NAMA

:___________________________

TINGKATAN :_________________

SMK MUNSHI ABDULLAH, SG. AIR TAWAR

SABAK BERNAM SELANGOR

PEPERIKSAAN PERTENGAHAN TAHUN 2012

4541/2

CHEMISTRY FORM 5
Kertas 2
Mei
2 1/2 jam

Dua jam tiga puluh minit

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU
Untuk Kegunaan Pemeriksa
Markah
Markah
Bahagian
Soalan
Penuh
Diperoleh
1
10
2
11
3
10
A
4
9
5
10
6
10
7
20
B
8
20
9
20
C
10
20
Jumlah

1Tuliskan nama dan tingkatan pada ruang yang

disediakan.
2. Kertas soalan ini adalah dwibahasa.
3. Calon dibenarkan menjawab keseluruhan atau
sebahagian soalan sama ada dalam bahasa Inggeris
atau bahasa Melayu.
INFORMATION FOR CANDIDATES
MAKLUMAT UNTUK CALON
1 This question paper consists of three sections.
Section A, Section B and Section C.
Kertas soalan ini mengandungi tiga bahagian
Bahagian A, Bahagian B dan Bahagian C.
2. You are advise to spend 90 minutes to answer
questions in Section A, 30 minutes for Section B and
30 minutes for Section C.
Anda dinasihat supaya mengambil masa 90 minit
untuk menjawab soalan Bahagian A, 30 minit untuk
Bahagian B dan 30 minit untuk Bahagian C.

1. (a) What is the meaning of empirical formula?

Apakah maksud formula empirik?
________________________________________________________________________
[ 1 mark ]
PPT 2012 CHEMISTRY (PAPER 2)

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(b) Diagram 1.1 shows an incomplete equation which is one of the steps involved in
determining the empirical formula.
Complete this equation.
Rajah 1.1 menunjukkan persamaan tak lengkap yang merupakan satu daripada
langkah dalam menentukan formula empirik.
Lengkapkan persamaan itu.
Mass /Jisim
___________________________________ = _______________________________
Relative atomic mass/Jisim atom relatif

Diagram 1.1/ Rajah 1.1

[ 1 mark ]
(c) Diagram 1.2 shows the apparatus set-up for two methods used to determine the
empirical formula of two compounds.
Rajah 1.2 menunjukkan susunan radas bagi dua kaedah yang digunakan untuk
menentukan formula empiric bagi dua sebatian.
(i)

(ii)

(iii)

Which is suitable to be used to determine the empirical formula of magnesium

oxide?
Kaedah yang manakah sesuai digunakan untuk menentukan formula empiric
bagi magnesium oksida?
_______________________________________________________________
[ 1 mark ]
Why did you choose the method in 3(c)(i)?
Mengapakah anda memilih kaedah di 3(c)(i)?
_______________________________________________________________
[ 1 mark ]
When carrying out an experiment using Method I, why does crucible lid need
to be opened once a while?
Semasa menjalankan eksperimen menggunakan Kaedah I, mengapakah
penutup mangkuk pijar dibuka sekali sekala?

_______________________________________________________________
[ 1 mark ]
(d) Diagram 1.3 shows the result for an experiment to determine the empirical formula of
lead oxide.
Rajah 1.3 menunjukkan keputusan bagi satu eksperimen untuk menentukan formula
empirik bagi
plumbum
oksida. tube
Mass
of combustion
= 64.00 g
Jisim tiub pembakaran
Mass of combustion tube + lead oxide
Jisim 2)
tiub pembakaran + 2plumbum oksida
PPT 2012 CHEMISTRY (PAPER
Mass of combustion tube + lead
Jisim tiub pembakaran + plumbum

= 117.52 g
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= 113.68 g

Diagram 1.3/Rajah 1.3

Based on Diagram 1.3, determine the values of the following:
Berdasarkan Rajah 1.3, tentukan nilai yang berikut:
[Relative atomic mass: O = 16, Pb = 207]
(i)

