring in electronics, telecommunications, physics, computer science.
Responsible scientist(s):
For further information or for application, please contact Wolfgang Eberle (Wolfgang.Eberle@imec.be).

61
Master Thesis/Internship Topics 2012-2013

Towards a non-linear time-varying I-V model for biomedical stimulation electrodes


In medical applications, micrometer-to-millimeter size electrodes are used for electrical stimulation of cells and
tissue. These electrodes operate in solution and exhibit a complex electrochemical reaction behavior which makes
their current-voltage relationship very non-linear and time-variant.
In current practice, such electrodes are either characterized for their large-signal behavior, e.g. using the cyclic
voltammetry technique, or for their small-signal behavior, e.g. using impedance spectroscopy. Separate models are
derived from measurements which can not be easily merged into a single common model describing the complete
electrode behavior.
The purpose is to develop a framework for measuring electrodes and complete model extraction. The starting
point is system identification of a non-linear time-varying system-under-test ("the electrode"), proper input signal
design, output signal analysis, and model extraction. Various kinds of electrodes are available for measurements as
well as programmable electrochemical measurement equipment.
The actual work is divided into 80% theoretical (computational model, data analysis) and 20% experimental work
(actual electrochemical measurements). Mathematical interest and some programming skills are a must.
Experimental experience is an asset.
Type of project: Thesis and/or internship of 6 months full-time.
Degree:
Master in Engineering or Master in Science majoring in electrical engineering, physics.
Responsible scientist(s):
For further information or for application, please contact Wolfgang Eberle (Wolfgang.Eberle@imec.be).

62
Master Thesis/Internship Topics 2012-2013

Investigating the long term behavior of TiN as electrode material for cell
interfacing technologies
The Bioelectronic Systems group at imec works towards the development of integrated circuit components and
prototype microsystems for in-vitro cell interfacing technologies (microelectrode arrays, biosensors) and well as
in-vivo applications (neural implants). The good electrical stimulation and recording performance of such systems
relies on the efficient, well characterized, and stable over time interface between the chip and the living tissue. This
interface is influenced not only by the electrode material, but also by a series of other factors such as the overall
chip design and topography, passivation, and barrier layers materials, prio- and post- electrode definition
processing conditions, packaging, and as well as the type of biological media involved.
This internship project will focus on structural, electrochemical characterization, and bio-compatibility of the TiN
electrode material currently used in our systems as a function of their exposure to various biological media. The
student will receive device wafers processed with different conditions and will perform the sample preparation for
all necessary characterization experiments. Some of the characterization techniques that will be performed by
other scientists (such as SEM, FIB, FTIR, etc.) but most of the electrochemical analysis (cyclic voltametry, EIS, etc.),
and as well as cell viability assays.(immunostaining, live/dead assays) will be conducted by the student itself with the
guidance of scientists working on this matter within the team. Given the international character of imec, fluency in
English is essential.
Type of project: Thesis or internship of 6 months.
Degree:
Master in Engineering or Master in Science majoring in chemistry, material sciences.
Responsible scientist(s):
For further information or for application, please contact Alexandru Andrei (Alexandru.Andrei@imec.be) and Silke
Musa (Silke.Musa@imec.be).

63
Master Thesis/Internship Topics 2012-2013

Localized electrical stimulation of in vitro neurons for guided growth


The effect of electrical gradients on cultured neurons and their outgrowth is still largely unknown. Most systems
used at present only allow for application of large electrical fields using large electrodes, which stimulate complete
networks of cells with low precision and efficiency.
The student/intern will use advanced microelectrode arrays (MEA) with high-density configurations - developed in
imec - to steer growth of in vitro cultured neurons in a much localized manner. Further, combination of
topographical and electrical guiding will be evaluated as well, as the MEAs contain small pillars, which are shown to
guide neurotic outgrowth.

The growth of the neurons will be monitored by long-term time-lapse confocal microscopy and fluorescent
immunohistological staining. Cellular growth patterns will be analyzed with image processing. Further, cell viability
will be checked at regular time points.
Type of project: Thesis and/or internship.
Degree:
Master in Industrial Sciences or Master in Sciences or Master in Engineering majoring in biology, bio-electronics,
biomedical sciences, nanotechnology.
Responsible scientist(s):
For further information or for application, please contact Dries Braeken (Dries.Braeken@imec.be) and Liesbeth
Micholt (Liesbeth.Micholt@imec.be).

64
Master Thesis/Internship Topics 2012-2013

Signal analysis of recorded electrical activity by advanced microelectrode arrays


Investigating the electrical activity of electrogenic cells, such as cardiomyocytes and nerve cells, has shifted from
single cell recording with patch clamp analysis towards the parallel readout of the electrical activity of multiple cells
with multi-electrode arrays (MEA). Recently, IMEC developed a CMOS-based MEA that is capable of assessing
individual cells in a cellular network for both electrical stimulation and recording. To fully understand the different
features of this new technology and the value of the recorded signals, several analyses have to be performed to
understand both the waveform of the recorded signal as well as the origins of the recorded wideband electrical
signal. These signals include components of noise that reflect issues of cell-electrode coupling, as well as signal
amplitudes that reflect cellular properties characteristic for depolarization and repolarization. Experiments will be
performed on monolayers of cardiomyocytes. The student will be involved in both experimental as signal analysis
parts.
Type of project: Thesis and/or internship.
Degree:
Master in Industrial Sciences or Master in Sciences or Master in Engineering majoring in biology, bio-electronics,
biomedical sciences, nanotechnology.
Responsible scientist(s):
For further information or for application, please contact Dries Braeken (Dries.Braeken@imec.be) and Danny Jans
(Danny.Jans@imec.be).

65
Master Thesis/Internship Topics 2012-2013

Improving the function, stability, and biocompatibility of carbon nanotube


microelectrodes for neuro-electronic applications
Device engineers are increasingly confronted with demands from neuroscientists and clinicians alike to develop
implantable microsystems that can probe and modulate neuronal activity down to cellular (10-50 m) and even
sub-cellular (<10 m) resolution. Ultimately, dense arrays with m-sized electrodes for single-unit, parallel, and
high-fidelity recording and selective stimulation of neurons or neuronal populations are envisaged.
Commonly used electrode materials such as Pt, Ir, and TiN face serious limitations in terms of their potential for
further electrode miniaturization. The electrode impedance, which scales inversely with the electrochemical
interface capacitance, may be too high - on the order of several MOhms - for small electrodes based on thin-film
materials to offer sufficient recording sensitivity. In addition, the high driving voltages required to supply sufficient
stimulation charge with small electrodes may damage the electrode and surrounding tissue. Recent efforts to grow
CNTs on multielectrode arrays have demonstrated that CNTs may boost the electrode performance by orders of
magnitude in comparison to other materials. Ensuring a low electrode impedance and good biocompatibility are
amongst the key requirements in this regard.
The objectives of this thesis/internship are to analyze the electrochemical, chemical, and structural properties of
microfabricated CNT electrodes of various diameters subjected to different (electro-) chemical and physical
treatments. The candidate will
characterize the CNT electrodes using various electrochemical techniques, including impedance spectroscopy,
cyclic voltammetry and chronopotentiometry and interpret the results.
explore (electro-)chemical and physical treatments such as acid and plasma exposure, and temporary coating
with oxide materials in order to introduce oxygenated surface functional groups which may improve the
wettablity and hence impedance of the CNT electrodes,
determine the qualitative and quantitative impact of these treatments on the chemical fingerprint and
morphology of the CNTs using Raman/infrared spectroscopy and SEM, respectively, and
investigate the CNT biocompatibility and in particular the influence of the Ni catalyst on cell viability by means
of primary rat hippocampal/cortical neuron cultures.
Type of project: Thesis or internship of minimum 6 months.
Degree:
Master in Science or Master in Engineering majoring in physics, electrical engineering, material sciences, chemistry.
Responsible scientist(s):
For further information or for application, please contact Silke Musa (Silke.Musa@imec.be) and Danielle Rand
(Danielle.Rand@imec.be).

66
Master Thesis/Internship Topics 2012-2013

Development of a test system for standards-compliance measurements for


biopotential amplifiers
Imec develops state-of-the art ultra-low-power biopotential amplifier integrated circuits for applications such as
electrocardiogram (ECG), electro-encephalogram (EEG), etc. International standards exist to which such circuits
should comply if they are to be included in products. The goal of the project is to develop a test system that allows
to characterize in an efficient manner these chips against the specifications of these standards. It will involve the
design of the hardware, outsourcing of the manufacturing of the hardware, design of the software, the writing of
documentation, as well as guidelines for the analog chip designers to help them make their circuits compliant and
testable.
Type of project: Internship (possibly with thesis) of minimum 6 months (full-time).
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in electronics.
Responsible scientist(s):
For further information or for application, please contact Tom Torfs (Tom.Torfs@imec.be).

Study of effects of thinning & design of test structures for analog chips
A novel way developed by imec to package chip is the ultra-thin chip package (UTCP). This requires the chips to
be extremely thinned to 20-30 micrometers thickness. At this thickness the chips become flexible. The goal of the
thesis is to study the effects of such thinning on the analog circuits (biopotential amplifiers, ADC, ...) realized by
imec, and as a next step to design and optimize test structures to be included on these analog circuits to simplify
functionality tests after such thinning.
Type of project: Internship (possibly with thesis) of minimum 6 months (full-time).
Degree:
Master in Science majoring in electronics.
Responsible scientist(s):
For further information or for application, please contact Tom Torfs (Tom.Torfs@imec.be).

67
Master Thesis/Internship Topics 2012-2013

Signal processing algorithms for a neuronal interface chip


We developed a mixed-signal CMOS chip with a high density array of integrated micro-electrodes for bidirectional interaction with biological neurons by means of electrical recording and stimulation.
In order to maximally exploit the performance of the system, signal processing algorithms can be used to compens
ate non idealities in the transducer. Further, more advanced measurement techniques can be implemented to extra
ct more detailed information about the cells.
In this project, you will work in collaboration with biologists to extract signals from live cells, and suggest and
demonstrate signal processing algorithms on real signals.
You will have the chance to participate in a dynamic team of multidisciplinary researchers in the field of bioelectronics.
Required background: Matlab, basic DSP, basic system theory
Type of project: Internship (possibly with thesis) of minimum 6 months.
Degree:
Master in Engineering majoring in electrical engineering, computer sciences.
Responsible scientist(s):
For further information or for application, please contact Roeland Huys (Roeland.Huys@imec.be).

Data acquisition system for integrated cell interfacing systems


In the field of bioelectronic research, the development of chips for interfacing brain cells with an automated
acquisition system requires a lot of development time.
In this thesis, you will look for options where this interfacing can be standardized from chip desig, high-speed I/O,
acquisition on PCB, DSP and software for data analysis. Starting from literature and existing commercial options,
you will make basic chip design circuits and simulation proof-of-concept, and make a demonstration using our
existing system with live cells.
You will have the chance to participate in a dynamic team of multidisciplinary researchers in the field of bioelectronics.
Background required: analog and digital VLSI design (preferably Cadence), Matlab
Type of project: Internship (possibly with thesis) of minimum 6 months.
Degree:
Master in Engineering majoring in electrical engineering, computer sciences.
Responsible scientist(s):
For further information or for application, please contact Roeland Huys (Roeland.Huys@imec.be).

68
Master Thesis/Internship Topics 2012-2013

V.

Energy
Degradation mechanisms in organic solar cells
Organic photovoltaic devices are one of the most promising applications of organic semiconductors. As organic
semiconductors can be manufactured by low temperature processes, such as printing from solution based inks,
these materials are compatible with flexible plastic substrates resulting in a lightweight, inexpensive and very
practical product. Over the last years impressive progress has been achieved in organic photovoltaic device
efficiency and promising roll-to-roll compatible deposition techniques have been also reported. This rapid
technological development brings applications close-by, and consequently also the importance of device reliability.
Cost evaluations suggest that a lifetime of 5-10 years is necessary with current power conversion efficiencies to
achieve low prices. Nevertheless, currently only 1 year of outdoor lifetime was reported on polymer solar cells,
other studies in accelerated conditions estimated the device lifetime to 2-3 years.
Currently, polymer solar cells are comprised of a multilayer stack of a transparent anode, a polymeric interlayer, a
photoactive bulk heterojunction composed of polymer and fullerene capped with an evaporated cathode. Reaction
with oxygen and humidity as well as light induces degradation both in the volume and at the interfaces of these
layers leading to multiple concurrent degradation mechanisms. Therefore discriminating between the parallel
mechanisms is one of the biggest challenges in reliability research.
The focus of this master thesis lies in the investigation of the degradation of the organic/electrode interfaces.
Implementation of new device architectures, advanced electrical measurements will assist the distinction between
the simultaneously occurring degradation mechanisms.
Most of the work will be done in the state-of-the-art organic device processing lab of imec. The student will
receive a broad training on full device processing (spin-coating, metal evaporation) and characterization tools. After
a short training period it is expected that the student can work independently and focusing on his/her investigation.
Type of project: Thesis and internship of minimum 6 months.
Degree:
Master in Industrial Sciences or Master in Engineering majoring in nanotechnology, physics, material sciences,
electrical engineering.
Responsible scientist(s):
For further information or for application, please contact Eszter Voroshazi (Eszter.Voroshazi@imec.be).

69
Master Thesis/Internship Topics 2012-2013

Solving the Caldeira-Leggett model with balance equations


Considering the electron-phonon interaction Hamiltonian bilinear in the electron and phonon coordinates, the
Caldeira-Leggett (CL) model provides an exactly solvable time-dependent model for studying transport of
electrons in a dissipative environment. On the other hand, a set of quantum mechanical energy and momentum
balance equations has been developed some time ago to study the non-equilibrium features of an electron gas in
the presence of various scattering mechanisms. In general, the resulting kinetic equations heavily rely on a clever
choice of the constraints fixing a truncated set of non-equilibrium averages (energy, momentum, current, ...) as
well as on the calculation of the corresponding Lagrange multipliers which determine the form of the
(approximate) density matrix. In this work the balance equations will be solved for the Caldeira-Leggett model and
the solutions will be compared with those obtained directly from the Heisenberg equations for the electron and
phonon coordinates. In particular, the validity of the balance equation approach and its inherent density matrix will
be critically assessed. Finally, the perspective of incorporating the difference between the CL model and the real
electron-phonon interaction as a perturbation into the frictional force will be studied.
Type of project: Thesis of 8 months.
Degree:
Master in Science majoring in physics.
Responsible scientist(s):
For further information or for application, please contact Wim Magnus (Wim.Magnus@imec.be) and Bart Soree
(Bart.Soree@imec.be).