Mass of lead / Jisim plumbum

=_________________________g

(ii)

Number of moles of lead/Bilangan mol plumbum

=_________________________mol

(iii)

[ 1 mark ]

Number of moles of oxygen/ Bilangan mol oksigen

=________________________mol

(v)

[ 1 mark ]

Mass of oxygen/ Jisim oksigen

=_________________________g

(iv)

[ 1 mark ]

[ 1 mark ]

Empirical formula of lead oxide/ Formula empiric bagi plumbum oksida

=________________________

[ 1 mark ]

2. Diagram 2 shows a part of the Periodic Table of Elements. The symbols P, Q, R, S and T
do not represent the actual symbols of the elements.
Rajah 2 menunjukkan sebahagian daripada Jadual Berkala Unsur. Simbol P, Q, R, S dan
T yang ditunjukkan tidak mewakili simbol sebenar unsur-unsur tersebut.

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Diagram 2/ Rajah 2
(a) (i) State the electron arrangement of element R?
Nyatakan susunan elektron bagi unsur R?
_________________________________________________________________
[ 1 mark ]
(ii) Explain why element R and element S are in the same period.
Terangkan mengapa unsure R dan unsur S berada dalam kala yang sama.
__________________________________________________________________
[ 1 mark ]
(b) (i) Which element is chemically unreactive?
Unsur manakah yang tidak reaktif secara kimia?
__________________________________________________________________
[ 1 mark ]
(ii) Explain your answer in (b) (i).
Terangkan jawapan anda di (b) (i).
__________________________________________________________________
[ 1 mark ]
(c) (i) Compare the atomic size of R and S.
Bandingkan saiz atom bagi R dan S.
__________________________________________________________________
[ 1 mark ]
(ii) Explain your answer in (c) (i).
Terangkan jawapan anda di (c) (i).
__________________________________________________________________
__________________________________________________________________
[ 2 marks ]
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(d) Element R react with element Q to form a compound.

Write a chemical equation for the reaction.
Unsur R bertindak balas dengan unsur Q untuk membentuk satu sebatian.
Tuliskan persamaan kimia bagi tindak balas tersebut.
_____________________________________________________________________
[ 2 marks ]
(e) Element P reacts with Q to form a compound. Draw the electron arrangement of the
compound formed between element P and element Q.
Unsur P bertindak balas dengan Q membentuk satu sebatian. Lukiskan susunan
electron bagi sebatian yang terbentuk antara unasur P dan unsur Q.

[ 2 marks ]
3. Diagram 3 shows two cells R and S.
Rajah 3 menunjukkan binaan sel R dan S.

Diagram 3/ Rajah 3
(a) Based on cell R in the diagram 3, answer the following questions.
Berdasarkan sel R dalam Rajah 3 , jawab soalan-soalan berikut.
(i)

(ii)

State the energy change in cell R.

Nyatakan perubahan tenaga yang berlaku bagi sel R.
_______________________________________________________________
[ 1 mark ]
Write the formulae of all the ions present in copper(II) sulphate solution.

PPT 2012 CHEMISTRY (PAPER 2)

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Tulis semua formula ion yang hadir dalam larutan kuprum(II) sulfat.

(iii)

(iv)

_______________________________________________________________
[ 1 mark ]
Write the half equation for the reaction that occurs at the anode of cell R.
Tuliskan setengah persamaan bagi tindak balas yang berlaku di anod sel R.
_______________________________________________________________
[ 1 mark ]
State one observation that occurs at the anode of cell R.
Nyatakan satu pemerhatian bagi tindak balas yang berlaku di anod sel R.

_______________________________________________________________
[ 1 mark ]
(b) Based on cell S in diagram 3, answer the following questions.
Berdasarkan sel S dalam Rajah 3, jawab soalan-soalan berikut.
(i)

(ii)

(iii)

Show the direction of electrons flow in the circuit of cell S in diagram 3.

Tunjukkan arah pengaliran electron dalam litar sel S dalam Rajah 3.
_______________________________________________________________
[ 1 mark ]
Write overall ionic equation for the reaction.
Tuliskan persamaan ion keseluruhan bagi tindak balas ini.
_______________________________________________________________
[ 1 mark ]
What is the changes that will happen to the reading of the voltmeter if the zinc
plate is placed with magnesium plate?
Explain your answer.
Apakah perubahan yang berlaku pada bacaan voltmeter sekiranya kepingan
zink digantikan dengan kepingan magnesium?
Jelaskan jawapan anda.
_______________________________________________________________

(iv)

______________________________________________________________
[ 2 marks ]
State two differences between cell R and cell S.
Nyatakan dua perbezaan antara sel R dan sel S.
Cell R/ Sel R

PPT 2012 CHEMISTRY (PAPER 2)

Cell S/ Sel S

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[ 2 marks ]
4. Diagram 4 shows the arrangement of atoms in two types of copper alloy.
Rajah 4 menunjukkan susunan atom dalam dua jenis aloi bagi kuprum.

Diagram 4/ Rajah 4
(a) State the meaning of alloy.
Nyatakan maksud aloi.
_____________________________________________________________________
[ 1 mark ]
(b) State the name of alloy X.
Nyatakan nama bagi aloi X.
_____________________________________________________________________
[ 1 mark ]

(c) State the name of atom M.

Nyatakan nama bagi atom M.
_____________________________________________________________________
[ 1 mark ]
(d) (i) What is the difference in terms of hardness between bronze and pure copper?
Apakah perbezaan daripada segi kekerasan antara gangsa dengan kuprum tulen?

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__________________________________________________________________
[ 1 mark ]
(ii) Complete Table 1 to show the differences in terms of size and arrangement of atoms
in bronze and pure copper.
Lengkapkan Jadual 1 untuk menunjukkan perbezaan daripada segi saiz dan susunan
atom dalam gangsa dengan kuprum tulen.
Difference/ Perbezaan
Bronze / Gangsa
Pure copper/ Kuprum tulen
Size of atoms/ Saiz atom

Arrangement of atoms/
susunan atom

[ 2 marks ]
(iii) Describe what happens to the atoms when a force is applied to a bronze and pure
copper.
Huraikan apa yang akan berlaku kepada atom-atom apabila satu daya dikenakan kepada
gangsa dan kuprum tulen.
Bronze/ gangsa:
_________________________________________________________________________
_________________________________________________________________________
Pure copper/ kuprum tulen:
_________________________________________________________________________
_________________________________________________________________________
[ 2 marks ]

(e) Pewter is also an example of an alloy.

State one use of pewter.
Pewter juga adalah satu contoh bagi aloi.
Nyatakan satu kegunaan pewter.
_____________________________________________________________________
_____________________________________________________________________
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[ 1 mark ]
5. Diagram 5.1 shows the set-up of apparatus of an experiment to investigate the effect of
size of reactant on the rate of reaction.
Rajah 5.1 menunjukkan susunan radas bagi eksperimen yang mengkaji kesan saiz bahan
terhadap kadar tindak balas.

Diagram 5.1/ Rajah 5.1

(a) Write a chemical equation for the reaction in Diagram 5.1.
Tulis persamaan kimia bagi tindak balas yang ditunjukkan dalam Rajah 5.1.
_____________________________________________________________________
[ 2 mark ]

A graph of the volume of hydrogen gas produce against time is drawn as show in
Diagram 5.2.
Graf isipadu gas hidrogen yang terhasil melawan masa ditunjukkan seperti di dalam
Rajah 5.2.

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Diagram 5.2/ Rajah 5.2

(b) Based on the graph, calculate:

Berdasarkan graf, hitung:
(i)

The average rate of reaction for the first minute.

Purata kadar tindak balas bagi minit yang pertama.

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[ 1 mark ]
(ii)

The rate of reaction at 90 seconds.

Kadar tindak balas pada masa 90 saat.