70
Master Thesis/Internship Topics 2012-2013

Modeling ionic diffusion in solid-state materials for energy storage applications


The development of fundamental understanding in material science starts at the atomic level, where concerted
movements set the properties of a material and its reaction upon the application of external factors. With the
current development of nano-structured materials as e.g. metal-organic frameworks which can be used for energy
storage applications, gaining insights into the dynamics that drive the evolution of a system along representative
time window is becoming a problem of prime importance.
With that respect, Molecular Dynamics (MD) has long proved to be a very robust and useful technique that offers
unique insights into the dynamical behavior of a system. However, a large gap is often observed between the
events captured by the MD simulations and the experimental observations, mainly due to the fact that monitoring
the evolution of a non-equilibrium system towards its equilibrium state is computationally very demanding. We
therefore developed a new technique which, together with other modern algorithms, is implemented in an imec
software package. This software package will be the necessary tool to bridge the gap mentioned.
The content of the project is then to further explore, develop and test these techniques with a striving to engineer
novel materials for energy storage applications. The student will gain insight into modern first principle calculation
executed on up-to-date infrastructure. Further he will get familiar with hot-topics in energy storage as solid-state
batteries and experience how imec can make a difference in this field. In the beginning of the project a work
schedule is made (together with the student!) with clear milestones which lead the student towards making
significant contributions to the energy storage group insight imec.
Type of project: Thesis
Degree:
Master in Science majoring in physics, chemistry.
Responsible scientist(s):
For further information or for application, please contact Geoffrey Pourtois (Geoffrey.Pourtois@imec.be).

71
Master Thesis/Internship Topics 2012-2013

Bonding of cells to glass for next-generation c-Si PV modules


Photovoltaics have always been mainly (over 80%) based on c-Si solar cells, and this will continue to be the case for
the foreseeable future. The module technology used for connecting and protecting these cells likewise has been
established already quite some time ago and has proven its worth with operational lifetimes exceeding 20 years in
harsh outdoor conditions.
However, cost (and other) considerations are continuously pushing technology development towards higher
performance, longer lifetimes and cheaper materials and processing. But while this pressure has in the past mostly
been focused on cell development, also module technology is now being pushed towards such improvements.
With this in mind, imec is developing a module concept, coined i-module, that provides an alternative for the
currently standard technology for making modules. The standard technology is based on stringing of cells for
electrical interconnection and subsequent EVA lamination for encapsulation of these strings between a
(transparent) front- and backsheet, whereas the i-module targets first bonding of the cells using a silicone adhesive,
and only after attaching them to the glass, interconnect them. This way, the fragile cells are supported as much as
possible during module manufacturing.
As might be clear from the description, silicone bonding is a crucial part in this concept, and many aspects have to
be taken into account: the silicone coating method and its parameters, the curing scheme and the bonding setup
itself. In this topic, the idea is to optimize these processes, depending on the types of glass and wafers to be
bonded: these can vary in thickness, in surface topography (texture) and surface finish.
Type of project: Thesis or internship of 6-9 months.
Degree:
Master in Industrial Sciences or Master in Engineering majoring in material sciences (polymers), physics,
electronics, ...
Responsible scientist(s):
For further information or for application, please contact Jonathan Govaerts (Jonathan.Govaerts@imec.be).

72
Master Thesis/Internship Topics 2012-2013

Radio-frequency communication with metal-oxide electronics on plastic


In recent years, fast progress was made in the technology of thin-film semiconductor devices based on organic
semiconductors (such as pentacene and derivatives) and oxides, such as Indium-Gallium-Zinc-Oxide (GIZO). In
particular this latter semiconductor offers over amorphous silicon the advantages of a much higher carrier
mobility, of the order of 10 cm2/Vs, and room temperature processing, making it fully compatible with plastic
substrates. This new technology opens the way to circuits and systems fabricated directly on flexible plastic foil.
RFID transponders and tags are one type of application that will greatly benefit from this opportunity.
The crucial component of a passive RFID tag is the rectifier, which must operate at HF (13.56MHz) or more
preferable at UHF (869MHz). The diodes must follow the high-frequency input signal, still providing enough power
supply for the tag circuitry, which is accomplished only by optimized devices with low leakage current and charge
transient time. These devices can have mainly two topologies: the Schottky and transistor connected diodes.
Transistor-diodes are based on a shorted gate-drain transistor configuration. In this configuration, the gate-drain
electrode and the source act as the injector and the blocking electrode, respectively. The main advantage of such
topology is the integration with other circuitry, as exactly the same process technology as for standard transistors
can be used for its fabrication. Their main drawback, on the other hand, is the relatively long minimal channel
length that can be achieved with standard photolithographic processes.
The main task of the student is to investigate the effects of GIZO deposition on the transistor-diode
characteristics, in order to achieve high on/off drain currents and high electron mobility, targeting mainly the
transistor onset voltage control. This activity includes the fabrication of devices within imec clean room and our
laboratories using mainly two deposition techniques: RF sputtering and thermal evaporation. The second step will
be to integrate these single devices in a rectifier with integrated capacitances and characterize its frequency
response. Initially, the devices will be fabricated on a hard substrate such as silicon, but the final device should be
completely realized on a flexible plastic carrier. In order to develop insightful ideas about the diode performance,
all experimental work will be followed by analytical and SPICE model.
Type of project: Thesis or internship of 6 months.
Degree:
Master in Science or Master in Engineering majoring in material physics, electronics, nanotechnology.
Responsible scientist(s):
For further information or for application, please contact Adrian Chasin (Adrian.Chasin@imec.be).

73
Master Thesis/Internship Topics 2012-2013

Metal contacts for amorphous Si solar cell applications


Amorphous (a-)Si layers offer several advantages for the production of cost-effective, high efficiency Si solar cells.
Apart from some beneficial intrinsic material properties, a-Si can be deposited at low temperature which facilitates
cell processing and integration. At imec, the i-module concept is developed in which part of the back-contact cell
processing is performed when the Si substrates are already attached to the module glass. This brings some
restrictions for the thermal budget of the process steps and a-Si is therefore a well suited candidate for fabricating
the active layers.
One of the critical parts for integrating a-Si in successful (solar cell) devices is maintaining the a-Si layer quality
after metal deposition and establishing a low contact resistance. Due to the lower amount of active dopants it is a
challenge to form a low Ohmic contact. A proper combination of tuning the a-Si properties and choosing the right
metal and deposition conditions is required for optimizing the metal contact. While the main focus for this position
will be on the metallization part, this work will be in close collaboration w/ different members of the Thin c-Si
Solar Cell and Modules team working on a-Si layer optimization.
This includes sample preparation by using different processing techniques like photo-lithography, and PVD (Physical
Vapour Deposition), as well as electrical characterization of various test structures and material combinations.
Type of project: Internship of minimum 4 months.
Degree:
Master in Industrial Sciences or Master in Engineering majoring in material sciences, physics or electronics.
Responsible scientist(s):
For further information or for application, please contact Riet Labie (Riet.Labie@imec.be).