[ 2 marks ]
(c) Experiment II is carried out by replacing sulphuric acid with hydrochloric acid of the
same volume and concentration.
Eksperimen II dijalankan dengan menggantikan asid sulfuric dengan asid hidroklorik
pada kepekatan yang sama.
(i)

Sketch the graph for reaction between magnesium ribbon and hydrochloric
acid in Diagram 5.2.
Lakarkan graf bagi tindak balas antara pita magnesium dengan asid
hidroklorik pada Rajah 5.2.
[ 2 marks ]

(ii)

Based on the collision theory, explain how the concentration of hydrochloric

acid in experiment II affects the rate of reaction.
Berdasarkan teori pelanggaran, terangkan bagaimana kepekatan asid
hidroklorik mempengaruhi kadar tindak balas dalam eksperimen II.
_______________________________________________________________
_______________________________________________________________
_______________________________________________________________

_______________________________________________________________
[ 3 marks ]
6. The following information is about the compound C2H5OH.
Maklumat berikut adalah mengenai sebatian C2H5OH.

Miscible in all proportions with water

Larut campur dalam air pada sebarang perkadaran

Undergoes combustion
Mengalami pembakaran

A member of a homologous series

11
Ahli suatu siri homolog

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(a) What is the name of this compound/

Apakah nama bagi sebatian ini?
_____________________________________________________________________
[ 1 mark ]
(b) What is the general formula for the homologous series of this compound?
Apakah formula am bagi siri homolog sebatian ini?
_____________________________________________________________________
[ 1 mark ]
(c) One mole of this compound undergoes complete combustion to form gas X and water
as shown below.
Satu mol sebatian ini mengalami pembakaran lengkap untuk menghasilkan gas X dan
air seperti ditunjukkan di bawah.
C2H5OH + mO2 nX + 3H2O
(i)

(ii)

State the name of gas X.

Nyatakan nama gas X.
_______________________________________________________________
[ 1 mark ]
What are the values of m and n ?
Apakah nilai bagi m dan n?
m =___________________________________________________________
n
=____________________________________________________________
[ 2 marks ]

(d) Compound C2H5OH reacts with ethanoic acid to produce compound Y which has
sweet pleasant smell.
Sebatian C2H5OH bertindak balas dengan asid etanoik untuk menghasilkan sebatian Y
yang berbau wangi.
(i)

State the name of compound Y.

Nyatakan nama sebatian Y.
_______________________________________________________________

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[ 1 mark ]
(ii)

Draw the structural formula of compound Y.

Lukis formula struktur bagi sebatian Y.

[ 1 mark ]
(e) Compound C2H5OH undergoes dehydration to produce ethane.
Sebatian C2H5OH mengalami pendehidratan untuk menghasilkan etena.
(i)

Suggest one dehydrating agent for this reaction.

Cadangkan satu agen pendehidratan bagi tindak balas ini.
_______________________________________________________________
[ 1 mark ]

(ii)

Draw an apparatus set-up this dehydration reaction to collect ehtene.

Lukis susunan radas untuk tindak balas pendehidratan ini untuk mengumpul
etena.

[ 2 marks ]
Section B
Bahagian B
[ 20 marks ]
Answer any one question
Jawab mana-mana satu soalan.
7. Diagram 7.1 and Diagram 7.2 show the diagrams of electron arrangement for atoms of
two elements from Group 17 in the Periodic Table of Elements.
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Rajah 7.1 dan Rajah 7.2 menunjukkan rajah susunan electron bagi atom dua unsur dari
Kumpulan 17 dalam Jadual Berkala Unsur.

Diagram 7.1/ Rajah 7.1

Diagram 7.2/ Rajah 7.2

(a) Based on Diagram 7.1:

Berdasarkan Rajah 7.1:
(i)

Write the electron arrangement for the atom of the element and name the
element.
Tulis susunan elektron bagi atom unsur itu dan namakan unsur itu.
[ 2 marks ]
(ii)
Write a chemical equation for the reaction between this element and sodium
hydroxide.
Tulis persamaan kimia bagi tindak balas antara unsur itu dengan natrium
hidroksida.
[ 3 marks ]
(b) Compare the attractive forces between the nuclei and the valence electrons in the
atoms in Diagram 7.1 and Diagram 7.2 and relate this to their respective reactivity.
Bandingkan daya tarikan antara nucleus dengan elektron valens dalam atom pada
Rajah 7.1 dan Rajah 7.2 dan kaitkan dengan kereaktifan masing-masing.
[ 6 marks ]
(c) Another element in Group 17 is a black coloured solid.
Predict the reactivity of this element in its reaction with sodium hydroxide compared
to that of the element in Diagram 7.2.
Satu unsur lain dalam Kumpulan 17 adalah pepejal yang berwarna hitam.
Ramalkan kereaktifan unsur itu dalam tindak balasnya dengan natrium hidroksida
berbanding dengan unsur dalam Rajah 7.2.
[ 1 mark ]
(d) Diagram 7.3 shows the set up of the apparatus to investigate the reaction of an
element from Group 17 with iron metal.
Rajah 7.3 menunjukkan susunan radas bagi satu eksperimen untuk mengkaji tindak
balas satu unsur dari Kumpulan 17 dengan logam ferum.

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Diagram 7.3/ Rajah 7.3

(i)

(ii)

State two precautions that must be taken while carrying out the experiment.
Nyatakan dua langkah keselamatan yang perlu diambil semasa menjalankan
eksperimen itu.
[ 2 marks ]
Describe and write the chemical equations for the reactions that occur in Part
G and Part H.
Huraikan dan tulis persamaan kimia bagi tindak balas yang berlaku di
Bahagian G dan Bahagian H.
[ 6 marks ]

8. (a) Food stored in a refrigerator lasts longer than food stored in a kitchen cabinet.
Explain why.
Makanan yang disimpan dalam peti sejuk tahan lebih lama daripada makanan yang
disimpan dalam almari dapur.
Terangkan mengapa.
[ 4 marks ]
(b) A group of pupils carried out three experiments to investigate the factors affecting the
rate of a reaction.
Table 8 shows information about the reactants and the temperature used in each
experiment.
Sekumpulan murid telah menjalankan tiga eksperimen untuk mengkaji kesan faktorfaktor yang mempengaruhi kadar tindak balas.
Jadual 8 menunjukkan maklumat tnetang bahan tindak balas dan suhu yang
digunakan dalam setiap eksperimen.

Experiment
Eksperimen
I
II

Reactants
Bahan tindak balas
Excess calcium carbonate chips and 30 cm3 of 0.5
mol dm-3 hydrochloric acid.
Ketulan kalsium carbonate berlebihan dan 30 cm3
asid hidroklorik 0.5 mol dm-3.
Excess calcium carbonate chips and 30 cm3 of 0.5
mol dm-3 hydrochloric acid.
Ketulan kalsium carbonate berlebihan dan 30 cm3

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Temperature/ oC
Suhu/ oC
30
40

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III

asid hidroklorik 0.5 mol dm-3.

Excess calcium carbonate powder and 30 cm3 of 0.5
mol dm-3 hydrochloric acid.
Serbuk kalsium carbonate berlebihan dan 30 cm3
asid hidroklorik 0.5 mol dm-3.
Table 8/ Jadual 8

40

Graph 8 shows the result of these experiments.

Graf 8 menunjukkan keputusan eksperimen-eksperimen ini.

Graph 8
(i)

Calculate the average rate of reaction for Experiment I.