74
Master Thesis/Internship Topics 2012-2013

Morphological control of organic bulk solar cells


Organic photovoltaics (OPV) are an emerging technology in the PV field. The core of OPV cells are carbon based
materials, in contrast to the traditional, silicon based technologies. The material choice is endless, and
encompasses both polymers as well as small molecules. The more critical material characteristics are decent
semiconducting properties and an absorption spectrum that covers part of the solar spectrum.
In this research, the focus will be on small molecule OPV devices, made by thermal evaporation. In its most basic
form, you need both an electron (=acceptor) and a hole conducting (=donor) material to generate a photocurrent.
More efficient architectures use a mixture of donor and acceptor material in the same layer. For thermal
evaporation, this can be achieved by co-evaporating the two layers, creating a dense blend. Next to the
composition of this blend, its structure is equally important. he used materials have a crystalline nature,
determining their absorption spectrum, while an increased crystallinity of the active layer induces higher charge
carrier mobilities, which is beneficial for the conversion efficiency. By selecting the correct evaporation conditions,
a limited control on the morphology and crystallinity of the blend can be achieved. More control is possible by
using a templating layer underneath the blend, and by post-deposition treatments such as thermal or solvent
annealing.
Your task will be the investigation of these processing steps, and selecting the optimal ones to create a donoracceptor mixture that leads to efficient solar cells. You will be involved in the processing of the cells, as well as the
characterization afterwards. The focus will be on lab work, but post-processing the data, and correlating the
processing steps with the characteristic parameters (absorption, electrical, morphology) is very important.
Type of project: Thesis or internship of 4-5 months.
Degree:
Master in Science or Master in Engineering majoring in nanoelectronics, material sciences, physics.
Responsible scientist(s):
For further information or for application, please contact David Cheyns (David.Cheyns@imec.be) and Kjell Cnops
(Kjell.Cnops@imec.be).

75
Master Thesis/Internship Topics 2012-2013

Spectral characterization of organic tandem solar cells


Organic photovoltaics (OPV) use carbon based semiconductors for the photon-to-carrier conversion. These
materials have the advantage of easy processing, with low thermal stress on the used substrate. However, the
disadvantages are charge carrier mobilities that are a few orders of magnitude lower than in silicon, and narrow
absorption spectra. These facts limit the overall conversion efficiencies of OPV cells, with a world record of 10% at
the time of writing.
Tandem cells provide a solution to overcome the narrow absorption spectra. In this configuration, two stacked
subcells are electrically connected in series. Each subcell utilizes different materials with complementary absorption
spectra, and the combination of these materials guarantee a good overlap with the solar spectrum.
The topic of this internship will be the development of characterization techniques to probe the separate subcells
of these tandem stacks. The main focus is the deconvolution of the spectral responses of both subcells. This
involves opto-electrical measurements in combination with optical simulations. To this end, you will adapt an
existing characterization system and simulation software. Once operational, you will give feedback for a device
stack with optimized conversion efficiency.
Type of project: Thesis or internship of 4-5 months.
Degree:
Master in Science or Master in Engineering majoring in nanoelectronics, physics.
Responsible scientist(s):
For further information or for application, please contact David Cheyns (David.Cheyns@imec.be).

Tunneling barriers for the passivation of metal contacts in silicon solar cells
Photovoltaic is a fast growing field, dominated by crystalline silicon solar cells. Yet there remains a significant
difference between the theoretical efficiency one could reach and the efficiency actually reached with these cells,
and this both in production lines and in laboratories. Part of the efficiency loss comes from the interface between
silicon and the metallic contacts of the cell: at this interface, light-generated free carriers recombine without being
collected by the cell contacts. To reduce the recombination rate, a thin dielectric layer, a so called tunneling
barrier, can be included between silicon and the metallic contact. If well chosen, this dielectric leads to a reduction
of the recombination rate. At the same time, the dielectric layer should be thin enough to allow for tunneling of
the charge carriers through it. While it has already been shown that tunneling barriers can lead to a cell efficiency
increase, your objective is here to investigate dielectric layers that could be used for contact passivation.
This work is experimental. The student will join a team of scientists from all around the world to work in
laboratories and cleanroom for processing silicon structures, characterizing them and analyzing your results.
He/she should have a liking for lab-work and a good knowledge of written and spoken English.
Type of project: Thesis and/or internship of minimum 6 months.
Degree:
Master in Industrial Sciences or Master in Engineering or Master in Science majoring in physics, material sciences,
nanotechnologies, ...
Responsible scientist(s):
For further information or for application, please contact Xavier Loozen (Xavier.Loozen@imec.be).

76
Master Thesis/Internship Topics 2012-2013

Development of amorphous silicon deposition for silicon heterojunction solar cells


By deposition of amorphous silicon on monocrystalline silicon, cost-effective, world-record efficiency solar cells
can be fabricated. This is because amorphous silicon has some beneficial intrinsic material properties. Moreover, it
is deposited at low temperatures (<200C) which brings about unique possibilities, but also restrictions, for cell
processing and integration.
At imec, a new concept for cell integration (termed i-module) has been developed that requires particularly
good control over amorphous silicon deposition. For this purpose, a state-of-the-art deposition tool (PECVD,
Plasma-enhanced chemical vapor deposition) has been purchased and installed. Following initial start-up of the tool,
deposition processes need to be developed. Typical requirements for these deposition processes are: low
recombination velocities at the a-Si/c-Si interface, maximum dopant activation and low contact resistivity. Examples
of characterization methods are: spectroscopic ellipsometry, quasi-steady-state photoconductance, infrared
absorption.
The focus of this internship is the deposition and characterization of amorphous silicon layers. The student will
work and interact with a team of experts, and the results will be followed up closely. At the same time it is
expected that the student takes initiative and is able to work independently once the initial training period has
finished.
It is expected that the students write high-quality reports at the conclusion of the internships (this can be a thesis).
Type of project: Internship of minimum 6 months, possibly with thesis.
Degree:
Master in Science or Master in Engineering majoring in material sciences, physics, electronics, chemistry.
Responsible scientist(s):
For further information or for application, please contact Twan Bearda (Twan.Bearda@imec.be).

77
Master Thesis/Internship Topics 2012-2013

CIGSSe and CZTSSe films formation from selenization/sulfurization of metals and


chalcogenide compounds
Chalcogenide thin film based solar cells display a record conversion efficiency above 20 %. Basically, two ways for
the film deposition are followed. The first one, leading to the higher efficiencies, implies the co-evaporation
process, preformed under vacuum (~10-6mbar) and at high temperature (~600C). In the aim of reducing the
photovoltaic modules production cost, the deposition at low temperature of the metal precursors and, if possible,
according a non-vacuum process, then followed by a chalcogenization (Selenium, Sulfur) step, constitutes the
second exploratory way.
At IMEC, the research efforts are focused on this second approach and more particularly on the Cu(In,Ga)(S,Se)2
and Cu(Zn,Sn)(S,Se)2 based solar cells. The material precursor from the first family (ink-based) is deposited by nonvacuum wet-coating process, while the second one arises from sputtered metals. The proposed master thesis will
take an interest in the thermal selenization/sulfurization process, necessary for the final active layer formation. By
adjusting different parameters (H2S/H2Se gas flows, substrate temperature ...), the goal is to understand the
physico-chemical phenomenon understandings occurring during this chalcogenization process in the aim of
obtaining an efficient conversion from the initial precursor layer to the final active thin film layer in term of
photovoltaic properties. At different steps, the electrical and optical properties of the layers will be characterized,
mainly by scanning electron microscopy, X-ray diffraction, 4 points probe measurements, photoluminescence and
Hall effect. The influences on the current-voltage characteristic and the spectral response of the complete solar
cell will be followed as well. Dependent on the quality of the layers, also improvements in the solar cell processing,
like the formation of an alternative hetero-junction can be studied.
Type of project: Preferably thesis, but 3 months internship is also possible.
Degree:
Master in Science majoring in material sciences, semi-conductor physics and electronics.
Responsible scientist(s):
For further information or for application, please contact Guy Brammertz (Guy.Brammertz@imec.be).

78
Master Thesis/Internship Topics 2012-2013

Optimization of the optical properties of the layers in a multi-junction solar cell


Imec is developing innovative multijunction solar cell structures based both on crystalline silicon and alternative
materials. A multijunction solar cell allows absorbing a broader range of the solar spectrum while minimising
thermal losses.
However, in order to have optimal properties, the alternative material optoelectronic properties should be tuned
in order to have the best trade-off between optical absorption (acting on the output current of the cell) and
electronic bandgap (acting mainly on the open-circuit voltage). Beyond the material, the full architecture of the
solar cell and module should be adapted to the various materials.
The goal of the study is to simulate the optimized optical properties of the various layers of the solar cell (active
layers as well as transparent contacts and antireflective coatings) and of the module (glass and glue).
The student will perform optical simulation work based on an open-source software developed by Ghent
University, CAMFR, written with Python using a plane wave calculation method (RCWA). The simulations will
allow optimizing the thicknesses and optical properties of the various elements of the structures, in order to
improve the absorption in the active layers of the cells. The student will participate therefore to the discussions in
the Novel Material team of the PV department at IMEC. He/She will also participate to the experimental
characterization of the corresponding layers. He/She will follow the fabrication processes.
Depending on the time available and on the advancement of the work, the student may perform additional
simulation and experiments in order to further improve the properties of the structures with advanced reflective
layers such as Bragg reflectors, or with nanostructured layers so as to improve light-trapping and front-side light
coupling.
Type of project: Internship, possibly with thesis.
Degree:
Master in Science or Master in Engineering majoring in material sciences, physics, electronics, nanotechnology.
Responsible scientist(s):
For further information or for application, please contact Ounsi El Daif (Ounis.ElDaif@imec.be).

79
Master Thesis/Internship Topics 2012-2013

Hydrogen generation with III-Nitrides and catalysts


Hydrogen receives a lot of attention as an alternative renewable energy source. Photoelectrolysis is a direct
approach to generate hydrogen from water using solar energy. III-Nitride semiconductor is a promising candidate
as photo anode in photoelectrolysis for its adjustable bandgap and right band edge potential. However, the charge
transfer from the solid state to the water solution is one of the bottlenecks in the system. Catalysts at the surface
of GaN anode can be used to lower the barrier energy for hydrogen/oxygen generation. In this project, the
student will focus on the structural, electrical and electrochemical characterization of catalyst deposition.
Furthermore the influence of catalysts on photoelectrolysis and the chemical stability of GaN will be investigated.
This project is interdisciplinary: physics, electronics and electrochemistry. The catalysts will be prepared by
chemical deposition, electroplating, sputtering, or evaporation. The aim is to improve hydrogen generation by
photoelectrolysis, using III-Nitrides and catalysts.
Type of project: Thesis or internship of minimum 3 months.
Degree:
Master in Science or Master in Engineering majoring in material sciences, physics, electronics, chemistry.
Responsible scientist(s):
For further information or for application, please contact Peter Tseng (Peter.Tseng@imec.be) and Ruben Lieten
(Ruben.Lieten@imec.be).

Novel semiconductor alloys for optoelectronics of the future


Semiconductor alloys, such as InxGa1-xN, show interesting electrical and optical properties. These properties can be
altered by changing the alloy composition and structure. By choosing the right composition and achieving the
appropriate structural quality, semiconductor alloys can be used for many applications: high speed electronics, light
emitting diodes, photovoltaics, photodetectors, etc. In this project, the student will focus on the structural,
electrical and optical characterization of semiconductor alloys. The crystalline quality will be investigated by X-ray
diffraction. The optical band gap will be determined by absorption spectroscopy. Capacitance-voltage and Hall
effect measurements will be used for electrical characterization. The aim is investigate the fundamental properties
of novel semiconductor alloys for optoelectronic applications of the future.
Type of project: Thesis or internship of minimum 3 months.
Degree:
Master in Science or Master in Engineering majoring in material sciences, physics, electronics.
Responsible scientist(s):
For further information or for application, please contact Ruben Lieten (Ruben.Lieten@imec.be).

80
Master Thesis/Internship Topics 2012-2013

Electrical characterisation of amorphous Si layers for solar cell applications


Amorphous silicon layers offer several advantages for the production of cost-effective, high efficiency Si solar cells.
These advantages stem from the presence of an ultra-thin intrinsic amorphous silicon passivation layer between
the doped (amorphous silicon) emitter region and the crystalline silicon base material. The presence of this
heterojunction, where the interface defect density can be very low, and with favourable band alignment to repel
minority carriers, enables achieving very high open circuit voltage values, and resulting high efficiency cells. To
maximise the solar cell efficiency, minimising the resistive losses in the electrical contact to a doped amorphous
silicon layer is also critical. Previous works have shown the significance of the amorphous layer processing
conditions on the layers resistivity, and its link to the contact resistance.
The presence of a heterojunction requires careful passivation, and an analysis of this passivation layer/doped layer
stack is one of the aims of this proposed research. It is foreseen that capacitance-voltage and conductance
measurements of a-Si layers, with varying layer thickness, processing conditions, substrate doping etc, will form the
basis for this research. Analysis of the measured data can yield information on defect densities in the layers, the
energy of these defects in the silicon bandgap, and resistivity of the amorphous silicon layers. The impact of
processing on these parameters will be examined. It is envisaged that this work will focus on electrical
characterisation of amorphous silicon layers, and interpretation of the data generated from this analysis.
Type of project: Internship of 4-6 months.
Degree:
Master in Industrial Sciences or Master in Engineering majoring in physics, material sciences, electronics.
Responsible scientist(s):
For further information or for application, please contact Barry OSullivan (Barry.OSullivan@imec.be).

81
Master Thesis/Internship Topics 2012-2013

Characterization and power-loss analysis of interdigitated back contact (IBC)


silicon solar cells
Photovoltaic is a fast growing field, dominated by crystalline silicon solar cells. In several roadmaps it is predicted
that back contact solar cells, with all metal contacts located at the rear of the solar cell, will become a more
prominent cell structure in the next years. Interdigitated back contacts are introduced to increase the conversion
efficiency of crystalline silicon solar cells and allow for further reduction of the cell thickness, simplification of
module fabrication and improved aesthetics of the final solar cell modules.
At imec we have developed a high efficiency baseline process for small area IBC silicon solar cells, reaching
efficiency conversion values up to 23%. In the next year this baseline process will be further optimized and
upscaled to larger wafer and solar cell area. Characterization and analysis of the realized IBC solar cells is crucial,
such that the experimental work can be focused on those parts of the solar cell where the losses are dominating.
This is done by means of a power-loss analysis, giving an overview of the magnitude of all the loss elements within
the realized solar cells. As input of this power-loss analysis, a detailed characterization of the solar cells and test
wafers is performed.
In this thesis you will learn how to perform the characterization and analysis of realized solar cells, you will get to
understand the power-loss analysis and use it to indicate where to improve the subsequent solar cell runs, both in
terms of process optimization and solar cell design.
As this work is focused on characterization and analysis of solar cells, you require a basic knowledge of device
physics; preferably already you have knowledge on solar cell physics. You will join a team of scientists from all
around the world to characterize the solar cells and analyze your results. You should have a liking for device
characterization and device physics and a good knowledge of written and spoken English.
Type of project: Thesis and/or internship of minimum 6 months.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in physics, materials science,
nanotechnologies.
Responsible scientist(s):
For further information or for application, please contact Niels Posthuma (Niels.Posthuma@imec.be).