Hitungkan kadar tindak balas purata bagi eksperimen I.
[ 2 marks ]

(ii)

Based on Table 8 and Graph 8, compare the rate of reaction between:

Berdasarkan Jadual 8 dan Graf 8, bandingkan kadar tindak balas antara:

Experiment I dan Experiment II

Eksperimen I dan Eksperimen II

Experiement II and Experiment III

Eksperimen II dan Experiment III

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In each case explain the different in rate of reaction with reference to the collision theory.
Bagi setiap kes terangkan perbezaan dalam kadar tindak balas dengan merujuk kepada
teori perlanggaran.
[ 10 marks ]
(iii)

The chemical equation below shows the reaction between calcium carbonate and
hydrochloric acid.
Persamaan kimia di bawah menunjukkan tindak balas antara kalsium karbonat
dengan asid hidroklorik.
CaCO3 + 2HCl CaCl2 + CO2 + H2O
Given that the relative atomic mass of C = 12, O = 16, Ca = 40 and molar volume of
any gas is 24 dm3 mol-1 at room temperature and pressure.
Diberi, jisim atom relatif bagi C = 12, O = 16, Ca = 40 dan isipadu molar sebarang
gas adalah 24 dm3 mol-1 pada suhu dan tekanan bilik.
Calculate the maximum volume of carbon dioxide gas produced in Experiment II.
Hitungkan isipadu maksimum gas karbon dioksida yang terhasil dalam Eksperimen
II.
[ 4 marks ]

Section C
Bahagian C
[ 20 marks ]
Answer any one question
Jawab mana-mana satu soalan

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9. Diagram 9 shows the arrangement of particles of a compound in two different states, X

and Y.
Rajah 9 menunjukkan susunan zarah-zarah satu sebatian dalam dua keadaan yang
berbeza, X dan Y.

Diagram 9/ Rajah 9
(a) The compound can conduct electricity in state X but cannot do so in state Y.
Name one example of a compound with this property.
Sebatian ini boleh mengalirkan arus elektrik dalam keadaan X dan tidak boleh
mengalirkan arus elektrik dalam keadaan Y.
Namakan satu contoh sebatian yang mempunyai sifat ini.
[ 1 mark ]
(b) Write one of the half equations for the electrolyse the compound you named in 9(a).
Tulis satu daripada dua setengah persamaan bagi eletrolisis sebatian yang
dinamakan di 9(a).
[ 3 marks ]
(c) Draw a labeled diagram of the apparatus that you can use to electrolyse the compound
you named in 9(a).
In your drawing, show by using arrows the movement of particles that accurs in the
compound.
Lukiskan satu rajah susunan radas berlabel yang anda dapat gunakan untuk
mengelektrolisis sebatian yang dinamakan di 9(a).
Dalam lukisan anda, tunjukkan anak panah pergerakan zara-zarah yang berlaku di
dalam sebatian itu.
[ 10 marks ]
(d) Describe the electrolysis process that occurs in 9(c).
Huraikan proses elektrolisis yang berlaku di 9(c).
[ 6 marks ]
10. (a) Diagram 10 shows how compound G is formed from an alkene.
Rajah 10 menunjukkan bagaimana sebatian G terbentuk daripada suatu alkena.

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Diagram 10/ Rajah 10

(i)

Name one alkene that has less than four carbon atoms.
Draw its structure formula.
Namakan satu alkena yang mempunyai kurang daripada empat atom karbon.
Lukiskan formula strukturnya.
[ 2 marks ]
(ii)
Based on the answer in 10(a)(i), what is the name of compound F and compound
G?
Berdasarkan jawapan di 10(a)(i), apakah nama sebatian F dan sebatian G?
[ 2 marks ]
(iii)
State three chemical properties of compound F and three chemical properties of
compound G.
Nyatakan tiga sifat kimia bagi sebatian F dan tiga sifat kimia bagi sebatian G.
[ 6 marks ]
(b) Alkenes, alcohols and carboxylic acids, are three different homologous series.
Construct a table to show the general formula, the functional group and the name of a
member in each of the series.
Alkena, alkohol dan asid karboksilik adalah tiga siri homolog yang berbeza.
Bina satu jadual untuk menunjukkan formula am, kumpulan berfungsi dan nama bagi
satu ahli dalam setiap siri homolog itu.
[ 10 marks ]
END OF QUESTION PAPER
KERTAS SOALAN TAMAT

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