82
Master Thesis/Internship Topics 2012-2013

Reliability testing of c-Si solar cells with Cu plated metallization


Replacing the standard Ag screen printed front side metallization in c-Si solar cells by electroplated Cu may lead to
significant cost reductions as well cell performance improvements. Apart from the obvious lower raw metal cost,
the benefits for introducing Cu also involve the potential for increasing the efficiency by reducing the front surface
shading area, lowering the overall resistance and limiting the recombination losses. Despite these advantages, due
to the required 20-to-25 years of customer warranty, the module manufacturers are still rather reluctant for
introducing such new materials with an unknown track record of in-the-field performance. Therefore, further
investigation
of
the
reliability
is
still
needed
before
industrialization
can
occur.
In general, the qualification procedure for PV modules involves the application of standardized test protocols (IECstandards). For new technologies like Cu-metallised cells, other degradation mechanisms may become more
dominant and current qualification tests may no longer be relevant. For instance, Cu is known to be more sensitive
to thermal and humid environments compared to Ag and therefore adjustments of the currently used standard
test conditions may be needed.
The objective of this work is to perform various accelerated ageing tests in order to get a better understanding of
potential new failure mechanisms. This work will involve testing finished solar cells and monitor the different cell
parameters as function of the environmental conditions. Furthermore, the aim is to investigate and prepare other
(simplified) electrical test structures and measure the impact of the presence of Cu on these device characteristics.
Type of project: Thesis
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in physics, material sciences,
electronics.
Responsible scientist(s):
For further information or for application, please contact Riet Labie (Riet.Labie@imec.be).

Copper contact plating for advanced solar cell contacts


Solar cells are a vital part of the energy mix of the future. Imec develops advanced solar cells, aiming at pushing
their efficiencies towards the theoretical limits. A new concept that is currently explored is a cell that makes use of
an advanced junction of an amorphous nano-layer. In order to fully exploit the potential of such a cell, imec wants
to make use of copper as a conductor material to extract the current. Copper has the advantage of being much
cheaper than the more commonly used silver metal, without giving in too much on the conductivity side. That is
what this thesis is about: What is the best way to put copper lines on a very advanced and thin layer? Can we
improve it by alloying? Or by using different deposition parameters? Will it be reliable?... To answer these
questions you will work together with experienced researchers from the imec photovoltaics team, defining the
right questions, setting up a plan and making it happen.
Type of project: Thesis with internship of minimum 6 months.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material sciences,
electrochemistry, surface technology, thin films ( electronics, physics or chemistry).
Responsible scientist(s):
For further information or for application, please contact Joachim John (Joachim.John@imec.be), Jan Vaes
(Jan.Vaes@imec.be) and Jef Poortmans (Jef.Poortmans@imec.be).
83
Master Thesis/Internship Topics 2012-2013

EBIC analysis of thin-film polycrystalline-silicon solar cells


Thin-film (TF) polycrystalline-silicon (pc-Si) solar cell technology combines the low-cost potential of a thin-film
silicon technology with the high-efficiency and stability of the crystalline Si photo-voltaic technology. One of the
key challenges in pc-Si technology is to control the grain growth to minimize the effect of the grain boundary and
the intragrain defects.
The electron beam induced current (EBIC) measurement technique is well suited for defect analysis of pc-Si
structures as it allows the direct visualization of defects on sub-micrometer scale. In EBIC measurements, the
electron beam of a scanning electron microscopy (SEM) system is used to locally generate free carriers in the
absorber layer of the solar cell operating in short circuit conditions. By correlating the electron beam position with
the collected current, information about the local recombination can be obtained. Typically the amount of the
induced current is qualitatively (not quantitatively) visualized as brightness in the SEM image. The induced current
is typically three orders of magnitude higher than the incident SEM beam current allowing for relatively sensitive
measurements with high lateral resolution.
At imec the EBIC measurement mode is available as an add-on of the nanoprober (NP) tool. The nanoprober
combines a SEM tool, an electrical parameter analyzer and several nanomanipulators in one unit. The use of the
NP for EBIC allows local contacting of structures with high precision. This enables to study very small structures at
any place on the sample surface. All the components of the NP can be remotely controlled with a computer which
allows automatization of repeated measurements.
The focus of this internship will be the combination of direct electrical measurements with EBIC imaging to obtain
quantitative information of the observed defect properties. An important part of the work is to implement a
software control of the SEM beam position and parameter analyzer in order to make quantitative line and 2D
current measurement possible. Next the newly developed quantitative EBIC measurements will be combined with
the high precision needles of the NP tool. By measuring the collected current in function of the position of one of
the nanoprobes, information about the carrier diffusion length in the material and carrier transport across grain
boundaries can be obtained. The achieved capabilities will then be used to investigate different polycrystalline
silicon material under different measuring conditions (external junction bias voltages, SEM beam energies,..).
This internship topic involves both the advanced use of existing tools and techniques (EBIC and SEM) as well as the
further development of these techniques by computer control (LabVIEW) of the nanomanipulators, the parameter
analyzer and the SEM. Thus, proficiency in experimental work and computer skills are required from the candidate.
The student will be part of the materials and component analysis (MCA) department and will interact also closely
with members of imecs photovoltaic program.
Type of project: Internship of 6 months.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material sciences, physics,
electrical engineering, ...
Responsible scientist(s):
For further information or for application, please contact Kai Arstila (Kai.Arstila@imec.be) and Thomas Hantschel
(Thomas.Hantschel@imec.be).

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Master Thesis/Internship Topics 2012-2013

Raman and EDS analysis for thin-film solar-cell applications


Thin-film (TF) photo-voltaic (PV) cells are the focus of extensive research as alternative to common poly- and
mono-crystalline Si cells. Despite their lower conversion efficiencies, they are looking promising mainly as they can
be fabricated from less material (Si needs about 40 microns for being able to absorb >90% light). Thin-film PV cells
aim to use direct band-gap materials with a thickness of 1-2 m to absorb >90% light. Besides the established TF
cells based on amorphous Si (a-Si), cadmium telluride (CdTe), and copper indium gallium selenide (CIGS),
alternative material systems are being studied. One promising material route which is being explored at the
moment are metal-sulfur / metal-selenium combinations such as Cu-Zn-Sn S/Se (CZTS). They allow for bandgap
and band alignment engineering between 1-2 eV which is perfect for multi-junction cells by adjusting the S/Se ratio.
Moreover, they are made from abundant and safe materials (Cu, Zn, Sn, S, Se, ...).
Recently, a cell of Cu2ZnSnSe4 was demonstrated with 10% efficiency. The main obstacles to obtain highperformance cells based on CZTS are the control of stoichiometry and crystal phases. Therefore, dedicated
characterization knowhow is essential.
Energy dispersive X-ray spectroscopy (EDS) looks suited to probe the stoichiometry of the micrometer thin films
with sufficient spatial resolution. In EDS, the electron beam of a scanning electron microscopy (SEM) system is
generating element-specific X-rays when hitting the sample. This can be used to quantify the thin-film composition.
Raman is an optical technique and relies on inelastic scattering of photons which means that the energy of photons
in monochromatic light changes upon interaction in a sample. It was recently suggested and demonstrated that
Raman can be used for characterizing the crystal phases within a CZTS-based system. Both EDS and Raman are
non-destructive and allow also for two-dimensional (2D) mapping.
The goal of this internship is to use Raman for studying the crystals phases and EDS for studying the composition
of CZTS-based thin films for solar applications. Thin-films of known composition will be used for calibration. The
analysis results will be used as feedback for improving the synthesis of CZTS stacks. For Raman a comparison will
be made with X-ray diffraction (XRD) which is commonly used for studying crystal phases but which seems to
suffer from peak overlaps. The student will work in a state-of-the-art materials characterization lab and will be
trained in Raman, SEM and EDS. He/she will be part of the materials and component analysis (MCA) department
and interact also closely with members of imecs PV program.
Type of project: Internship of 6 months.
Degree:
Master in Industrial Sciences or Master in Science or Master in Engineering majoring in material sciences, physics,
electrical engineering, ...
Responsible scientist(s):
For further information or for application, please contact Kai Arstila (Kai.Arstila@imec.be) and Thomas Hantschel
(Thomas.Hantschel@imec.be).

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Master Thesis/Internship Topics 2012-2013

Organic solar-cell material characterization by TOF-SIMS


A significant fraction of the cost of solar panels comes from the photoactive materials and sophisticated, energy
intensive processing technologies. Recently, it has been shown that inorganic components can be replaced by
semiconducting polymers capable of achieving reasonably high power conversion efficiencies. These polymers are
inexpensive to synthesize and can be solution processed in roll-to-roll fashion with high-throughput. There is
however still a large number of challenges to be overcome to improve the technology that imply sophisticated
material analysis techniques.
TOF-SIMS has long been applied to organic material but has often been limited by its difficult interpretation and by
the loss of information during sputter profiling. Recent technological development (Cluster ion source, ) and
theoretical ones (combination of several spectra from the same surface with different analysis source, known as GSIMS) have open the possibilities for the characterization of polymer material.
The objective of this work is to investigate the possibilities of TOF-SIMS analysis through this new development for
materials related to organic solar cells such as P3HT, PCBM, PEDOT, PSS, CuPc, C60. This project will be mostly
devoted to the profiling of these materials in multi layers or in blend. It has been shown that the optimal sputter
condition in order to preserve organic information may differ from material to material, but little is understood of
the origin of these differences. This will thus not only be devoted to finding optimal conditions, but also to
understand (predict) which conditions should be used for an arbitrary material. The most recent innovation in
TOFSIMS profiling of organic materials is the introduction of large gas-clusters as sputter source. This thesis will be
performed on one of the first commercial source installed in the world on a TOFSIMS instrument.
At the end of this thesis, it is expected on one side that conclusion will be drawn on the usability of TOFSIMS as a
valuable analysis technique and on the other side to improve the understanding of physico-chemical effects
happening during sputtering in order to narrow down the profiling options of polymers.
Type of project: Thesis of 6 months.
Degree:
Master in Science or Master in Engineering majoring in physics, chemistry, material sciences.
Responsible scientist(s):
For further information or for application, please contact Thierry Conard (Thierry.Conard@imec.be).

86
Master Thesis/Internship Topics 2012-2013

Characterization of organic materials using UHV conductive AFM at low


temperatures
C-AFM (Conductive Atomic Force Microscopy) is an AFM based technique wherein a small conductive tip (moved
via a piezo-electric control) is used to measure simultaneously topography and current map of a material at the
nanometer scale. C-AFM represents an attractive approach to probe at controlled very low forces (nano/pico
newton range) organic material systems, enabling to correlate structural variations with the electrical properties.
The pioneering work of Park et.al [Nature 407:57 (2000)] has demonstrated that low temperature measurements
are important in understanding conducting mechanism of the molecule. Many molecular systems have shown to
behave as quantum dots, showing single electron charging behavior.
The objective of the project is to investigate the current conduction seen through vertically aligned self assembled
monolayers and conductive polymers at low temperature (liquid N2) in UHV environment and variation of
conductance with respect to variation in chain length of the molecule, using conductive AFM technique.
Self Assembled Monolayers dealt in this project have conducting properties with aromatic rings with chain length
varying from 0.2nm to 0.7nm.
Objectives to achieve and understand:
Charge injection and Charge transport through the molecules
Effect of Loading Force/Contact force on conductance
Effect of Tip work-function on conduction
Type of project: Thesis or internship of 6 months.
Degree:
Master in Industrial Sciences majoring in electrical/electronic engineering.
Responsible scientist(s):
For further information or for application, please contact Ravi Chintala (Ravi.Chandra.Chintala@imec.be) and
Pierre Eyben (Pierre.Eyben@imec.be).

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Master Thesis/Internship Topics 2012-2013

Characterization and modeling of Back-surface field formation in Si-based solar


cells
In order to obtain high performance solar-cells, it is important to minimize the minority carriers recombination at
the rear contact. In advanced solar cell concepts, like the i-PERC solar cell developed at imec, this is done by
creating a locally defined, highly doped layer of the same carrier type as the base substrate. This layer, named back
surface field (BSF), induces an electric field which shields minority carriers from recombining. As the doping level
and extent of this BSF impacts strongly on the solar cell efficiency it is important to optimize its formation process.
A common approach used to create this BSF is by forming a local backside contacts using local laser ablation to
open a hole in the passivation layer, coat the surface with an aluminum layer and to perform a heat treatment
which leads to Al-incorporation in the Si-lattice.
The fundamental mechanisms leading to this incorporation and BSF formation can be understood from the details
of the Al-Si phase diagram. Using cross-sectional scanning spreading resistance microscopy (SSRM), we have
already studied the two-dimensional dopant (Al) maps of the BSF and analyzed the thickness, shape and maximum
carrier concentration for various processing conditions (Al layer thickness, thermal budget, size,..) The SSRM
results demonstrate a highly p-doped layer (~ 2 e19at/cm3) in a quasi-conformal shape around the solidified Al in
the Si-etch pit creating the BSF-field.
The objective of the project is to explore the impact of the experimental processing conditions (Al-layer thickness
and temperature budget, size of the opening,..), on the detailed shape of the etched region, the Al-incorporation
and extent of the BSF. This work will be a combination of experimental observations with SSRM, (SEM,..) and finite
element (heat) modelling in order to develop a comprehensive module for the BSF formation.
Type of project: Thesis of 6 months.
Degree:
Master in Industrial Sciences or Master in Science majoring in electrical/electronic engineering.
Responsible scientist(s):
For further information or for application, please contact Pierre Eyben (Pierre.Eyben@imec.be) and Angel Uruena
De Castro, (Angel.UruenaDeCastro@imec.be).

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Master Thesis/Internship Topics 2012-2013

Initiation of random pyramid formation: impact of contamination and surface


roughness
One of the factors contributing to solar cell efficiency is its ability to as much as possible absorb the incident light.
Two techniques are combined to reduce the amount of light reflected on the solar cell: texturing the surface of
the solar cell and the deposition of an anti-reflective coating. The most efficient (industrial) texturing process
consists of a random distribution of pyramids. These pyramids are formed due to the anisotropic etching
properties of alkaline mixtures.
These pyramids need a nucleation/initiation site before the pyramid is recessed into the silicon. The nature of this
nucleation site is still uncertain. In order to get more insight into the nature of these nucleation site, the impact of
contamination (metal, particles or organic) on random pyramid formation will be investigated during the alkaline
etching. In addition the impact of the surface roughness will be investigated.
The experiments will consist of:
Adding and quantifying controlled changes to the Si surface prior to alkaline texturization
Controlled changes to the alkaline texturization mixture
Measuring the random pyramids (reflectivity, pyramid size (distribution), pyramid density)
Type of project: Thesis and/or internship.
Degree:
Master in Industrial Sciences or Master in Science majoring in material sciences, chemistry.
Responsible scientist(s):
For further information or for application, please contact Herbert Struyf (Herbert.Struyf@imec.be) and Paul
Mertens (Paul.Mertens@imec.be).

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Master Thesis/Internship Topics 2012-2013

VI.

INVOMEC
Visualisatie van DfX analyse feedback in een elektronisch ontwerp
Onder Design-for-X worden alle ontwerpaspecten van een elektronisch product verstaan die buiten het zuiver
elektrische ontwerp vallen. Hieronder vallen zaken zoals de maakbaarheid van het product (DfManufacturing), de
bedrijfszekerheid (DfReliability), de testbaarheid (DfTest), enz.
Het eindwerk kadert binnen de onderzoeksactiviteiten van het EDM programma van imec (www.edmp.be) dat zich
richt op het uitwerken van ontwerp- en kwalificatierichtlijnen voor Printed Board Assemblies (PBA) voor de
Vlaamse elektronica-industrie en elektronica-implementatoren. Binnen dit programma is er een PBA simulatie tool
ontwikkeld (Visual studio 2010 visual basic & excel ribbon integratie) die analyses doet op elektronische
ontwerpen. De resultaten van deze tool worden nu in Excel voorgesteld aan de gebruikers.
Het eindwerk richt zich op het grafisch visualiseren van de gerichte analyse feedback naar de gebruiker:
Studie van de gebruikte CAD formaten en selectie van een formaat. Dit formaat wordt nadien gebruikt om
data van een elektronisch ontwerp in te lezen en te visualiseren.
Importeren van de CAD Data: extraheren van gegevens en opslaan in de gebruikte datastructuur van de PBA
simulatie tool.
Grafische visualisatie van deze CAD data.
Visualisatie van diverse feedback gegevens:
Testanalyses: defect rates, meest falende componenten,
Betrouwbaarheidsgegevens
Thermische analyses
Mechanische vibratie analyses
Optioneel: 3D voorstelling van de CAD gegevens.
Ontwerp van een applicatie en/of custom control in MS Visual Basic 2010.
Type of project: Thesis
Degree:
Master in Industrial Sciences majoring in electronics-ICT.
Responsible scientist(s):
For further information or for application, please contact Wesley Van Meensel (Wesley.VanMeensel@imec.be).

90
Master Thesis/Internship Topics 2012-2013

Pre-routing metal layer estimation


This project will implement theoretical wiring models from the literature as practical algorithms for the estimation
of the number of metal layers required to place and route specific IC designs.
Correctly estimating the correct number of metal layers required to route the wiring associated with a design is
critical for the lowest cost manufacturing of the product. An underestimate will require extra white-space to be
inserted to provide the additional routing resources, thus increasing the die area and cost. An overestimate will
require the creation of unnecessary masks and also increase costs. The goal of this project is:
1. To survey the various theoretical models that exist in the literature to predict the distribution of post-layout
wire lengths using characteristic statistical parameters extracted from the pre-layout netlist.
2. To develop pre-layout netlist characterization and parameter extraction tools.
3. To develop a practical method for metal layer estimation from pre-layout netlist data and to compare the
results with actual place/route experiments on actual designs.
Type of project: Internship or thesis with internship
Degree:
Master in Engineering majoring in electronics.
Responsible scientist(s):
For further information or for application, please contact Phillip Christie (Phillip.Christie@imec.be).

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Master Thesis/Internship Topics 2012-2013

VII.

NERF
Studying the function of neural circuits
Investigating the computations performed by the brain requires simultaneous recordings from many individual
neurons. Moreover, it is essential to dissect and perturb genetically defined functional components of neural
circuits to test the effects of these perturbations. Neuroscience is currently constrained by a limited ability to
make specific perturbations in neural circuits. Yet, neural circuits are perturbed in various ways during
development. As the brain develops, not only the numbers of neurons increase drastically but also the composition
of the neural circuits change. Constant spatial and functional reorganization of the developing brain also affects the
connectivity between the components of neural circuits. Yet, the brains of both developing and adult animals
function properly and generate behaviours essential for life.
Zebrafish is a rising model organism for studying the function and development of neural circuits. First, zebrafish
brain development and organizational principles are highly similar to the mammalian brain. Zebrafish larvae are
optically transparent and posses a small and easily accessible brain for electrophysiology, imaging and optogenetic
manipulations. The molecular toolbox associated with zebrafish is well developed, easily accessible and expanding
rapidly.
The main aim of the proposed research is to understand the fundamental principles underlying the function and
development of neural circuits. Towards this overarching goal the successful student candidate will investigate how
sensory information is processed along the brain pathways; how this information is stored and recalled in the
process of learning and memory; how neural circuits are established in development and which cells give rise to
the necessary components of this system; how the neural circuits change throughout development of the embryo
and how this relates to the behaviour of the organism.
To accomplish these goals, the successful candidate will be trained in functional imaging, electrophysiology,
computer based analytical methods and genetics. Using these techniques we will study the activity of thousands of
neurons in response to odor stimulation and perturb the genetically defined components of these neural circuits
to understand their function in olfactory information processing. Moreover we will develop and use anatomical and
physiological methods to trace the functional connectivity of olfactory circuits in both adult and larval zebrafish
brain. Ultimately, the experiments that are designed by using these new tools will help us to understand the
fundamental principles of sensory information processing in the brains of vertebrates, including humans.
Type of project: Thesis and/or internship.
Degree:
Master in Engineering majoring in physics, bio-engineering, mathematics.
Responsible scientist(s):
For further information or for application, please contact Emre Yaksi (Emre.Yaksi@nerf.be).

92
Master Thesis/Internship Topics 2012-2013

Design, prototyping and testing of miniaturized brain implants


The Kloosterman laboratory at the Neuro-Electronics Research Flanders (NERF) studies how neural circuits and
systems in the brain process and store information. For this, we monitor the activity of tens to hundreds of
neurons simultaneously as rodents (rats or mice) behave freely. Previously, we have used custom designed brain
implants that carry an array of wire electrodes. In collaboration with the Bioelectronic Systems group at imec, new
silicon-based neural probes have been developed that will allow us to record from a larger number of neurons in a
wide network of brain regions. These probes will be used in combination with techniques to perturb activity of
certain types of cells (for example by optical stimulation) in order to study their role in memory processing. The
aim of this project is to design and build prototypes of novel brain implants for rats and mice that combine multiple
silicon neural probes for recording of neural activity and optical fibers for stimulation. The project will be
conducted as a joint effort of two research groups at NERF and imec and involves 3D computer-aided design
(CAD), rapid prototyping and printed circuit board (PCB) design. Developed implants will be characterized
mechanically and eventually tested in in vivo experiments. We are looking for a candidate with strong background
and skills in biomedical, mechanical or electrical engineering and with interest in neuroscience.
Type of project: Thesis or internship of 6-12 months.
Degree:
Master in Science or Master in Engineering majoring in mechanic engineering, electric engineering, biomedical
engineering. Bachelor students can also apply.
Responsible scientist(s):
For further information or for application, please contact Dimiter Prodanov (Dimiter.Prodanov@imec.be) and
Fabian Kloosterman (Fabian.Kloosterman@nerf.be).

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Master Thesis/Internship Topics 2012-2013

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Master Thesis/Internship Topics 2012-2013

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